CN110240977A - A kind of multifunction detergent and preparation method thereof - Google Patents
A kind of multifunction detergent and preparation method thereof Download PDFInfo
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- CN110240977A CN110240977A CN201910576987.4A CN201910576987A CN110240977A CN 110240977 A CN110240977 A CN 110240977A CN 201910576987 A CN201910576987 A CN 201910576987A CN 110240977 A CN110240977 A CN 110240977A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/361—Phosphonates, phosphinates or phosphonites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/78—Neutral esters of acids of phosphorus
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Abstract
The invention discloses a kind of multifunction detergents and preparation method thereof, belong to detergent technical field, the multifunction detergent includes the following raw material: sodium hydroxide, sodium gluconate, four sodium of 1-hydroxy ethylidene-1,1-diphosphonic acid, metasilicate pentahydrate sodium, sodium hypochlorite, alkyl glycosides, ethoxylated dodecyl alcohol, Phosphate of Polyoxyethylene Isooctyl Ether, essence, water.The present invention, without organic solvent, it is a kind of using more environmentally friendly product, simultaneously as formulation cost can also be reduced by not having to organic solvent, the compatibility of formula is very good, scale, oily dirt etc. can be effectively removed, have effects that degerming and dispel stink, may also reach up the effect for killing bacterium, has and prepare simply, the advantages that cleaning efficiency is high, speed is fast, applied widely；It is widely used in cleaning building or industrial equipment, safeguards, such as floor, the cleaning of wall, furniture, carpet, door and window, bathroom.
Description
Technical field
The invention belongs to detergent technical fields, in particular it relates to a kind of multifunction detergent and its preparation side
Method.
Background technique
Detergent is generally used for conventional cleaning, disinfection or the sterilization of family, public place, warehouse and industrial plants.Cleaning
Agent industry is affected by macroeconomic, works as economic growth slows down, when people consider reduced cost, cleaning frequency usually can
Slow down, or even cleaning can be cancelled, this increases the very big market for restricting detergent；On the contrary, if economic dynamic development is good,
Detergent market will increase.2014, global detergent market was about 41,000,000,000 dollars, and Middle and North America accounts for 34%, and West Europe accounts for
19%, China accounts for 12%, and middle Eastern Europe accounts for 9%, and the Middle East accounts for 8%, and Africa accounts for 6%, and Japan accounts for 4%.
The application field of detergent includes light industry, household, kitchen, laundry, industry, traffic and other industry, the base used
Plinth chemicals has surfactant, fungicide, thickener, filler, dyestuff, enzyme, solvent, corrosion inhibiter, chelating agent, fragrance, fluorescence
15 class such as brightening agent, stabilizer, acid, alkali, grinding agent, surfactant refer to fixed hydrophilic lipophilic group, in solution
Surface can align, the substance that the surface tension of solution can be made to be remarkably decreased.In addition, should also have as surfactant
Application features, the surfactants such as solubilising, emulsification, dispersion, wetting, decontamination, sterilization, defoaming and blistering have aliphatic alcohol polyethenoxy
Ether, alkylaryl sulfonates, dimercaptodimethyl ammonium chloride, fatty alcohol polyoxyethylene ether sulfate, alkyl phenol polyoxyethylene ether,
Glycol ether, alkylbenzene sulfonate, phosphate, sodium alklyarylsulfonate, Negel, Triton X-100
Deng fungicide has benzalkonium chloride, sodium hypochlorite, sodium dichloro cyanurate etc., and solvent has dipropylene glycol methyl ether, ethyl alcohol, isopropanol
Deng corrosion inhibiter has ethanol amine and sodium metasilicate etc..Detergent is all formulation product, and concentration is higher, is generally diluted before use.
Detergent can be made into solid-state or liquid, and liquid form product is more typical at present, mainly be compounded since liquid form product is relatively easy.
It is different according to specific demand, detergent can be it is water-soluble be also possible to it is oil-soluble.
Household cleaning be to be cleaned, safeguarded to building or industrial equipment, as floor, wall, furniture, carpet, door and window,
The cleaning of bathroom.Such cleaning agent generally refers to the cleaning for hard surface.
Detergent can be divided into liquid form product, creamy product and powder product.Liquid cleaning agent is because its manufacturing process is simple, removes
Dirty efficiency is fast, easy to use, using more in life.The solvent of solvent type greasy dirt detergent early application is the dissolution such as acetone
The stronger organic solvent of ability, but acetone is volatile solvent, be will form during the production and transportation of greasy dirt detergent
Some potential safety problems, manufacturing condition are also more complicated.Ethers is commonly used in later period improved technology as organic solvent, but
The boiling point of ethyl alcohol is also relatively low, and the smell is awful for ether organic solvent, pungent, and some even will cause in prolonged use process
Phenomena such as number of people is swooned, is vomitted.Therefore, the present invention is directed to develop a kind of liquid cleaner of alkalinity.Currently, market liquid alkalinity is clear
Clean dose of product cleaning effect is poor, results in waste of resources.
Summary of the invention
To solve the above-mentioned problems, the present invention provides a kind of multifunction detergents and preparation method thereof, have and prepare letter
The advantages that single, cleaning efficiency is high, speed is fast, applied widely.
