CN111979553A - Water-based bearing cleaning fluid - Google Patents

Water-based bearing cleaning fluid Download PDF

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Publication number
CN111979553A
CN111979553A CN202011000737.5A CN202011000737A CN111979553A CN 111979553 A CN111979553 A CN 111979553A CN 202011000737 A CN202011000737 A CN 202011000737A CN 111979553 A CN111979553 A CN 111979553A
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CN
China
Prior art keywords
parts
water
sodium
cleaning solution
based bearing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202011000737.5A
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Chinese (zh)
Inventor
崔建昕
王志刚
闫志福
栾洪东
刘�东
孙继伟
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Harbin Railway Petrochemical Sales Co ltd
Original Assignee
Harbin Railway Petrochemical Sales Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Harbin Railway Petrochemical Sales Co ltd filed Critical Harbin Railway Petrochemical Sales Co ltd
Priority to CN202011000737.5A priority Critical patent/CN111979553A/en
Publication of CN111979553A publication Critical patent/CN111979553A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/14Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
    • C23G1/16Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions using inhibitors
    • C23G1/18Organic inhibitors

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Abstract

The invention discloses a water-based bearing cleaning solution which is prepared by mixing and uniformly stirring the following components in parts by weight: 3-5 parts of hydroxyl ethylidene diphosphonic acid tetrasodium, 0.8-1.5 parts of sodium metasilicate pentahydrate, 1-2 parts of sodium citrate, 1-3 parts of sodium tripolyphosphate, 0.3-0.6 part of sodium secondary alkyl sulfonate, 1-5 parts of triethanolamine, 0.3-0.6 part of sodium molybdate, 1-3 parts of ethylene glycol ether and 75-85 parts of water. The water-based bearing cleaning solution has a wide decontamination range, can be combined with most of the existing cooling liquid or lubricating liquid, and promotes the surface separation of the water-based bearing cleaning solution from the bearing and the like, so that the decontamination effect is achieved. The cleaning solution has good cleaning effect, strong cleaning capability, high speed and certain antirust effect. The cleaning liquid can also be used for cleaning other metal surfaces.

