CN101434891A - Glass cleaning agent - Google Patents
Glass cleaning agent Download PDFInfo
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- CN101434891A CN101434891A CNA2007101871372A CN200710187137A CN101434891A CN 101434891 A CN101434891 A CN 101434891A CN A2007101871372 A CNA2007101871372 A CN A2007101871372A CN 200710187137 A CN200710187137 A CN 200710187137A CN 101434891 A CN101434891 A CN 101434891A
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- 239000011521 glass Substances 0.000 title claims abstract description 28
- 239000012459 cleaning agent Substances 0.000 title abstract description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000004094 surface-active agent Substances 0.000 claims abstract description 19
- 239000002904 solvent Substances 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- -1 siloxanes Chemical class 0.000 claims description 27
- 239000004593 Epoxy Substances 0.000 claims description 17
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 17
- 239000003431 cross linking reagent Substances 0.000 claims description 16
- 239000013543 active substance Substances 0.000 claims description 11
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 8
- HGHNORQXVBJKAU-UHFFFAOYSA-N decoxybenzene;sodium Chemical compound [Na].CCCCCCCCCCOC1=CC=CC=C1 HGHNORQXVBJKAU-UHFFFAOYSA-N 0.000 claims description 8
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 4
- 229930182478 glucoside Natural products 0.000 claims description 4
- 229940048842 sodium xylenesulfonate Drugs 0.000 claims description 4
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 claims description 4
- NRCIPQBRBAFTIA-UHFFFAOYSA-N 1-methoxy-1-oxooctadecane-2-sulfonic acid Chemical group CCCCCCCCCCCCCCCCC(S(O)(=O)=O)C(=O)OC NRCIPQBRBAFTIA-UHFFFAOYSA-N 0.000 claims description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 3
- 239000004141 Sodium laurylsulphate Substances 0.000 claims description 3
- 238000004132 cross linking Methods 0.000 claims description 3
- HTDJPCNNEPUOOQ-UHFFFAOYSA-N hexamethylcyclotrisiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O1 HTDJPCNNEPUOOQ-UHFFFAOYSA-N 0.000 claims description 3
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 3
- 229920000053 polysorbate 80 Polymers 0.000 claims description 3
- 239000001509 sodium citrate Substances 0.000 claims description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 3
- 235000010288 sodium nitrite Nutrition 0.000 claims description 3
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 claims description 3
- 229940038773 trisodium citrate Drugs 0.000 claims description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 2
- 125000005233 alkylalcohol group Chemical group 0.000 claims description 2
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 2
- 239000012964 benzotriazole Substances 0.000 claims description 2
- 229910021538 borax Inorganic materials 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 claims description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 2
- 235000011152 sodium sulphate Nutrition 0.000 claims description 2
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 2
- 239000004328 sodium tetraborate Substances 0.000 claims description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 claims description 2
- 239000001384 succinic acid Substances 0.000 claims description 2
- 229960004418 trolamine Drugs 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 6
- 125000002947 alkylene group Chemical group 0.000 abstract 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 abstract 2
- 239000005456 alcohol based solvent Substances 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- 239000003112 inhibitor Substances 0.000 abstract 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 12
- 238000000034 method Methods 0.000 description 12
- 239000000463 material Substances 0.000 description 8
- 238000004140 cleaning Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 230000008014 freezing Effects 0.000 description 3
- 238000007710 freezing Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000009736 wetting Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 230000001476 alcoholic effect Effects 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 150000002632 lipids Chemical class 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- 230000002000 scavenging effect Effects 0.000 description 2
- 241000255925 Diptera Species 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- WPPOGHDFAVQKLN-UHFFFAOYSA-N N-Octyl-2-pyrrolidone Chemical compound CCCCCCCCN1CCCC1=O WPPOGHDFAVQKLN-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000010795 gaseous waste Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Abstract
A glass cleaning agent contains alcohol, a surfactant and water, as well as a solubilizer and a corrosion inhibitor which can be selectively contained, wherein, the cleaning agent further contains a siloxane/alkylene oxide cross-linked matter. The addition of the water-soluble siloxane/alkylene oxide cross-linked matter can enhance the film-forming performance of alcohol solvents, improve anti-static effect and effectively prevent glass from hanging fog at low temperature.
Description
Technical field
The present invention relates to a kind of glass cleaner.
