CN104130871A - Summer automotive wind-shield cleaning composition and preparation method thereof - Google Patents
Summer automotive wind-shield cleaning composition and preparation method thereof Download PDFInfo
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- CN104130871A CN104130871A CN201410327576.9A CN201410327576A CN104130871A CN 104130871 A CN104130871 A CN 104130871A CN 201410327576 A CN201410327576 A CN 201410327576A CN 104130871 A CN104130871 A CN 104130871A
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Abstract
The invention relates to a summer automotive wind-shield cleaning composition and a preparation method thereof. The composition is obtained by stirring and mixing the following components, by mass: 0.02-0.1% of a nonionic surfactant, 0.05-0.4% of an organosilicon polyether compound, 0.5-2% of water-soluble monohydric alcohol, 0.2-2% of water-soluble polyol ether, 0.04-0.2% of an amine substance, and balance of deionized water, wherein a total amount of the mass percentages of the components is 100%. According to the invention, on a basis that automotive wind-shield glass surface and surrounding metal, rubber, plastic, and paint parts are not damaged, organic dirts on the wind-shield can be effectively removed. Also, the composition can dry fast on the surface of glass, such that driver view is not blocked. Also, the composition leaves no stain after drying.
Description
Technical field
The present invention relates to use cleaning compositions and the preparation method at outer surface of automobile, especially relate to a kind of summer and use cleaning compositions and the preparation method on windshield surface.
Background technology
Along with automobile uses and the development of the maintenance industry of being correlated with, also more and more higher to the requirement of windshield cleaning compositions.For the windshield cleaning compositions that used summer, except will thering is the ability of clean windscreen surface dirt, also need to there is oilness, protection against corrosion, antistatic, rapid drying, do not stay the function of steeping mark.China starts late to the research of windshield cleaning compositions, and integral level is not high.Use windshield glass cleaning compositions in summer inferior not only can damage windshield glass, swollen rubber and plastics, corroding metal parts, stained automobile finish, also can hinder pilot's line of vision and then cause traffic accident to occur when more serious.
In summer, the windshield that is exposed to outside can be accumulated more dirt, and a kind of effectively summer, cleaning glass composition should be able to be removed various dirts, comprised mineral contaminants and organic dirt.Specifically, typical mineral contaminants comprises earth, dust, dust and dirt, gravel, carbon soot particles and acid rain settling; Typical organic dirt comprises grease, pitch, shellac, natural gum and birds droppings.The method that mineral contaminants can adopt physical action (pendulum is scraped in rain brush left and right) to match with chemical action (windshield glass cleaning compositions in summer) is conventionally removed effectively from windscreen surface, but traditional windshield glass cleaning compositions in summer but can not be removed organic dirt from windscreen surface effectively.In recent years, there is the organic dirt that adopts the method for zymin substitution tables surface-active agent to remove windscreen surface, but being subject to enzymic activity changed and causes active decline and enzymic activity to remove the weak impact of ability to shellac with environment and time, the method can not meet the requirement that organic dirt is effectively removed, as WO2000003007 A1; Adopt in addition hydrophobizing agent that windscreen surface is modified to last layer hydrophobic film, and then protection windshield glass, but this method can not effectively be removed the organic dirt of windscreen surface, as US 5753310 A.
Summer, windshield cleaning compositions was in effective cleaning glass surface contaminants, also needed dryly at glass surface as soon as possible, reduced the impact on pilot's line of vision, also should not leave obvious stain mark at dried glass surface.Water is the main component of windshield cleaning compositions in summer, but because the surface tension of water is larger, make water can not wetting and spreading in windscreen surface.In vehicle traveling process, the left and right of rain brush is scraped pendulum and can be caused cleaning compositions in the inhomogeneous dispersion of windscreen surface, and then affects officer's sight line, also can aggravate the friction between rain brush and windscreen surface simultaneously.At present, windshield glass cleaning compositions on domestic market is normally by adding the tensio-active agent of more amount to reduce the surface tension of water, improve the wetting and spreading of cleaning compositions at glass surface, but too much use tensio-active agent, can strengthen on the one hand the viscosity of cleaning compositions, form the thick liquid film of one deck in windscreen surface, the rate of drying of cleaning compositions in windscreen surface slowed down; The use of tensio-active agent more amount can produce glare effect on the other hand, and cleaning compositions can leave obvious white stain mark in windscreen surface after dry, and these all can cause detrimentally affect to officer's driving.Therefore, in meeting oilness, protection against corrosion and antistatic condition, develop there is the clean power of efficient organic dirt, fast glass surface rate of drying and dry after do not stay the windshield cleaning compositions in summer of obvious stain mark to have great significance.
