CN106947979A - A kind of magnadure cleaning agent - Google Patents
A kind of magnadure cleaning agent Download PDFInfo
- Publication number
- CN106947979A CN106947979A CN201710173780.3A CN201710173780A CN106947979A CN 106947979 A CN106947979 A CN 106947979A CN 201710173780 A CN201710173780 A CN 201710173780A CN 106947979 A CN106947979 A CN 106947979A
- Authority
- CN
- China
- Prior art keywords
- cleaning agent
- combination
- cleaning
- mass fraction
- magnadure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/14—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
- C23G1/22—Light metals
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
The present invention relates to a kind of magnadure cleaning agent, the composition of the cleaning agent includes alkalescent material, surfactant, cleaning additive, corrosion inhibiter, environmentally friendly solvent and water, wherein the surfactant includes isomery alcohol ether and APG.The cleaning agent cleaning performance is good, and alkalescent, the corrosivity to magnadure is low, and easily biological-degradable is environment-friendly, and harm to the human body is small.
Description
Technical field
The invention belongs to cleaning agent technical field, more particularly to a kind of magnadure cleaning agent.
Background technology
With the popularization and development of the electronic products such as smart mobile phone, panel computer, motion bracelet, magnadure is due to light weight
The characteristics of intensity is big, is gradually widely used.But in process of metal working, processing workpiece can adsorb some greasy dirts,
The foreign matters such as dust, this can be had a huge impact to follow-up technique, it is therefore desirable to the cleaning of oil removing, scale removal is carried out to it
Journey.
Aqueous cleaning agent in the market, is used for cleaning ferrous metal, it is adaptable to which the cleaning agent of magnadure is very mostly
Few, people mainly clean magnadure using degreasing powder.Degreasing powder is mostly using highly basic, meeting such as NaOH or potassium hydroxide
Magnadure workpiece is caused to corrode equivalent damage, and cleaning performance is poor, speed is slow, it is impossible to meet wanting for work pieces process technique
Ask.
The A of CN 104947126 disclose a kind of magnesium alloy cleaning agent, the magnesium alloy cleaning agent, by the group of following concentration
It is grouped into：50~120g/L of alkali, 5~50g/L of additive, 1~5g/L of complexing agent, 1~5g/L of wetting agent, surplus is water.The hair
There is no strong acid, chromate and fluoride in bright component, environment will not be polluted, and magnesium alloy will not be caused
Corrosion, on the basis of being cleaned up thoroughly to magnesium alloy, will not cause damage to magnesium alloy.But, in above-mentioned cleaning agent
Alkali is selected from NaOH and/or potassium hydroxide, and equally environment can be impacted, and highly basic can produce corrosion to aluminium, therefore
It is not suitable for the cleaning of magnadure.
The A of CN 104451709 disclose a kind of aqueous cleaning agent of surface of magnesium aluminium alloy, the composition bag of the cleaning agent
Include：Surfactant A O90 2.5-3.0g/L, surfactant SDBS 2.0-2.5g/L, surfactant NP-10 2.0-
2.2g/L, builder 0.5-0.6g/L, composite corrosion inhibitor 0.8-1g/L, solvent is water.Contain three kinds of surfaces in the cleaning agent
Activating agent, but simply the simple effect by three kinds of surfactants is superimposed, and without alkaline matter, cleaning performance is general,
Cleaning agent consumption is big.
Therefore, a kind of new magnadure cleaning agent is worked out particularly significant.
The content of the invention
The technical problem existed for prior art, the present invention provides a kind of magnadure cleaning agent, and the cleaning agent is clear
Wash effect good, alkalescent, the corrosivity to magnadure is low, easily biological-degradable is environment-friendly, and harm to the human body is small.
To reach the effect above, the present invention uses following technical scheme：
The present invention provides a kind of magnadure cleaning agent, and the composition of the cleaning agent includes alkalescent material, surface-active
Agent, cleaning additive, corrosion inhibiter, environmentally friendly solvent and water, wherein the surfactant includes isomery alcohol ether and APG.