Background technology
Automobile is in daily driving process, and the glass of automobile especially windshield glass is easy to be attached dust, greasy dirt, mosquito corpse, industrial gaseous waste coagulum etc.These pollute, and bring influence not only for the outward appearance of automobile, have also constituted potential safety hazard owing to block officer's sight line.In addition, in the winter time because temperature is low, and windshield glass is very easily hung mist, can influence sight line equally, so need use clean-out system winter with resistance to fogging energy.
Though automotive industry constantly develops, but the windscreen cleaning liquid as one of automobile maintenance articles for use does not but have great improvement all the time, have only a basic cleaning function mostly, and the rubber of rain brush is existed certain corrodibility, also be not suitable under cold condition, using.In clean-out system, add alcohols and can reduce freezing point, as disclosed automobile windscreen cleaning agent among the CN101041793A, reduce freezing point by adding ethanol, strengthen the volatility of solvent, and use the composite mode of nonionic/anion surfactant to strengthen soil removability, widened the normal temperature range of using of clean-out system and improved cleaning effect.But, adding a certain amount of alcohols merely, its resistance to fogging can still can not satisfy the requirement that low temperature environment (such as below 0 ℃) uses.
Summary of the invention
The objective of the invention is to satisfy the shortcoming that low temperature environment uses by the freezing point of adding alcohols reduction glass cleaner merely, a kind of glass cleaner that has high resistance to fogging energy, can use under low temperature environment is provided in order to overcome in the prior art.
The invention provides a kind of glass cleaner, this clean-out system contains solubilizing agent and the inhibiter that alcohol, tensio-active agent, water and selectivity contain, and wherein, this clean-out system also contains siloxanes/epoxy alkane cross-linking agent.
The interpolation of water miscible siloxanes/epoxy alkane cross-linking agent can strengthen the film forming properties of alcoholic solvent, improves the effect of anti-electrostatic, can prevent from effectively to produce when glass from cleaning at low temperatures to freeze film.
Embodiment
Solubilizing agent and inhibiter that contain glass cleaner of the present invention alcohol, tensio-active agent, water and selectivity contain, wherein, this clean-out system also contains siloxanes/epoxy alkane cross-linking agent.
Gross weight with clean-out system is a benchmark, and the content of alcohol is 10-40 weight %, is preferably 15-35 weight %; The content of tensio-active agent is 1-6 weight %, is preferably 1.5-5.5 weight %; The content of solubilizing agent is 0-0.5 weight %, is preferably 0.1-0.3 weight %; The content of inhibiter is 0-0.5 weight %, is preferably 0.1-0.4 weight %; The content of siloxanes/epoxy alkane cross-linking agent is 0.05-2 weight %, is preferably 0.1-1 weight %; The content of water is 55-85 weight %, is preferably 58-80 weight %.
Described alcohol preferably includes monohydroxy-alcohol and polyvalent alcohol, and the weight ratio of monohydroxy-alcohol and polyvalent alcohol is 1:3-5:2.Monohydroxy-alcohol has good mobility, but film forming properties is general, and polyvalent alcohol cleaning solvency power is strong, and film forming properties is good, but flowing property is poor slightly, and both are composite can to mutually promote, and reaches better effect.Described monohydroxy-alcohol is that carbonatoms is the monohydroxy-alcohol of 2-4; Described polyvalent alcohol is that carbonatoms is 2 or 3 polyvalent alcohol.
The tensio-active agent that clean-out system of the present invention is used can adopt the conventional tensio-active agent that is used for clean-out system, preferably include aniorfic surfactant and nonionic surface active agent, the weight ratio of aniorfic surfactant and nonionic surface active agent is 2:3-4:1.Aniorfic surfactant wetting ability height, volatility is good, is not adsorbed on glass surface; Nonionic surface active agent foams, solubilizing effect is good, and two types tensio-active agent uses simultaneously, can play the effect of mutually promoting, and strengthens the washing soil removability.Described aniorfic surfactant is selected from one or more in alkyl succinic acid sulfonated ester, polyoxyethylenated alcohol sodium sulfate, sodium lauryl sulphate, alpha-sulfo fatty acid methyl ester and the positive decyl phenyl ether sodium disulfonate; Described nonionic surface active agent is selected from one or more in alkyl alcohol Soxylat A 25-7, alkyl polyglycoside and the N-acyl-pyrrolidine ketone.Under the preferable case, described aniorfic surfactant is alpha-sulfo octadecanoic acid methyl esters and/or positive decyl phenyl ether sodium disulfonate; Described nonionic surface active agent is butane group glucoside and/or N-acyl-pyrrolidine ketone.Alpha-sulfo octadecanoic acid methyl esters has good soil removability and anti-performance of hard water, and the good hydrotropy is arranged simultaneously; Positive decyl phenyl ether sodium disulfonate has good wetting, emulsification and dispersing property, can improve the cloud point of nonionogenic tenside, effectively reduces the surface tension of cleaning system; The butane group glucoside has whipability preferably, and foam is fine and smooth and stablize, cooperates with anion surfactant, can improve the viscosity of system, the ability of enhancing removal lipid dirt; The N-octylpyrrolidone has hydrophilic and hydrophobic two groups, can quicken wetting, the infiltration and softening of lipid dirt, soap class dirt and mineral scale, thereby quickens dirt removing from the substrate.