Summary of the invention
In order to solve the technical problem of above-mentioned existence, the invention provides one windshield cleaning compositions in summer, component by following mass percent forms through being uniformly mixed: be made up of nonionogenic tenside 0.02-0.1%, organic silicon polyether compound 0.05-0.4%, water-soluble monohydroxy-alcohol 0.5-2%, water-soluble polyol ether 0.2-2%, amine substance 0.04-0.2% and surplus deionized water, the mass percent sum of each component is 100%.
Further, described nonionogenic tenside is selected from the composition of aliphatic alcohol polyethenoxy (EO) ether and aliphatic alcohol polyethenoxy polyoxypropylene (PO) ether.The chemical formula of fatty alcohol-polyoxyethylene ether is:
Wherein, R is selected from containing one or more in straight chain, half straight chain and the isomery fatty alcohol of 10 to 17 carbon atoms, n(EO mole number) be selected from one or more in 5 to 12.Preferably R is the isomery fatty alcohol containing 13 carbon atoms, and preferably n is one or more in 5 to 9.As Lutensol TO 5, Lutensol TO 6, Lutensol TO 65, Lutensol TO 7 and the Lutensol TO 8 of BASF AG's production; MARLOSOL TA50, MARLOSOL TA60, MARLOSOL TA70, MARLOSOL TA80 and MARLOSOL TA90 that Sasol company produces.
The chemical formula of aliphatic alcohol polyethenoxy polyethenoxy ether is:
Wherein, R is selected from containing one or more in straight chain and half straight-chain fatty alcohol of 10 to 18 carbon atoms, x(EO mole number) be selected from one or more in 4 to 8, y(PO mole number) be selected from one or more in 2 to 9.Preferably R is the straight-chain fatty alcohol containing 10 to 12 carbon atoms, and preferably x is one or more in 6 to 8, and preferably y is one or more in 4 to 9.As MARLOX FK64, MARLOX FK86 and the MARLOX FK69 of the production of Sasol company.
Further, described nonionogenic tenside accounts for the 0.02-0.1% of cleaning compositions, and the mass ratio between fatty alcohol-polyoxyethylene ether and aliphatic alcohol polyethenoxy polyethenoxy ether is 1:0.6-1.6.
Fatty alcohol-polyoxyethylene ether and aliphatic alcohol polyethenoxy polyoxypropylene ether composition have excellent organic dirt removal, wetting and spreading and antifoam performance, organic dirt on cleaning vehicle windshield glass effectively, distinctive antifoam performance has ensured the security of production, transport and use.
Further, described organic silicon polyether compound is selected from one or more in polyether grafting polydimethylsiloxane, polyethers-polydimethylsiloxanecopolymer copolymer and polyether grafting trisiloxanes, as the XIAMETER OFX-0193 of Dow-Corning company, XIAMETER OFX-5211, XIAMETER OFX-5103 and XIAMETER OFX-3667; The Silwet L-77 of Momentive company, Silwet 408, Silwet 806, Silwet ECO and Silwet 560.
Further, described organic silicon polyether compound accounts for the 0.05-0.4% of cleaning compositions.
Organic silicon polyether compound can promote wettability and the spreadability of water, and the surface tension of water is dropped to 25-30 dyn/cm from 72 dyn/cm, makes its liquid layer that is thin layer cover windshield surface.Because the trickling speed of liquid layer is compared fast many of drop, so can obviously accelerate the rate of drying of water on windshield surface.
Further, described water-soluble monohydroxy-alcohol is selected from the monohydroxy-alcohol containing 1 to 3 carbon atom, and wherein, preferred water-soluble monohydroxy-alcohol is one or more in methyl alcohol, ethanol and Virahol.
Further, described water-soluble monohydroxy-alcohol accounts for the 0.5-2% of cleaning compositions.
Further, described water-soluble polyol ether is selected from the polyol ethers containing 3 to 10 carbon atoms.Wherein, preferred water-soluble polyol ether is one or more in ethylene glycol monomethyl ether, ethylene glycol monobutyl ether, diethylene glycol monobutyl ether, propylene glycol monomethyl ether, propylene glycol monobutyl ether, dipropylene glycol monomethyl ether, dipropylene glycol dme and Dipropylene glycol mono-n-butyl Ether.