In order to solve the above technical problems, the technical solution adopted by the present invention is that:
A kind of multifunction detergent, including the following raw material: sodium hydroxide, sodium gluconate, four sodium of 1-hydroxy ethylidene-1,1-diphosphonic acid,
Metasilicate pentahydrate sodium, sodium hypochlorite, alkyl glycosides, ethoxylated dodecyl alcohol, Phosphate of Polyoxyethylene Isooctyl Ether, essence,
Water.
A kind of multifunction detergent, by weight, including the following raw material: 5-5.5 parts of sodium hydroxide, sodium gluconate
10.5-11 parts, 0.6-0.9 parts of four sodium of 1-hydroxy ethylidene-1,1-diphosphonic acid, 0.6-1 parts of metasilicate pentahydrate sodium, 11-1.5 parts of sodium hypochlorite, alkane
4-4.5 parts of base glucosides, 1.5-2 parts of fatty alcohol polyoxyethylene ether, 3-3.5 parts of Phosphate of Polyoxyethylene Isooctyl Ether, essence 0.1-
0.3 part, 61.5-62.5 parts of water.
The mass fraction of the sodium hypochlorite is 8-12wt%.
The Phosphate of Polyoxyethylene Isooctyl Ether is Phosphate of Polyoxyethylene Isooctyl Ether sylvite, the isooctanol polyoxy
The mass fraction of vinethene phosphate kalium salt is 68-72wt%.
The alkyl glycosides is C5-C12 alkyl glycosides.
Preferably, the alkyl glycosides is C8-C10 alkyl glycosides.
The fatty alcohol polyoxyethylene ether is ethoxylated dodecyl alcohol, hexadecanol polyoxyethylene ether, octadecyl alcolol polyoxy second
At least one of alkene ether.
The essence is at least one of flavoring apple essence, lemon extract, lavender oil, flavoring rose essence.
Preferably, the multifunction detergent further includes 1-4 parts by weight synergist.
The synergist is at least one of water-soluble cationic cellulose, carboxymethyl hemicellulose.
Preferably, the synergist is made of water-soluble cationic cellulose, carboxymethyl hemicellulose, the water-soluble sun
Ion fiber element, carboxymethyl hemicellulose mass ratio be 1:(0.3-0.7).
The present invention also provides the preparation method of above-mentioned multifunction detergent, step includes: Jiang Geyuan by weight ratio
Material be added to the water be uniformly mixed to get.
The utility model has the advantages that multifunction detergent of the present invention, can directly use, used after can also diluting, without organic molten
Agent is a kind of more environmentally friendly product, simultaneously as formulation cost can also be reduced by not having to organic solvent, the compatibility of formula is very
It is good, scale, oily dirt etc. can be effectively removed, has effects that degerming and dispels stink, may also reach up and kill bacterium
The advantages that effect has and prepares simply, and cleaning efficiency is high, speed is fast, applied widely；It is widely used in building or industry
Equipment is cleaned, is safeguarded, such as floor, the cleaning of wall, furniture, carpet, door and window, bathroom.
Detailed description of the invention
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, to embodiment or will show below
There is attached drawing needed in technical description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this
Some embodiments of invention for those of ordinary skill in the art without creative efforts, can be with
It obtains other drawings based on these drawings.
Fig. 1 is the infrared spectrum after the drying of 1 sample of the embodiment of the present invention.
Fig. 2 is the NMR test chart of 1 sample original sample of the embodiment of the present invention.
Specific embodiment
It is further clear, complete that the technical characteristic work in technical solution is provided to the present invention With reference to embodiment
Description, not to the limitation of its protection scope.
Word " preferred " in the present invention, " further preferred " etc. refer to, can provide certain has in some cases
The embodiment of the present invention of beneficial effect.However, other embodiments are also likely to be excellent under identical circumstances or in the case of other
Choosing.In addition, not implying that other embodiments are unavailable to the statement of one or more preferred embodiments, also it is not intended to
Other embodiments are excluded except the scope of the present invention.
When a numberical range disclosed herein, above range is considered as continuously, and the minimum value including the range and most
Big value and each value between this minimum value and maximum value.Further, when range refers to integer, including the model
Each integer between minimum value and maximum value enclosed.In addition, when providing multiple range Expressive Features or characteristic, Ke Yihe
And the range.In other words, unless otherwise specified, otherwise all ranges disclosed herein are understood to include and are wherein included into
Any and all subrange.For example, should be regarded as including between minimum value 1 and maximum value 10 from the specified range of " 1 to 10 "
Any and all subrange.The Exemplary range of range 1 to 10 include but is not limited to 1 to 6.1,3.5 to 7.8,5.5 to
10 etc..
A kind of multifunction detergent, including the following raw material: sodium hydroxide, sodium gluconate, four sodium of 1-hydroxy ethylidene-1,1-diphosphonic acid,
Metasilicate pentahydrate sodium, sodium hypochlorite, alkyl glycosides, ethoxylated dodecyl alcohol, Phosphate of Polyoxyethylene Isooctyl Ether, essence,
Water.