As currently preferred technical scheme, the mass fraction for stating surfactant is 8~20%, such as 8%, 9%,
10%th, 11%, 12%, 13%, 14%, 15%, 16%, 17%, 18%, 19% or 20% etc., it is not limited to cited
Numerical value, other unrequited numerical value are equally applicable in the number range, preferably 10~15%.
Preferably, the isomery alcohol ether and the mass ratio of the APG are (1.5~1.8):1, such as 1.5:1、1.55:
1、1.6:1、1.65:1、1.7:1、1.75:1 or 1.8:1 etc., it is not limited to cited numerical value, in the number range its
His unrequited numerical value is equally applicable, and more preferably 1.6:1.
Both surfactants act synergistically isomery alcohol ether with APG, mixed monomolecular adsorption layer are formed, molten
Liquid is internally formed mixed micelle, improves the binding ability of surfactant and greasy dirt, so as to improve the cleaning energy of cleaning agent
Power.With the addition of APG, the surface tension of system is gradually reduced, when the addition of APG is more than 5%, system
Surface tension variations less, and excessive APG can make cleaning agent foam excessive on the contrary, the rinsing of influence later stage, thus this
The addition for inventing preferred APG is no more than 5%.
Simultaneously as cleaning agent of the prior art would generally add highly basic, because highly basic can occur instead with vegetable and animals oils
The effect degreased should be improved, and APG of the present invention and isomery alcohol ether are used in conjunction with, and improve the energy of cleaning agent degreasing
Power, thus can replace highly basic, it is to avoid corrosion of the highly basic to magnadure using weak base.When the addition of isomery alcohol ether is
At 1.5~1.8 times of APG, the surface tension of cleaning agent is minimum, and cleaning performance is optimal, and its clean effect can replace completely
The effect of highly basic.
As currently preferred technical scheme, the mass fraction of the alkalescent material is 5~15%, such as 5%, 6%,
7%th, 8%, 9%, 10%, 11%, 12%, 13%, 14% or 15% etc., it is not limited to cited numerical value, the numerical value
In the range of other unrequited numerical value it is equally applicable, preferably 8~12%.
Preferably, the mass fraction of the cleaning additive be 5~15%, such as 5%, 6%, 7%, 8%, 9%, 10%,
11%th, 12%, 13%, 14% or 15% etc., it is not limited to other are unrequited in cited numerical value, the number range
Numerical value is equally applicable, and more preferably 8~12%.
Preferably, the mass fraction of the corrosion inhibiter be 1~5%, such as 1%, 1.5%, 2%, 2.5%, 3%, 3.5%,
4%th, 4.5% or 5% etc., it is not limited to other unrequited numerical value are equally fitted in cited numerical value, the number range
With.
Preferably, the mass fraction of the environmentally friendly solvent be 1~10%, such as 1%, 2%, 3%, 4%, 5%, 6%, 7%,
8%th, 9% or 10% etc., it is not limited to other unrequited numerical value are equally fitted in cited numerical value, the number range
With more preferably 3~8%.
As currently preferred technical scheme, the composition of the cleaning agent includes as mass fraction：
As currently preferred technical scheme, the composition of the cleaning agent includes as mass fraction：
As currently preferred technical scheme, the composition of the cleaning agent includes as mass fraction：
As currently preferred technical scheme, the alkalescent material includes diethylamine, triethylamine, monoethanolamine, diethyl
Any one in hydramine or dicyclohexyl amine or at least two combination, the combination is typical but non-limiting example has：Diethyl
The combination of amine and triethylamine, the combination of diethylamine and monoethanolamine, combination, diethanol amine and two hexamethylenes of monoethanolamine and diethanol amine
The combination of amine, the combination or diethylamine of diethylamine and dicyclohexyl amine, the combination of diethanol amine and dicyclohexyl amine etc..
As currently preferred technical scheme, the isomery alcohol ether includes isomerous tridecanol polyoxyethylene ether, isooctanol
Any one in APEO or heterogeneous ten alcohol polyoxyethylene ether or at least two combination, the combination are typical but unrestricted
Property example has combination, isooctanol polyethoxylate and the isomery ten of isomerous tridecanol polyoxyethylene ether and isooctanol polyethoxylate
Combination, the combination of isomerous tridecanol polyoxyethylene ether and heterogeneous ten alcohol polyoxyethylene ether or the isomerous tridecanol of alcohol APEO
Combination of APEO, isooctanol polyethoxylate and heterogeneous ten alcohol polyoxyethylene ether etc..