Further, described water-soluble polyol ether accounts for the 0.2-2% of cleaning compositions.
After the composition of water-soluble monohydroxy-alcohol and water-soluble polyol ether and nonionogenic tenside and organic silicon polyether compound are composite, organic dirt on windshield is had to good solvency action, and the evaporation rate that can also accelerate cleaning compositions so that quick-drying simultaneously.Especially, water-soluble monohydroxy-alcohol and water-soluble polyol ether be combined in cleaning compositions cleaning vehicle windshield glass time effectively reduce stain mark or residue, make glass surface not leave obvious stain mark.
Further, described amine substance is selected from the one in ammoniacal liquor, Monoethanolamine MEA BASF, diethanolamine, trolamine, morpholine, isoquinoline 99.9, tetrahydroglyoxaline, vulkacit H and hexahydroaniline.Preferred amine substance is the one in ammoniacal liquor, morpholine and isoquinoline 99.9.
Further, described amine substance accounts for the 0.04-0.2% of cleaning compositions.
Amine substance can vehicles windshield glass cleaning compositions pH value, make the pH value of cleaning compositions be greater than 7.0, be alkalescence, and then more effectively dissolve organic dirt.Especially, can also effectively suppress the corrosion of aluminium, brass and steel plate galvanized, play the effect of metal inhibitor.
The present invention also provides the preparation method of said composition, comprise the following steps: according to the mass percent of each material, after being mixed, water-soluble monohydroxy-alcohol and deionized water put in reactor, add successively nonionogenic tenside, water-soluble polyol ether and organic silicon polyether compound in reactor, under room temperature, at the uniform velocity stir after 1h, in reactor, add again amine substance, continue to stir until the raw material in reactor mixes.
The composition that preparation method of the present invention prepares preferably uses at outer surface of automobile, more preferably, uses on windshield surface.
Composition of the present invention is by the combination of each component, the nonionogenic tenside being combined by isomerous tridecanol polyoxyethylene ether and straight chain alcohol polyoxyethylene poly-oxygen propylene aether not only has excellent organic dirt cleaning capacity with its special structure, also has the effect of wetting glass surface.The super wettability in the distinctive surface of organic silicon polyether compound can well be by nonionogenic tenside, water-soluble monohydroxy-alcohol and water-soluble polyol ether wetting and spreading at glass surface, they and the contacting of glass surface organic dirt are promoted, improve the clean power of cleaning compositions, simultaneously, it also greatly reduces the surface tension of water, can expedite clean-up composition at the rate of drying of glass surface.The synergy of water-soluble monohydroxy-alcohol and water-soluble polyol ether has reduced the stay stain of cleaning compositions at glass surface effectively, they can dissolve the organic dirt of glass surface together with nonionogenic tenside, improve the clean power of cleaning compositions entirety, meanwhile, the evaporation rate that they can also accelerate cleaning compositions together with organic silicon polyether compound is so that quick-drying.Amine substance has good provide protection to aluminium, brass and the steel plate galvanized of cleaning compositions contact, and its weakly alkaline can contribute to cleaning compositions to dissolve the organic dirt of glass surface simultaneously.Composition of the present invention do not damage windscreen surface and around metal, rubber, plastics and lacquer painting parts prerequisite under, can effectively remove the organic dirt on windshield glass, simultaneously can be dry at glass surface fast, do not stop pilot's line of vision, and do not leave obvious stain mark after dry.And compared with cleaning glass composition conventional in prior art, composition of the present invention have more excellent clean power, faster rate of drying and dry after without the obvious performance of stain mark.
Embodiment
Below in conjunction with embodiment, the present invention will be further described.
Windshield cleaning compositions formula of the present invention is through a large amount of screening experiments, obtained the formula combination of economical rationality, technology excellence.Concrete component and the ratio of embodiment are as shown in table 1.