In one embodiment, a kind of multifunction detergent, by weight, including the following raw material: sodium hydroxide 5-
5.5 parts, it is 10.5-11 parts of sodium gluconate, 0.6-0.9 parts of four sodium of 1-hydroxy ethylidene-1,1-diphosphonic acid, 0.6-1 parts of metasilicate pentahydrate sodium, secondary
11-1.5 parts of sodium chlorate, 4-4.5 parts of alkyl glycosides, 1.5-2 parts of fatty alcohol polyoxyethylene ether, isooctanol polyethoxylate phosphoric acid
3-3.5 parts of ester, 0.1-0.3 parts of essence, 61.5-62.5 parts of water.
In one embodiment, a kind of multifunction detergent, by weight, including the following raw material: sodium hydroxide 5.3
Part, 10.8 parts of sodium gluconate, 0.75 part of four sodium of 1-hydroxy ethylidene-1,1-diphosphonic acid, 0.8 part of metasilicate pentahydrate sodium, sodium hypochlorite 11.3
Part, 4.3 parts of alkyl glycosides, 1.7 parts of fatty alcohol polyoxyethylene ether, 3.4 parts of Phosphate of Polyoxyethylene Isooctyl Ether, essence 0.15
Part, 61.8 parts of water.
In one embodiment, the mass fraction of the sodium hypochlorite is 8-12wt%.
Sodium hypochlorite
Sodium hypochlorite is " chlorine " bleaching agent in most common home washings.Other similar bleaching agent have postassium hypochlorite,
Lithium hypochlorite or calcium hypochlorite, sodium hypobromite or hypoiodous acid sodium, solution containing oxides of chlorine, the tertiary sodium phosphate of chlorination, trichlorine are different
NaDCC or potassium etc., but be often used without in home washings.Bleaching agent is to destroy color development system or generate one to help color
The variant of group.
In one embodiment, the Phosphate of Polyoxyethylene Isooctyl Ether is Phosphate of Polyoxyethylene Isooctyl Ether potassium
Salt, the mass fraction of the Phosphate of Polyoxyethylene Isooctyl Ether sylvite are 68-72wt%.
Phosphate of Polyoxyethylene Isooctyl Ether sylvite
Phosphate of Polyoxyethylene Isooctyl Ether sylvite have splendid anti-concentrated base, high temperature resistant, antioxidant, resistance to reducing agent,
Stability in hard water, and have preferable stabilization to hydrogen peroxide, penetration is superior, have under basic conditions brilliant emulsification,
Degreasing, washing, dispersibility.
In one embodiment, the alkyl glycosides is C5-C12 alkyl glycosides.
In one embodiment, the alkyl glycosides is C8-C10 alkyl glycosides.
In one embodiment, the fatty alcohol polyoxyethylene ether is ethoxylated dodecyl alcohol, hexadecanol polyoxy second
At least one of alkene ether, polyoxyethylene octadecanol.
In one embodiment, the essence is flavoring apple essence, in lemon extract, lavender oil, flavoring rose essence
It is at least one.
In one embodiment, the multifunction detergent further includes 1-4 parts by weight synergist.
In one embodiment, the multifunction detergent further includes 3 parts by weight synergist.
In one embodiment, the synergist be water-soluble cationic cellulose, in carboxymethyl hemicellulose extremely
Few one kind.
In one embodiment, the synergist is made of water-soluble cationic cellulose, carboxymethyl hemicellulose, institute
State water-soluble cationic cellulose, the mass ratio of carboxymethyl hemicellulose is 1:(0.3-0.7).
Synergist
Synergist can extend cleaning agent in the attachment time of sanitary surfaces, enhance cleaning effect, reduce waste, and
The safety in transportational process can be increased, to prevent liquid under external force from going out.
Cellulose is environmentally protective renewable resource, and abundance is had been surprisingly found that during the experiment when using specific
The cleaning effect of detergent can be improved in cationized cellulose substance, it may be possible to because of each Portugal on cellulose macromolecule
All there are three hydroxyl on grape sugar unit, one of primary hydroxyl, two secondary hydroxyls are high by under relatively mild reaction condition
Effect ground be cationized to the hydroxyl of cellulose glucose unit, replace uniformly, it is obtained can completely water-soluble cation
Cellulosic material has certain surface-active, has good solubilising power, and can increase the viscosity of detergent system, makes
The surface of solids can be preferably attached to by obtaining detergent, extend detergent to the cleaning efficiency and cleaning speed of spot.
During the experiment it has also been found that when the synergist is by the matter of water-soluble cationic cellulose, carboxymethyl hemicellulose
The detergent comprehensive performance is preferable when amount for 1:(0.3-0.7) than forming；It may be since water-soluble cationic cellulose adds
System viscosity is still lower after entering system, and dispersion effect is poor, when certain carboxymethyl hemicellulose is added, can quickly be formed
Uniform sticky system is conducive to further detergent adhesive force, and detergent quickly reaches inside spot, to improve cleaning
Efficiency and cleaning speed.
Carboxymethyl hemicellulose is prepared according to the Chinese patent of Publication No. 101838349A.Specifically: the first step uses hydrogen
The wheat straw of potassium oxide solution extraction delignification, then isolation and purification is carried out to the hemicellulose of dissolved in filtrate；Second step, half fiber
Water is added in dimension element, in 60~85 DEG C of 5~30min of heating；Catalyst is added in third step, at 20~40 DEG C, reaction 10~
30min；Ethyl alcohol is added in 4th step, controls the volume ratio of ethyl alcohol and water in 3:2~9:1, power is the microwave spoke of 200~400W
It penetrates down, etherifying agent is added, at 40~80 DEG C, react 2~30min；5th step, it is cooling, it neutralizes, filters, washing freezes dry
It is dry to precipitate to get carboxymethyl hemicellulose is arrived.
