CN102492582B - Automobile air window glass washing liquid - Google Patents

Automobile air window glass washing liquid Download PDF

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Publication number
CN102492582B
CN102492582B CN201110387919.7A CN201110387919A CN102492582B CN 102492582 B CN102492582 B CN 102492582B CN 201110387919 A CN201110387919 A CN 201110387919A CN 102492582 B CN102492582 B CN 102492582B
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washing liquid
window glass
ethylene glycol
automobile air
environment
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CN201110387919.7A
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CN102492582A (en
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蔡金芳
王强
史永亮
李强
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SHAANXI CNNC DADI INDUSTRIAL Co Ltd
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SHAANXI CNNC DADI INDUSTRIAL Co Ltd
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Abstract

The invention relates to an automobile air window glass washing liquid which is a non-toxic environment-friendly automobile air window glass washing liquid which can prevent freezing, prevent fog and remove ice and snow. The washing liquid is formed by stirring and reacting the following raw materials by mass weight: ethanol, ethylene glycol monobutyl ether, alkylphenol polyoxyethylene ether, dodecyl benzyl ammonium chlorine, glycol, glycerol, polyoxyethylene alkyl phenyl ether, sodium benzoate, methyl benzotriazole, sodium molybdate, disodium ethylene diamine tetraacetate, sodium chloride, sunlight-resisting blue, triethanolamine, a defoaming agent and industrial pure water. By using the washing liquid, industrial methanol is prevented from being used as a solvent in the traditional formula; and simultaneously, the washing liquid and ethylene glycol monobutyl ether are matched and used, thereby greatly improving the dissolution effect of a single solvent on blots. The washing liquid disclosed by the invention is prepared by using non-toxic and easily biodegradable raw materials and is environment-friendly, can not pollute environment if being used for a long term, and prevents toxic gases from volatilization to harm a driver in the use process. The washing liquid has the characteristics of preventing fog, removing ice and snow, maintaining no icing on the surface of the glass for a long term, is not burnt and does not corrode.

