CN104194964B - A kind of automobile glass cleaning agent and preparation method thereof - Google Patents
A kind of automobile glass cleaning agent and preparation method thereof Download PDFInfo
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- CN104194964B CN104194964B CN201410369554.9A CN201410369554A CN104194964B CN 104194964 B CN104194964 B CN 104194964B CN 201410369554 A CN201410369554 A CN 201410369554A CN 104194964 B CN104194964 B CN 104194964B
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Abstract
The invention discloses a kind of automobile glass cleaning agent and preparation method thereof, use non-ion fluorin surfactant and other surfactant compound modes, not only increase dirt-removing power, scattered when can also substantially reduce light beam by windshield, good anti-dazzle light effect is reached, while can also play the performance of good stream antifog, high under low temperature condition below 0 DEG C.
Description
Technical field
The present invention relates to a kind of cleaning agent and preparation method thereof, especially a kind of automobile glass cleaning agent and its preparation side
Method.
Background technology
Summer sunlight is dazzling, and sunlight is easy to pass through windshield in automobile cab, stimulates the eyes of driver, holds
It is also easy to produce traffic accident；And in the winter time during car steering, a large amount of moisture convergences for suspending are produced on the glass of low temperature in driver's cabin
Raw one layer ambiguous vaporific, with the continuous decline of temperature, a thin layer of ice crystal can be also formed on windshield, can see
The very low driving environment of degree, the operation to human pilot brings certain difficulty, easily causes a traffic accident, current automotive windshield glass
Glass defrosting blows drying method using Hot-air fan mostly, and this method power consumption is more, and easily forms fog, it is difficult to quickly disperse.
The content of the invention
It is an object of the invention to provide a kind of automobile glass cleaning agent and preparation method thereof, non-ion fluorin surface-active is used
Agent and other surfactant compound modes, not only increase dirt-removing power, moreover it is possible to when substantially reducing light beam by windshield
Scatter, reach good anti-dazzle light effect, while can also play good antifog, height under low temperature condition below 0 DEG C
The performance of stream.
A kind of automobile glass cleaning agent, is made up of the raw material of following masses number：Pigment 0.1-0.5 parts, non-ion fluorin table
1.0-4.5 parts of face activating agent, polyether silicone oil 0.1-3.0 parts, ethoxylated dodecyl alcohol 0.01-0.1 parts, Nonyl pheno
Ether 0.01-0.1 parts, 0.05-0.5 parts of C8-C10 APGs, 1, ammediol 2.0-10.0 parts, ethanol 2.0-60.0 parts, ten
0.01-0.5 parts, composite corrosion inhibitor 0.01-0.5 parts, preservative 0.2-0.5 parts of dialkyl dimethyl benzyl ammonium chloride.Ethylenediamine
Tetraacethyl disodium 0.001-0.5 parts, remainder is deionized water, totally 100 parts.
A kind of automobile glass cleaning agent, preparation method is：Pigment is put into stainless steel cauldron, then in reactor
Deionized water, ethanol and 1, ammediol are added, stainless steel stirring slurry is opened, controls mixing speed for 50-70r/min, made
Pigmentolysis be simultaneously stirred for it is uniform, under stirring to stainless steel cauldron in add non-ion fluorin surfactant, poly-
Ether silicone oil, ethoxylated dodecyl alcohol, NPE, C8-C10 APGs, dodecyl dimethyl benzyl chloride
Change ammonium, preservative, composite corrosion inhibitor, disodium ethylene diamine tetraacetate, material stirring is uniformly automobile glass cleaning agent afterwards.
Wherein non-ion fluorin surfactant is Du Pont non-ion fluorin surfactant Capstone FS-3100, is combined slow
Erosion agent by etc. quality ZnSO4, Na2SiO3And Na2WO4Composition, preservative is OIT, and pigment is light blue pigment or methyl
Haematochrome.
The advantage of the invention is that：
1st, nonionic surfactant plays wetting and emulsifying agent from ethoxylated dodecyl alcohol, NPE
Decontamination.