Water-soluble cationic cellulose is prepared according to the Chinese patent of Publication No. 102863543A.Specifically:
A. it takes alpha-cellulose content to be not less than 98% cellulosic material, is dissolved in non-protonic solvent；B. it reacted
Journey chooses any one of following four method: under stiring, catalyst is added in i., adds band uncle after reacting 10~30min
The primary alkyl halide of amine structure reacts 1~15 hour；PH value is adjusted to 6~8, under stiring, alkylating reagent, reaction 1 is added
~8 hours；Ii. under stiring, paratoluensulfonyl chloride and acid binding agent is added, reacts 0.5~3 hour, adds catalyst and band
The mixture of the alcohol of tertiary amine structure reacts 1~15 hour；PH value is adjusted to 6~8, under stiring, alkylating reagent is added,
Reaction 1~8 hour；Iii. under stiring, catalyst, the epoxide with quaternary ammonium structure is added, reacts 1~18 hour；iv.
Under stiring, catalyst, and the carboxylic acid halides with quaternary ammonium structure and/or the acid anhydrides with quaternary ammonium structure is added, reacts 1~10 hour；
Alkylating reagent described in I, II is any one or two kinds in active primary alkyl halide, dimethyl suflfate and dimethyl carbonate
More than；C. reactant is taken out, is precipitated out cationic cellulose from reaction solution with precipitating reagent, filters, is washed with cleaning agent
It washs；Then it is dialysed 1~5 day with semi-permeable membrane；D. the solvent of dialysis is evaporated, solid-state cationic cellulose is collected；It is dry in vacuum
In dry case 40-80 DEG C dry 3-10 hours to get arrive cationic cellulose materials.
In one embodiment, the preparation method of above-mentioned multifunction detergent, step include: by weight ratio, to incite somebody to action
Each raw material be added to the water be uniformly mixed to get.
The present invention is specifically described below by embodiment, in addition, if without other explanations, it is raw materials used to be all
It is commercially available.
Flavoring apple essence is the red fuji apple essence that superior food Industrial Co., Ltd., Shantou City provides in embodiment.
Phosphate of Polyoxyethylene Isooctyl Ether sylvite is provided by Jiangsu Hai'an Petrochemical Plant in embodiment, model
OEP-70, Phosphate of Polyoxyethylene Isooctyl Ether potassium salts content 68wt%.
Sodium hypochlorite is provided by Shanghai Huan Fa Chemical Co., Ltd. in embodiment, food-grade, sodium hypochlorite content
10wt%.
Ethoxylated dodecyl alcohol is provided by Shandong Li Ang new material Science and Technology Ltd. in embodiment, model: DN-
86W3, product hierarchy: top grade product.
C8-10 alkyl glucoside is provided by Shandong Quan Jin Fine Chemical Co., Ltd in embodiment, model APG-0810.
Microcrystalline cellulose is provided by Huzhou Linghu Xinwang Chemical Co., Ltd. in embodiment, food-grade.
Embodiment
Embodiment 1
Multifunction detergent, by weight, including the following raw material: 5.3 parts of sodium hydroxide, 10.8 parts of sodium gluconate,
0.75 part of four sodium of 1-hydroxy ethylidene-1,1-diphosphonic acid, 0.8 part of metasilicate pentahydrate sodium, 11.3 parts of sodium hypochlorite, 4.3 parts of alkyl glycosides, fat
1.7 parts of alcohol polyoxyethylene ether, 3.4 parts of Phosphate of Polyoxyethylene Isooctyl Ether, 0.15 part of essence, 61.8 parts of water.
The mass fraction of the sodium hypochlorite is 10wt%.
The Phosphate of Polyoxyethylene Isooctyl Ether is Phosphate of Polyoxyethylene Isooctyl Ether sylvite, the isooctanol polyoxy
The mass fraction of vinethene phosphate kalium salt is 70wt%.
The alkyl glycosides is C8-C10 alkyl glycosides.
The fatty alcohol polyoxyethylene ether is ethoxylated dodecyl alcohol.
The essence is flavoring apple essence.
The preparation method of above-mentioned multifunction detergent, step include: by weight ratio, each raw material to be added to the water stirring
Be uniformly mixed to get.
Embodiment 2
Multifunction detergent, by weight, including the following raw material: 5 parts of sodium hydroxide, 10.5 parts of sodium gluconate, hydroxyl
0.6 part of four sodium of base ethylene-diphosphonic acid, 0.6 part of metasilicate pentahydrate sodium, 11 parts of sodium hypochlorite, 4 parts of alkyl glycosides, fatty alcohol polyoxy second
1.5 parts of alkene ether, 3 parts of Phosphate of Polyoxyethylene Isooctyl Ether, 0.1 part of essence, 61.5 parts of water.
The mass fraction of the sodium hypochlorite is 10wt%.
