CN104629964A - Capsule type liquid detergent - Google Patents

Capsule type liquid detergent Download PDF

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Publication number
CN104629964A
CN104629964A CN201510094973.0A CN201510094973A CN104629964A CN 104629964 A CN104629964 A CN 104629964A CN 201510094973 A CN201510094973 A CN 201510094973A CN 104629964 A CN104629964 A CN 104629964A
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China
Prior art keywords
capsule
liquid
capsule type
liquid detergent
type washing
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Granted
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CN201510094973.0A
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Chinese (zh)
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CN104629964B (en
Inventor
刘世超
刘伟毅
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Shanghai Soap Factory Co ltd
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SHANGHAI SOAPMAKING CO Ltd
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Abstract

The invention discloses capsule type liquid detergent; the capsule type liquid detergent is composed of liquid detergent and a capsule; the liquid detergent is wrapped by the capsule; and the capsule type liquid detergent is characterized in that the liquid detergent comprises the following raw materials in percentage by weight: 15-25% offatty alcohol polyoxyethylene ether sodium sulphate, 30-40% of fatty alcohol polyoxyethylene ether or iso-tridecanol polyoxyethylene ether, 5-15% of coconut oleic acid potassium soap, and the balance of an organic solvents. The capsule type liquid detergent disclosed by the invention is designed special for machine washing, has the advantages of being simple to operate, convenient, free from dirtying of hands, soft and smooth in texture, proper in dense, moderate in property, free from injury of clothing and easier to rinse, and is also capable of removing stubborn stains effectively and rapidly, so that clothes can clean as new.