Can also add solubilizing agent and inhibiter in the clean-out system of the present invention.Solubilizing agent can impel in the clean-out system each component to be homogeneous phase to distribute, increase the soil removability of clean-out system; Inhibiter can effectively protect the metal of rain brush not to be corroded, and simultaneously, the rubber of rain brush is had softening provide protection, not only increases the contact area of rain brush sheet rubber and windshield glass, can also delay the aging of sheet rubber.Described solubilizing agent can be used in solubilizing agent in the clean-out system for routine, for example can be in sodium xylene sulfonate, Tween-80, the alkyl polyoxyethylene ether one or more; Described inhibiter can be various iron and steel inhibiter commonly used, for example can be in Starso, Sodium Nitrite, borax, trolamine, benzotriazole, succinate, tributyl phosphate and the Trisodium Citrate one or more.
Water miscible siloxanes/the interpolation of epoxy alkane cross-linking agent can strengthen the film forming properties of alcoholic solvent, improves the effect of anti-electrostatic, prevents that windshield glass from hanging mist at low temperatures.Described siloxanes is selected from one or more in dimethyl siloxane, hexamethyl cyclotrisiloxane, the octamethylcyclotetrasiloxane; Described epoxy alkane is oxyethane and/or propylene oxide.The mol ratio of siloxanes and epoxy alkane is 3:1-1:1 in described siloxanes/epoxy alkane cross-linking agent, is preferably 2:1-1:1, and the degree of crosslinking of the two is 30-60%.Siloxanes/epoxy alkane cross-linking agent can carry out crosslinked making with siloxanes and epoxy alkane by the method for routine, also can be commercially available.
Under the preferable case, concrete steps of the invention process are as follows:
(1) gross weight with clean-out system is a benchmark, the tensio-active agent of the pure and mild 1.5-5.5 weight % of 15-35 weight % is joined stir 2-3 hour in the agitator, and temperature is controlled at 50-60 ℃.
(2) be cooled to 30 ℃.With the clean-out system gross weight is benchmark, siloxanes/epoxy alkane the cross-linking agent (degree of crosslinking 40%, the two weight ratio are 3:2) that adds 0.1-1 weight % adds the solubilizing agent of 0.1-0.3 weight % and the inhibiter of 0.1-0.4 weight %, continue to stir 1-2 hour, promptly obtain product.
Below, will be described in more detail the present invention by embodiment.
Embodiment 1
Present embodiment is used to illustrate the preparation of glass cleaner provided by the invention.
(1) 20 gram Virahols, 3 gram ethylene glycol, 3 gram glycerol, 1 gram alpha-sulfo octadecanoic acid methyl esters, the positive decyl phenyl ether sodium disulfonate of 0.7 gram, 0.5 gram butane group glucoside, 0.6 gram N-acyl-pyrrolidine ketone and 70 gram deionized waters are joined in the agitator stirred 2.5 hours, temperature is controlled at 50 ℃.
(2) step (1) gained material is cooled to 30 ℃.To wherein adding 0.5 gram dimethyl siloxane/oxyethane cross-linking agent (Guangzhou Si Luoke chemistry company limited, 7231.0219), 0.3 the gram sodium xylene sulfonate, 0.2 the gram Trisodium Citrate and 0.2 the gram tributyl phosphate, continue to stir 1.5 hours, the product that obtains note is made A1.
Embodiment 2
Present embodiment is used to illustrate the preparation of glass cleaner provided by the invention.
(1) according to the identical method of embodiment 1 step (1), different is that the material of adding is: ethanol 15 gram, ethylene glycol 5 grams, positive decyl phenyl ether sodium disulfonate 4 grams, N-acyl-pyrrolidine ketone 1 gram and deionized water 74.5 grams.