Preferably, the APG includes any one in APG081, APG1214, APG10 or APG06 or at least two
The combination planted, the combination typical case but non-limiting examples have APG081 and APG1214 combination, APG1214 and APG10 group
Combination, APG06 and APG081 combination or APG081, APG1214 and APG10 combination of conjunction, APG10 and APG06 etc..
As currently preferred technical scheme, the cleaning additive includes potassium silicate, metasilicate pentahydrate sodium, gluconic acid
Any one in sodium or potassium pyrophosphate or at least two combination, the combination is typical but non-limiting examples have：Potassium silicate and
The combination of metasilicate pentahydrate sodium, the combination of metasilicate pentahydrate sodium and sodium gluconate, the combination of sodium gluconate and potassium pyrophosphate,
The combination or potassium silicate of potassium silicate and potassium pyrophosphate, the combination of metasilicate pentahydrate sodium and sodium gluconate etc..
Preferably, complexing agent is contained in the cleaning additive.
Preferably, the mass fraction of the complexing agent be 3~7%, such as 3%, 3.5%, 4%, 4.5%, 5%, 5.5%,
6%th, 6.5% or 7% etc., it is not limited to other unrequited numerical value are equally fitted in cited numerical value, the number range
With.
Preferably, the complexing agent includes tetrasodium ethylenediamine tetraacetate, the sodium of 1-hydroxy ethylidene-1,1-diphosphonic acid four or hydroxy ethylidene two
Any one in phosphonic acids disodium or at least two combination, the combination is typical but non-limiting examples have：Ethylenediamine tetra-acetic acid
The combination of four sodium and the sodium of 1-hydroxy ethylidene-1,1-diphosphonic acid four, the combination of the sodium of 1-hydroxy ethylidene-1,1-diphosphonic acid four and 1-hydroxy ethylidene-1,1-diphosphonic acid disodium,
The combination of tetrasodium ethylenediamine tetraacetate and 1-hydroxy ethylidene-1,1-diphosphonic acid disodium or tetrasodium ethylenediamine tetraacetate, 1-hydroxy ethylidene-1,1-diphosphonic acid four
Combination of sodium and 1-hydroxy ethylidene-1,1-diphosphonic acid disodium etc..
As currently preferred technical scheme, the corrosion inhibiter is included in thiocarbamide, heterocyclic amine, sodium molybdate or sodium metasilicate
Any one or at least two combination, combination typical case but non-limiting examples have：The combination of thiocarbamide and heterocyclic amine, heterocycle
The combination of amine and sodium molybdate, the combination of sodium molybdate and sodium metasilicate, combination or thiocarbamide, the heterocyclic amine and molybdenum of sodium metasilicate and thiocarbamide
Combination of sour sodium etc..
Preferably, the environmentally friendly solvent includes isopropanol, propane diols, propylene glycol monomethyl ether, glycol tertiary butyl ether or dipropyl two
Any one in alcohol methyl ether or at least two combination, the combination is typical but non-limiting examples have：Isopropanol and propane diols
Combination, the combination of propane diols and propylene glycol monomethyl ether, the combination of propylene glycol monomethyl ether and glycol tertiary butyl ether, glycol tertiary butyl ether and
The combination of dipropylene glycol methyl ether or the combination of propane diols, propylene glycol monomethyl ether and glycol tertiary butyl ether etc..
Compared with prior art, the present invention at least has the advantages that：
(1) a kind of magnadure cleaning agent for providing of the present invention, the cleaning agent is using isomery alcohol ether and APG
Synergy, obtains excellent scourability, i.e., the water droplet angle of the surface of magnesium aluminium alloy after being cleaned using the cleaning agent is existed
It is minimum up to 60 degree less than 90 degree；
(2) a kind of magnadure cleaning agent that the present invention is provided, using the magnadure after cleaning agent cleaning and clearly
Mass change before washing is -0.01g, shows that cleaning agent is minimum to the corrosivity of magnadure；
(2) a kind of magnadure cleaning agent that the present invention is provided, the cleaning agent weak base high efficiency, easily biological-degradable, ring
Border is friendly and harmless.