Description

Capsule type washing liquid
Technical field
The present invention relates to a kind of washing liquid, particularly relate to a kind of capsule type washing liquid.
Background technology
The laundry liquid market growth of China is fast especially, and according to the data of prospect of Chinese washing products research report in 2012, the amplitude that increases by a year-on-year basis of liquid washing agent is 15.05%, reaches 4,600,000 tons.The amplitude that increases by a year-on-year basis that association's 1-6 month liquid washing agent in 2013 is washed by China is 12% exceed synthetic detergent powder and soap, is the fastest washing composition kind of increasing degree.
The year per capita consuming level of current China articles for washing is lower, only 5.9 kilograms, 12 kilograms, Europe, about 15 kilograms, the U.S..China's articles for washing kind, based on synthetic detergent, accounts for 85% of articles for washing ultimate production, and liquid washing agent accounts for 26% of full one-tenth washing composition total amount.Light industry " 12. five " planning in the prediction of domestic articles for washing consumption is claimed: along with the raising of people's quality of life, people are in the consumption of articles for washing, and the consumption ratio of synthetic detergent and liquid washing agent focuses on continuous increase.Be about 6,800,000 tons to articles for washing consumption in 2009, the ratio of synthetic detergent total quantity consumed will reach 90%, and consumption is about 6,120,000 tons.Laundry liquid accounts for 20% of consumption, is about 1,200,000 tons.
Capsule type washing liquid be a kind of washing composition to be loaded in small-sized hydrolyzable packing bag from the appearance shape like a kind of washing liquid of capsule.It is easy to use, is convenient to the metering of washing composition during washing clothes, and each capsule is applicable to washing a collection of clothing, and when can avoid toppling over washing liquid, the phenomenon of leakage occurs simultaneously, reduces the trouble of user.Have the brands such as Surf, Persil, Bold, Fairy abroad at present, domestic have green wave on sale.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of capsule type washing liquid.
For solving the problems of the technologies described above, the present invention is achieved through the following technical solutions:
A kind of capsule type washing liquid, be made up of liquid washing agent and capsule, described capsule wraps up described liquid washing agent.
Described liquid washing agent, comprises following materials in percentage by mass: polyoxyethylenated alcohol sodium sulfate 15-25%, fatty alcohol-polyoxyethylene ether or isomerous tridecanol polyoxyethylene ether 30-40%, cocinic acid potash soap 5-15%, surplus are organic solvent.
Described organic solvent is one in butyl, triethylene glycol butyl ether and dipropylene or its mixture.
Preferably, described organic solvent is made up of the component of following weight parts: 5-15 part butyl, 5-15 part triethylene glycol butyl ether and 10-20 part dipropylene.
Polyoxyethylenated alcohol sodium sulfate, Sodium Alcohol Ether Sulphate, is called for short AES, No. CAS: 9004-82-4.
Fatty alcohol-polyoxyethylene ether, Primary Alcobol Ethoxylate is natural fatty alcohol and ethylene oxide adduct, No. CAS: 68131-39-5, No. EINECS: 500-195-7.
Isomerous tridecanol polyoxyethylene ether, molecular formula: RO (CH 2cH 2o) 5h R is isomerous tridecanol, Chinese name: isomerous tridecanol polyoxyethylene ether, Isomeric alcohol ethoxylates, CAS:9043-30-5, and easily dispersion or water-soluble, has excellent wettability, perviousness and emulsifying property.
Described cocinic acid potash soap, is called for short potash soap, also known as cocinic acid sylvite or coconut oil potash soap, and No. CAS: 91032-02-9.Cocinic acid potash soap is reacted by Oleum Cocois or coconut oil and potassium hydroxide to form.
Butyl, No. CAS: 112-34-5; Triethylene glycol butyl ether, No. CAS: 143-22-6; Dipropylene, No. CAS: 29911-28-2.
The material of described capsule is water-soluble film, and be preferably PVA film, PVOH film or PVP film, optimum is PVA film.
Described capsule thickness is 0.10-0.30mm.
PVA film has water soluble nature, cold water solubles.The mechanical property of PVA film: epistasis modulus 2500-400kg/cm 2, tensile strength 400-200kg/cm 2, tear edge 200-50kg/cm 2, unit elongation 150-220%.
In the present invention, according to actual needs, the whitening agent of the conventional addition of washing liquid, sanitas, pigment and essence can also be added, to meet corresponding demand.
Capsule type washing liquid of the present invention, aims at machine washing design, simple to operate, convenient not dirty hand, and the soft cunning of quality is dense thick moderate, and character gentleness does not hinder clothing, easier rinsing, can also remove stain effectively fast clean as new by clothing.
Embodiment
Raw material is introduced: fatty alcohol-polyoxyethylene ether (3) sodium sulfate, Cognis company, SLES N70, active matter content 70 ± 2%; C7 Branched fatty polyoxyethylenated alcohol, German BASF BASF, tO 7, active matter content 100%.; Cocinic acid potash soap, the cocinic acid potash soap that Shanghai Soap Making Co., Ltd. produces, active matter content 25%.
Embodiment 1
A kind of capsule type washing liquid, is made up of liquid washing agent and capsule, capsule parcel liquid washing agent.Capsule wall thickness is 0.20mm, and liquid washing agent weight is 25 grams.
Described capsule material PVA film.
Liquid detergent formula: fatty alcohol-polyoxyethylene ether (3) sodium sulfate 20wt%, C7 Branched fatty polyoxyethylenated alcohol 35wt%, cocinic acid potash soap 10wt%, butyl 20wt%, dipropylene 15wt%.
Adopt industry universal method, by capsule sealed envelope liquid washing agent, form capsule type washing liquid of the present invention.
Embodiment 2
A kind of capsule type washing liquid, is made up of liquid washing agent and capsule, capsule parcel liquid washing agent.Capsule wall thickness is 0.20mm, and liquid washing agent weight is 25 grams.
Described capsule material PVA film.
Liquid detergent formula: fatty alcohol-polyoxyethylene ether (3) sodium sulfate 20wt%, C7 Branched fatty polyoxyethylenated alcohol 35wt%, cocinic acid potash soap 10wt%, triethylene glycol butyl ether 20wt%, dipropylene 15wt%.
Adopt industry universal method, by capsule sealed envelope liquid washing agent, form capsule type washing liquid of the present invention.
Embodiment 3
A kind of capsule type washing liquid, is made up of liquid washing agent and capsule, capsule parcel liquid washing agent.Capsule wall thickness is 0.20mm, and liquid washing agent weight is 25 grams.
Described capsule material PVA film.
Liquid detergent formula: fatty alcohol-polyoxyethylene ether (3) sodium sulfate 20wt%, C7 Branched fatty polyoxyethylenated alcohol 35wt%, cocinic acid potash soap 10wt%, butyl 10wt%, triethylene glycol butyl ether 25wt%.
Adopt industry universal method, by capsule sealed envelope liquid washing agent, form capsule type washing liquid of the present invention.
Embodiment 4
A kind of capsule type washing liquid, is made up of liquid washing agent and capsule, capsule parcel liquid washing agent.Capsule wall thickness is 0.20mm, and liquid washing agent weight is 25 grams.
Described capsule material PVA film.
Liquid detergent formula: fatty alcohol-polyoxyethylene ether (3) sodium sulfate 20wt%, C7 Branched fatty polyoxyethylenated alcohol 35wt%, cocinic acid potash soap 10wt%, butyl 10wt%, triethylene glycol butyl ether 10wt%, dipropylene 15wt%.
Adopt industry universal method, by capsule sealed envelope liquid washing agent, form capsule type washing liquid of the present invention.
Capsule type washing liquid of the present invention includes high density and concentrates washing liquid elite, potent decontamination stain, a pouch, easy to use, without the need to outer layer plastic is torn, directly put into washing machine, the outer capsule dissolves of capsule type washing liquid after 1-3 minute, can effective washing clothes.
Test case
Detergency test: the method specified according to QB/T 1224-2007, extracts the liquid washing agent in capsule type washing liquid, detects the detersive power of this liquid washing agent (0.2wt%).
Concrete detection data, refer to table 1.
Table 3: soap lye detergency test table
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4
Decontamination ratio, (carbon black soiled cotton), P 1.02 1.03 1.01 1.06
Decontamination ratio, (albumen soiled cotton), P 1.05 1.04 1.01 1.12
Decontamination ratio, (sebum soiled cotton), P 1.09 1.06 1.04 1.28
Certainly, the present invention, can also have multiple conversion and remodeling, is not limited to the specific embodiment of above-mentioned embodiment.In a word, protection scope of the present invention should comprise those apparent conversion or alternative and remodeling to those skilled in the art.