Component and the ratio of table 1 windshield in summer cleaning compositions
The preparation of standard organic dirt:
Table 2 standard organic dirt component and ratio
According to the project demand preparation standard organic dirt of automobile window glass scavenging solution GB/T 23436-2009 standard.First, the kerosene weighing up in table 2 ratio, No. 1, carnauba wax, GM46 hydraulic efficiency oil, polydimethylsiloxane, oleic acid and gac are mixed and heated to 100 DEG C, and stir, obtain mixing organic dirt 1, then, again the water weighing up in table 2 ratio, morpholine and diatomite are mixed and heated to 90 DEG C, obtain mixing organic dirt 2.In 2min, the mixing organic dirt 1 preparing is slowly joined mix in organic dirt 2 while stirring, continue to stir after 5min, be cooled to room temperature for subsequent use.Before each use, above-mentioned standard organic dirt fully need to be mixed again.
The clean power test of glass surface
First, the sheet glass deionized water that is of a size of 5cm × 2.5cm × 0.2cm is cleaned up, at 100 DEG C, dry, weigh and obtain sheet glass quality m
0.Subsequently, the sheet glass after cleaning up is immersed in to 2s in the above-mentioned standard organic dirt preparing, the standard organic dirt of making is coated in the two sides of sheet glass, at 50 DEG C, after dry 2h, weighs and obtains sheet glass quality m
1.Then, in the clean beaker of 500ml, pour the test test solution of 300ml into, vertically clamp the sheet glass that is coated with standard organic dirt with clip, vertical immersion is in test test solution, under the condition that is 2000rpm at magneton rotating speed, keep 5min, after taking out sheet glass, be dried 1h with deionized water rinsing and at 50 DEG C, weigh and obtain sheet glass quality m
2.Finally, calculate test test solution clean power be:
Rate of drying and the test of dry rear stain mark
The glass surface deionized water scrub that will be of a size of 50cm × 50cm, dries naturally, then with atomizer by the test test solution (m of 10g
test fluid) be ejected into the clean glass surface of vertical placement, effectively projected area (S
spray) be 132cm
2, jet length is 15cm, subsequently with stopwatch record test test solution from be ejected into glass surface to it at the time of glass surface complete drying (t
dry), and the rate of drying v of calculating test test solution is:
Meanwhile, after observation test test solution complete drying in the stain mark situation of glass surface.
Taking embodiment 3 as example, summer of the present invention windshield glass cleaning compositions surface cleaning power, rate of drying and dry after stain mark test-results in table 3.
Table 3 is tested the clean power of test solution glass surface, rate of drying and dry rear stain mark test-results
From table 3, can find, embodiment 3 has excellent clean power and very fast rate of drying, and obviously stain mark of nothing after dry.For the over-all properties that proves windshield glass cleaning compositions in summer of the present invention is better than traditional windshield scavenging solution in summer, further to three kinds summer windshield glass scavenging solution carried out the clean power of contrast, rate of drying and dry after the test of stain mark, comparative test result is as shown in table 3.Test-results show summer of the present invention windshield glass cleaning compositions compare with windshield scavenging solution summer with the Great Wall board of selling on market and tortoise board there is more excellent clean power, faster rate of drying and dry after without the obvious performance of stain mark.
The embodiment of the present invention 3 has been carried out to testing experiment according to the project demand of automobile window glass scavenging solution GB/T 23436-2009 standard and corresponding test method, and specific performance achievement data is as shown in table 4.
Table 4 performance index
By on summer of the present invention windshield glass cleaning compositions carry out metal protection inspection, rubber impact inspection, plastics impact inspection, automobile organic coating film and affect inspection, stability test and hard water consistency check; show that summer of the present invention, windshield glass cleaning compositions had excellent protective value to metal, rubber, plastics and paint film; its good stability simultaneously, stability in hard water is strong.
The present invention has been carried out to exemplary description above in conjunction with the embodiments; obvious realization of the present invention is not restricted to the described embodiments; as long as the various improvement that adopted method design of the present invention and technical scheme to carry out; or without improving, design of the present invention and technical scheme are directly applied to other occasion, all in protection scope of the present invention.
Claims (9)
- One kind summer windshield cleaning compositions, component by following mass percent forms through being uniformly mixed: nonionogenic tenside 0.02-0.1%, organic silicon polyether compound 0.05-0.4%, water-soluble monohydroxy-alcohol 0.5-2%, water-soluble polyol ether 0.2-2%, amine substance 0.04-0.2% and surplus deionized water, the mass percent sum of each component is 100%.