(2) according to the identical method of embodiment 1 step (2), different is that the material of adding is: dimethyl siloxane/oxyethane cross-linking agent 0.1 gram, sodium xylene sulfonate 0.2 gram and tributyl phosphate 0.2 gram, the product note is made A2.
Embodiment 3
Present embodiment is used to illustrate the preparation of glass cleaner provided by the invention.
(1) according to the identical method of embodiment 1 step (1), different is that the material of adding is: butanols 25 gram, alpha-sulfo fatty acid methyl ester 4 grams and deionized water 69.5 grams.
(2) according to the identical method of embodiment 1 step (2), different is, the material that adds is: hexamethyl cyclotrisiloxane/oxyethane cross-linking agent (Guangzhou Si Luoke chemistry company limited, 7231.0219) 0.8 gram, Tween-80 0.3 gram and tributyl phosphate 0.4 gram, the product note is made A3.
Embodiment 4
Present embodiment is used to illustrate the preparation of glass cleaner provided by the invention.
(1) according to the identical method of embodiment 1 step (1).
(2) according to the identical method of embodiment 1 step (2), different is, contains 1 gram dimethyl siloxane/oxyethane cross-linking agent in the material, the product note is made A4.
Embodiment 5
Present embodiment is used to illustrate the preparation of glass cleaner provided by the invention.
(1) according to the identical method of embodiment 1 step (1); different is that the material of adding is: ethylene glycol 30 grams, alpha-sulfo fatty acid methyl ester 1 gram, positive decyl phenyl ether sodium disulfonate 1 gram, alkyl polyglycoside 0.5 gram, N-acyl-pyrrolidine ketone 0.3 gram and deionized water 66 grams.
(2) according to the identical method of embodiment 1 step (2), product note is made A5.
Comparative Examples 1
This Comparative Examples is used to illustrate the preparation of the glass cleaner of prior art.
Material sodium lauryl sulphate 0.5 gram, Virahol Soxylat A 25-7 0.5 gram, ethanol 30 grams, ethylene glycol 3 grams, Sodium Nitrite 0.5 gram and deionized water 65.5 grams are added one by one, be stirred to homogeneous transparent, obtain the product note and make C1.
Embodiment 6-10
Embodiment 6-10 is used to measure the performance of the glass cleaner that embodiment 1-5 makes.
Use after clean-out system A1-A5 is mixed with scavenging solution in the ratio of 1:20.Under-10 ℃ of conditions, the nozzle by the automobile front is sprayed at scavenging solution on the vehicle glass, starts rain brush and cleans windshield.Observe to clean to have or not on the vehicle glass in back 4 hours and freeze the film appearance, and record observation situation, the results are shown in table 1.
Comparative Examples 2
This Comparative Examples is used to measure the performance of the glass cleaner that Comparative Examples 1 makes.
According to the method identical clean-out system C1 is tested, the results are shown in table 1 with embodiment 6-10.
Table 1
| Numbering | Clean the situation of back vehicle glass |
| A1 | Do not have and freeze film |
| A2 | Do not have and freeze film |
| A3 | Do not have and freeze film |
| A4 | Do not have and freeze film |
| A5 | Do not have and freeze film |
| C1 | There is the flaky film that freezes to occur |
By table 1 as can be seen, clean-out system provided by the invention is compared with the clean-out system that Comparative Examples 1 makes, and has higher resistance to fogging energy, is adapted at using under the low temperature environment.
Claims (10)
1, solubilizing agent and inhibiter that contain a kind of glass cleaner, this clean-out system alcohol, tensio-active agent, water and selectivity contain is characterized in that, this clean-out system also contains siloxanes/epoxy alkane cross-linking agent.
2, clean-out system according to claim 1, wherein, gross weight with clean-out system is a benchmark, the content of alcohol is 10-40 weight %, the content of tensio-active agent is 1.5-5.5 weight %, and the content of solubilizing agent is 0-0.5 weight %, and the content of inhibiter is 0-0.5 weight %, the content of siloxanes/epoxy alkane cross-linking agent is 0.1-1 weight %, and the content of water is 55-85 weight %.
3, clean-out system according to claim 2, wherein, gross weight with clean-out system is a benchmark, the content of alcohol is 15-35 weight %, the content of tensio-active agent is 1.5-5.5 weight %, and the content of solubilizing agent is 0.1-0.3 weight %, and the content of inhibiter is 0.1-0.4 weight %, the content of siloxanes/epoxy alkane cross-linking agent is 0.1-1 weight %, and the content of water is 58-80 weight %.