Claims (8)

1. a capsule type washing liquid, is characterized in that, is made up of liquid washing agent and capsule, and described capsule wraps up described liquid washing agent.
2. a capsule type washing liquid, be made up of liquid washing agent and capsule, described capsule wraps up described liquid washing agent, it is characterized in that, described liquid washing agent comprises following materials in percentage by mass: polyoxyethylenated alcohol sodium sulfate 15-25%, fatty alcohol-polyoxyethylene ether or isomerous tridecanol polyoxyethylene ether 30-40%, cocinic acid potash soap 5-15%, surplus are organic solvent.
3. capsule type washing liquid as claimed in claim 2, is characterized in that, described organic solvent is one in butyl, triethylene glycol butyl ether and dipropylene or its mixture.
4. capsule type washing liquid as claimed in claim 3, it is characterized in that, described organic solvent is made up of the component of following weight parts: 5-15 part butyl, 5-15 part triethylene glycol butyl ether and 10-20 part dipropylene.
5. the capsule type washing liquid according to any one of claim 1-4, is characterized in that, the material of described capsule is water-soluble film.
6. capsule type washing liquid as claimed in claim 5, it is characterized in that, described water-soluble film is PVA film, PVOH film or PVP film.
7. capsule type washing liquid as claimed in claim 6, it is characterized in that, described water-soluble film is PVA film.
8. the capsule type washing liquid according to any one of claim 1-4, is characterized in that, described capsule thickness is 0.10-0.30mm.
CN201510094973.0A 2015-03-03 2015-03-03 Capsule-type liquid detergent Active CN104629964B (en)