The Phosphate of Polyoxyethylene Isooctyl Ether is Phosphate of Polyoxyethylene Isooctyl Ether sylvite, the isooctanol polyoxy
The mass fraction of vinethene phosphate kalium salt is 70wt%.
The alkyl glycosides is C8-C10 alkyl glycosides.
The fatty alcohol polyoxyethylene ether is ethoxylated dodecyl alcohol.
The essence is flavoring apple essence.
The preparation method of above-mentioned multifunction detergent, step include: by weight ratio, each raw material to be added to the water stirring
Be uniformly mixed to get.
Embodiment 3
Multifunction detergent, by weight, including the following raw material: 5.3 parts of sodium hydroxide, 10.8 parts of sodium gluconate,
0.75 part of four sodium of 1-hydroxy ethylidene-1,1-diphosphonic acid, 0.8 part of metasilicate pentahydrate sodium, 11.3 parts of sodium hypochlorite, 4.3 parts of alkyl glycosides, fat
1.7 parts of alcohol polyoxyethylene ether, 3.4 parts of Phosphate of Polyoxyethylene Isooctyl Ether, 0.15 part of essence, 3 parts of synergist, 61.8 parts of water.
The mass fraction of the sodium hypochlorite is 10wt%.
The Phosphate of Polyoxyethylene Isooctyl Ether is Phosphate of Polyoxyethylene Isooctyl Ether sylvite, the isooctanol polyoxy
The mass fraction of vinethene phosphate kalium salt is 70wt%.
The alkyl glycosides is C8-C10 alkyl glycosides.
The fatty alcohol polyoxyethylene ether is ethoxylated dodecyl alcohol.
The essence is flavoring apple essence.
The synergist is water-soluble cationic cellulose.
Water-soluble cationic cellulose is added the preparation method comprises the following steps: take 10g microcrystalline cellulose in the three-necked flask of 1000mL
DMAC N,N' dimethyl acetamide/lithium chloride (DMAC N,N' dimethyl acetamide/lithium chloride mass volume ratio is 0.1g/mL) solution
400mL under nitrogen protection, is warming up to 120 DEG C, and motor machine stirs lower 10 hours, dissolution；It is down to room temperature, 20mL pyridine is added,
52g is added in two hours to chloroformyl phenyl trimethicone ammonium chloride, after 1 hour, is warming up to 55 DEG C；Reaction solution is transferred to
In the beaker of 2000mL, the ethyl alcohol of 3 times of volumes is added, stands 3 hours, supernatant liquor is transferred in returnable bottle, filters, uses
95% ethanol solution washing filter residue three times, then by obtained solid is dissolved in deionized water, is transferred in bag filter, is spent
Ionized water is dialysed 5 days；Water is rotated, solid is collected；60 DEG C are dried in vacuo 6 hours to obtain the final product.
The preparation method of above-mentioned multifunction detergent, step include: by weight ratio, each raw material to be added to the water stirring
Be uniformly mixed to get.
Embodiment 4
Multifunction detergent, by weight, including the following raw material: 5.3 parts of sodium hydroxide, 10.8 parts of sodium gluconate,
0.75 part of four sodium of 1-hydroxy ethylidene-1,1-diphosphonic acid, 0.8 part of metasilicate pentahydrate sodium, 11.3 parts of sodium hypochlorite, 4.3 parts of alkyl glycosides, fat
1.7 parts of alcohol polyoxyethylene ether, 3.4 parts of Phosphate of Polyoxyethylene Isooctyl Ether, 0.15 part of essence, 3 parts of synergist, 61.8 parts of water.
The mass fraction of the sodium hypochlorite is 10wt%.
The Phosphate of Polyoxyethylene Isooctyl Ether is Phosphate of Polyoxyethylene Isooctyl Ether sylvite, the isooctanol polyoxy
The mass fraction of vinethene phosphate kalium salt is 70wt%.
The alkyl glycosides is C8-C10 alkyl glycosides.
The fatty alcohol polyoxyethylene ether is ethoxylated dodecyl alcohol.
The essence is flavoring apple essence.
The synergist is carboxymethyl hemicellulose.
Carboxymethyl hemicellulose is the preparation method comprises the following steps: step 1: the wheat straw waste for taking 50g to grind first uses 1000mL acetone-second
Alcohol (acetone: ethyl alcohol=2:1, v/v) extracts 6h in Soxhlet extractor.Then 1000mL water is added in residue to extract at 75 DEG C
2h removes water-soluble hemicellulose, and residual substance and 75g sodium chlorite are added in 1000mL water in 75 DEG C of heating 2h, used
Acetic acid tune pH value obtains the wheat straw of delignification 3.8.It is 1 in the wheat straw of delignification and the solid-to-liquid ratio of potassium hydroxide solution:
20g·mL-1Under conditions of with concentration be 10wt% potassium hydroxide in 23 DEG C of extracting 10h.Obtained filtrate 6mol/L acetic acid tune
PH value is saved to 5.5,70% (volume of acidification is finally used in 95% ethanol precipitation for being then 3 times of filtrate volume with volume, filtering
Score) ethanol washing precipitating, 16h is dried at 60 DEG C after being air-dried 12h.Step 2: hemicellulose (the phase after 6.6g is purified
When the xylan unit in hemicellulose forms is 0.05 mole) it is placed in tri- mouthfuls of reaction flasks of 250mL, 30mL water is added,
85 DEG C of dissolution 15min.Step 3: it is cooling, 2.0g NaOH is added in three mouthfuls of reaction flasks, at 30 DEG C, reacts 20min.4th
Step: being added the ethyl alcohol of 120mL, and device is placed in micro-wave oven, and when power is 200W, the sodium chloroacetate of 11.65g is added,
65 DEG C are warming up to, after reacting 20min.Step 5: it is cooling, the acetic acid tune pH of 6mol/L is added to neutrality, filters, with 80% (body
Fraction) methanol washed once, and it is then primary with 90% (volume fraction) ethanol washing, finally with 95% (volume fraction) second
Alcohol (uses AgNO until being washed till no chloride ion3Solution detection), obtained pellet frozen is dry for 24 hours, obtains carboxymethyl hemicellulose.