Embodiment
Specific embodiment of the invention part, which provides a kind of composition of the cleaning agent, includes alkalescent material, surface-active
Agent, cleaning additive, corrosion inhibiter, environmentally friendly solvent and water, wherein the surfactant includes isomery alcohol ether and APG.
For ease of understanding the present invention, it is as follows that the present invention enumerates embodiment.Those skilled in the art are it will be clearly understood that the implementation
Example is only to aid in understanding the present invention, is not construed as the concrete restriction to the present invention.
Embodiment 1
A kind of magnadure cleaning agent, includes according to the composition of cleaning agent described in mass fraction meter：
Embodiment 2
A kind of magnadure cleaning agent, includes according to the composition of cleaning agent described in mass fraction meter：
Embodiment 3
A kind of magnadure cleaning agent, includes according to the composition of cleaning agent described in mass fraction meter：
Embodiment 4
A kind of magnadure cleaning agent, includes according to the composition of cleaning agent described in mass fraction meter：
Embodiment 5
A kind of magnadure cleaning agent, includes according to the composition of cleaning agent described in mass fraction meter：
Embodiment 6
A kind of magnadure cleaning agent, includes according to the composition of cleaning agent described in mass fraction meter：
Embodiment 7
A kind of magnadure cleaning agent, includes according to the composition of cleaning agent described in mass fraction meter：
Embodiment 8
A kind of magnadure cleaning agent, includes according to the composition of cleaning agent described in mass fraction meter：
Comparative example 1
A kind of magnadure cleaning agent, the isomerous tridecanol polyoxyethylene ether except APG-0810 is the quality such as to be replaced with to
Outside, other conditions are same as Example 1.
Comparative example 2
A kind of magnadure cleaning agent, the APG-0810 except isomerous tridecanol polyoxyethylene ether is the quality such as to be replaced with to
Outside, other conditions are same as Example 1.
Comparative example 3
A kind of magnadure cleaning agent, in addition to being both free of isomerous tridecanol polyoxyethylene ether or being free of APG-0810, its
His condition is same as Example 1.
Comparative example 4
Do not have alloy cleaning agent using described in embodiment 1 in the A of CN 104947126, be made up of the component of following concentration：
NaOH 70g/L, sodium phosphate 20g/L, sodium citrate 2g/L, neopelex 2g/L, APES
3g/L, solvent is water.
The surface of magnesium aluminium alloy of unified specification is carried out using the cleaning agent described in embodiment 1-8 and comparative example 1-3 clear
Wash, and water droplet angle test is carried out to the surface after cleaning；Using GB HGT3523-2008 specification, to the magnalium before and after cleaning
Alloy mass change is tested, and test result is shown in Table 1.
Table 1
| Project | Water droplet angle/degree | Mass change/g |
| Embodiment 1 | 61 | -0.01 |
| Embodiment 2 | 66 | -0.01 |
| Embodiment 3 | 59 | -0.01 |
| Embodiment 4 | 61 | -0.01 |
| Embodiment 5 | 60 | -0.01 |
| Embodiment 6 | 62 | -0.01 |
| Embodiment 7 | 71 | -0.01 |
| Embodiment 8 | 75 | -0.01 |
| Comparative example 1 | 91 | -0.01 |
| Comparative example 2 | 93 | -0.01 |
| Comparative example 3 | 99 | -0.01 |
| Comparative example 4 | 91 | -0.25 |
From embodiment 1-8 test as can be seen that using the magnalium after magnadure cleaning agent of the present invention cleaning
The water droplet angle of alloy surface is less than 90 degree, and minimum up to 60 degree, the metal surface of cleaning is hydrophily, therefore contact angle is less than 90
Degree, shows good hydrophilic property, it was demonstrated that the surface of magnesium aluminium alloy cleanliness factor after magnadure cleaning agent cleaning of the present invention is good, and
Noresidue.Isomery alcohol ether and the mass ratio of persistent ailment glucosides are 1 in embodiment 7:1, less than 1.5:1, and isomery alcohol ether in embodiment 8
Mass ratio with persistent ailment glucosides is 10:3, it is more than, 1.8:1, the table of the magnadure after cleaning agent cleaning described in embodiment 7 and 8
The contact angle in face is 71 degree and 75 degree, and cleaning performance has declined compared with embodiment 1-6.