2nd, the addition of non-ion fluorin surfactant can further reduce surface tension, surface tension of liquid is dropped to 17-
19dyn/cm（25℃）, hence it is evident that wetting and the penetrating power of product are improved, cleaning performance is improved.Non-ion fluorin surfactant because
Containing various fluorocarbon groups, it is had extraordinary adhesion with glass surface, glass can be very well attached to during cleaning panes of motor vehicle
Glass surface, because it has Superhydrophilic, the water smoke (or even steam) of any temperature, mist pearl are contacted with regard to energy once with glass surface
Infiltrate immediately and sprawl into transparent moisture film, move moisture film due to its Superhydrophilic rapid, and drop can not be gathered into, it is good
Anti- fog effect（Also good drip performance antifog, high can be played under low temperature condition below 0 DEG C.）Other tables can be reduced simultaneously
The consumption of face activating agent, reduces cost.
3rd, non-ion fluorin surfactant and polyether silicone oil are used cooperatively, and are sent out when can substantially reduce light beam by windshield
Raw scattering（Light beam is reflective essentially from highway street lamp, dipped headlights, road surface or the water surface etc.）, and the vision of driver is influenceed,
Good anti-dazzle light effect can be played.
4th, dodecyl benzyl dimethyl ammonium chloride can be eliminated due to the electrostatic that friction is produced, to reduce inhaling again for dust
Attached, while playing sterilization and anticorrosion, coordinating with nonionic has wetting and decontamination.
5th, polyether silicone oil and APG can increase lubrication in cleaning, and water resistance is scraped in reduction and wiper rubber piece is damaged
Wound, can play increase wiper rubber elastic reaction, scrape water more thorough.
Specific embodiment：
Embodiment 1：
A kind of automobile glass cleaning agent and preparation method thereof, is made up of the raw material of following masses number：It is 0.1 part of pigment, non-
1.0 parts of ion fluorine surfactant, 0.1 part of polyether silicone oil, 0.01 part of ethoxylated dodecyl alcohol, NPE
0.01 part, 0.05 part of C8-C10 APGs, 1,2.0 parts of ammediol, 2.0 parts of ethanol, dodecyl dimethyl Benzylmagnesium chloride
0.01 part of ammonium, 0.01 part of composite corrosion inhibitor, 0.2 part of preservative.0.001 part of disodium ethylene diamine tetraacetate, remainder is deionized water,
Totally 100 parts.
A kind of automobile glass cleaning agent, preparation method is：Pigment is put into stainless steel cauldron, then in reactor
Deionized water, ethanol and 1, ammediol are added, stainless steel stirring slurry is opened, controls mixing speed for 50r/min, make color
Element dissolving be simultaneously stirred for it is uniform, under stirring to stainless steel cauldron in add non-ion fluorin surfactant, polyethers
Silicone oil, ethoxylated dodecyl alcohol, NPE, C8-C10 APGs, dodecyl dimethyl Benzylmagnesium chloride
Ammonium, preservative, composite corrosion inhibitor, disodium ethylene diamine tetraacetate, automobile glass cleaning agent is uniformly by material stirring afterwards.
Wherein non-ion fluorin surfactant is Du Pont non-ion fluorin surfactant Capstone FS-3100, is combined slow
Erosion agent by etc. quality ZnSO4, Na2SiO3And Na2WO4Composition, preservative is OIT, and pigment is light blue pigment.
Embodiment 2：
A kind of automobile glass cleaning agent and preparation method thereof, is made up of the raw material of following masses number：It is 0.3 part of pigment, non-
2.5 parts of ion fluorine surfactant, 1.5 parts of polyether silicone oil, 0.05 part of ethoxylated dodecyl alcohol, NPE
0.05 part, 0.25 part of C8-C10 APGs, 1,6.0 parts of ammediol, 31.0 parts of ethanol, dodecyl dimethyl Benzylmagnesium chloride
0.25 part of ammonium, 0.25 part of composite corrosion inhibitor, 0.3 part of preservative.0.25 part of disodium ethylene diamine tetraacetate, remainder is deionized water,
Totally 100 parts.