The preparation method of above-mentioned multifunction detergent, step include: by weight ratio, each raw material to be added to the water stirring
Be uniformly mixed to get.
Embodiment 5
Multifunction detergent, by weight, including the following raw material: 5.3 parts of sodium hydroxide, 10.8 parts of sodium gluconate,
0.75 part of four sodium of 1-hydroxy ethylidene-1,1-diphosphonic acid, 0.8 part of metasilicate pentahydrate sodium, 11.3 parts of sodium hypochlorite, 4.3 parts of alkyl glycosides, fat
1.7 parts of alcohol polyoxyethylene ether, 3.4 parts of Phosphate of Polyoxyethylene Isooctyl Ether, 0.15 part of essence, 3 parts of synergist, 61.8 parts of water.
The mass fraction of the sodium hypochlorite is 10wt%.
The Phosphate of Polyoxyethylene Isooctyl Ether is Phosphate of Polyoxyethylene Isooctyl Ether sylvite, the isooctanol polyoxy
The mass fraction of vinethene phosphate kalium salt is 70wt%.
The alkyl glycosides is C8-C10 alkyl glycosides.
The fatty alcohol polyoxyethylene ether is ethoxylated dodecyl alcohol.
The essence is flavoring apple essence.
The synergist is mixed to obtain the final product by water-soluble cationic cellulose, carboxymethyl hemicellulose, the water-soluble sun from
Subbundle element, carboxymethyl hemicellulose mass ratio be 1:0.5.
Water-soluble cationic cellulose is added the preparation method comprises the following steps: take 10g microcrystalline cellulose in the three-necked flask of 1000mL
DMAC N,N' dimethyl acetamide/lithium chloride (DMAC N,N' dimethyl acetamide/lithium chloride mass volume ratio is 0.1g/mL) solution
400mL under nitrogen protection, is warming up to 120 DEG C, and motor machine stirs lower 10 hours, dissolution；It is down to room temperature, 20mL pyridine is added,
52g is added in two hours to chloroformyl phenyl trimethicone ammonium chloride, after 1 hour, is warming up to 55 DEG C；Reaction solution is transferred to
In the beaker of 2000mL, the ethyl alcohol of 3 times of volumes is added, stands 3 hours, supernatant liquor is transferred in returnable bottle, filters, uses
95% ethanol solution washing filter residue three times, then by obtained solid is dissolved in deionized water, is transferred in bag filter, is spent
Ionized water is dialysed 5 days；Water is rotated, solid is collected；60 DEG C are dried in vacuo 6 hours to obtain the final product.
Carboxymethyl hemicellulose is the preparation method comprises the following steps: step 1: the wheat straw waste for taking 50g to grind first uses 1000mL acetone-second
Alcohol (acetone: ethyl alcohol=2:1, v/v) extracts 6h in Soxhlet extractor.Then 1000mL water is added in residue to extract at 75 DEG C
2h removes water-soluble hemicellulose, and residual substance and 75g sodium chlorite are added in 1000mL water in 75 DEG C of heating 2h, used
Acetic acid tune pH value obtains the wheat straw of delignification 3.8.It is 1 in the wheat straw of delignification and the solid-to-liquid ratio of potassium hydroxide solution:
20g·mL-1Under conditions of with concentration be 10wt% potassium hydroxide in 23 DEG C of extracting 10h.Obtained filtrate 6mol/L acetic acid tune
PH value is saved to 5.5,70% (volume of acidification is finally used in 95% ethanol precipitation for being then 3 times of filtrate volume with volume, filtering
Score) ethanol washing precipitating, 16h is dried at 60 DEG C after being air-dried 12h.Step 2: hemicellulose (the phase after 6.6g is purified
When the xylan unit in hemicellulose forms is 0.05 mole) it is placed in tri- mouthfuls of reaction flasks of 250mL, 30mL water is added,
85 DEG C of dissolution 15min.Step 3: it is cooling, 2.0g NaOH is added in three mouthfuls of reaction flasks, at 30 DEG C, reacts 20min.4th
Step: being added the ethyl alcohol of 120mL, and device is placed in micro-wave oven, and when power is 200W, the sodium chloroacetate of 11.65g is added,
65 DEG C are warming up to, after reacting 20min.Step 5: it is cooling, the acetic acid tune pH of 6mol/L is added to neutrality, filters, with 80% (body
Fraction) methanol washed once, and it is then primary with 90% (volume fraction) ethanol washing, finally with 95% (volume fraction) second
Alcohol (uses AgNO until being washed till no chloride ion3Solution detection), obtained pellet frozen is dry for 24 hours, obtains carboxymethyl hemicellulose.
