CN108410354A - A kind of oil-film removing expelling water agent - Google Patents

A kind of oil-film removing expelling water agent Download PDF

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Publication number
CN108410354A
CN108410354A CN201810174598.4A CN201810174598A CN108410354A CN 108410354 A CN108410354 A CN 108410354A CN 201810174598 A CN201810174598 A CN 201810174598A CN 108410354 A CN108410354 A CN 108410354A
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oil
glass
parts
component
expelling water
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李想
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • C09D183/08Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/32Phosphorus-containing compounds
    • C08K2003/329Phosphorus containing acids

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Detergent Compositions (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of oil-film removing expelling water agent comprising the component of following mass percentage:Waterproofing agent 0.1% 0.2%, organosilan 7.4% 32%, pH adjusting agent 4.5% 5%, lubricant 6% 10.8%, nonionic surfactant 2%, remaining is solvent, and the sum of mass percentage of the above component is 100%.Advantageous effect:Driver is avoided when driving since dazzling, halation occurs in oil film, eliminates security risk, the effective generation for reducing Traffic Accidents;The hydrophobic effect of reinforcing glass so that rainwater Automatic-falling, it is so very big that improve driver in the formation safety of rainy day, effectively raise the service life of rain brush;It ensure that the cleanliness factor of glass.

Description

A kind of oil-film removing expelling water agent
Technical field:
Patent of the present invention belongs to cleaning glass art, and in particular to a kind of oil-film removing expelling water agent.
Background technology:
As economic growth and personal income increasingly increase, the usage amount of China's automobile gives each family also in rapid growth Bring the influence of various influences, especially secure context in front yard;It is well known that having hair at night and rainy day traffic accident Raw, when driving, the sight of driver is unintelligible in the rain, and the swing of rain brush also be easy to cause driver distraction, simultaneously Rain brush can not thoroughly clean out the rainwater on glass, still there is residual droplet and blind area;It clears up after rain, the water on glass Accumulate over a long period refraction and effect of convex lens caused by the oil film to be formed on film and glass, and driver is made more to be difficult to see front road conditions clearly And vehicle;And original oil film will appear halation or spot in face sunlight on vehicle glass, have seriously to safe driving Security risk.
Although current market sales of expelling water type bath of glass, expelling water agent have the function of expelling water, still remain with Lower problem:1, the normal use of rain brush can be influenced by being formed by expelling water film, and rain brush is caused interim card, spring and abnormal sound etc. occur Situation, while the adhesive tape in rain brush can be corroded, accelerate the aging of rain brush, reduces the service life that rain rinses device;2, institute's shape At expelling water film can stick the particulate matter in air, so that glass is more easy to dirty, need again to clean glass;3 while existing Expelling water bath of glass, the water on glass can only be removed, original oil film on glass can not be cleaned, i.e., can only be on glass Expelling water film is formed on original oil film surface;Cause expelling water film timeliness shorter, simultaneous oil film can cause driver driving There is situations such as dazzling, halation when driving in vehicle, and there are security risks.
Invention content:
The purpose of the present invention is to provide the oil films on a kind of removable glass, and expelling water film can be formed on glass, drive The good oil-film removing expelling water agent of water effect.
Technical scheme of the present invention discloses a kind of oil-film removing expelling water agent comprising the component of following mass percentage: Waterproofing agent 0.1%-0.2%, organosilan 7.4%-32%, pH adjusting agent 4.5%-5%, lubricant 6%-10.8%, it is non-from Sub- surfactant 2%, remaining is solvent, and the sum of mass percentage of the above component is 100%.
Further, the waterproofing agent is sodium methyl silicate.
Further, the organosilan is tridecafluoro-n-octyltriethoxysilane.