A kind of automobile glass cleaning agent, preparation method is：Pigment is put into stainless steel cauldron, then in reactor
Deionized water, ethanol and 1, ammediol are added, stainless steel stirring slurry is opened, controls mixing speed for 60r/min, make color
Element dissolving be simultaneously stirred for it is uniform, under stirring to stainless steel cauldron in add non-ion fluorin surfactant, polyethers
Silicone oil, ethoxylated dodecyl alcohol, NPE, C8-C10 APGs, dodecyl dimethyl Benzylmagnesium chloride
Ammonium, preservative, composite corrosion inhibitor, disodium ethylene diamine tetraacetate, automobile glass cleaning agent is uniformly by material stirring afterwards.
Wherein non-ion fluorin surfactant is Du Pont non-ion fluorin surfactant Capstone FS-3100, is combined slow
Erosion agent by etc. quality ZnSO4, Na2SiO3And Na2WO4Composition, preservative is OIT, and pigment is methyl haematochrome.
Embodiment 3：
A kind of automobile glass cleaning agent and preparation method thereof, is made up of the raw material of following masses number：It is 0.5 part of pigment, non-
4.5 parts of ion fluorine surfactant, 3.0 parts of polyether silicone oil, 0.1 part of ethoxylated dodecyl alcohol, NPE 0.1
Part, 0.5 part of C8-C10 APGs, 1,10.0 parts of ammediol, 60.0 parts of ethanol, dodecyl benzyl dimethyl ammonium chloride
0.5 part, 0.5 part of composite corrosion inhibitor, 0.5 part of preservative.0.5 part of disodium ethylene diamine tetraacetate, remainder is deionized water, totally 100
Part.
A kind of automobile glass cleaning agent, preparation method is：Pigment is put into stainless steel cauldron, then in reactor
Deionized water, ethanol and 1, ammediol are added, stainless steel stirring slurry is opened, controls mixing speed for 70r/min, make color
Element dissolving be simultaneously stirred for it is uniform, under stirring to stainless steel cauldron in add non-ion fluorin surfactant, polyethers
Silicone oil, ethoxylated dodecyl alcohol, NPE, C8-C10 APGs, dodecyl dimethyl Benzylmagnesium chloride
Ammonium, preservative, composite corrosion inhibitor, disodium ethylene diamine tetraacetate, automobile glass cleaning agent is uniformly by material stirring afterwards.
Wherein non-ion fluorin surfactant is Du Pont non-ion fluorin surfactant Capstone FS-3100, is combined slow
Erosion agent by etc. quality ZnSO4, Na2SiO3And Na2WO4Composition, preservative is OIT, and pigment is methyl haematochrome.
Embodiment 4：
A kind of automobile glass cleaning agent and preparation method thereof, is made up of the raw material of following masses number：It is 0.08 part of pigment, non-
0.7 part of ion fluorine surfactant, 0.08 part of polyether silicone oil, 0.007 part of ethoxylated dodecyl alcohol, NPE
0.009 part, 0.03 part of C8-C10 APGs, 1,1.0 parts of ammediol, 1.0 parts of ethanol, dodecyl dimethyl Benzylmagnesium chloride
0.007 part of ammonium, 0.009 part of composite corrosion inhibitor, 0.1 part of preservative.0.0009 part of disodium ethylene diamine tetraacetate, remainder is deionization
Water, totally 100 parts.
A kind of automobile glass cleaning agent, preparation method is：Pigment is put into stainless steel cauldron, then in reactor
Deionized water, ethanol and 1, ammediol are added, stainless steel stirring slurry is opened, controls mixing speed for 40r/min, make color
Element dissolving be simultaneously stirred for it is uniform, under stirring to stainless steel cauldron in add non-ion fluorin surfactant, polyethers
Silicone oil, ethoxylated dodecyl alcohol, NPE, C8-C10 APGs, dodecyl dimethyl Benzylmagnesium chloride
Ammonium, preservative, composite corrosion inhibitor, disodium ethylene diamine tetraacetate, automobile glass cleaning agent is uniformly by material stirring afterwards.
Wherein non-ion fluorin surfactant is Du Pont non-ion fluorin surfactant Capstone FS-3100, is combined slow
Erosion agent by etc. quality ZnSO4, Na2SiO3And Na2WO4Composition, preservative is OIT, and pigment is light blue pigment.