4, clean-out system according to claim 1, wherein, the mol ratio of siloxanes and epoxy alkane is 2:1-1:1 in described siloxanes/epoxy alkane cross-linking agent, the degree of crosslinking of the two is 30-60%.
5, according to any described clean-out system among the claim 1-4, wherein, described siloxanes is selected from one or more in dimethyl siloxane, hexamethyl cyclotrisiloxane and the octamethylcyclotetrasiloxane; Described epoxy alkane is oxyethane and/or propylene oxide.
6, according to any described clean-out system among the claim 1-3, wherein, described alcohol comprises monohydroxy-alcohol and polyvalent alcohol, and the weight ratio of monohydroxy-alcohol and polyvalent alcohol is 1:3-5:2, and described monohydroxy-alcohol is that carbonatoms is the monohydroxy-alcohol of 2-4; Described polyvalent alcohol is that carbonatoms is 2 or 3 polyvalent alcohol.
7, clean-out system according to claim 1, wherein, described tensio-active agent comprises aniorfic surfactant and nonionic surface active agent, the weight ratio of aniorfic surfactant and nonionic surface active agent is 2:3-4:1.
8, clean-out system according to claim 7, wherein, described aniorfic surfactant is one or more in alkyl succinic acid sulfonated ester, polyoxyethylenated alcohol sodium sulfate, sodium lauryl sulphate, alpha-sulfo fatty acid methyl ester and the positive decyl phenyl ether sodium disulfonate; Described nonionic surface active agent is one or more in alkyl alcohol Soxylat A 25-7, alkyl polyglycoside and the N-acyl-pyrrolidine ketone.
9, according to claim 7 or 8 described clean-out systems, wherein, described aniorfic surfactant is alpha-sulfo octadecanoic acid methyl esters and/or positive decyl phenyl ether sodium disulfonate; Described nonionic surface active agent is butane group glucoside and/or N-acyl-pyrrolidine ketone.
10, according to any described clean-out system among the claim 1-3, wherein, described solubilizing agent is one or more in sodium xylene sulfonate, Tween-80, the alkyl polyoxyethylene ether; Described inhibiter is one or more in Starso, Sodium Nitrite, borax, trolamine, benzotriazole, succinate, tributyl phosphate and the Trisodium Citrate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007101871372A CN101434891B (en) | 2007-11-16 | 2007-11-16 | Glass cleaning agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007101871372A CN101434891B (en) | 2007-11-16 | 2007-11-16 | Glass cleaning agent |
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| Publication Number | Publication Date |
|---|---|
| CN101434891A true CN101434891A (en) | 2009-05-20 |
| CN101434891B CN101434891B (en) | 2011-03-30 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007101871372A Expired - Fee Related CN101434891B (en) | 2007-11-16 | 2007-11-16 | Glass cleaning agent |
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Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103224852A (en) * | 2012-12-28 | 2013-07-31 | 青岛润鑫伟业科贸有限公司 | Glass cleaning agent |
| CN103224843A (en) * | 2012-12-28 | 2013-07-31 | 青岛润鑫伟业科贸有限公司 | Glass cleaning agent |
| CN103224842A (en) * | 2012-12-28 | 2013-07-31 | 青岛润鑫伟业科贸有限公司 | Glass cleaning agent |
| CN103773615A (en) * | 2014-01-09 | 2014-05-07 | 鹤壁宝发能源科技股份有限公司 | Non-combustible, uniform and environment-friendly multifunctional cleaning aerosol |
| CN103923757A (en) * | 2014-04-25 | 2014-07-16 | 湖州华鼎贸易有限公司 | Novel wall stain remover |
| CN104194964A (en) * | 2014-07-30 | 2014-12-10 | 南昌印仁贸易有限公司 | Automobile glass cleaner and preparation method thereof |
| CN104357252A (en) * | 2014-11-19 | 2015-02-18 | 柳州市二和汽车零部件有限公司 | Automobile window cleaning solution |
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| WO1996008553A1 (en) * | 1994-09-12 | 1996-03-21 | Ecolab Inc. | Rinse aid for plasticware |
| CN101041793A (en) * | 2007-04-23 | 2007-09-26 | 北京交通大学 | Automobile windscreen cleaning agent |
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