Cleaning agent described in comparative example 1 of the present invention is addition isomery alcohol ether, and comparative example 2 is not added with APG, and comparative example 3 is
APG is also not added with for addition isomery alcohol ether, the water droplet of the magnesium-aluminum metal performance after cleaning agent cleaning described in comparative example 1-3
Angle is all higher than 90 degree, and comparative example 4 uses a kind of magnesium alloy cleaning agent of the prior art, the surface of magnesium aluminium alloy after cleaning
Contact angle page is more than 90 degree, and there are greasy residues on the magnesium-aluminum metal surface after comparative example 1-4 cleanings.Magnesium after the cleaning of comparative example 4
The Mass lost of aluminium alloy 0.25g, and embodiment 1-8 and comparative example 1-3 only reduces 0.01g, it was demonstrated that it is clear described in comparative example 4
Lotion is corrosive to magnadure, and embodiment 1-8 and comparative example 1-3 is minimum to the corrosivity of magnadure.
Applicant states that the present invention illustrates detailed process equipment and the technological process of the present invention by above-described embodiment,
But the invention is not limited in above-mentioned detailed process equipment and technological process, that is, do not mean that the present invention has to rely on above-mentioned detailed
Process equipment and technological process could be implemented.Person of ordinary skill in the field it will be clearly understood that any improvement in the present invention,
Addition, selection of concrete mode of equivalence replacement and auxiliary element to each raw material of product of the present invention etc., all fall within the present invention's
Within the scope of protection domain and disclosure.
Claims (10)
1. a kind of magnadure cleaning agent, it is characterised in that the composition of the cleaning agent includes alkalescent material, surface-active
Agent, cleaning additive, corrosion inhibiter, environmentally friendly solvent and water, wherein the surfactant includes isomery alcohol ether and APG.
2. cleaning agent according to claim 1, it is characterised in that the mass fraction of the surfactant is 8~20%,
Preferably 10~15%；
Preferably, the isomery alcohol ether and the mass ratio of the APG are (1.5~1.8):1, more preferably 1.6:
1。
3. cleaning agent according to claim 1 or 2, it is characterised in that the mass fraction of the alkalescent material is 5~
15%, preferably 8~12%；
Preferably, the mass fraction of the cleaning additive is 5~15%, more preferably 8~12%；
Preferably, the mass fraction of the corrosion inhibiter is 1~5%；
Preferably, the mass fraction of the environmentally friendly solvent is 1~10%, more preferably 3~8%.
4. the cleaning agent according to claim any one of 1-3, it is characterised in that the group of the cleaning agent as mass fraction
Into including：
5. the cleaning agent according to claim any one of 1-4, it is characterised in that the group of the cleaning agent as mass fraction
Into including：
6. the cleaning agent according to claim any one of 1-5, it is characterised in that the group of the cleaning agent as mass fraction
Into including：
7. the cleaning agent according to claim any one of 1-6, it is characterised in that the alkalescent material include diethylamine,
Any one in triethylamine, monoethanolamine, diethanol amine or dicyclohexyl amine or at least two combination.
8. the cleaning agent according to claim any one of 1-7, it is characterised in that the isomery alcohol ether includes isomerous tridecanol
Any one in APEO, isooctanol polyethoxylate or heterogeneous ten alcohol polyoxyethylene ether or at least two combination；
Preferably, the APG includes any one in APG081, APG1214, APG10 or APG06 or at least two
Combination.
9. the cleaning agent according to claim any one of 1-8, it is characterised in that the cleaning additive includes potassium silicate, five
Any one in water sodium metasilicate, sodium gluconate or potassium pyrophosphate or at least two combination；
Preferably, complexing agent is contained in the cleaning additive；
Preferably, the mass fraction of the complexing agent is 3~7%；
Preferably, the complexing agent includes tetrasodium ethylenediamine tetraacetate, the sodium of 1-hydroxy ethylidene-1,1-diphosphonic acid four or 1-hydroxy ethylidene-1,1-diphosphonic acid
Any one in disodium or at least two combination.