Further, the organosilan includes the component of following mass parts:Hexadecyl trimethoxy silane 0.9-2 Part, 6.5-30 parts of tridecafluoro-n-octyltriethoxysilane;Or include the component of following mass parts:Y- aminopropyl triethoxysilanes 3.5-10 parts, 3.9-22 parts of tridecafluoro-n-octyltriethoxysilane;Or include the component of following mass parts:Cetyl trimethoxy 0.9-2 parts of base silane, 3.5-10 parts of Y- aminopropyl triethoxysilanes, 3-20 parts of tridecafluoro-n-octyltriethoxysilane.
Further, the pH adjusting agent includes the component of following mass parts:0.5-1 parts of sodium hydroxide, phosphatase 24 part.
Further, the lubricant includes the component of following mass parts:4 parts of propylene glycol monomethyl ether, it is 2- that Qula, which leads to X-114, 6.8 part.
Further, the nonionic surfactant is abietyl bis-quaternary ammonium salt cationic surfactant.
Further, the nonionic surfactant includes the component of following mass parts:1 part of fluorocarbon surfactant, 1 part of abietyl bis-quaternary ammonium salt cationic surfactant.
Advantages of the present invention:1, the present invention provides a kind of oil-film removing expelling water agent, wherein component abietyl bi-quaternary ammonium salt sun Oil film can be decomposed peeling by ionic surface active agent from glass, and solvent, which can then dissolve the oil film peeled off, to be washed, can Easily, the oil film on vehicle glass is rapidly removed, avoids driver when driving since dazzling, halation occurs in oil film Situations such as, security risk is eliminated, the effective generation for reducing Traffic Accidents;2, oil-film removing expelling water agent provided by the invention After being applied on glass, wherein component sodium methyl silicate, hexadecyl trimethoxy silane, tridecafluoro-n-octyltriethoxysilane The expelling water film of timeliness length is formd on glass with Y- aminopropyl triethoxysilanes;It is formed by expelling water film and enhances glass Hydrophobic effect so that rainwater Automatic-falling, greatly improve driver the rainy day traffic safety;3, provided by the invention to remove Lead to X-114 components containing the propylene glycol monomethyl ether and Qula for playing lubricating action in oil film expelling water agent;Rain brush is avoided to use When, there is situations such as interim card, spring and abnormal sound, ensure that the normal use of rain brush, while above-mentioned oil-film removing expelling water agent is passed through The neutralization of pH adjusting agent ensure that the agent of oil-film removing expelling water will not corrode the adhesive tape in rain brush, effectively raise rain brush Service life;4, oil-film removing expelling water agent provided by the invention is applied on glass, abietyl bis-quaternary ammonium salt cationic surface-active Agent and fluorocarbon surfactant make the expelling water film surface to be formed smooth, are not easy to adhere to the particulate matter in air, ensure that glass Cleanliness factor.
Specific implementation mode:
Below by embodiment, the present invention is described in further detail.
Embodiment 1:A kind of oil-film removing expelling water agent, component include by mass percentage:Waterproofing agent 0.15%, organosilan 20.2%, pH adjusting agent 4.75%, lubricant 8.4%, nonionic surfactant 2%, remaining is solvent, the matter of the above component It is 100% to measure the sum of percentage composition.
Wherein waterproofing agent is sodium methyl silicate;Organosilan is tridecafluoro-n-octyltriethoxysilane;PH adjusting agent includes The component of following mass parts:0.75 part of sodium hydroxide, phosphatase 24 part;Lubricant includes the component of following mass parts:Propylene glycol monomethyl ether 4 parts, it is 4.4 parts that Qula, which leads to X-114,;Nonionic surfactant includes the component of following mass parts:Fluorocarbon surfactant 1 Part, 1 part of abietyl bis-quaternary ammonium salt cationic surfactant.
Sodium methyl silicate, tridecafluoro-n-octyltriethoxysilane, sodium hydroxide, phosphoric acid, propylene glycol monomethyl ether, Qula are led into X- 114, abietyl bis-quaternary ammonium salt cationic surfactant, fluorocarbon surfactant and solvent mixing, are stirred at normal temperatures to equal It is even, obtain oil-film removing expelling water agent.