Description

A kind of automobile window glass scavenging solution
One, technical field
The present invention relates to a kind of automobile window glass scavenging solution, be a kind of antifreeze, antifog, can the non-toxic, environmental friendly automobile window glass scavenging solution of deicing.
Two, background technology
In recent years, China's automobile demand amount and recoverable amount present a rapidly rising trend.Within 2010, Chinese annual sale of automobile total amount is 1,806 ten thousand, and it is very general that automobile enters into ordinary family, and people are while use automobile, and environmentally safe, personal health, use safety have had higher requirement gradually.Life-time service glass cleaning solution inferior, windshield, metal parts also can be made to corrode, and rain brush is swelling, and lacquer painting is stained, causes traffic accident time serious because pilot's line of vision is bad.
At present, China's automobile window glass scavenging solution also exists serious phenomenon of manufacturing in a rough and slipshod way, and most objectionable impuritiess such as methyl alcohol that use, as the main raw material of glass cleaning solution, cause serious pollution to environment, cause certain injury to officer and passenger.After glass cleaning solution has cleaned glass, can flow near Air Conditioning blast inlet, the smell of glass cleaning solution volatilization can enter in wheel house along the ventilation duct of automative air conditioning, the obnoxious flavour of glass cleaning solution volatilization inferior can become the stealthy killer of driver health, so the automobile window glass scavenging solution inventing a kind of asepsis environment-protecting seems particularly important.
Three, summary of the invention
The object of the invention is to provide a kind of automobile window glass scavenging solution, this scavenging solution adopts component compounded technology, optimizes consumption, reaches best washing effect with minimum composite amount.Particularly use winter, can antifog, deicing, and one deck organic membrane can be formed at glass surface, stop frost formation again when driving, for officer provides a kind of driving environment got a clear view.Meanwhile, nontoxic, pollution-free solvent and easy biodegradable cats product are selected in this invention, environmentally friendly, can not cause environmental pollution, also can not in use produce obnoxious flavour and pollute cab environment.This scavenging solution adopts solvent complex technology, can more good dissolving glass surface dirt; Adopt surfactant compound technology, improve cleaning and the emulsifying effectiveness of scavenging solution; Adopt antifreeze membrane-forming agent compounded technology, decrease the consumption of single membrane-forming agent, reduce product cost; Adopt inhibiter compounded technology, can effectively delay the aging of rain brush rubber, on automobile finish without impact, metal parts does not produce corrosion, effectively extends the work-ing life of windscreen and rain brush.
This glass cleaning solution has that cleaning effect is obvious, nontoxic, environmental protection, antifog, deicing, and burn into such as not to burn at the feature.
In order to realize object of the present invention, the present invention by mass percentage, is made up through stirring of following raw material:
A kind of automobile window glass scavenging solution of the present invention, by mass percentage, be made up through stirring of following raw material, it is applicable to the area of minimum temperature-25 DEG C in the present invention:
A kind of automobile window glass scavenging solution of the present invention, by mass percentage, be made up through stirring of following raw material, it is applicable to the area of minimum temperature-40 DEG C:
Preparation method of the present invention:
(1), under agitation successively by ethanol, ethylene glycol monobutyl ether, alkylphenol polyoxyethylene, dodecylbenzyl ammonium chloride, add industrial pure water, start and stir, make it abundant dissolving;
(2), under agitation methyl phenylpropyl alcohol triazole is added ethylene glycol, make it fully dissolving for subsequent use;
(3), under agitation successively Sodium Benzoate, Sodium orthomolybdate, disodium ethylene diamine tetraacetate and sodium-chlor are added, make it abundant dissolving;
(4), under agitation the methyl phenylpropyl alcohol triazole that ethylene glycol dissolves is added;
(5), products obtained therefrom pH value to 6.5 ~ 10.0 are adjusted to trolamine;
(6), add defoamer and sun-proof indigo plant, mend to 100% with industrial pure water;
(7), fully stir 30 minutes, leave standstill 4 hours, through using the metre filter packing of 1 μm after the assay was approved.
Mainly be described as follows for instant component and characteristic:
1, ethanol and ethylene glycol monobutyl ether.The Main Function of ethanol reduces freezing point, ethylene glycol monobutyl ether is a kind of organic solvent of brilliance, has good solvency action, have synergy when using together with ethanol to spots such as oil stain, natural gum, shellac, can well dissolve glass surface spot, improve cleaning performance.
2, alkylphenol polyoxyethylene.Feature does not form streak marks, non-residual solids after washing; major function is wetting and emulsification; under the environment that nonionogenic tenside exists at the organic solvent such as alcohol, ethylene glycol; one deck unit molecule protective membrane can be formed at glass surface; this layer of protective membrane can prevent from forming droplet; guarantee windshield glass is as clear as crystal, and becoming clear in the visual field, has anti-fog function.
3, dodecylbenzyl ammonium chloride.Its major function is the electrostatic that elimination windshield glass and air friction produce, and has antistatic property, plays sterilization and anticorrosion effect simultaneously, and cats product readily biodegradable, life-time service can not to environment, environmental protection.
4, ethylene glycol and glycerol.Its Main Function is coordinate with ethanol to reduce freezing point on the one hand, has frost prevention, antifreeze effect; On the other hand, its viscosity is large compared with ethanol, and volatility is little, forms a skim, prevent the generation again of ice and snow in winter driving process at glass surface, simultaneously can lubricate, reduces the friction between rain brush and glass, prevents from scratching glass.
5, polyoxyethylene alkyl phenyl ether.Its Main Function coordinates ethylene glycol and glycerol to use, and improves the residence time of composition on glass, and make frost protection, anti-ice-snow effect more lasting, the visual field bright when effectively ensureing that winter, ice and snow weather was driven a vehicle, improves drive safety.Polyoxyethylene alkyl phenyl ether has attachment, wetting action, can make ethylene glycol and glycerol longtime drying on glass, can get rid of ice and snow and frosting material, makes ethylene glycol and the easier film forming of glycerol.
6, Sodium Benzoate, methyl phenylpropyl alcohol triazole, Sodium orthomolybdate.Sodium Benzoate effect is sanitas, has the effect extended the shelf life, and Sodium Benzoate, methyl phenylpropyl alcohol triazole, the composite use of Sodium orthomolybdate have good preservative effect to the various metals that automobile windshield cleaning system contacts;
7, trolamine is used to regulate the pH value of scavenging solution between 6.5 ~ 10.0, can play shock absorption, makes scavenging solution pH value in 6.5 ~ 10.0 scopes, remain stable, increases emulsifying capacity and the emulsifying stability of scavenging solution, prevent dirt from again being formed.
8, disodium ethylene diamine tetraacetate.Here disodium ethylene diamine tetraacetate is selected, it is a kind of sequestrant, can with the calcium in water, magnesium, iron plasma generation chelating, be attracted to incrustation scale crystal surface, no longer continued growth and lattice distortion occurs, thus prevent the generation of glass surface hard scale, effectively extend the work-ing life of automobile window glass, simultaneously can reduce the generation of incrustation scale with the calcium in system water, magnesium, iron plasma generation chelating, prevent automotive system from blocking.
9, sodium-chlor.Sodium-chlor plays solublization, adding of sodium-chlor, substantially increases the speed and effect of removing frost.
10, direct fast blue.Its Main Function is and other product differentiations on the one hand, is easy to hunt leak in use procedure on the other hand.
11, present invention, avoiding conventional formulation uses industrial methanol as solvent, simultaneously with ethylene glycol monobutyl ether with the use of, substantially increase the solute effect of single solvent to spot, the present invention uses nontoxic, biological easily degraded preparation of raw material to form, environmentally friendly, life-time service can not to environment, the toxic gas that in use also can not volatilize harm officer.This invention can antifog, deicing, snow removing and the features such as glass surface does not freeze can be kept the long period, do not burn, do not corrode, environmentally friendly.
Embodiment
Below by concrete example, the present invention will be further described:
Embodiment 1: the area being applicable to minimum temperature-25 DEG C:
300kg industrial pure water is added reactor, opens and stir, under whipped state, add the ethanol of 400kg, 15kg ethylene glycol monobutyl ether, 1.5kg alkylphenol polyoxyethylene, 0.5kg dodecylbenzyl ammonium chloride makes it abundant dissolving.Then under whipped state, 8kg glycerol, 5kg polyoxyethylene alkyl phenyl ether, 5kg Sodium Benzoate, 2kg Sodium orthomolybdate, 0.5kg disodium ethylene diamine tetraacetate, 2kg sodium-chlor is added successively, again 0.5kg methyl phenylpropyl alcohol triazole is dissolved in 10kg ethylene glycol, after methyl phenylpropyl alcohol triazole fully dissolves in ethylene glycol, add in reactor and stir 10 minutes, with 2.5kg trolamine adjustment pH value in 6.5 ~ 10.0 scopes, reactor is added together with sun-proof basket, through the strainer packing after the assay was approved by 1 μm with the industrial pure water mixture foam killer of surplus.
The leading indicator of this example is as follows:
Embodiment 2: the area being applicable to minimum temperature-40 DEG C.
200kg industrial pure water is added reactor, opens and stir, under whipped state, add the edible ethanol of 580kg, 20kg ethylene glycol monobutyl ether, 2kg alkylphenol polyoxyethylene, 1kg dodecylbenzyl ammonium chloride makes it abundant dissolving.Then under whipped state, 10kg glycerol, 8kg polyoxyethylene alkyl phenyl ether, 5kg Sodium Benzoate, 3kg Sodium orthomolybdate, 0.5kg disodium ethylene diamine tetraacetate, 3kg sodium-chlor is added successively, again 0.5kg methyl phenylpropyl alcohol triazole is dissolved in 15kg ethylene glycol, after methyl phenylpropyl alcohol triazole fully dissolves in ethylene glycol, add in reactor and stir 10 minutes, with 3kg trolamine adjustment pH value in 6.5 ~ 10.0 scopes, reactor is added together with sun-proof basket, through the strainer packing after the assay was approved by 1 μm with the industrial pure water mixture foam killer of surplus.
The leading indicator of this example is as follows:

Claims (3)

1. an automobile window glass scavenging solution, is characterized in that: by mass percentage, is made up of following raw materials according through stirring:
2. a kind of automobile window glass scavenging solution according to claim 1, it is characterized in that: by mass percentage, be made up of following raw materials according through stirring, it is applicable to the area of minimum temperature-25 DEG C:
3. a kind of automobile window glass scavenging solution according to claim 1, it is characterized in that: by mass percentage, be made up of following raw materials according through stirring, this automobile window glass scavenging solution is applicable to the area of minimum temperature-40 DEG C:
CN201110387919.7A 2011-11-29 2011-11-29 Automobile air window glass washing liquid Active CN102492582B (en)

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* Cited by examiner, † Cited by third party
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CN108753496A (en) * 2018-07-06 2018-11-06 天津津龙汽车用品有限公司 A kind of automobile window glass cleaning agent and preparation method

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CN104277924A (en) * 2013-07-12 2015-01-14 中国石油天然气股份有限公司 Automobile windshield cleaning fluid
CN103396897B (en) * 2013-08-06 2014-12-31 张家港迪克汽车化学品有限公司 Automobile wind window washing liquid
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CN104357252A (en) * 2014-11-19 2015-02-18 柳州市二和汽车零部件有限公司 Automobile window cleaning solution
CN105199870A (en) * 2015-09-30 2015-12-30 江苏耀兴安全玻璃有限公司 Preparation method of glass detergent for automobiles
CN106609193A (en) * 2015-10-21 2017-05-03 中国石油化工股份有限公司 Vehicle headlamp cleaning agent
CN105838511A (en) * 2016-04-11 2016-08-10 河南工程学院 A novel environmental-friendly automobile windshield washing concentrated liquid
CN106085618A (en) * 2016-06-08 2016-11-09 山东源根石油化工有限公司 A kind of glass for vehicle window cleaning agent and preparation method thereof
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CN107254366A (en) * 2017-05-31 2017-10-17 江苏精盾节能科技有限公司 A kind of glass cleaner and preparation method thereof
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CN107557172A (en) * 2017-09-29 2018-01-09 洛娃日化(江苏)股份有限公司 A kind of antifreeze glass cleaner and preparation method
CN108624416A (en) * 2018-05-11 2018-10-09 肥西县碧涛建材有限公司 A kind of preparation method of door glass efficient cleaner
CN115491264A (en) * 2022-09-28 2022-12-20 抚顺润益化工有限公司 Environment-friendly multifunctional glass cleaning fluid

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