- 2. composition according to claim 1, it is characterized in that, described nonionogenic tenside is selected from the composition of fatty alcohol-polyoxyethylene ether and aliphatic alcohol polyethenoxy polyethenoxy ether, wherein, the mass ratio between fatty alcohol-polyoxyethylene ether and aliphatic alcohol polyethenoxy polyethenoxy ether is 1:0.6-1.6.
- 3. composition according to claim 2, it is characterized in that, described fatty alcohol-polyoxyethylene ether be BASF AG produce Lutensol TO 5, Lutensol TO 6, Lutensol TO 65, Lutensol TO 7 and Lutensol TO 8, and Sasol company produce MARLOSOL TA50, MARLOSOL TA60, MARLOSOL TA70, MARLOSOL TA80 and MARLOSOL TA90 in one or more; Described aliphatic alcohol polyethenoxy polyethenoxy ether be Sasol company produce MARLOX FK64, MARLOX FK86 and MARLOX FK69 in one or more.
- 4. composition according to claim 1, is characterized in that, described organic silicon polyether compound is selected from one or more in polyether grafting polydimethylsiloxane, polyethers-polydimethylsiloxanecopolymer copolymer and polyether grafting trisiloxanes.
- 5. composition according to claim 4, it is characterized in that, described organic silicon polyether compound is XIAMETER OFX-0193, XIAMETER OFX-5211, XIAMETER OFX-5103 and the XIAMETER OFX-3667 of Dow-Corning company, and one or more in the Silwet L-77 of Momentive company, Silwet 408, Silwet 806, Silwet ECO and Silwet 560.
- 6. composition according to claim 1, is characterized in that, described water-soluble monohydroxy-alcohol is selected from the monohydroxy-alcohol containing 1 to 3 carbon atom, and preferred water-soluble monohydroxy-alcohol is one or more in methyl alcohol, ethanol and Virahol.
- 7. composition according to claim 1, it is characterized in that, described water-soluble polyol ether is selected from the polyol ethers containing 3 to 10 carbon atoms, and preferred water-soluble polyol ether is one or more in ethylene glycol monomethyl ether, ethylene glycol monobutyl ether, diethylene glycol monobutyl ether, propylene glycol monomethyl ether, propylene glycol monobutyl ether, dipropylene glycol monomethyl ether, dipropylene glycol dme and Dipropylene glycol mono-n-butyl Ether.
- 8. composition according to claim 1, it is characterized in that, described amine substance is selected from the one in ammoniacal liquor, Monoethanolamine MEA BASF, diethanolamine, trolamine, morpholine, isoquinoline 99.9, tetrahydroglyoxaline, vulkacit H and hexahydroaniline, and preferred amine substance is the one in ammoniacal liquor, morpholine and isoquinoline 99.9.
- 9. according to the preparation method of the composition described in any one in claim 1-8, it is characterized in that, comprise the following steps: according to the mass percent of each material, after being mixed, water-soluble monohydroxy-alcohol and deionized water put in reactor, add successively nonionogenic tenside, water-soluble polyol ether and organic silicon polyether compound in reactor, under room temperature, at the uniform velocity stir after 1h, then add amine substance in reactor, continue to stir until the raw material in reactor mixes.
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104388217A (en) * | 2014-11-19 | 2015-03-04 | 柳州市二和汽车零部件有限公司 | Automobile glass water and preparation method thereof |
| CN104479935A (en) * | 2014-12-30 | 2015-04-01 | 江苏健神生物农化有限公司 | Carbinol cleaning solution for automobile windshield |
| CN104498980A (en) * | 2015-01-08 | 2015-04-08 | 中山市优贝汽车用品科技有限公司 | Automobile surface cleaning composition and preparation method thereof |
| CN105385513A (en) * | 2015-09-15 | 2016-03-09 | 陕西领途信息技术有限公司 | Automobile body cleaning agent |
| CN105400613A (en) * | 2015-09-15 | 2016-03-16 | 陕西领途信息技术有限公司 | Universal vehicle body cleaning agent |
