CN108385119A - A kind of metal cleaner and preparation method thereof - Google Patents

A kind of metal cleaner and preparation method thereof Download PDF

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Publication number
CN108385119A
CN108385119A CN201810330089.6A CN201810330089A CN108385119A CN 108385119 A CN108385119 A CN 108385119A CN 201810330089 A CN201810330089 A CN 201810330089A CN 108385119 A CN108385119 A CN 108385119A
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CN
China
Prior art keywords
parts
metal
metal cleaner
starch
silica
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810330089.6A
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Chinese (zh)
Inventor
杨伟帅
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Ruinaijie Electronic Science & Technology New Material Co Ltd
Original Assignee
Suzhou Ruinaijie Electronic Science & Technology New Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Ruinaijie Electronic Science & Technology New Material Co Ltd filed Critical Suzhou Ruinaijie Electronic Science & Technology New Material Co Ltd
Priority to CN201810330089.6A priority Critical patent/CN108385119A/en
Publication of CN108385119A publication Critical patent/CN108385119A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G5/00Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a kind of metal cleaners, in parts by mass, including:25 parts of 30 50 parts of starch, 95 10 parts of ethoxylated dodecyl alcohol, 5 10 parts of neopelex, 5 10 parts of porous silica, 25 parts of silicone oil and antirust agent.The invention also discloses the preparation methods of the metal cleaner.In the metal cleaner of the present invention, it is added to granular starch and silica, rusty stain can be effectively removed.The surfactant adsorbed in starch granules can carry out dissolving removal in cleaning to the greasy dirt of metal surface.The efficient and mild removal to metal surface oil stain and rusty stain is realized using the metal cleaner of the present invention, and secondary abrasion will not be caused to metal after cleaning, and effective protective layer is formed in metal surface.