Description

Water-based bearing cleaning fluid
Technical Field
The invention belongs to the technical field of cleaning protection, and particularly relates to a water-based bearing cleaning solution.
Background
In the machining process of mechanical parts, a large amount of cooling liquid or lubricating liquid is used, most of the liquid contains oily substances, a certain amount of residues are left on the surfaces of the parts, and the subsequent processes such as electroplating or coating treatment of the parts are influenced to a certain degree, so that the parts need to be cleaned and removed before assembly.
Particularly, for a bearing, the bearing is used as a precise part, the requirements on vibration value and noise are high, the dimensional accuracy of the bearing with good quality is correspondingly high, and a few tiny impurities can bring serious adverse effects. In addition, the ring channel of part of the bearing is deep, and the cleaning effect is greatly influenced because the common cleaning agent is not thorough to clean.
Disclosure of Invention
In order to solve the problems in the prior art, the invention provides a water-based bearing cleaning solution.
The invention is realized by the following technical scheme:
a water-based bearing cleaning fluid is characterized in that: the water-based bearing cleaning solution is prepared by mixing and uniformly stirring the following components in parts by weight: 3-5 parts of hydroxyl ethylidene diphosphonic acid tetrasodium, 0.8-1.5 parts of sodium metasilicate pentahydrate, 1-2 parts of sodium citrate, 1-3 parts of sodium tripolyphosphate, 0.3-0.6 part of sodium secondary alkyl sulfonate, 1-5 parts of triethanolamine, 0.3-0.6 part of sodium molybdate, 1-3 parts of ethylene glycol ether and 75-85 parts of water.
Further: the water-based bearing cleaning solution is prepared by mixing and uniformly stirring the following components in parts by weight: 4 parts of hydroxyl ethylidene diphosphonic acid tetrasodium, 1 part of sodium metasilicate pentahydrate, 1.5 parts of sodium citrate, 2 parts of sodium tripolyphosphate, 0.4 part of secondary alkyl sodium sulfonate, 0.4 part of triethanolamine, 0.4 part of sodium molybdate, 2 parts of ethylene glycol ethyl ether and 82 parts of water.
The invention has the advantages that: the water-based bearing cleaning solution has a wide decontamination range, can be combined with most of the existing cooling liquid or lubricating liquid, and promotes the surface separation of the water-based bearing cleaning solution from the bearing and the like, so that the decontamination effect is achieved. The cleaning solution has good cleaning effect, strong cleaning capability, high speed and certain antirust effect. The cleaning liquid can also be used for cleaning other metal surfaces.
Detailed Description
The following examples are given to facilitate a better understanding of the invention, but do not limit the invention. The experimental procedures in the following examples are conventional unless otherwise specified.
The invention discloses a water-based bearing cleaning solution which is prepared by mixing and uniformly stirring the following components in parts by weight: 3-5 parts of hydroxyethylidene diphosphonic acid tetrasodium (HEDP 4 sodium), 0.8-1.5 parts of sodium metasilicate pentahydrate, 1-2 parts of sodium citrate, 1-3 parts of sodium tripolyphosphate, 0.3-0.6 part of sodium secondary alkyl sulfonate (SAS 60), 1-5 parts of triethanolamine, 0.3-0.6 part of sodium molybdate, 1-3 parts of ethylene glycol ether and 75-85 parts of water.
The invention is further illustrated by the following specific examples.
Example 1
The formulation of the water-based bearing cleaning solution of this example is as follows:
4kg of HEDP4 sodium, 1kg of sodium metasilicate pentahydrate, 1.5kg of sodium citrate, 2kg of sodium tripolyphosphate, 600.5 kg of SAS600.5kg of triethanolamine, 0.5kg of sodium molybdate, 2kg of ethylene glycol ethyl ether and 80kg of water.
The preparation method of the water-based bearing cleaning solution comprises the following steps:
4kg of HEDP4 sodium, 1kg of sodium silicate, 1.5kg of sodium citrate, 2kg of sodium tripolyphosphate, 600.5 kg of SAS, 4kg of triethanolamine, 0.5kg of sodium molybdate, 2kg of ethylene glycol ethyl ether and 80kg of water are mixed and stirred uniformly to obtain the sodium-containing aqueous solution.
Example 2
The formula of the water-based bearing cleaning solution is as follows:
3kg of HEDP4 sodium, 1.2kg of sodium metasilicate pentahydrate, 1kg of sodium citrate, 3kg of sodium tripolyphosphate, 600.6 kg of SAS600, 5kg of triethanolamine, 0.4kg of sodium molybdate, 2kg of ethylene glycol ethyl ether and 80kg of water.
The preparation method of the water-based bearing cleaning solution in this example is the same as that of example 1.
Example 3
The formula of the water-based bearing cleaning solution is as follows:
5kg of HEDP4 sodium, 0.8kg of sodium metasilicate pentahydrate, 2kg of sodium citrate, 1kg of sodium tripolyphosphate, 600.4 kg of SAS600, 3kg of triethanolamine, 0.6kg of sodium molybdate, 2kg of ethylene glycol ether and 83kg of water.
The preparation method of the water-based bearing cleaning solution in this example is the same as that of example 1.
Example 4
The formula of the water-based bearing cleaning solution is as follows:
5kg of HEDP4 sodium, 0.9kg of sodium metasilicate pentahydrate, 1.2kg of sodium citrate, 1kg of sodium tripolyphosphate, 600.45kg of SAS, 3.5kg of triethanolamine, 0.45kg of sodium molybdate, 2kg of ethylene glycol ethyl ether and 81kg of water.
The preparation method of the water-based bearing cleaning solution in this example is the same as that of example 1.
When the bearing cleaning agent is used, the bearing is soaked in the cleaning solution for 1-2 hours, and then the clean cleaning solution is taken for washing, so that the bearing cleaning agent is simple and convenient to use, non-toxic, pollution-free, non-flammable and non-explosive.
After the cleaning agent is cleaned by the cleaning agent,
in the invention, the etidronate tetrasodium, HEDP Na4, which is a sodium salt of HEDP, is an excellent calcium carbonate scale inhibitor, and HEDP Na4 is mainly used for metal corrosion inhibition of low-pressure boiler water treatment, circulating water treatment, industrial and municipal water for cleaning and swimming pool sterilization. HEDP Na4 is white powder solid, easily soluble in water, not hygroscopic, convenient for transportation, and suitable for use under severe cold conditions. HEDP Na4 belongs to organic phosphonate scale and corrosion inhibitor, can form stable complex with iron, copper, zinc and other metal ions, and can dissolve oxide on metal surface. It still has good corrosion and scale inhibition effects at 250 ℃.
The secondary alkyl sodium sulfonate anionic surfactant has strong penetrability under strong alkali and high temperature conditions, and has the functions of emulsification, deoiling and washing. Has good compatibility with anionic and nonionic surfactants, and can remarkably improve the application effect of the system.
Ethylene glycol ethyl ether: the solvent is mainly used for nitrocellulose, cellulose acetate, synthetic resin and paint, the coating industry is used for preparing paint thinner and paint remover and preparing raw materials for spray painting, the pharmaceutical industry is used as a medicine extracting agent, the plastic industry is used for resin plasticizer, the textile industry is used as a fiber lubricant and a dispersing agent for chemical fiber oil agent, and the solvent can also be used as an automobile brake fluid, a pesticide dispersing agent, a dry cleaning agent, a cutting oil solvent, an organic synthetic intermediate, an auxiliary solvent for mineral oil emulsion, an analytical reagent and the like.
The cleaning agent obtained by the invention is aqueous and alkaline, not only has good environmental protection property, but also can improve the oil removal capability. The stable complex is formed by the etidronate tetrasodium and the metal, so that not only can the oxide on the surface of the metal be dissolved, but also the metal powder and the like generated in the prior procedure or adhered can be well dissolved and stripped, and a layer of compact protective film can be formed on the surface of the metal by the synergistic effect of sodium molybdate formed by various sodium salts in the scheme, so that the stable cleaning effect on the surface of the metal is realized, the adhesion effect on metal particles is prevented again, and meanwhile, the antirust protective film has the antirust protection function; in addition, the protective film has no adverse effect on the downstream process such as plating. The scheme is also effective in cleaning the bearing during the replacement of lubricating grease in the using process, and after the cleaning, the protective film can provide long-term protection.
The above description is only a preferred embodiment of the present invention, and is not intended to limit the present invention, and it is still possible for those skilled in the art to modify the technical solutions described in the above embodiments or to substitute part of the technical features thereof with equivalent functions. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (2)