| CN105586168A (en) * | 2015-12-30 | 2016-05-18 | 北京蓝星清洗有限公司 | Water-based shellac-removing cleaning agent and preparation method thereof |
| CN105969534A (en) * | 2016-05-16 | 2016-09-28 | 王景峰 | Automobile glass anti-fogging cleaning aerosol and preparation method thereof |
| EP3128366A1 (en) * | 2015-08-06 | 2017-02-08 | Imaging Solutions AG | Aqueous bath for processing photographic materials |
| CN109985876A (en) * | 2018-01-03 | 2019-07-09 | 蓝思科技（长沙）有限公司 | For stripping the degumming agent of mobile phone glass rear cover gum, the Degumming method and mobile phone glass rear cover of mobile phone glass rear cover gum |
| CN112159736A (en) * | 2020-09-30 | 2021-01-01 | 南京承奕科技有限公司 | Anti-ultraviolet and anti-fouling glass water and preparation method thereof |
| CN112708509A (en) * | 2020-12-24 | 2021-04-27 | 广东好顺欧迪斯科技股份有限公司 | Aerosol type automobile glass solar film adhesive residue cleaning agent and preparation method thereof |
| CN113430057A (en) * | 2021-07-09 | 2021-09-24 | 桂林理工大学 | Automobile windshield cleaning fluid and preparation method thereof |
| CN114149875A (en) * | 2021-12-06 | 2022-03-08 | 广东舒洁环境科技有限公司 | Neutral environment-friendly cleaning agent and preparation method thereof |
| CN114958498A (en) * | 2022-06-21 | 2022-08-30 | 济宁海富光学科技有限公司 | Glass cover plate cleaning agent and cleaning method |
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2014
- 2014-07-10 CN CN201410327576.9A patent/CN104130871A/en active Pending
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| CN104388217A (en) * | 2014-11-19 | 2015-03-04 | 柳州市二和汽车零部件有限公司 | Automobile glass water and preparation method thereof |
| CN104479935A (en) * | 2014-12-30 | 2015-04-01 | 江苏健神生物农化有限公司 | Carbinol cleaning solution for automobile windshield |
| CN104498980A (en) * | 2015-01-08 | 2015-04-08 | 中山市优贝汽车用品科技有限公司 | Automobile surface cleaning composition and preparation method thereof |
| CN104498980B (en) * | 2015-01-08 | 2017-12-05 | 中山市优贝科技股份有限公司 | Car surface Cleasing compositions and preparation method thereof |
| EP3128366A1 (en) * | 2015-08-06 | 2017-02-08 | Imaging Solutions AG | Aqueous bath for processing photographic materials |
| CN105400613A (en) * | 2015-09-15 | 2016-03-16 | 陕西领途信息技术有限公司 | Universal vehicle body cleaning agent |
| CN105385513A (en) * | 2015-09-15 | 2016-03-09 | 陕西领途信息技术有限公司 | Automobile body cleaning agent |
| CN105586168A (en) * | 2015-12-30 | 2016-05-18 | 北京蓝星清洗有限公司 | Water-based shellac-removing cleaning agent and preparation method thereof |
| CN105586168B (en) * | 2015-12-30 | 2018-12-28 | 北京蓝星清洗有限公司 | A kind of aqua type worming gluing cleaning agent and preparation method thereof |
| CN105969534A (en) * | 2016-05-16 | 2016-09-28 | 王景峰 | Automobile glass anti-fogging cleaning aerosol and preparation method thereof |
| CN109985876A (en) * | 2018-01-03 | 2019-07-09 | 蓝思科技（长沙）有限公司 | For stripping the degumming agent of mobile phone glass rear cover gum, the Degumming method and mobile phone glass rear cover of mobile phone glass rear cover gum |
| CN112159736A (en) * | 2020-09-30 | 2021-01-01 | 南京承奕科技有限公司 | Anti-ultraviolet and anti-fouling glass water and preparation method thereof |
| CN112708509A (en) * | 2020-12-24 | 2021-04-27 | 广东好顺欧迪斯科技股份有限公司 | Aerosol type automobile glass solar film adhesive residue cleaning agent and preparation method thereof |
| CN113430057A (en) * | 2021-07-09 | 2021-09-24 | 桂林理工大学 | Automobile windshield cleaning fluid and preparation method thereof |
| CN114149875A (en) * | 2021-12-06 | 2022-03-08 | 广东舒洁环境科技有限公司 | Neutral environment-friendly cleaning agent and preparation method thereof |
| CN114958498A (en) * | 2022-06-21 | 2022-08-30 | 济宁海富光学科技有限公司 | Glass cover plate cleaning agent and cleaning method |
| CN114958498B (en) * | 2022-06-21 | 2024-04-12 | 济宁海富光学科技有限公司 | Glass cover plate cleaning agent and cleaning method |
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Application publication date: 20141105 |