10. the cleaning agent according to claim any one of 1-9, it is characterised in that the corrosion inhibiter includes thiocarbamide, heterocycle
Any one in amine, sodium molybdate or sodium metasilicate or at least two combination；
Preferably, the environmentally friendly solvent includes isopropanol, propane diols, propylene glycol monomethyl ether, glycol tertiary butyl ether or DPG first
Any one in ether or at least two combination.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710173780.3A CN106947979B (en) | 2017-03-22 | 2017-03-22 | Magnesium-aluminum alloy cleaning agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710173780.3A CN106947979B (en) | 2017-03-22 | 2017-03-22 | Magnesium-aluminum alloy cleaning agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106947979A true CN106947979A (en) | 2017-07-14 |
| CN106947979B CN106947979B (en) | 2020-08-14 |
Family
ID=59473384
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710173780.3A Active CN106947979B (en) | 2017-03-22 | 2017-03-22 | Magnesium-aluminum alloy cleaning agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106947979B (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107177856A (en) * | 2017-07-27 | 2017-09-19 | 贾春燕 | A kind of aluminum fin-stock cleaning agent and cleaning method |
| CN108613782A (en) * | 2018-04-13 | 2018-10-02 | 华阳新兴科技（天津）集团有限公司 | A kind of antirust leak-checking agent and preparation method thereof |
| CN109056025A (en) * | 2018-09-13 | 2018-12-21 | 巩义市欧洁源环保技术服务有限公司 | A kind of aluminium alloy extrusions differential arc oxidation pre-treating method |
| CN109136953A (en) * | 2018-09-13 | 2019-01-04 | 巩义市欧洁源环保技术服务有限公司 | A kind of aluminium alloy extrusions differential arc oxidation pre-treatment cleaning agent and preparation method thereof |
| CN109680283A (en) * | 2019-01-16 | 2019-04-26 | 惠州市阿特斯润滑技术有限公司 | Magnesium alloy cleaning agent and its cleaning method |
| CN110240977A (en) * | 2019-06-28 | 2019-09-17 | 天津市博仁易洁物业服务有限公司 | A kind of multifunction detergent and preparation method thereof |
| CN111500375A (en) * | 2020-05-19 | 2020-08-07 | 兴核科学研究(福建)有限责任公司 | Radioactive foam detergent and preparation method thereof |
| CN112267121A (en) * | 2020-09-18 | 2021-01-26 | 广州亦盛环保科技有限公司 | Cleaning agent and application thereof |
| CN112808684A (en) * | 2020-12-30 | 2021-05-18 | 蓝思科技股份有限公司 | Method for dewaxing nickel-plated metal product |
| CN113881943A (en) * | 2021-10-28 | 2022-01-04 | 广东凯盟钝化防锈技术有限公司 | Aluminum material alkaline cleaning agent and preparation method thereof |
| CN114318353A (en) * | 2021-12-27 | 2022-04-12 | 广东红日星实业有限公司 | Ash remover and preparation method and application thereof |
| CN115197792A (en) * | 2022-08-19 | 2022-10-18 | 广州亦盛环保科技有限公司 | Water-based cleaning agent and preparation method and application thereof |
| CN115466964A (en) * | 2022-09-15 | 2022-12-13 | 杭州和韵科技有限公司 | All-in-one cleaning agent for aluminum and aluminum alloy precision parts and application thereof |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101705496A (en) * | 2009-11-16 | 2010-05-12 | 南通飞拓生物科技有限公司 | Environment-friendly metal cleaner |
| CN101928950A (en) * | 2010-09-01 | 2010-12-29 | 常州市永丰油脂厂 | Metal cleaner used for coating production line and preparation method thereof |
| CN102912368A (en) * | 2012-09-05 | 2013-02-06 | 昆山市源丰铝业有限公司 | Aluminum cleaning agent |