Description

A kind of metal cleaner and preparation method thereof
Technical field
The present invention relates to cleaning agent technical fields, more particularly to a kind of metal cleaner and preparation method thereof.
Background technology
In machinery and automobile and other industries, it is often necessary to use diesel oil, coal Water Oil Or Gas cleans part as cleaning solution, thus Often remain greasy dirt in metal surface, in addition, metallic surface can increasingly generate the substances such as rusty stain with the time, influences The performance of mechanical equipment and parts, thus usually need to carry out mechanical part or metal surface using metal cleaner clear It washes.Common metal cleaner is mostly liquid-type alkaline cleaner, although instant cleaning performance is pretty good, can be clear The secondary damage to metal surface is caused during washing.Moreover, when needing to remove rusty stain, the amount for consuming cleaning agent is needed It is bigger, and the corrosivity of cleaning agent is also relatively strong.Thus, mild cleaning how is realized as far as possible and metal surface is being cleaned It is formed and is effectively protected with more importantly meaning later.
Invention content
The present invention solves the technical problem of:One, existing metal cleaner is deposited after the washing mostly to metal Surface has the problem of corroding to a certain degree;Two, the problem of rusty stain of metal surface cannot being removed efficiently;Three, after cleaning Metal surface the problem of can not forming protective layer.
In order to solve the above technical problems, one aspect of the present invention is:The present invention provides a kind of metal is clear Lotion, in parts by mass, including:30-50 parts of starch, -9 5-10 parts of ethoxylated dodecyl alcohol, neopelex 5-10 parts, 5-10 parts of porous silica, 2-5 parts of 2-5 parts of silicone oil and antirust agent.
Preferably, the grain size of the starch is 50-100 microns.
Preferably, the aperture of the silica is 100-300 nanometers.
Preferably, the grain size of the silica is 100-500 microns.
Preferably, the antirust agent is benzotriazole or moon silicon substrate phosphoric acid octadecylamine salt.
The preparation method of the metal cleaner, includes the following steps:
1)After mixing by ethoxylated dodecyl alcohol -9 and neopelex, spare;
2)Under stirring conditions, step 1 is added into starch)Mixed liquor, be stirred until homogeneous, starch free dough;
3)Silicone oil is slowly added in the powder of porous silica, is mixed to uniformly without conglomeration;
4)By step 2)With step 3)Obtained material mixing is uniformly added antirust agent and is uniformly mixed afterwards.
The beneficial effects of the invention are as follows:The metal cleaner of the present invention is risen by adding granular starch and silica To the effect for carrying out friction removal to rusty stain, meanwhile, the surfactant adsorbed in starch granules can be in cleaning to gold The greasy dirt of metal surface carries out dissolving removal.In the metal cleaner of the present invention, silicone oil is adsorbed in silica, will be clear When metal surface, silicone oil can be released slowly from silica lotion applications, and smooth in one layer of metal surface formation Oil film, the antirust agent arranged in pairs or groups in being formulated so that metal cleaner of the invention has certain protective after cleaning Energy.
Description of the drawings
Nothing.
Specific implementation mode
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common All other embodiment that technical staff is obtained without making creative work belongs to the model that the present invention protects It encloses.
Embodiment 1-5:
The metal detergent of the present invention, by weight, formula composition is as follows:30-50 parts of starch, lauryl alcohol polyethylene glycol oxide - 9 5-10 parts of ether, 5-10 parts of neopelex, 5-10 parts of porous silica, 2-5 parts of silicone oil and antirust agent 2-5 Part.
It is prepared in accordance with the following steps:
1)After ethoxylated dodecyl alcohol -9 and neopelex are stirred evenly with 20-30 revs/min of speed, It is spare;
2)It is stirred with 5-10 revs/min of speed, step 1 is added into starch)Mixed liquor, be stirred until homogeneous, no dough;
3)It is stirred with 5-10 revs/min of speed, silicone oil is slowly added into the powder of porous silica, is mixed to uniform Without conglomeration;
4)It is stirred with 5-10 revs/min of speed, by step 2)With step 3)Antirust agent is uniformly added in obtained material mixing afterwards It is uniformly mixed.
Cleaning agent Performance Evaluation:
1)The assay method of cleaning rate:The one side of 2*2 centimetres of metal testing plate is uniformly coated into greasy dirt(Machine oil 70%, vaseline 30%), greasy dirt additive amount is 0.3g/ pieces, and the metal testing plate to having smeared greasy dirt is weighed as W1.The cleaning agent of the 5g present invention is weighed, After sheet metal mantle friction 2-3 minutes, washed in water spray.After washing, with distilled water rinse 30s, room temperature transfer to It is W2 that coupon weight is weighed after drying.Cleaning rate calculation formula be cleaning rate=(W1-W2)/0.3.
2)Rustless property appraisal procedure:By 2*2 centimetres of metal testing plate after 5% aqueous citric acid solution impregnates 30min, It is 80% to be placed in humidity, and in the climatic chamber that temperature is 25 degrees Celsius, whether have rusty stain appearance, and remember if being observed every 4h There is the time of rusty stain earliest in record.
The specific formula composition of each embodiment is as shown in table 1:
1 embodiment 1-5 formula components tables of table
The cleaning rate of the metal cleaner of the present invention has reached 80% or more, and occurs again under high humidity environment after cleaning The secondary time got rusty is longer, and metal cleaner of the invention can form the metal after cleaning certain protective action.
Example the above is only the implementation of the present invention is not intended to limit the scope of the invention, every to utilize this hair Equivalent structure or equivalent flow shift made by bright description is applied directly or indirectly in other relevant technology necks Domain is included within the scope of the present invention.