The preparation method of above-mentioned multifunction detergent, step include: by weight ratio, each raw material to be added to the water stirring
Be uniformly mixed to get.
Comparative example 1
Multifunction detergent, by weight, including the following raw material: 5.3 parts of sodium hydroxide, 10.8 parts of sodium gluconate,
0.75 part of four sodium of 1-hydroxy ethylidene-1,1-diphosphonic acid, 0.8 part of metasilicate pentahydrate sodium, 11.3 parts of sodium hypochlorite, 4.3 parts of alkyl glycosides, fat
5.1 parts of alcohol polyoxyethylene ether, 0.15 part of essence, 61.8 parts of water.
The mass fraction of the sodium hypochlorite is 10wt%.
The alkyl glycosides is C8-C10 alkyl glycosides.
The fatty alcohol polyoxyethylene ether is ethoxylated dodecyl alcohol.
The essence is flavoring apple essence.
The preparation method of above-mentioned multifunction detergent, step include: by weight ratio, each raw material to be added to the water stirring
Be uniformly mixed to get.
Comparative example 2
Multifunction detergent, by weight, including the following raw material: 5.3 parts of sodium hydroxide, 10.8 parts of sodium gluconate,
It is 0.75 part of four sodium of 1-hydroxy ethylidene-1,1-diphosphonic acid, 0.8 part of metasilicate pentahydrate sodium, 11.3 parts of sodium hypochlorite, 4.3 parts of alkyl glycosides, different pungent
5.1 parts of alcohol polyoxyethylene ether phosphate, 0.15 part of essence, 61.8 parts of water.
The mass fraction of the sodium hypochlorite is 10wt%.
The Phosphate of Polyoxyethylene Isooctyl Ether is Phosphate of Polyoxyethylene Isooctyl Ether sylvite, the isooctanol polyoxy
The mass fraction of vinethene phosphate kalium salt is 70wt%.
The alkyl glycosides is C8-C10 alkyl glycosides.
The essence is flavoring apple essence.
The preparation method of above-mentioned multifunction detergent, step include: by weight ratio, each raw material to be added to the water stirring
Be uniformly mixed to get.
Comparative example 3
Multifunction detergent, by weight, including the following raw material: 5.3 parts of sodium hydroxide, 10.8 parts of sodium gluconate,
0.75 part of four sodium of 1-hydroxy ethylidene-1,1-diphosphonic acid, 0.8 part of metasilicate pentahydrate sodium, 11.3 parts of sodium hypochlorite, 4.3 parts of alkyl glycosides, fat
1.7 parts of alcohol polyoxyethylene ether, 3.4 parts of Phosphate of Polyoxyethylene Isooctyl Ether, 0.15 part of essence, 3 parts of synergist, 61.8 parts of water.
The mass fraction of the sodium hypochlorite is 10wt%.
The Phosphate of Polyoxyethylene Isooctyl Ether is Phosphate of Polyoxyethylene Isooctyl Ether sylvite, the isooctanol polyoxy
The mass fraction of vinethene phosphate kalium salt is 70wt%.
The alkyl glycosides is C8-C10 alkyl glycosides.
The fatty alcohol polyoxyethylene ether is ethoxylated dodecyl alcohol.
The essence is flavoring apple essence.
The synergist is mixed to obtain the final product by microcrystalline cellulose, carboxymethyl hemicellulose, the microcrystalline cellulose, carboxymethyl half
The mass ratio of cellulose is 1:0.5.
Carboxymethyl hemicellulose is the preparation method comprises the following steps: step 1: the wheat straw waste for taking 50g to grind first uses 1000mL acetone-second
Alcohol (acetone: ethyl alcohol=2:1, v/v) extracts 6h in Soxhlet extractor.Then 1000mL water is added in residue to extract at 75 DEG C
2h removes water-soluble hemicellulose, and residual substance and 75g sodium chlorite are added in 1000mL water in 75 DEG C of heating 2h, used
Acetic acid tune pH value obtains the wheat straw of delignification 3.8.It is 1 in the wheat straw of delignification and the solid-to-liquid ratio of potassium hydroxide solution:
20g·mL-1Under conditions of with concentration be 10wt% potassium hydroxide in 23 DEG C of extracting 10h.Obtained filtrate 6mol/L acetic acid tune
PH value is saved to 5.5,70% (volume of acidification is finally used in 95% ethanol precipitation for being then 3 times of filtrate volume with volume, filtering
Score) ethanol washing precipitating, 16h is dried at 60 DEG C after being air-dried 12h.Step 2: hemicellulose (the phase after 6.6g is purified
When the xylan unit in hemicellulose forms is 0.05 mole) it is placed in tri- mouthfuls of reaction flasks of 250mL, 30mL water is added,
85 DEG C of dissolution 15min.Step 3: it is cooling, 2.0g NaOH is added in three mouthfuls of reaction flasks, at 30 DEG C, reacts 20min.4th
Step: being added the ethyl alcohol of 120mL, and device is placed in micro-wave oven, and when power is 200W, the sodium chloroacetate of 11.65g is added,
65 DEG C are warming up to, after reacting 20min.Step 5: it is cooling, the acetic acid tune pH of 6mol/L is added to neutrality, filters, with 80% (body
Fraction) methanol washed once, and it is then primary with 90% (volume fraction) ethanol washing, finally with 95% (volume fraction) second
Alcohol (uses AgNO until being washed till no chloride ion3Solution detection), obtained pellet frozen is dry for 24 hours, obtains carboxymethyl hemicellulose.
The preparation method of above-mentioned multifunction detergent, step include: by weight ratio, each raw material to be added to the water stirring
Be uniformly mixed to get.
Performance evaluation
Soil removal efficiency test: length and width are the Dali stone ceramic tile of 20cm, measure its weight W1, one layer 50 is coated on the stone ceramic tile of Dali
Gram dirt, roasted one hour at 230 DEG C, measure its weight W2, 20 grams of multifunction detergents are uniformly sprayed to solarization in marble
It on ceramic tile, places 2 hours, is then rinsed in the case where 60 DEG C of hot water are flowed with sponge at room temperature, 60 DEG C of baking oven drying measure its weight
W3.By gravimetric method, soil removal efficiency is obtained.Above-mentioned dirt is by 50wt% chicken fat, 30wt% vegetable oil, 10wt% flour, 5wt% tomato
Sauce and 5wt% particulate sugar composition.Soil removal efficiency (%)=[(W2-W3)/(W2-W1)]×100.Each sample test three times, is made even
Mean value.
Wall built-up performance test: selecting the Dali stone ceramic tile of 25 × 25cm, and surface keeps smooth (make liquid can streamlined flow),
Sample flow time when with 25 DEG C of stopwatch record.The specific operation method is as follows: Dali stone ceramic tile near vertical is put in desktop,
0.5 ± 0.01g sample drop is drawn in Dali stone ceramic tile one end, records the time, when the sample flow Dali stone ceramic tile other end, is stopped
Timing.Each sample test three times, is averaged.
Test result is shown in Table 1.
Table 1: soil removal efficiency is surveyed and wall built-up the performance test results table
Example above-mentioned is merely illustrative, and is used to explain the present invention some features of the method.Appended right is wanted
The range as wide as possible for being intended to require to be contemplated that is sought, and embodiments as presented herein is only according to all possible implementation
The explanation of the embodiment of the combined selection of example.Therefore, the purpose of applicant is that the attached claims are not illustrated this hair
The exemplary selectional restriction of bright feature.Some numberical ranges used also include sub- model in the claims
It encloses, the variation in these ranges should also be construed to be covered by the attached claims in the conceived case.
Claims (10)
1. a kind of multifunction detergent, which is characterized in that including the following raw material: sodium hydroxide, sodium gluconate, hydroxy ethylidene two
Four sodium of phosphonic acids, metasilicate pentahydrate sodium, sodium hypochlorite, alkyl glycosides, ethoxylated dodecyl alcohol, isooctanol polyethoxylate phosphoric acid
Ester, essence, water.
2. multifunction detergent as described in claim 1, which is characterized in that by weight, including the following raw material: hydroxide
5-5.5 parts of sodium, 10.5-11 parts of sodium gluconate, 0.6-0.9 parts of four sodium of 1-hydroxy ethylidene-1,1-diphosphonic acid, metasilicate pentahydrate sodium 0.6-1
Part, 11-1.5 parts of sodium hypochlorite, 4-4.5 parts of alkyl glycosides, 1.5-2 parts of fatty alcohol polyoxyethylene ether, isooctanol polyethoxylate
3-3.5 parts of phosphate, 0.1-0.3 parts of essence, 61.5-62.5 parts of water.
3. multifunction detergent as claimed in claim 1 or 2, which is characterized in that the mass fraction of the sodium hypochlorite is 8-
12wt%.
4. multifunction detergent as claimed in claim 1 or 2, which is characterized in that the Phosphate of Polyoxyethylene Isooctyl Ether
For Phosphate of Polyoxyethylene Isooctyl Ether sylvite, the mass fraction of the Phosphate of Polyoxyethylene Isooctyl Ether sylvite is 68-
72wt%.
5. multifunction detergent as claimed in claim 1 or 2, which is characterized in that the alkyl glycosides is C5-C12 alkyl sugar
Glycosides.
6. multifunction detergent as claimed in claim 5, which is characterized in that the alkyl glycosides is C8-C10 alkyl glycosides.
7. multifunction detergent as claimed in claim 1 or 2, which is characterized in that the fatty alcohol polyoxyethylene ether is laurel
At least one of alcohol polyoxyethylene ether, hexadecanol polyoxyethylene ether, polyoxyethylene octadecanol.
8. multifunction detergent as claimed in claim 1 or 2, which is characterized in that the multifunction detergent further includes 1-4 weight
Measure part synergist.
9. multifunction detergent as claimed in claim 8, which is characterized in that the synergist is water-soluble cationic fiber
At least one of element, carboxymethyl hemicellulose.
10. a kind of preparation method of the multifunction detergent as described in any one of claim 1-9, step includes: by weight
Proportion, each raw material is added to the water be uniformly mixed to get.
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