| CN103469237A (en) * | 2013-09-25 | 2013-12-25 | 太仓市微贯机电有限公司 | Metal oil contamination cleaner |
| CN104278283A (en) * | 2014-09-25 | 2015-01-14 | 巢湖广丰金属制品有限公司 | Special water-based cleaning agent for aluminum magnesium alloy |
| CN105040013A (en) * | 2015-07-24 | 2015-11-11 | 苏州华冲精密机械有限公司 | Environment-friendly and efficient cleaning process for metal parts |
| CN105296190A (en) * | 2015-11-20 | 2016-02-03 | 上海斯麦尔日化有限公司 | Detergent composition |
| CN105401159A (en) * | 2015-12-08 | 2016-03-16 | 刘方旭 | Aluminum alloy surface antirust cleaning agent composition |
| CN106221964A (en) * | 2016-07-21 | 2016-12-14 | 南京信息工程大学 | A kind of environment-friendly cleaning agent and preparation method thereof |
-
2017
- 2017-03-22 CN CN201710173780.3A patent/CN106947979B/en active Active
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101705496A (en) * | 2009-11-16 | 2010-05-12 | 南通飞拓生物科技有限公司 | Environment-friendly metal cleaner |
| CN101928950A (en) * | 2010-09-01 | 2010-12-29 | 常州市永丰油脂厂 | Metal cleaner used for coating production line and preparation method thereof |
| CN102912368A (en) * | 2012-09-05 | 2013-02-06 | 昆山市源丰铝业有限公司 | Aluminum cleaning agent |
| CN103469237A (en) * | 2013-09-25 | 2013-12-25 | 太仓市微贯机电有限公司 | Metal oil contamination cleaner |
| CN104278283A (en) * | 2014-09-25 | 2015-01-14 | 巢湖广丰金属制品有限公司 | Special water-based cleaning agent for aluminum magnesium alloy |
| CN105040013A (en) * | 2015-07-24 | 2015-11-11 | 苏州华冲精密机械有限公司 | Environment-friendly and efficient cleaning process for metal parts |
| CN105296190A (en) * | 2015-11-20 | 2016-02-03 | 上海斯麦尔日化有限公司 | Detergent composition |
| CN105401159A (en) * | 2015-12-08 | 2016-03-16 | 刘方旭 | Aluminum alloy surface antirust cleaning agent composition |
| CN106221964A (en) * | 2016-07-21 | 2016-12-14 | 南京信息工程大学 | A kind of environment-friendly cleaning agent and preparation method thereof |
Non-Patent Citations (4)
| Title |
|---|
| 刘程等: "《表面活性剂应用手册》", 30 September 2004, 化学工业出版社 * |
| 古蒙蒙等: "高效绿色多功能水基清洗剂的研制", 《化工进展》 * |
| 杨岩等: "环保型金属清洗剂的研制及其清洗效果", 《材料保护》 * |
| 钱苗根等: "《材料表面技术及其应用手册》", 30 November 1998, 机械工业出版社 * |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107177856A (en) * | 2017-07-27 | 2017-09-19 | 贾春燕 | A kind of aluminum fin-stock cleaning agent and cleaning method |
| CN108613782A (en) * | 2018-04-13 | 2018-10-02 | 华阳新兴科技（天津）集团有限公司 | A kind of antirust leak-checking agent and preparation method thereof |
| CN108613782B (en) * | 2018-04-13 | 2020-06-05 | 华阳新兴科技（天津）集团有限公司 | Antirust leak detector and preparation method thereof |
| CN109056025A (en) * | 2018-09-13 | 2018-12-21 | 巩义市欧洁源环保技术服务有限公司 | A kind of aluminium alloy extrusions differential arc oxidation pre-treating method |
| CN109136953A (en) * | 2018-09-13 | 2019-01-04 | 巩义市欧洁源环保技术服务有限公司 | A kind of aluminium alloy extrusions differential arc oxidation pre-treatment cleaning agent and preparation method thereof |
| CN109056025B (en) * | 2018-09-13 | 2019-12-24 | 上海沸莱德表面处理有限公司 | Micro-arc oxidation pretreatment method for aluminum alloy section |
| CN109680283A (en) * | 2019-01-16 | 2019-04-26 | 惠州市阿特斯润滑技术有限公司 | Magnesium alloy cleaning agent and its cleaning method |
| CN110240977A (en) * | 2019-06-28 | 2019-09-17 | 天津市博仁易洁物业服务有限公司 | A kind of multifunction detergent and preparation method thereof |
| CN111500375A (en) * | 2020-05-19 | 2020-08-07 | 兴核科学研究(福建)有限责任公司 | Radioactive foam detergent and preparation method thereof |