Embodiment 2:A kind of oil-film removing expelling water agent, component include by mass percentage:Waterproofing agent 0.15%, organosilan 19.7%, pH adjusting agent 4.75%, lubricant 8.4%, nonionic surfactant 2%, remaining is solvent, the matter of the above component It is 100% to measure the sum of percentage composition.
Wherein waterproofing agent is sodium methyl silicate;Organosilan includes the component of following mass parts:Hexadecyl trimethoxy 1.45 parts of silane, 18.25 parts of tridecafluoro-n-octyltriethoxysilane;PH adjusting agent includes the component of following mass parts:Hydroxide 0.75 part of sodium, phosphatase 24 part;Lubricant includes the component of following mass parts:4 parts of propylene glycol monomethyl ether, it is 4.4 parts that Qula, which leads to X-114,; Nonionic surfactant includes the component of following mass parts:1 part of fluorocarbon surfactant, abietyl bis-quaternary ammonium salt cationic table 1 part of face activating agent.
By sodium methyl silicate, hexadecyl trimethoxy silane, tridecafluoro-n-octyltriethoxysilane, sodium hydroxide, phosphorus Acid, propylene glycol monomethyl ether, Qula lead to X-114, abietyl bis-quaternary ammonium salt cationic surfactant, fluorocarbon surfactant and solvent Mixing, is stirred until homogeneous, obtains oil-film removing expelling water agent at normal temperatures.
Embodiment 3:A kind of oil-film removing expelling water agent, component include by mass percentage:Waterproofing agent 0.15%, organosilan 25%, pH adjusting agent 4.75%, lubricant 8.4%, nonionic surfactant 2%, remaining is solvent, the quality of the above component The sum of percentage composition is 100%.
Wherein waterproofing agent is sodium methyl silicate;Organosilan includes the component of following mass parts:Ten trifluoro octyls, three ethoxy 18.25 parts of base silane, 6.75 parts of Y- aminopropyl triethoxysilanes;PH adjusting agent includes the component of following mass parts:Hydroxide 0.75 part of sodium, phosphatase 24 part;Lubricant includes the component of following mass parts:4 parts of propylene glycol monomethyl ether, it is 4.4 parts that Qula, which leads to X-114,; Nonionic surfactant includes the component of following mass parts:1 part of fluorocarbon surfactant, abietyl bis-quaternary ammonium salt cationic table 1 part of face activating agent.
By sodium methyl silicate, tridecafluoro-n-octyltriethoxysilane, Y- aminopropyl triethoxysilanes, sodium hydroxide, phosphorus Acid, propylene glycol monomethyl ether, Qula lead to X-114, abietyl bis-quaternary ammonium salt cationic surfactant, fluorocarbon surfactant and solvent Mixing, is stirred until homogeneous, obtains oil-film removing expelling water agent at normal temperatures.
Embodiment 4:A kind of oil-film removing expelling water agent, component include by mass percentage:Waterproofing agent 0.15%, organosilan 19.7%, pH adjusting agent 4.75%, lubricant 8.4%, nonionic surfactant 2%, remaining is solvent, the matter of the above component It is 100% to measure the sum of percentage composition.
Wherein waterproofing agent is sodium methyl silicate;Organosilan includes the component of following mass parts:Hexadecyl trimethoxy 1.45 parts of silane, 6.75 parts of Y- aminopropyl triethoxysilanes, 11.5 parts of tridecafluoro-n-octyltriethoxysilane;PH adjusting agent packet Include the component of following mass parts:0.75 part of sodium hydroxide, phosphatase 24 part;Lubricant includes the component of following mass parts:Propylene glycol first 4 parts of ether, it is 4.4 parts that Qula, which leads to X-114,;Nonionic surfactant includes the component of following mass parts:Fluorocarbon surfactant 1 Part, 1 part of abietyl bis-quaternary ammonium salt cationic surfactant.
By sodium methyl silicate, hexadecyl trimethoxy silane, Y- aminopropyl triethoxysilanes, ten trifluoro octyls, three second Oxysilane, sodium hydroxide, phosphoric acid, propylene glycol monomethyl ether, Qula lead to X-114, abietyl bis-quaternary ammonium salt cationic surfactant, Fluorocarbon surfactant and solvent mixing, are stirred until homogeneous, obtain oil-film removing expelling water agent at normal temperatures.
Embodiment 5:A kind of oil-film removing expelling water agent, component include by mass percentage:Waterproofing agent 0.15%, organosilan 19.7%, pH adjusting agent 4.75%, lubricant 8.4%, nonionic surfactant 2%, remaining is solvent, the matter of the above component It is 100% to measure the sum of percentage composition.
Wherein waterproofing agent is sodium methyl silicate;Organosilan includes the component of following mass parts:Hexadecyl trimethoxy 1.45 parts of silane, 6.75 parts of Y- aminopropyl triethoxysilanes, 11.5 parts of tridecafluoro-n-octyltriethoxysilane;PH adjusting agent packet Include the component of following mass parts:0.75 part of sodium hydroxide, phosphatase 24 part;Lubricant includes the component of following mass parts:Propylene glycol first 4 parts of ether, it is 4.4 parts that Qula, which leads to X-114,;Nonionic surfactant is abietyl bis-quaternary ammonium salt cationic surfactant.
By sodium methyl silicate, hexadecyl trimethoxy silane, Y- aminopropyl triethoxysilanes, ten trifluoro octyls, three second Oxysilane, sodium hydroxide, phosphoric acid, propylene glycol monomethyl ether, Qula lead to X-114, abietyl bis-quaternary ammonium salt cationic surfactant It is mixed with solvent, is stirred until homogeneous at normal temperatures, obtains oil-film removing expelling water agent.
Experiment 1:Identical using two stock materials, for the identical glass of size as experimental subjects, two blocks of glass are respectively first Block glass and second block of glass;It is first that above-mentioned two pieces of glass wipings is clean, then on first block of glass and second block of glass in drop A certain amount of machine oil, and the machine oil on first block of glass and second piece of glass surface is smeared uniformly;It then will be extra Grease is wiped from first block of glass and second block of glass, with first block of glass of light-illuminating and second block of glass, finds two pieces There are obvious halation or spot in the surface of glass, and the oil-film removing expelling water agent of the present invention is then sprayed on first block of glass On surface, group is divided into sodium methyl silicate, hexadecyl trimethoxy silane, Y- aminopropyl triethoxysilanes, ten trifluoros are pungent Ethyl triethoxy silicane alkane, sodium hydroxide, phosphoric acid, propylene glycol monomethyl ether, Qula lead to X-114, fluorocarbon surfactant and solvent it is mixed It closes liquid to be sprayed on the surface of second block of glass, after the regular hour, with first block of glass of light-illuminating and second piece of glass Glass finds that either the spot second block of glass that obviously disappears still has the presence of halation or spot to the halation on first piece;It compares Contain component abietyl bis-quaternary ammonium salt cationic surfactant, component abietyl in the oil-film removing expelling water agent of the mixed liquor present invention Bis-quaternary ammonium salt cationic surfactant can fast decoupled be removed from glass by oil film.
Experiment 2:Identical using three stock materials, the identical glass of size is respectively A glass as experimental subjects, three blocks of glass Glass, B glass and C glass;It is first that above-mentioned three pieces of glass wipings is clean, the oil-film removing expelling water agent of the present invention is sprayed on A glass, Group is divided into the common expelling water agent of containing hydrogen silicone oil lotion, nonylphenol polyoxyethylene ether NP-10, phosphoric acid, methanol, triethanolamine and water It is sprayed on B glass, C glass does not smear anything, later by three pieces of glass slant settings, then rinses A glass simultaneously with water Glass, B glass and C glass find that the droplet on A glass and B glass fast moves, are fallen from glass, the water droplet on C glass is complete It is attached on glass entirely, oil-film removing expelling water agent of the invention and common expelling water agent all have expelling water effect;By A glass and B glass Glass is placed on 8 months in the environment of dried and clean and takes out, and by A glass and B glass slant settings, and A glass is rinsed simultaneously with water With B glass, it is found that the droplet on A glass fast moves, fallen from glass, droplet is attached on B glass;With common expelling water Agent compares, sodium methyl silicate, hexadecyl trimethoxy silane in oil-film removing expelling water agent of the invention, ten trifluoro octyls three Ethoxysilane and Y- aminopropyl triethoxysilanes form the expelling water film of timeliness length on glass.
Experiment 3:Prepare the adhesive tape in four rain brush, first cleaned and dried, then adhesive tape is weighed successively, It is impregnated in four parts of oil-film removing expelling water agent produced by the present invention respectively after weighing, is taken out after impregnating 120 hours, clean and dry, Four adhesive tape are weighed successively again, are below weighing result:
It does not impregnate 7.8469g 9.2497g 6.3192g 8.4613g
After immersion 7.8475g 9.2501g 6.3197g 8.4620g
Changing value 0.0006g 0.0004g 0.0005g 0.0007g
Soaking and washing dry after adhesive tape compared with adhesive tape when not impregnating weight have subtle increase, do not occur glue The case where weight is reduced, at the same soaking and washing dry after adhesive tape it is still flexible, be not found showing for embrittlement and hardening As illustrating that there is no corrosivenesses to adhesive tape for neutralization of the oil-film removing expelling water agent of the present invention Jing Guo pH adjusting agent.
Experiment 4:It is identical to prepare three stock materials, for the identical glass of size as experimental subjects, it is 1 that three blocks of glass are numbered respectively Flint glass F, 2 flint glass Fs and 3 flint glass Fs;First above-mentioned three blocks of glass is wiped over clean and is dried at dustless, after drying, in No. 1 glass The oil-film removing expelling water agent that the present invention is smeared on glass, it is sodium methyl silicate, hexadecyl trimethoxy that ingredient is smeared on 2 flint glass Fs Silane, Y- aminopropyl triethoxysilanes, tridecafluoro-n-octyltriethoxysilane, sodium hydroxide, phosphoric acid, propylene glycol monomethyl ether, song The mixed liquor for leading to X-114 and solvent, 3 flint glass Fs is drawn not to apply any substance, 1 flint glass F for being coated with solution and 2 flint glass Fs are led to It crosses pure water to rinse the residual solution on glass well, and is dried at dustless;Until 1 flint glass F, 2 flint glass Fs and No. 3 glass The surface of glass reaches the standard of the dustless soil of no washmarking, then by three pieces of glass slant settings;Then it is derived from right soil to be ground, grind After mill by screening obtain experiment sandy soil, in front of three blocks of glass at a certain distance from put a certain amount of experiment sandy soil respectively, Wind turbine is blowed with equivalent three heap of wind speed pair experiment sandy soil to the direction of glass, by after a certain period of time, closing wind turbine, and from glass Fall down pure water above glass, allows water to flow to lower section above glass with nature and is cleaned to glass, is finally placed on light It is observed under source, it is found that 1 flint glass F and 3 flint glass F surfaces are adhered to without dust particle, there is dust particle adherency on 2 flint glass F surfaces, by This can be found that 2 flint glass Fs for being coated with mixed liquor are easier compared to 1 flint glass F of the oil-film removing expelling water agent for being coated with the present invention Dust particle is adhered to, this is because the component abietyl bis-quaternary ammonium salt cationic surface-active in the oil-film removing expelling water agent of the present invention Agent and fluorocarbon surfactant make the surface of the expelling water film formed on 1 flint glass F more smooth, are not easy to adhere in air Grain object.
The above is merely preferred embodiments of the present invention, be not intended to limit the invention, it is all the present invention spirit and Within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention.

Claims (8)

1. a kind of oil-film removing expelling water agent, which is characterized in that it includes the component of following mass percentage:Waterproofing agent 0.1%- 0.2%, organosilan 7.4%-32%, pH adjusting agent 4.5%-5%, lubricant 6%-10.8%, nonionic surfactant 2%, remaining is solvent, and the sum of mass percentage of the above component is 100%.
2. a kind of oil-film removing expelling water agent according to claim 1, which is characterized in that the waterproofing agent is sodium methyl silicate.
3. a kind of oil-film removing expelling water agent according to claim 1, which is characterized in that the organosilan is ten trifluoro octyls Triethoxysilane.
4. a kind of oil-film removing expelling water agent according to claim 3, which is characterized in that the organosilan includes following quality The component of part:0.9-2 parts of hexadecyl trimethoxy silane, 6.5-30 parts of tridecafluoro-n-octyltriethoxysilane;Or including such as The component of lower mass parts:3.5-10 parts of Y- aminopropyl triethoxysilanes, 3.9-22 parts of tridecafluoro-n-octyltriethoxysilane;Or Include the component of following mass parts:0.9-2 parts of hexadecyl trimethoxy silane, Y- aminopropyl triethoxysilanes 3.5-10 Part, 3-20 parts of tridecafluoro-n-octyltriethoxysilane.
5. a kind of oil-film removing expelling water agent according to claim 1, which is characterized in that the pH adjusting agent includes following quality The component of part:0.5-1 parts of sodium hydroxide, phosphatase 24 part.
6. a kind of oil-film removing expelling water agent according to claim 1, which is characterized in that the lubricant includes following mass parts Component:4 parts of propylene glycol monomethyl ether, it is 2-6.8 parts that Qula, which leads to X-114,.
7. a kind of oil-film removing expelling water agent according to claim 1, which is characterized in that the nonionic surfactant is pine Perfume base bis-quaternary ammonium salt cationic surfactant.
8. a kind of oil-film removing expelling water agent according to claim 7, which is characterized in that the nonionic surfactant includes The component of following mass parts:1 part of fluorocarbon surfactant, 1 part of abietyl bis-quaternary ammonium salt cationic surfactant.
CN201810174598.4A 2018-03-02 2018-03-02 A kind of oil-film removing expelling water agent Pending CN108410354A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109810800A (en) * 2019-02-02 2019-05-28 江苏云瀚股份有限公司 Expelling water light self-emulsifying composition
CN113549353A (en) * 2021-08-06 2021-10-26 车泊喜智能科技(山东)有限公司 Special water repellent agent for intelligent car washing equipment and preparation method

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11130987A (en) * 1997-10-29 1999-05-18 Hideaki Tanaka Snow-removing coating material and method for removing snow
CN106542608A (en) * 2016-11-02 2017-03-29 烟台史密得机电设备制造有限公司 A kind of degreaser for heavy crude heat extraction sewage process
CN107163805A (en) * 2017-05-11 2017-09-15 芜湖扬展新材料科技服务有限公司 A kind of vehicle glass waterproofing agent and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11130987A (en) * 1997-10-29 1999-05-18 Hideaki Tanaka Snow-removing coating material and method for removing snow
CN106542608A (en) * 2016-11-02 2017-03-29 烟台史密得机电设备制造有限公司 A kind of degreaser for heavy crude heat extraction sewage process
CN107163805A (en) * 2017-05-11 2017-09-15 芜湖扬展新材料科技服务有限公司 A kind of vehicle glass waterproofing agent and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109810800A (en) * 2019-02-02 2019-05-28 江苏云瀚股份有限公司 Expelling water light self-emulsifying composition
CN113549353A (en) * 2021-08-06 2021-10-26 车泊喜智能科技(山东)有限公司 Special water repellent agent for intelligent car washing equipment and preparation method

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