CN111500375A - Radioactive foam detergent and preparation method thereof - Google Patents
Radioactive foam detergent and preparation method thereof Download PDFInfo
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- CN111500375A CN111500375A CN202010425240.1A CN202010425240A CN111500375A CN 111500375 A CN111500375 A CN 111500375A CN 202010425240 A CN202010425240 A CN 202010425240A CN 111500375 A CN111500375 A CN 111500375A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0073—Anticorrosion compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/32—Protein hydrolysates; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a radioactive foam detergent which is prepared from the following raw materials: 0.5-5% of sodium bicarbonate, 0.5-8% of ethanolamine or 0.5-8% of triethanolamine, 0.5-3% of surfactant, 0.5-3% of complexing agent, 5-10% of cosolvent and the balance of water. The detergent in the invention has weak alkalinity, less corrosion to the surfaces of various materials, and stronger complexing and detergent capacities to various metal ions due to the existence of the sodium glucoheptonate. The contained sodium glucoheptonate has better environmental compatibility, compared with other complexing agents, an EDTA complex product is difficult to degrade, phosphate can cause phosphorus enrichment, the sodium glucoheptonate is made of glucose and is easy to degrade, and the sodium glucoheptonate has stronger complexing capability on calcium ions and magnesium ions, so that the detergent can be applied to the condition of harder water quality without deionized water configuration.
Description
Technical Field
The invention relates to a radioactive foam detergent and a preparation method thereof.
Background
Since the 60's of the 20 th century, the U.S. began investigating the use of chemical foams for radioactive decontamination. The principle of the foam detergent is that the foam carries the detergent to perform decontamination operation on the surface of a contaminated part, and the method has the greatest advantage that the generation amount of secondary waste is far less than that of a common decontamination solution soaking method, and is particularly suitable for large-volume cavities or complex-shaped objects. The foam decontamination technology has been developed for 60 years and has become mature in engineering, and the most representative method is to develop a two-step foam decontamination device by combining the English method. The foam detergent components used in engineering have characteristics tailored to the decontamination conditions, for example, the American savanay factory uses nitric acid foam to clean metal walls and valves, and France uses alkaline foam to remove oil from coolant, then uses acid foam to remove rust, and finally uses buffer solution to rinse.
The research of the foam decontamination technology in China is started late, and China radiation protection research institute in 2001 adopts the foam cleaning technology to carry out decontamination experimental research on a simulated contaminated sample of a post-processing factory, wherein the decontamination coefficient of a ceric sulfate decontaminating agent on a stainless steel sample is 12.39-24.08, and the decontamination coefficient of a painted carbon steel sheet sample is 3.62-5.14; the oxalic acid detergent has a decontamination coefficient of 8.87-14.34 for stainless steel samples and a decontamination coefficient of 6.57-8.40 for painted carbon steel sheet samples, the decontamination coefficients are all lower than foreign levels, and the effect of the alkaline foam detergent is worse. The decontamination factor of the foam decontaminant capable of completely defoaming developed by the science and technology university of southwest 2016 is about 50. In summary, the components of the existing foam detergent in China are yet to be further developed, and the decontamination coefficient, the application range of the detergent and the treatment difficulty of the decontamination waste liquid need to be further improved.
Disclosure of Invention
Aiming at the technical defects, the invention aims to provide a novel radioactive foam detergent which has high decontamination efficiency and can be used for decontaminating various materials such as stainless steel, carbon steel, aluminum alloy, magnesium alloy, cement, plastics and the like, and meanwhile, the effective components in the detergent can realize secondary treatment, thereby effectively simplifying the decontamination process of the existing contaminated materials and further reducing the decontamination economy and environmental cost.
In order to solve the technical problems, the invention adopts the following technical scheme:
the invention provides a radioactive foam detergent, which is used on the surfaces of various materials such as stainless steel, carbon steel, aluminum alloy, magnesium alloy, cement, plastics and the like, and the pH value of the detergent is selected to be in a weak alkaline environment, so a small amount of alkaline substances are required to be added, and the radioactive foam detergent comprises the following components: 0.5-5% of sodium bicarbonate, 0.5-8% of ethanolamine or 0.5-8% of triethanolamine;
in order to achieve the foaming purpose, a surfactant is required to be added, wherein the surfactant comprises 1-10% of N-lauroyl sodium glutamate, 3-7% of narrow-distribution sodium fatty alcohol-polyoxyethylene ether sulfate and 4-8% of alkyl glycoside; because the foaming performance required by various surfaces is possibly inconsistent, the product adopts the design of a multi-type surfactant, and can adjust the foaming performance and the foam durability;
in order to achieve the purpose of improving the decontamination effect, 0.5-3% of a complexing agent is required to be added, wherein the complexing agent is sodium glucoheptonate;
in order to improve the dissolving effect of the components, a cosolvent is added by 5-10%, and the cosolvent is any one of propylene glycol, propylene glycol methyl ether and propylene glycol tertiary butyl ether;
except the above components, the rest is water.
Preferably, the compound is prepared from the following raw materials: 0.5% of sodium bicarbonate, 8% of ethanolamine, 1% of N-lauroyl sodium glutamate, 7% of narrow-distribution sodium fatty alcohol-polyoxyethylene ether sulfate, 8% of alkyl glycoside, 0.5-3% of sodium glucoheptonate, 7% of propylene glycol and the balance of water.
Preferably, the compound is prepared from the following raw materials: 1% of sodium bicarbonate, 4% of triethanolamine, 2% of N-lauroyl sodium glutamate, 5% of narrow-distribution sodium alcohol ether sulfate, 8% of alkyl glycoside, 0.5% of sodium glucoheptonate, 5% of propylene glycol methyl ether and the balance of water.
Preferably, the compound is prepared from the following raw materials: 3% of sodium bicarbonate, 2% of ethanolamine, 2% of sodium N-lauroyl glutamate, 5% of narrow-distribution sodium fatty alcohol polyoxyethylene ether sulfate, 8% of alkyl glycoside, 1% of sodium glucoheptonate, 8% of propylene glycol tert-butyl ether and the balance of water.
Preferably, the compound is prepared from the following raw materials: 5% of sodium bicarbonate, 0.5% of triethanolamine, 10% of N-lauroyl sodium glutamate, 3% of narrow-distribution sodium alcohol ether sulfate, 2% of alkyl glycoside, 3% of sodium glucoheptonate, 10% of propylene glycol methyl ether and the balance of water.
The invention also provides a preparation method of the radioactive foam detergent, which comprises the steps of weighing water with a formula amount, adding sodium bicarbonate, dissolving and uniformly stirring; and then adding ethanolamine or triethanolamine, a complexing agent and a cosolvent, stirring to completely dissolve the ethanolamine or triethanolamine, and finally adding a surfactant to obtain the finished product of the radioactive foam detergent.
The invention has the beneficial effects that: the detergent in the invention has weak alkalinity, less corrosion to the surfaces of various materials, and stronger complexing and detergent capacities to various metal ions due to the existence of the sodium glucoheptonate. The contained sodium glucoheptonate has better environmental compatibility, compared with other complexing agents, an EDTA complex product is difficult to degrade, phosphate can cause phosphorus enrichment, the sodium glucoheptonate is made of glucose and is easy to degrade, and the sodium glucoheptonate has stronger complexing capability on calcium ions and magnesium ions, so that the detergent can be applied to the condition of harder water quality without deionized water configuration.
Detailed Description
The technical solutions of the present invention will be described clearly and completely with reference to the following embodiments of the present invention, and it should be understood that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
The radioactive foam detergent is prepared from the following raw materials: 0.5% of sodium bicarbonate, 8% of ethanolamine, 1% of N-lauroyl sodium glutamate, 7% of narrow-distribution sodium fatty alcohol-polyoxyethylene ether sulfate, 8% of alkyl glycoside, 0.5-3% of sodium glucoheptonate, 7% of propylene glycol and the balance of water.
The preparation method comprises the following steps: firstly, weighing water with a formula amount, adding sodium bicarbonate, dissolving and uniformly stirring; and then adding ethanolamine, sodium glucoheptonate and propylene glycol, stirring to completely dissolve the mixture, and finally adding 1% of N-lauroyl sodium glutamate, 7% of narrow-distribution fatty alcohol-polyoxyethylene ether sodium sulfate and 8% of alkyl glycoside to obtain the finished product of the radioactive foam detergent.
Example 2
The radioactive foam detergent is prepared from the following raw materials: 1% of sodium bicarbonate, 4% of triethanolamine, 2% of N-lauroyl sodium glutamate, 5% of narrow-distribution sodium alcohol ether sulfate, 8% of alkyl glycoside, 0.5% of sodium glucoheptonate, 5% of propylene glycol methyl ether and the balance of water.
The preparation method is the same as that of example 1.
Example 3
The radioactive foam detergent is prepared from the following raw materials: 3% of sodium bicarbonate, 2% of ethanolamine, 2% of sodium N-lauroyl glutamate, 5% of narrow-distribution sodium fatty alcohol polyoxyethylene ether sulfate, 8% of alkyl glycoside, 1% of sodium glucoheptonate, 8% of propylene glycol tert-butyl ether and the balance of water.
The preparation method is the same as that of example 1.
Example 4
The radioactive foam detergent is prepared from the following raw materials: 5% of sodium bicarbonate, 0.5% of triethanolamine, 10% of N-lauroyl sodium glutamate, 3% of narrow-distribution sodium alcohol ether sulfate, 2% of alkyl glycoside, 3% of sodium glucoheptonate, 10% of propylene glycol methyl ether and the balance of water.
The preparation method is the same as that of example 1.
Examples 1-4 formulations are given in the following table
Table 1 detergent formulations (weight ratio)
The experimental results of the above examples are as follows:
preparing a detergent solution No. 1, a detergent solution No. 2, a detergent solution No. 3 and a detergent solution No. 4 according to the formula shown in the table 1, putting the prepared detergent solution No. 1, detergent solution No. 2, detergent solution No. 3 and detergent solution No. 4 into a sealed glass container for later use, taking a stainless steel plate, a carbon steel plate, an aluminum alloy plate and a plastic plate, cutting the stainless steel plate, the carbon steel plate, the aluminum alloy plate and the plastic plate into square sheets with the size of 5cm × 5cm, respectively 6 sheets, cleaning.
Weighing 0.5g of uranyl nitrate, adding the uranyl nitrate into 50m L deionized water, shaking up to prepare a uranyl nitrate water solution with the concentration of 10mg/m L for later use, and adding a Cs-137 standard substance solution with the activity of 3.7 × 104Bq into 50m L deionized water to prepare a Cs-137 simulation solution.
5ml of uranyl nitrate aqueous solution is uniformly dripped on the surfaces of three stainless steel square pieces and three plastic square pieces, and 5ml of Cs-137 simulation solution is uniformly dripped on the surfaces of three carbon steel square pieces and three aluminum alloy square pieces. All the square pieces added with the solution are placed in a clean closed container and naturally dried for 30 days.
After the square piece is naturally air-dried, the surface pollution values of three stainless steel square pieces and a plastic square piece are measured by a Berthhold L B-124 type surface contamination instrument, wherein the stainless steel square pieces are respectively 22.82Bq/cm2, 23.17Bq/cm2 and 22.94Bq/cm2, the plastic square pieces are respectively 21.78Bq/cm2, 22.35Bq/cm2 and 22.12Bq/cm2, the gamma counting rates of three carbon steel pieces and three aluminum alloy pieces are respectively measured by a Kannala BE6530 type high-purity germanium gamma spectrometer, wherein the carbon steel pieces are respectively 2.04 × 105 count/min, 2.16 × 105 count/min and 2.12 × 105 count/min, and the aluminum alloy pieces are respectively 2.11 × 105 count/min, 2.19 × 105 count/min and 2.07 × 105 count/min.
A glass cup with the volume of 5 liters is taken and placed into three stainless steel brackets, three stainless steel sheets are vertically placed on the stainless steel brackets, a No. 1 decontamination solution is foamed and filled into the glass cup with the volume of 5 liters, the three stainless steel sheets are soaked in the No. 1 decontamination solution foam of the glass cup for 4 hours, after 4 hours, the stainless steel sheets are taken out and washed by deionized water and dried in a vacuum drying box, after drying, the surface pollution values are respectively measured by a L B-124 type surface contamination instrument and are respectively 0.48Bq/cm2, 0.39Bq/cm2 and 0.51Bq/cm2, and the decontamination coefficients are calculated to be 47.54, 59.41 and 44.98.
A glass cup with the volume of 5 liters is taken and placed into three stainless steel brackets, and three carbon steel sheets are vertically placed on the stainless steel brackets. Foaming the No. 2 decontamination solution, filling the foaming solution into a glass with the volume of 5 liters, soaking three carbon steel sheets in the foaming solution of the No. 2 decontamination solution in the glass for 4 hours, taking out the carbon steel sheets after 4 hours, cleaning the carbon steel sheets by deionized water, drying the carbon steel sheets in a vacuum drying box, measuring gamma counting rates by a Kanbera BE6530 type high-purity germanium gamma spectrometer after drying, wherein the gamma counting rates are 3849 counts/minute, 4217 counts/minute and 4065 counts/minute respectively, and the decontamination coefficients are 53.00, 51.22 and 52.15 after calculation.
A glass cup with the volume of 5 liters is taken and placed into three stainless steel brackets, and three aluminum alloy sheets are vertically placed on the stainless steel brackets. Foaming the No. 3 decontamination solution, filling the glass with the volume of 5 liters, soaking three aluminum alloy sheets in the No. 3 decontamination solution foam of the glass for 4 hours, taking out the aluminum alloy sheets after 4 hours, washing the aluminum alloy sheets by deionized water, drying the aluminum alloy sheets in a vacuum drying box, measuring gamma counting rates by a Kanbera BE6530 type high-purity germanium gamma spectrometer after drying, wherein the gamma counting rates are 6017 counts/minute, 5836 counts/minute and 5914 counts/minute respectively, and the decontamination coefficients are 35.07, 37.53 and 35.00 through calculation.
A glass cup with the volume of 5 liters is taken and placed into three stainless steel brackets, three plastic sheets are vertically placed on the stainless steel brackets, a No. 4 decontamination solution is foamed and filled into the glass cup with the volume of 5 liters, the three plastic sheets are soaked in the No. 4 decontamination solution foam of the glass cup for 4 hours, after 4 hours, the plastic sheets are taken out and washed by deionized water and dried in a vacuum drying box, after drying, the surface pollution values are respectively measured by a L B-124 type surface contamination instrument and are respectively 0.74Bq/cm2, 0.80Bq/cm2 and 0.78Bq/cm2, and the decontamination coefficients are calculated to be 29.43, 27.94 and 28.36.
It will be apparent to those skilled in the art that various changes and modifications may be made in the present invention without departing from the spirit and scope of the invention. Thus, if such modifications and variations of the present invention fall within the scope of the claims of the present invention and their equivalents, the present invention is also intended to include such modifications and variations.
Claims (6)
1. The radioactive foam detergent is characterized by being prepared from the following raw materials: 0.5-5% of sodium bicarbonate, 0.5-8% of ethanolamine or 0.5-8% of triethanolamine, 0.5-3% of surfactant, 0.5-3% of complexing agent, 5-10% of cosolvent and the balance of water; the surfactant comprises 1-10% of N-lauroyl sodium glutamate, 3-7% of narrow-distribution sodium fatty alcohol-polyoxyethylene ether sulfate and 4-8% of alkyl glycoside, the complexing agent is sodium glucoheptonate, and the cosolvent is any one of propylene glycol, propylene glycol methyl ether and propylene glycol tertiary butyl ether.
2. The radioactive foam detergent of claim 1, prepared from the following raw materials: 0.5% of sodium bicarbonate, 8% of ethanolamine, 1% of N-lauroyl sodium glutamate, 7% of narrow-distribution sodium fatty alcohol-polyoxyethylene ether sulfate, 8% of alkyl glycoside, 0.5-3% of sodium glucoheptonate, 7% of propylene glycol and the balance of water.
3. The radioactive foam detergent of claim 1, prepared from the following raw materials: 1% of sodium bicarbonate, 4% of triethanolamine, 2% of N-lauroyl sodium glutamate, 5% of narrow-distribution sodium alcohol ether sulfate, 8% of alkyl glycoside, 0.5% of sodium glucoheptonate, 5% of propylene glycol methyl ether and the balance of water.
4. The radioactive foam detergent of claim 1, prepared from the following raw materials: 3% of sodium bicarbonate, 2% of ethanolamine, 2% of sodium N-lauroyl glutamate, 5% of narrow-distribution sodium fatty alcohol polyoxyethylene ether sulfate, 8% of alkyl glycoside, 1% of sodium glucoheptonate, 8% of propylene glycol tert-butyl ether and the balance of water.
5. The radioactive foam detergent of claim 1, prepared from the following raw materials: 5% of sodium bicarbonate, 0.5% of triethanolamine, 10% of N-lauroyl sodium glutamate, 3% of narrow-distribution sodium alcohol ether sulfate, 2% of alkyl glycoside, 3% of sodium glucoheptonate, 10% of propylene glycol methyl ether and the balance of water.
6. The method for preparing the radioactive foam detergent according to claim 1, wherein the water is weighed according to the formula amount, the sodium bicarbonate is added, dissolved and stirred uniformly; and then adding ethanolamine or triethanolamine, a complexing agent and a cosolvent, stirring to completely dissolve the ethanolamine or triethanolamine, and finally adding a surfactant to obtain the finished product of the radioactive foam detergent.
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| Application Number | Priority Date | Filing Date | Title |
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| CN202010425240.1A CN111500375A (en) | 2020-05-19 | 2020-05-19 | Radioactive foam detergent and preparation method thereof |
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| CN202010425240.1A CN111500375A (en) | 2020-05-19 | 2020-05-19 | Radioactive foam detergent and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116421923A (en) * | 2023-04-12 | 2023-07-14 | 江阴市月城昇利生物科技有限公司 | Preparation method of incineration fly ash treated glucohept composite liquid |
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| CN101785749A (en) * | 2010-02-09 | 2010-07-28 | 广东名臣有限公司 | Sterilizing skin moistening liquid soap |
| CN106947979A (en) * | 2017-03-22 | 2017-07-14 | 广州亦盛环保科技有限公司 | A kind of magnadure cleaning agent |
| CN109252176A (en) * | 2018-10-30 | 2019-01-22 | 河南海利未来科技有限公司 | A kind of two-in-one cleaning agent of decontamination antirust |
| CN109370801A (en) * | 2018-11-26 | 2019-02-22 | 蓝思科技（长沙）有限公司 | A kind of glass Wax removal water and bonding wax cleaning method |
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2020
- 2020-05-19 CN CN202010425240.1A patent/CN111500375A/en active Pending
Patent Citations (4)
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|---|---|---|---|---|
| CN101785749A (en) * | 2010-02-09 | 2010-07-28 | 广东名臣有限公司 | Sterilizing skin moistening liquid soap |
| CN106947979A (en) * | 2017-03-22 | 2017-07-14 | 广州亦盛环保科技有限公司 | A kind of magnadure cleaning agent |
| CN109252176A (en) * | 2018-10-30 | 2019-01-22 | 河南海利未来科技有限公司 | A kind of two-in-one cleaning agent of decontamination antirust |
| CN109370801A (en) * | 2018-11-26 | 2019-02-22 | 蓝思科技（长沙）有限公司 | A kind of glass Wax removal water and bonding wax cleaning method |
Non-Patent Citations (1)
| Title |
|---|
| 化学工业出版社: "《中国化工产品大全下卷》", 31 January 2005, 化学工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116421923A (en) * | 2023-04-12 | 2023-07-14 | 江阴市月城昇利生物科技有限公司 | Preparation method of incineration fly ash treated glucohept composite liquid |
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