1. The water-based bearing cleaning solution is characterized in that: the water-based bearing cleaning solution is prepared by mixing and uniformly stirring the following components in parts by weight:
3-5 parts of hydroxyethylidene diphosphonic acid tetrasodium
0.8 to 1.5 portions of sodium metasilicate pentahydrate
1-2 parts of sodium citrate
1-3 parts of sodium tripolyphosphate
0.3 to 0.6 portion of secondary alkyl sodium sulfonate
1-5 parts of triethanolamine
0.3 to 0.6 portion of sodium molybdate
1-3 parts of ethylene glycol monoethyl ether
And 75-85 parts of water.
2. The water-based bearing cleaning fluid as claimed in claim 1, wherein: the water-based bearing cleaning solution is prepared by mixing and uniformly stirring the following components in parts by weight:
4 parts of hydroxyethylidene diphosphonic acid tetrasodium
Sodium metasilicate pentahydrate 1 part
1.5 parts of sodium citrate
Sodium tripolyphosphate 2 parts
0.4 part of secondary alkyl sodium sulfonate
0.4 portion of triethanolamine
0.4 part of sodium molybdate
Ethylene glycol Ether 2 parts
And 82 parts of water.
CN202011000737.5A 2020-09-22 2020-09-22 Water-based bearing cleaning fluid Pending CN111979553A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202011000737.5A CN111979553A (en) 2020-09-22 2020-09-22 Water-based bearing cleaning fluid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202011000737.5A CN111979553A (en) 2020-09-22 2020-09-22 Water-based bearing cleaning fluid

Publications (1)

Publication Number Publication Date
CN111979553A true CN111979553A (en) 2020-11-24

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Country Status (1)

Country Link
CN (1) CN111979553A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114457339A (en) * 2022-02-22 2022-05-10 深圳市加逸科技有限公司 Metal antirust agent and preparation method thereof
CN114592196A (en) * 2022-03-14 2022-06-07 潍坊佳钢贸易有限公司 Environment-friendly neutral rust remover and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103600080A (en) * 2013-11-12 2014-02-26 东莞市安美润滑科技有限公司 Degumming cleaning fluid for processing neodymium iron boron magnetic materials
CN108425123A (en) * 2018-06-14 2018-08-21 如皋市华阳铝制品有限公司 A kind of anti-rust cleaning agent and preparation method thereof of aluminium and aluminium alloy
CN109370801A (en) * 2018-11-26 2019-02-22 蓝思科技(长沙)有限公司 A kind of glass Wax removal water and bonding wax cleaning method
CN109971560A (en) * 2019-05-13 2019-07-05 上海恩坤化学品有限公司 A kind of cleaning agent for metal parts and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103600080A (en) * 2013-11-12 2014-02-26 东莞市安美润滑科技有限公司 Degumming cleaning fluid for processing neodymium iron boron magnetic materials
CN108425123A (en) * 2018-06-14 2018-08-21 如皋市华阳铝制品有限公司 A kind of anti-rust cleaning agent and preparation method thereof of aluminium and aluminium alloy
CN109370801A (en) * 2018-11-26 2019-02-22 蓝思科技(长沙)有限公司 A kind of glass Wax removal water and bonding wax cleaning method
CN109971560A (en) * 2019-05-13 2019-07-05 上海恩坤化学品有限公司 A kind of cleaning agent for metal parts and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114457339A (en) * 2022-02-22 2022-05-10 深圳市加逸科技有限公司 Metal antirust agent and preparation method thereof
CN114592196A (en) * 2022-03-14 2022-06-07 潍坊佳钢贸易有限公司 Environment-friendly neutral rust remover and preparation method thereof

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Application publication date: 20201124