Claims (6)

1. a kind of metal cleaner, which is characterized in that in parts by mass, including:
30-50 parts of starch,
- 9 5-10 parts of ethoxylated dodecyl alcohol,
5-10 parts of neopelex,
5-10 parts of porous silica,
2-5 parts of silicone oil,
2-5 parts of antirust agent.
2. a kind of metal cleaner according to claim 1, which is characterized in that the grain size of the starch is that 50-100 is micro- Rice.
3. a kind of metal cleaner according to claim 1, which is characterized in that the aperture of the silica is 100- 300 nanometers.
4. a kind of metal cleaner according to claim 3, which is characterized in that the grain size of the silica is 100- 500 microns.
5. a kind of metal cleaner according to claim 1, it is characterised in that:The antirust agent is benzotriazole or the moon Silicon substrate phosphoric acid octadecylamine salt.
6. the preparation method of the metal cleaner according to any one of claim 1-5 claims, which is characterized in that Include the following steps:
1)After mixing by ethoxylated dodecyl alcohol -9 and neopelex, spare;
2)Under stirring conditions, step 1 is added into starch)Mixed liquor, be stirred until homogeneous, starch free dough;
3)Silicone oil is slowly added in the powder of porous silica, is mixed to uniformly without conglomeration;
4)By step 2)With step 3)Obtained material mixing is uniformly added antirust agent and is uniformly mixed afterwards.
CN201810330089.6A 2018-04-13 2018-04-13 A kind of metal cleaner and preparation method thereof Pending CN108385119A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810330089.6A CN108385119A (en) 2018-04-13 2018-04-13 A kind of metal cleaner and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810330089.6A CN108385119A (en) 2018-04-13 2018-04-13 A kind of metal cleaner and preparation method thereof

Publications (1)

Publication Number Publication Date
CN108385119A true CN108385119A (en) 2018-08-10

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810330089.6A Pending CN108385119A (en) 2018-04-13 2018-04-13 A kind of metal cleaner and preparation method thereof

Country Status (1)

Country Link
CN (1) CN108385119A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110284143A (en) * 2019-08-14 2019-09-27 重庆市联坤科技开发有限责任公司 A kind of metal cleaner
CN113862689A (en) * 2021-09-26 2021-12-31 南通科星化工股份有限公司 Efficient metal cleaning agent and preparation method thereof
CN114107999A (en) * 2021-11-29 2022-03-01 厦门普诺尔新材料科技有限公司 Plane grinding cleaning agent and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104313612A (en) * 2014-09-12 2015-01-28 湖州鑫隆镀膜科技有限公司 Water-based metal cleaning agent convenient for workpiece oil removal
CN105463478A (en) * 2015-11-30 2016-04-06 芜湖成德龙过滤设备有限公司 Metal cleaner material composition and preparation method and application of metal cleaner
CN106283089A (en) * 2016-08-25 2017-01-04 仇颖超 A kind of preparation method of solid-liquid biphase mechanical metal abluent
CN106319536A (en) * 2016-08-08 2017-01-11 青岛友诚高新技术有限公司 Industrial metal cleaner and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104313612A (en) * 2014-09-12 2015-01-28 湖州鑫隆镀膜科技有限公司 Water-based metal cleaning agent convenient for workpiece oil removal
CN105463478A (en) * 2015-11-30 2016-04-06 芜湖成德龙过滤设备有限公司 Metal cleaner material composition and preparation method and application of metal cleaner
CN106319536A (en) * 2016-08-08 2017-01-11 青岛友诚高新技术有限公司 Industrial metal cleaner and preparation method thereof
CN106283089A (en) * 2016-08-25 2017-01-04 仇颖超 A kind of preparation method of solid-liquid biphase mechanical metal abluent

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110284143A (en) * 2019-08-14 2019-09-27 重庆市联坤科技开发有限责任公司 A kind of metal cleaner
CN113862689A (en) * 2021-09-26 2021-12-31 南通科星化工股份有限公司 Efficient metal cleaning agent and preparation method thereof
CN113862689B (en) * 2021-09-26 2022-10-25 南通科星化工股份有限公司 Efficient metal cleaning agent and preparation method thereof
CN114107999A (en) * 2021-11-29 2022-03-01 厦门普诺尔新材料科技有限公司 Plane grinding cleaning agent and preparation method thereof

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Application publication date: 20180810