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CN104629964B CN104629964B (en) 2017-12-22

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106833996A (en) * 2017-01-05 2017-06-13 广州品圣洗涤用品有限公司 A kind of single-chamber of chamber film stabilization or the liquid detergent of multi-cavity packaging
CN107384615A (en) * 2017-07-12 2017-11-24 江苏卓尔美物联科技股份有限公司 Pearl liquid and its preparation technology are coagulated in a kind of ecological, environmental protective health type concentration laundry
CN108192767A (en) * 2018-01-09 2018-06-22 广州市加茜亚化妆品有限公司 A kind of hyperconcetration dishwashing liquid and preparation method thereof
CN108795606A (en) * 2018-07-11 2018-11-13 泉州市倍斯豪日用品有限公司 A kind of detergent capsule and its manufacturing method

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1096442A (en) * 1993-06-18 1994-12-21 佛山友联医药发展有限公司 A kind of water-proof insoluble capsule
CN1935970A (en) * 2006-09-22 2007-03-28 王涛 Independant washing matter disintegrating agent and its use
CN101002720A (en) * 2000-03-01 2007-07-25 Pvaxx研究和开发有限公司 Method and apparatus for blowmolding capsules of polyvinylalcohol and blowmolded polyvinylalcohol capsules
CN203199403U (en) * 2012-12-19 2013-09-18 梁晓军 Laundry capsule
CN103820239A (en) * 2014-02-28 2014-05-28 刘菊 Mild safe laundry detergent

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1096442A (en) * 1993-06-18 1994-12-21 佛山友联医药发展有限公司 A kind of water-proof insoluble capsule
CN101002720A (en) * 2000-03-01 2007-07-25 Pvaxx研究和开发有限公司 Method and apparatus for blowmolding capsules of polyvinylalcohol and blowmolded polyvinylalcohol capsules
CN1935970A (en) * 2006-09-22 2007-03-28 王涛 Independant washing matter disintegrating agent and its use
CN203199403U (en) * 2012-12-19 2013-09-18 梁晓军 Laundry capsule
CN103820239A (en) * 2014-02-28 2014-05-28 刘菊 Mild safe laundry detergent

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
王玉忠: "《实用化学品配方手册》", 31 March 2009, 四川科学技术出版社 *
蒋雪涛: "《生物药剂学》", 31 March 1985, 解放军出版社 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106833996A (en) * 2017-01-05 2017-06-13 广州品圣洗涤用品有限公司 A kind of single-chamber of chamber film stabilization or the liquid detergent of multi-cavity packaging
CN106833996B (en) * 2017-01-05 2020-04-21 广东优凯科技有限公司 Single-cavity or multi-cavity packaged liquid detergent with stable cavity film
CN107384615A (en) * 2017-07-12 2017-11-24 江苏卓尔美物联科技股份有限公司 Pearl liquid and its preparation technology are coagulated in a kind of ecological, environmental protective health type concentration laundry
CN108192767A (en) * 2018-01-09 2018-06-22 广州市加茜亚化妆品有限公司 A kind of hyperconcetration dishwashing liquid and preparation method thereof
CN108795606A (en) * 2018-07-11 2018-11-13 泉州市倍斯豪日用品有限公司 A kind of detergent capsule and its manufacturing method

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Effective date of registration: 20221125

Address after: 7th Floor, Building 143, No. 2310, Yangshupu Road, Yangpu District, Shanghai 200090

Patentee after: Shanghai Soap Factory Co.,Ltd.

Address before: 200431 building 35, No. 1001, Changjiang West Road, Baoshan District, Shanghai

Patentee before: Shanghai Soap Co.,Ltd.