Embodiment 5：
A kind of automobile glass cleaning agent and preparation method thereof, is made up of the raw material of following masses number：It is 0.6 part of pigment, non-
5.0 parts of ion fluorine surfactant, 4.0 parts of polyether silicone oil, 0.2 part of ethoxylated dodecyl alcohol, NPE 0.2
Part, 0.6 part of C8-C10 APGs, 1,12.0 parts of ammediol, 65.0 parts of ethanol, dodecyl benzyl dimethyl ammonium chloride
0.7 part, 0.6 part of composite corrosion inhibitor, 0.7 part of preservative.0.7 part of disodium ethylene diamine tetraacetate, remainder is deionized water, totally 100
Part.
A kind of automobile glass cleaning agent, preparation method is：Pigment is put into stainless steel cauldron, then in reactor
Deionized water, ethanol and 1, ammediol are added, stainless steel stirring slurry is opened, controls mixing speed for 80r/min, make color
Element dissolving be simultaneously stirred for it is uniform, under stirring to stainless steel cauldron in add non-ion fluorin surfactant, polyethers
Silicone oil, ethoxylated dodecyl alcohol, NPE, C8-C10 APGs, dodecyl dimethyl Benzylmagnesium chloride
Ammonium, preservative, composite corrosion inhibitor, disodium ethylene diamine tetraacetate, automobile glass cleaning agent is uniformly by material stirring afterwards.
Wherein non-ion fluorin surfactant is Du Pont non-ion fluorin surfactant Capstone FS-3100, is combined slow
Erosion agent by etc. quality ZnSO4, Na2SiO3And Na2WO4Composition, preservative is OIT, and pigment is methyl haematochrome.
The present invention prepared embodiment 1-5 automobile glass cleanings agent is used for the vehicle glass of same model, without clear
Clean same model vehicle glass is contrasted as a comparison case, tests mist degree and light transmission rate（Determined using light transmittance mist degree
Instrument WGT-S is detected）Contrasted, it is as a result as shown in the table：
| Mist degree（0-30%） | Light transmission rate（0-100%） | |
| Embodiment 1 | 1.49% | 92.9% |
| Embodiment 2 | 1.40% | 95.2% |
| Embodiment 3 | 1.45% | 94.3% |
| Embodiment 4 | 2.44% | 90.6% |
| Embodiment 5 | 2.42% | 90.2% |
| Comparative example（It is not used） | 4.81% | 79.3% |
The embodiment 1-3 that be can be seen that in the range of present invention process from upper table result is obtained automobile glass cleaning agent
Effect is substantially better than embodiment 4,5 and comparative example outside processing range, especially with the best results of embodiment 2, therefore the present invention
Scattered when can substantially reduce light beam by windshield, reach good anti-dazzle light effect, while can also play well
Anti- fog effect.
Claims (4)
1. a kind of automobile glass cleaning agent, it is characterized by：It is made up of the raw material of following masses number：Pigment 0.1-0.5 parts, it is non-from
Sub- fluorine surfactant 1.0-4.5 parts, polyether silicone oil 0.1-3.0 parts, ethoxylated dodecyl alcohol 0.01-0.1 parts, nonyl phenol gather
0.01-0.1 parts of oxygen vinethene, 0.05-0.5 parts of C8-C10 APGs, 1, ammediol 2.0-10.0 parts, ethanol 2.0-60.0
Part, dodecyl benzyl dimethyl ammonium chloride 0.01-0.5 parts, composite corrosion inhibitor 0.01-0.5 parts, preservative 0.2-0.5 parts, second
Edetate disodium 0.001-0.5 parts, remainder is deionized water, totally 100 parts；
Preparation method is：Pigment is put into stainless steel cauldron, then to adding deionized water in reactor, ethanol and 1,
Ammediol, opens stainless steel stirring slurry, controls mixing speed for 50-70r/min, makes pigmentolysis and is stirred for uniformly,
Under stirring to stainless steel cauldron in add non-ion fluorin surfactant, polyether silicone oil, ethoxylated dodecyl alcohol,
NPE, C8-C10 APGs, dodecyl benzyl dimethyl ammonium chloride, preservative, composite corrosion inhibitor, second
Edetate disodium, automobile glass cleaning agent is uniformly by material stirring afterwards.