| CN112267121A (en) * | 2020-09-18 | 2021-01-26 | 广州亦盛环保科技有限公司 | Cleaning agent and application thereof |
| CN112267121B (en) * | 2020-09-18 | 2022-09-20 | 广州亦盛环保科技有限公司 | Cleaning agent and application thereof |
| CN112808684A (en) * | 2020-12-30 | 2021-05-18 | 蓝思科技股份有限公司 | Method for dewaxing nickel-plated metal product |
| CN112808684B (en) * | 2020-12-30 | 2022-05-03 | 蓝思科技股份有限公司 | Method for dewaxing nickel-plated metal product |
| CN113881943A (en) * | 2021-10-28 | 2022-01-04 | 广东凯盟钝化防锈技术有限公司 | Aluminum material alkaline cleaning agent and preparation method thereof |
| CN113881943B (en) * | 2021-10-28 | 2023-12-01 | 广东凯盟钝化防锈技术有限公司 | Alkaline cleaning agent for aluminum material and preparation method thereof |
| CN114318353A (en) * | 2021-12-27 | 2022-04-12 | 广东红日星实业有限公司 | Ash remover and preparation method and application thereof |
| CN114318353B (en) * | 2021-12-27 | 2023-12-05 | 广东红日星实业有限公司 | Ash remover and preparation method and application thereof |
| CN115197792A (en) * | 2022-08-19 | 2022-10-18 | 广州亦盛环保科技有限公司 | Water-based cleaning agent and preparation method and application thereof |
| CN115466964A (en) * | 2022-09-15 | 2022-12-13 | 杭州和韵科技有限公司 | All-in-one cleaning agent for aluminum and aluminum alloy precision parts and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106947979B (en) | 2020-08-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106947979A (en) | A kind of magnadure cleaning agent | |
| CN107130253A (en) | A kind of aluminum alloy cleaning agent | |
| CN102732899B (en) | Water-based anti-rusting type washing agent for metal parts | |
| CN104403813A (en) | Cleaning agent | |
| CN103774164A (en) | Water-based metal-degreasing cleaning agent | |
| CN103740487B (en) | Outer surface cleaning agent for high-speed trains and using method thereof | |
| CN103469237A (en) | Metal oil contamination cleaner | |
| CN103469228A (en) | Environmentally-friendly water-based metal cleaner | |
| CN105200443A (en) | Efficient cleanser for aluminum products | |
| CN103695911A (en) | Water-soluble metal polishing agent | |
| CN106567088A (en) | Environmentally friendly industrial heavy oil cleaning agent | |
| CN108385117B (en) | multifunctional alkaline cleaning agent and preparation method and application thereof | |
| DOP2006000228A (en) | ACID CLEANING COMPOSITIONS | |
| EP3511401A1 (en) | Multiuse, high-efficiency and environment-friendly cleaning solution and preparation method therefor | |
| CN107326375A (en) | One Albatra metal cleaning agent | |
| CN102953071A (en) | Highly-efficiently degreasing and rust-removal surface treating agent for metal | |
| CN107384628A (en) | Motor train unit train skirtboard cleaning agent, preparation method and application method | |
| CN106867695A (en) | A kind of preparation of the Novel tableware cleaning agent of efficient green | |
| CN103882461A (en) | Detergent for steel meshes | |
| CN105441962A (en) | Water-based metal cleaning agent | |
| CN103469229A (en) | Water-based metal surface cleaner | |
| CN104450238A (en) | Environment-friendly heavy-duty detergent | |
| CN107587142A (en) | A kind of cleaning agent for being applied to implantation medical-therapeutic treatment of human body apparatus | |
| CN110577863A (en) | multipurpose cleaning powder | |
| CN107345302A (en) | A kind of precision metal bloom cleaning agent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |