CN109370801A - A kind of glass Wax removal water and bonding wax cleaning method - Google Patents
A kind of glass Wax removal water and bonding wax cleaning method Download PDFInfo
- Publication number
- CN109370801A CN109370801A CN201811419957.4A CN201811419957A CN109370801A CN 109370801 A CN109370801 A CN 109370801A CN 201811419957 A CN201811419957 A CN 201811419957A CN 109370801 A CN109370801 A CN 109370801A
- Authority
- CN
- China
- Prior art keywords
- glass
- sodium
- removal water
- wax
- wax removal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011521 glass Substances 0.000 title claims abstract description 83
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 73
- 238000004140 cleaning Methods 0.000 title claims abstract description 35
- 238000000034 method Methods 0.000 title claims abstract description 35
- 239000001993 wax Substances 0.000 claims abstract description 101
- 239000004615 ingredient Substances 0.000 claims abstract description 18
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 16
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 15
- 239000004094 surface-active agent Substances 0.000 claims abstract description 11
- 239000012188 paraffin wax Substances 0.000 claims abstract description 10
- 239000002738 chelating agent Substances 0.000 claims abstract description 7
- 239000006184 cosolvent Substances 0.000 claims abstract description 7
- 150000003839 salts Chemical class 0.000 claims abstract description 7
- 238000004506 ultrasonic cleaning Methods 0.000 claims description 25
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 19
- -1 fatty acid diethanol amine amide Chemical class 0.000 claims description 19
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 12
- 239000007864 aqueous solution Substances 0.000 claims description 11
- 239000011734 sodium Substances 0.000 claims description 11
- 229910052708 sodium Inorganic materials 0.000 claims description 11
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 10
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims description 8
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 8
- 239000000194 fatty acid Substances 0.000 claims description 8
- 229930195729 fatty acid Natural products 0.000 claims description 8
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 235000019864 coconut oil Nutrition 0.000 claims description 7
- 239000003240 coconut oil Substances 0.000 claims description 7
- 150000002191 fatty alcohols Chemical class 0.000 claims description 7
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 7
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 229940043237 diethanolamine Drugs 0.000 claims description 6
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N isopropyl alcohol Natural products CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 6
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 claims description 5
- 229940049964 oleate Drugs 0.000 claims description 5
- 239000000344 soap Substances 0.000 claims description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 5
- 239000000176 sodium gluconate Substances 0.000 claims description 5
- 235000012207 sodium gluconate Nutrition 0.000 claims description 5
- 229940005574 sodium gluconate Drugs 0.000 claims description 5
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 5
- HQAITFAUVZBHNB-UHFFFAOYSA-N sodium;pentahydrate Chemical compound O.O.O.O.O.[Na] HQAITFAUVZBHNB-UHFFFAOYSA-N 0.000 claims description 5
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 claims description 5
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 4
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical group OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 4
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 claims description 4
- 239000004115 Sodium Silicate Substances 0.000 claims description 4
- 229960004275 glycolic acid Drugs 0.000 claims description 4
- 229930182470 glycoside Natural products 0.000 claims description 4
- 238000005096 rolling process Methods 0.000 claims description 4
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 4
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 4
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 claims description 3
- 125000005227 alkyl sulfonate group Chemical group 0.000 claims description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 2
- IDQBJILTOGBZCR-UHFFFAOYSA-N 1-butoxypropan-1-ol Chemical compound CCCCOC(O)CC IDQBJILTOGBZCR-UHFFFAOYSA-N 0.000 claims description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 2
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 claims description 2
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims description 2
- 239000005642 Oleic acid Substances 0.000 claims description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical group [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- PCHPORCSPXIHLZ-UHFFFAOYSA-N diphenhydramine hydrochloride Chemical compound [Cl-].C=1C=CC=CC=1C(OCC[NH+](C)C)C1=CC=CC=C1 PCHPORCSPXIHLZ-UHFFFAOYSA-N 0.000 claims description 2
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims description 2
- LRMHFDNWKCSEQU-UHFFFAOYSA-N ethoxyethane;phenol Chemical compound CCOCC.OC1=CC=CC=C1 LRMHFDNWKCSEQU-UHFFFAOYSA-N 0.000 claims description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 2
- 235000019799 monosodium phosphate Nutrition 0.000 claims description 2
- 229910000403 monosodium phosphate Inorganic materials 0.000 claims description 2
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 claims description 2
- HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 claims description 2
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 claims description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 2
- 235000011152 sodium sulphate Nutrition 0.000 claims description 2
- 239000001433 sodium tartrate Substances 0.000 claims description 2
- 229960002167 sodium tartrate Drugs 0.000 claims description 2
- 235000011004 sodium tartrates Nutrition 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims 3
- QGJDXUIYIUGQGO-UHFFFAOYSA-N 1-[2-[(2-methylpropan-2-yl)oxycarbonylamino]propanoyl]pyrrolidine-2-carboxylic acid Chemical compound CC(C)(C)OC(=O)NC(C)C(=O)N1CCCC1C(O)=O QGJDXUIYIUGQGO-UHFFFAOYSA-N 0.000 claims 1
- URDCARMUOSMFFI-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid Chemical compound OCCN(CC(O)=O)CCN(CC(O)=O)CC(O)=O URDCARMUOSMFFI-UHFFFAOYSA-N 0.000 claims 1
- 235000005979 Citrus limon Nutrition 0.000 claims 1
- 244000131522 Citrus pyriformis Species 0.000 claims 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims 1
- 229960001484 edetic acid Drugs 0.000 claims 1
- 235000019353 potassium silicate Nutrition 0.000 claims 1
- 229940083542 sodium Drugs 0.000 claims 1
- 235000015424 sodium Nutrition 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract description 11
- 230000000694 effects Effects 0.000 abstract description 6
- 238000004945 emulsification Methods 0.000 abstract description 5
- 239000012752 auxiliary agent Substances 0.000 abstract description 4
- 239000000470 constituent Substances 0.000 abstract description 3
- 230000000052 comparative effect Effects 0.000 description 12
- 238000012360 testing method Methods 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 230000000740 bleeding effect Effects 0.000 description 6
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 5
- 238000005498 polishing Methods 0.000 description 4
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 description 3
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000012943 hotmelt Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- HAEVLZUBSLBWIX-UHFFFAOYSA-N 2-octylphenol;oxirane Chemical group C1CO1.CCCCCCCCC1=CC=CC=C1O HAEVLZUBSLBWIX-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- QGMRQYFBGABWDR-UHFFFAOYSA-M Pentobarbital sodium Chemical compound [Na+].CCCC(C)C1(CC)C(=O)NC(=O)[N-]C1=O QGMRQYFBGABWDR-UHFFFAOYSA-M 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 229920001800 Shellac Polymers 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 229940031098 ethanolamine Drugs 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- OUDSFQBUEBFSPS-UHFFFAOYSA-N ethylenediaminetriacetic acid Chemical compound OC(=O)CNCCN(CC(O)=O)CC(O)=O OUDSFQBUEBFSPS-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- WSHYKIAQCMIPTB-UHFFFAOYSA-M potassium;2-oxo-3-(3-oxo-1-phenylbutyl)chromen-4-olate Chemical compound [K+].[O-]C=1C2=CC=CC=C2OC(=O)C=1C(CC(=O)C)C1=CC=CC=C1 WSHYKIAQCMIPTB-UHFFFAOYSA-M 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 229960001790 sodium citrate Drugs 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 230000017105 transposition Effects 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 238000004018 waxing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/10—Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/10—Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration
- B08B3/12—Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration by sonic or ultrasonic vibrations
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
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- C11D2111/18—
Abstract
The present invention provides a kind of glass Wax removal water, ingredients are as follows: the alkalescent inorganic salts of 2~6wt%；The chelating agent of 3~6wt%；The surfactant of 10~25wt%；The cosolvent of 2~10wt%；Surplus is water；The surfactant is anionic surfactant and nonionic surfactant, and the mass ratio of the anionic surfactant and nonionic surfactant is (2~8): (10~20).Glass provided by the invention is according to designed by the characteristic of bonding wax with Wax removal water, it is free of the strong basicities auxiliary agents such as sodium hydroxide and potassium hydroxide in being formulated, it is compounded simultaneously by anionic surfactant and nonionic surfactant, under the collective effect of above-mentioned paraffin removal water constituent, its emulsification and cleaning ability are improved while can be improved Wax removal water cloud point.The present invention also provides a kind of cleaning methods for bonding wax.
Description
Technical field
The present invention relates to bonding wax technical field more particularly to a kind of glass Wax removal waters and bonding wax cleaning method.
Background technique
Bonding wax is mainly made of paraffin, rosin and shellac, suitable for carrier and glass elements, precision instrument element
It is adhesively fixed, in order to carry out polishing or other surfaces processing.It can be adjusted by changing the proportion of each ingredient in bonding wax
Fusing point, fusing point are the key that bonding wax physicochemical properties, and the height of fusing point directly affects the hot melt for bonding wax and cleaning, fusing point are too low
It can cause to bond wax softening generation transposition and the changing of the relative positions due to product heating in process, influence to process；The too high influence of fusing point
Hot melt waxing efficiency, it is difficult to also result in later product cleaning, or even can not clean up.The fusing point of bonding wax is generally controlled at present
System is between 50~85 DEG C.
The fixed progress surface polishing of dental lamina can be used in general glass polishing, but when thickness of glass≤0.3mm, needs to use
The fixed product of bonding wax is polished again.But the prior art needs to consume in the bonding wax on the glass product after removal polishing
Take the plenty of time and removal effect is poor.Therefore it provides a kind of bonding wax that can rapidly, completely remove glass surface
Method becomes the hot spot of this field research.
Summary of the invention
In view of this, the purpose of the present invention is to provide a kind of glass Wax removal water and bonding wax cleaning method, the present invention
The bonding wax cleaning method of offer can fast and efficiently remove the bonding wax of glass surface.
The present invention provides a kind of glass Wax removal water, ingredients are as follows:
The alkalescent inorganic salts of 2~6wt%；
The chelating agent of 3~6wt%；
The surfactant of 10~25wt%；
The cosolvent of 2~10wt%；
Surplus is water.
In the present invention, the mass content of the alkalescent inorganic salts is preferably 3~5%, and more preferably 4%.In this hair
In bright, the alkalescent inorganic salts are preferably selected from sodium carbonate, sodium tripolyphosphate, sodium dihydrogen phosphate, sodium metasilicate, metasilicate pentahydrate sodium
One or more of with potassium pyrophosphate, more preferably in sodium tripolyphosphate, sodium carbonate, potassium pyrophosphate and anhydrous sodium metasilicate
One or both of one or more, most preferably sodium tripolyphosphate, sodium carbonate, potassium pyrophosphate and anhydrous sodium metasilicate.
Without using the strong basicities auxiliary agents such as sodium hydroxide or potassium hydroxide, Neng Gou in glass Wax removal water provided by the invention
Emulsification and cleaning ability are improved while improving Wax removal water cloud point.
In the present invention, the mass content of the chelating agent is preferably 4~5%.In the present invention, the chelating agent is preferred
Selected from tetrasodium ethylenediamine tetraacetate (ETDA-4Na), disodium ethylene diamine tetraacetate (ETDA-2Na), sodium gluconate, glucoheptonic acid
Sodium, aminotriacetic acid, four sodium of 1-hydroxy ethylidene-1,1-diphosphonic acid (HEDP-4Na), sodium citrate, sodium tartrate, hydroxyacetic acid and ethoxy
One or more of ethylenediamine triacetic acid (HEDTA), more preferably ETDA-4Na, HEDP-4Na, sodium gluconate, amino three
One or both of acetic acid and hydroxyacetic acid.
In the present invention, the mass content of the surfactant is preferably 15~20%, and more preferably 17~18%.?
In the present invention, the surfactant is anionic surfactant and nonionic surfactant.Glass provided by the invention
It is compounded with Wax removal water using anionic surfactant and nonionic surfactant.
In the present invention, the anionic surfactant is preferably selected from enuatrol, sodium secondary alkyl sulfonate (SAS60), rouge
One or more of fat alcohol polyethenoxy ether sodium sulfate (AES) and fatty acid methyl ester ethoxylate sulfonate (FMES).
In the present invention, the nonionic surfactant is preferably selected from trihydroxy ethylamine oleate soap, coco-nut oil fatty acid two
Diethanol amide (6501), isopropanol amide (6508), aliphatic acid polyethenoxy ether (AEO-9), isomeric alcohol polyethenoxy ether
(TO-8), polyoxethylene octylphenyl phenol ether (OP-10), fatty acid methyl ester ethoxylate (FMEE), fatty alcohol polyoxyethylene ether
One or more of (JFC bleeding agent) and alkoxy quaternary ammonium compounds (REWOQUAT CQ AL 100), more preferably 6501,
One of OP-10, JFC bleeding agent, trihydroxy ethylamine oleate soap, AEO-9, TO-8, FMEE and REWOQUAT CQ AL 100 or
It is several.
The present invention is compounded using anionic surfactant and nonionic surfactant, it is preferred to use mentioned kind
Anionic surfactant and nonionic surfactant, the two have synergistic effect, can under the interaction of the two
Emulsification and the cleaning ability that product is improved while improving Wax removal water cloud point have Wax removal water provided by the invention preferable
Cleaning effect.
In the present invention, the mass ratio of the anionic surfactant and nonionic surfactant is (2~8): (10
~20), preferably (3~7): (12~13).The present invention is preferably according to aforementioned proportion by anionic surfactant and nonionic
Surfactant is compounded, and the glass obtained can be made to be imitated with Wax removal water with preferable paraffin removal using aforementioned proportion compounding
Fruit.
In the present invention, the mass content of the cosolvent is preferably 3~9%, and more preferably 4~8%, most preferably 5
~7%.In the present invention, the cosolvent be preferably selected from isopropanol, propylene glycol monomethyl ether, dipropylene glycol methyl ether, propandiol butyl ether,
One or more of alkyl glycosides, triethanolamine and monoethanolamine, more preferably alkyl glycosides and propylene glycol monomethyl ether, three second
One or more of hydramine and propylene glycol monomethyl ether.
Glass provided by the invention is that hydroxide is free of in formula according to designed by the characteristic of bonding wax with Wax removal water
The strong basicities auxiliary agent such as sodium and potassium hydroxide, while being compounded by anionic surfactant and nonionic surfactant,
Under the collective effect of above-mentioned paraffin removal water constituent, its emulsification and cleaning ability are improved while can be improved Wax removal water cloud point.
Using Wax removal water provided by the invention and combine subsequent cleaning method can be rapid, clean cleaning glass product
The bonding wax of upper remnants.
The present invention does not have special limitation to the preparation method of the glass Wax removal water, according to described in above-mentioned technical proposal
Glass Wax removal water ingredient and component content by various composition mix can be obtained glass Wax removal water.
The present invention provides a kind of bonding wax cleaning methods, comprising:
Glass product with bonding wax is shaken in glass paraffin removal aqueous solution and is washed；
The glass product after washing will be shaken and carry out ultrasonic cleaning.
The present invention does not have special limitation to the type of the bonding wax and source, and use is well known to those skilled in the art
Bond wax.In the present invention, the fusing point of the bonding wax is preferably 65~75 DEG C, and more preferably 70 DEG C.
In the present invention, the glass is preferably glass Wax removal water aqueous solution with paraffin removal aqueous solution, and the glass is with removing
The volumetric concentration of Wax removal water is preferably 8~12% in wax water aqueous solution, and more preferably 9~11%, most preferably 10%.In this hair
In bright, the glass Wax removal water is consistent with glass Wax removal water described in above-mentioned technical proposal, and details are not described herein.
In the present invention, the temperature washed of shaking is preferably 75~80 DEG C, and more preferably 76~79 DEG C, most preferably 77~
78℃；The speed washed of shaking is preferably 0.08~0.12m/s, more preferably 0.09~0.11m/s, most preferably 0.1m/s；
The time that the rolling is washed is preferably 4~7min, more preferably 5~6min.The present invention is to the specific method washed that shakes without spy
Different limitation, those skilled in the art can carry out rocking cleaning according to above-mentioned technological parameter.Present invention preferably employs above-mentioned
Technique is washed in the rolling of technological parameter, is carried out shaking with this condition and is washed the bonding wax that can preferably remove glass product surface, is convenient for
Subsequent ultrasonic cleaning.
The present invention washes carry out prerinse using rolling, can largely reduce and bring the bonding wax on product into supersonic wave cleaning machine
In cleaned, reduce the difficulty of ultrasonic cleaning, can be improved ability and the service life of supersonic wave cleaning machine.
In the present invention, reagent used by the ultrasonic cleaning is glass Wax removal water aqueous solution；The glass is used
The volumetric concentration of Wax removal water is preferably 3~6% in Wax removal water aqueous solution, and more preferably 4~5%.In the present invention, the paraffin removal
Water is consistent with Wax removal water described in above-mentioned technical proposal, and details are not described herein.
In the present invention, the temperature of the ultrasonic cleaning is preferably 75~80 DEG C, and more preferably 76~79 DEG C, most preferably
It is 77~78 DEG C；The frequency of the ultrasonic cleaning is preferably 35~45KHz, more preferably 40KHz；The ultrasonic cleaning
Electric current is preferably 1.0~1.5A, more preferably 1.1~1.4A, most preferably 1.2~1.3A；The time of the ultrasonic cleaning
Preferably 200~300s, more preferably 220~280s, most preferably 240~260s.In the present invention, the ultrasonic cleaning
It is preferred that being carried out in supersonic wave cleaning machine.In the present invention, it is contemplated that the working time of ultrasonic cleaning apparatus is preferably in two times
Ultrasonic cleaning is completed, the time of each ultrasonic cleaning is preferably 100~150s, more preferably 110~140s, most preferably
120~130s.Present invention preferably employs the ultrasonic cleaning process of above-mentioned technological parameter, under this process condition can be better
Ultrasonic cleaning is completed, there is good cleaning effect.
Method provided by the invention is mainly used for the remaining bonding wax on the glass product after clean the surface processing, the present invention
It is viscous that the glass of offer Wax removal water and cleaning process matched with its can fast and efficiently clean the remnants on glass product
Wax deposition.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common
Technical staff it is improved or retouching all other example, shall fall within the protection scope of the present invention.
Raw materials used following embodiment of the present invention is commercial goods.
Embodiment 1
The ingredient of glass Wax removal water provided in this embodiment are as follows: the sodium tripolyphosphate of 2wt%, 2wt% sodium carbonate,
The enuatrol of EDTA-4Na, 7wt% of 5wt%, the coco-nut oil fatty acid diethanol amine amide (6501) of 5wt%, 3wt% it is poly-
It is ethylene oxide octyl phenol ether (OP-10), the fatty alcohol polyoxyethylene ether (JFC bleeding agent) of 2wt%, the alkyl glycosides of 5wt%, remaining
Amount is water.
Mentioned component is mixed according to dosage, obtains glass Wax removal water.
It is applied to 200pcs glass product surface after the bonding wax heating for being 70 DEG C by commercially available fusing point, then produces glass
Product are cooled to room temperature, and are formed on its surface bonding wax layer.By the above-mentioned glass product with bonding wax layer in Wax removal water aqueous solution
In shake and wash, the volumetric concentration of Wax removal water aqueous solution is 10%, and shaking the temperature washed is 75 DEG C, and shaking the speed washed is 0.1m/s,
Shaking the time washed is 5min；Then two groove ultrasonic cleanings are successively carried out again, and the reagent of ultrasonic cleaning is that volumetric concentration is 5%
Wax removal water aqueous solution, the temperature of ultrasonic cleaning is 75 DEG C, and the frequency of ultrasonic cleaning is 40KHz, the electricity of ultrasonic cleaning
Stream is 1.2A, and the time of every groove ultrasonic cleaning is 120s.
Glass product after the glass for using embodiment 1 to provide is cleaned with Wax removal water illumination for
It under the fluorescent lamp of 1200~1400Lux, is placed on black and white bottom plate, dries net products with non-dust cloth, both hands take product
Kept for 45 ° with table top, product firmly made slowly to overturn 15 ° up and down, judge whether glass product surface has a bad order, product away from
20~25cm of eyes, product to light distance are greater than 40cm.
Testing result is the 200pcs glass product after over cleaning, scratches 4pcs, dirty 5pcs, chipping 3pcs, yield
Reach 94%.
Embodiment 2
The ingredient of glass Wax removal water provided in this embodiment are as follows: the sodium tripolyphosphate of 2wt%, 2wt% potassium pyrophosphate,
The fatty acid polyoxy second of the sodium gluconate of EDTA-4Na, 3wt% of 3wt%, the trihydroxy ethylamine oleate soap of 10wt%, 5wt%
Alkene ether (AEO-9), the isomeric alcohol polyethenoxy ether (TO-8) of 3wt%, the fatty alcohol polyoxyethylene ether of 2wt% (JFC bleeding agent),
The % fatty acid methyl ester ethoxylate sulfonate (FMES) of 2wt, the dipropylene glycol methyl ether of 8wt%, surplus are water.
Mentioned component is mixed according to dosage, obtains glass Wax removal water.
The glass Wax removal water provided according to the method for embodiment 1 using the embodiment of the present invention 2 is to bonding wax layer
Glass product is cleaned.
According to the method for embodiment 1, the product after the embodiment of the present invention 2 being cleaned detects.Testing result is to pass through
200pcs glass product after cleaning, scratches 3pcs, dirty 3pcs, chipping 5pcs, and yield reaches 94.5%.
Embodiment 3
The ingredient of glass Wax removal water provided in this embodiment are as follows: the amino three of the metasilicate pentahydrate sodium of 4wt%, 3wt%
Acetic acid, the hydroxyacetic acid of 3wt%, the trihydroxy ethylamine oleate soap of 7wt%, 5wt% coco-nut oil fatty acid diethanol amine amide
(6501), the fatty acid methyl ester ethoxylate (FMES) of 3wt%, the sodium secondary alkyl sulfonate (SAS60) of 2wt%, 5wt% three
Ethanol amine, the propylene glycol monomethyl ether of 4wt%, surplus are water.
Mentioned component is mixed according to dosage, obtains glass Wax removal water.
The glass Wax removal water provided according to the method for embodiment 1 using the embodiment of the present invention 3 is to bonding wax layer
Glass product is cleaned.
According to the method for embodiment 1, the product after the embodiment of the present invention 3 being cleaned detects.Testing result is to pass through
200pcs glass product after cleaning, scratches 5pcs, dirty 6pcs, chipping 3pcs, and yield reaches 93%.
Embodiment 4
The ingredient of glass Wax removal water provided in this embodiment are as follows: the HEDP- of the metasilicate pentahydrate sodium of 5wt%, 3wt%
The sodium gluconate of 4Na, 3wt%, the enuatrol of 8wt%, 5wt% coco-nut oil fatty acid diethanol amine amide (6501),
The alkoxy quaternary ammonium compounds (REWOQUAT CQ AL 100) of 2wt%, the isomeric alcohol polyethenoxy ether (TO-8) of 3wt%,
Fatty alcohol polyoxyethylene ether (JFC bleeding agent), the triethanolamine of 5wt%, the propylene glycol monomethyl ether of 5wt%, the surplus of 2wt% be
Water.
Mentioned component is mixed according to dosage, obtains glass Wax removal water.
The glass Wax removal water provided according to the method for embodiment 1 using the embodiment of the present invention 4 is to bonding wax layer
Glass product is cleaned.
According to the method for embodiment 1, the product after the embodiment of the present invention 4 being cleaned detects.Testing result is to pass through
200pcs glass product after cleaning, scratches 2pcs, dirty 0pcs, chipping 1pcs, and yield reaches 98.5%.
Comparative example 1
The ingredient of glass Wax removal water and the difference of embodiment 4 that this comparative example provides are, using the hydroxide of 5wt%
Sodium replaces the metasilicate pentahydrate sodium of the 5wt% in embodiment 4, remaining ingredient and component content and embodiment 4 consistent.
The glass Wax removal water provided according to the method for embodiment 1 using comparative example 1 of the present invention is to bonding wax layer
Glass product is cleaned.
According to the method for embodiment 1, the product after comparative example 1 of the present invention cleaning is detected.Testing result is to pass through
200pcs glass product after cleaning, scratches 11pcs, dirty 5pcs, chipping 0pcs, and yield reaches 92%.
Comparative example 2
The ingredient of glass Wax removal water and the difference of embodiment 4 that this comparative example provides are, using the oleic acid of 20wt%
Sodium, it is removal coco-nut oil fatty acid diethanol amine amide (6501), alkoxy quaternary ammonium compounds (REWOQUAT CQ AL 100), different
Structure alcohol polyoxyethylene ether (TO-8) and fatty alcohol polyoxyethylene ether (JFC bleeding agent) ingredient, remaining ingredient and component content with
Embodiment 4 is consistent.
The glass Wax removal water provided according to the method for embodiment 1 using comparative example 2 of the present invention is to bonding wax layer
Glass product is cleaned.
According to the method for embodiment 1, the product after comparative example 2 of the present invention cleaning is detected.Testing result is to pass through
200pcs glass product after cleaning, scratches 3pcs, dirty 24pcs, chipping 0pcs, and yield reaches 86.5%.
Comparative example 3
The ingredient of glass Wax removal water and the difference of embodiment 4 that this comparative example provides are, remove enuatrol ingredient, adopt
With the coco-nut oil fatty acid diethanol amine amide (6501) of 13wt%, remaining ingredient and component content and embodiment 4 are unanimously.
The glass Wax removal water provided according to the method for embodiment 1 using comparative example 3 of the present invention is to bonding wax layer
Glass product is cleaned.
According to the method for embodiment 1, the product after comparative example 3 of the present invention cleaning is detected.Testing result is to pass through
200pcs glass product after cleaning, scratches 1pcs, dirty 17pcs, chipping 1pcs, and yield reaches 90.5%.
As seen from the above embodiment, the present invention provides a kind of glass Wax removal water, ingredients are as follows: the alkalescent of 2~6wt%
Inorganic salts；The chelating agent of 3~6wt%；The surfactant of 10~25wt%；The cosolvent of 2~10wt%；Surplus is water；Institute
Stating surfactant is anionic surfactant and nonionic surfactant, the anionic surfactant and nonionic
The mass ratio of surfactant is (2~8): (10~20).Glass provided by the invention is according to the spy for bonding wax with Wax removal water
Property designed by, without the strong basicities auxiliary agent such as sodium hydroxide and potassium hydroxide in formula, while passing through anion surface active
Agent and nonionic surfactant are compounded, and under the collective effect of above-mentioned paraffin removal water constituent, can be improved Wax removal water cloud point
While improve its emulsification and cleaning ability.The present invention also provides a kind of cleaning methods for bonding wax.
What has been described above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill of the art
For personnel, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications
It should be regarded as protection scope of the present invention.
Claims (10)
1. a kind of glass Wax removal water, ingredient are as follows:
The alkalescent inorganic salts of 2~6wt%；
The chelating agent of 3~6wt%；
The surfactant of 10~25wt%, the surfactant are anionic surfactant and non-ionic surface active
The mass ratio of agent, the anionic surfactant and nonionic surfactant is (2~8): (10~20)；
The cosolvent of 2~10wt%；
Surplus is water.
2. glass Wax removal water according to claim 1, which is characterized in that the alkalescent inorganic salts be selected from sodium carbonate,
One or more of sodium tripolyphosphate, sodium dihydrogen phosphate, sodium metasilicate, metasilicate pentahydrate sodium and potassium pyrophosphate.
3. glass Wax removal water according to claim 1, which is characterized in that the chelating agent is selected from ethylenediamine tetra-acetic acid four
Sodium, disodium ethylene diamine tetraacetate, sodium gluconate, sodium glucoheptonate, aminotriacetic acid, four sodium of 1-hydroxy ethylidene-1,1-diphosphonic acid, lemon
One or more of sour sodium, sodium tartrate, hydroxyacetic acid and hydroxyethylethylene diamine tri-acetic acid.
4. glass Wax removal water according to claim 1, which is characterized in that the anionic surfactant is selected from oleic acid
One of sodium, sodium secondary alkyl sulfonate, sodium sulfate of polyethenoxy ether of fatty alcohol and fatty acid methyl ester ethoxylate sulfonate or
It is several.
5. glass Wax removal water according to claim 1, which is characterized in that the nonionic surfactant is selected from three second
Hydramine oleate soap, coco-nut oil fatty acid diethanol amine amide, isopropanol amide, aliphatic acid polyethenoxy ether, isomery alcohol polyoxy second
Alkene ether, polyoxethylene octylphenyl phenol ether, fatty acid methyl ester ethoxylate, fatty alcohol polyoxyethylene ether and alkoxy quaternary ammonium chemical combination
One or more of object.
6. glass Wax removal water according to claim 1, which is characterized in that the cosolvent is selected from isopropanol, propylene glycol
One or more of methyl ether, dipropylene glycol methyl ether, propandiol butyl ether, alkyl glycosides, triethanolamine and monoethanolamine.
7. a kind of bonding wax cleaning method, comprising:
Glass product with bonding wax is shaken in glass paraffin removal aqueous solution and is washed, the glass is claim with Wax removal water
Glass Wax removal water described in 1；
The glass product after washing will be shaken and carry out ultrasonic cleaning.
8. the method according to the description of claim 7 is characterized in that the glass is dense with the volume of Wax removal water in paraffin removal aqueous solution
Degree is 8~12%.
9. the method according to the description of claim 7 is characterized in that the temperature washed of shaking is 75~80 DEG C, described shake is washed
Speed is 0.08~0.12m/s；The time that the rolling is washed is 4~7min.
10. the method according to the description of claim 7 is characterized in that the temperature of the ultrasonic cleaning is 75~80 DEG C；It is described
The frequency of ultrasonic cleaning is 35~45KHz；The electric current of the ultrasonic cleaning is 1.0~1.5A；The ultrasonic cleaning
Time is 200~300s.
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| CN112592768A (en) * | 2020-12-15 | 2021-04-02 | 广东红日星实业有限公司 | Glass cleaning agent and preparation method thereof |
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| CN111979553A (en) * | 2020-09-22 | 2020-11-24 | 哈尔滨铁路石化销售有限公司 | Water-based bearing cleaning fluid |
| CN112592768A (en) * | 2020-12-15 | 2021-04-02 | 广东红日星实业有限公司 | Glass cleaning agent and preparation method thereof |
| CN112808684A (en) * | 2020-12-30 | 2021-05-18 | 蓝思科技股份有限公司 | Method for dewaxing nickel-plated metal product |
| CN112808684B (en) * | 2020-12-30 | 2022-05-03 | 蓝思科技股份有限公司 | Method for dewaxing nickel-plated metal product |
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