2. a kind of automobile glass cleaning agent as claimed in claim 1, it is characterized by：It is made up of the raw material of following masses number：
0.3 part of pigment, 2.5 parts of non-ion fluorin surfactant, 1.5 parts of polyether silicone oil, 0.05 part of ethoxylated dodecyl alcohol, nonyl phenol
0.05 part of APEO, 0.25 part of C8-C10 APGs, 1,6.0 parts of ammediol, 31.0 parts of ethanol, dimethyl
0.25 part of base benzyl ammonium chloride, 0.25 part of composite corrosion inhibitor, 0.3 part of preservative, 0.25 part of disodium ethylene diamine tetraacetate, remainder is
Deionized water, totally 100 parts.
3. a kind of automobile glass cleaning agent as claimed in claim 1, it is characterized by：Preparation method is：Pigment is put into stainless
In steel reactor, then to deionized water, ethanol and 1, ammediol is added in reactor, stainless steel stirring slurry, control are opened
Mixing speed processed is 60r/min, make pigmentolysis and be stirred for it is uniform, under stirring to stainless steel cauldron in plus
Enter non-ion fluorin surfactant, polyether silicone oil, ethoxylated dodecyl alcohol, NPE, C8-C10 alkyl sugar
Glycosides, dodecyl benzyl dimethyl ammonium chloride, preservative, composite corrosion inhibitor, disodium ethylene diamine tetraacetate, material stirring is uniform
Automobile glass cleaning agent is afterwards.
4. a kind of automobile glass cleaning agent as described in claim 1-3 one of which, it is characterized by：Non-ion fluorin surface-active
Agent be Du Pont non-ion fluorin surfactant Capstone FS-3100, composite corrosion inhibitor by etc. quality ZnSO4, Na2SiO3With
Na2WO4Composition, preservative is OIT, and pigment is light blue pigment or methyl haematochrome.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201410369554.9A CN104194964B (en) | 2014-07-30 | 2014-07-30 | A kind of automobile glass cleaning agent and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410369554.9A CN104194964B (en) | 2014-07-30 | 2014-07-30 | A kind of automobile glass cleaning agent and preparation method thereof |
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| CN104194964A CN104194964A (en) | 2014-12-10 |
| CN104194964B true CN104194964B (en) | 2017-06-20 |
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| CN106635470A (en) * | 2016-09-30 | 2017-05-10 | 东莞市蓝鲸化工科技有限公司 | Vehicle body surface water-free deterging antifouling protective spray and preparation method thereof |
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| CN107881024A (en) * | 2017-11-14 | 2018-04-06 | 广州沿江科技有限公司 | A kind of cleanser for vehicle windscreen and preparation method thereof |
| CN108441331A (en) * | 2018-04-18 | 2018-08-24 | 鹤山市金润纳新型材料有限公司 | A kind of automobile glass cleaning agent and preparation method thereof |
| CN109152291B (en) * | 2018-09-06 | 2020-08-11 | 上海理工大学 | Method for enhancing spray cooling heat exchange performance |
| CN109385337A (en) * | 2018-11-20 | 2019-02-26 | 萍乡亨厚新材科技有限公司 | A kind of automobile exempts to clean car washing liquid and its application method |
| CN109370797B (en) * | 2018-12-26 | 2021-01-01 | 合肥普庆新材料科技有限公司 | Neutral cleaning agent for mobile phone cover plate glass |
| CN113105868B (en) * | 2021-04-19 | 2022-05-17 | 江苏南创化学与生命健康研究院有限公司 | Antibacterial antifogging agent and antibacterial long-acting antifogging wet tissue prepared from same |
| CN117511504B (en) * | 2024-01-04 | 2024-03-26 | 荷塘探索国际健康科技发展（北京）有限公司 | Medical antifogging agent, preparation method and antifogging mirror cloth prepared from medical antifogging agent |
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