KR101408272B1 - Colourless surface lubricant for warm and hot forging, a manufacturing method thereof and a manufacturing method of forging product using the same - Google Patents

Abstract

TECHNICAL FIELD The present invention relates to a surface lubricating agent for forging, a method for producing the same, and a method for manufacturing a forged product using the same, and more particularly, to a colorless transparent environmentally friendly surface lubricant for use in the hot forging or warm- And a method for manufacturing a forged product using the same. The lubricating surface treatment agent for forging according to the present invention is colorless and transparent and does not use a black or white lubricating material having particles such as graphite, zirconium oxide, boron nitride, silicon dioxide, zinc oxide, aluminum oxide, titanium dioxide and the like, Since the pH is 6 ~ 9 neutral and weakly alkaline in the previous strong alkali, the working environment is clean and 100% water-soluble, so the cleaning and working environment of the product is clean and the hazard to the operator is greatly reduced.
In addition, heat resistance and lubricity are superior to conventional colored lubricants, surface conditions after heat treatment are uniform, and product quality is excellent. In addition, by preheating the forged material, applying the lubrication agent, and then drying the material, the pigment is hardly volatilized during the forging operation, and the lubrication of the forging product and the mold is enhanced. High strength and corrosion resistance of the forgings, and it is possible to obtain a high-precision product, and it has an excellent effect on the prolongation of the life of the mold by the mold protection and the rust prevention of the forgings, Lt; RTI ID = 0.0 > C, < / RTI >

Description

TECHNICAL FIELD The present invention relates to a colorless surface lubricant for warm and hot forging, a method for producing the same, and a method for manufacturing a forged product using the same.

TECHNICAL FIELD The present invention relates to a surface lubricating agent for forging, a method for producing the same, and a method for manufacturing a forged product using the same, and more particularly, to a colorless transparent environmentally friendly surface lubricant for use in the hot forging or warm- And a method for manufacturing a forged product using the same.

Forging is one of the metal working methods for pressing and deforming metal agglomerations or thick plates. Forging includes hot forging at high temperature, hot tempering at a temperature lower than hot, and cold forging at room temperature. Hot forging is generally carried out without special lubricant since it is forged at a high temperature such as aluminum at about 500 DEG C, steel at about 900 DEG C, stainless steel at about 1300 DEG C, and the like.

However, the surface lubrication treatment in hot forging increases the lubricity of forging products and molds, prevents seizure, increases physical properties such as oxidation resistance, high strength, corrosion resistance and the like of forgings, It is also used to extend the life of the mold by mold protection and to obtain excellent effects on the rust prevention of forging products.

The conventional surface lubrication treatment is a method in which a scale formed on a surface is removed by a degreasing and pickling process or the like and then a coating is applied by chemically treating the phosphate and then sodium soap is applied after neutralization so that direct contact with the material surface and mold surface Thereby preventing sticking at the time of molding and keeping the life of the mold long. In the conventional surface lubrication treatment, 10 steps consisting of degreasing, two-stage washing, sulfuric acid washing, washing, bending, zinc phosphate coating, washing, neutralization, metal lubrication and drying are sequentially carried out. The tank is filled with the chemical, the material is loaded into the tank filled with chemicals, the tank is processed for the relevant time, and the process is moved to the next process. When the 10 processes are completed, the product is taken out.

Further, in the past, black or white lubricating materials having particles such as graphite, zirconium oxide, boron nitride, silicon dioxide, zinc oxide, aluminum oxide, titanium dioxide and the like having almost all of the constituents of the lubricant are used, , The sedimentation stability of the product of the lubricating coating agent is poor and easily deteriorated, which greatly affects the forging product.

The first step of conventional surface lubrication processing is a degreasing process, and the most widely used method in cold forging is alkali degreasing. The alkali degreasing agent is cheap, and can remove all contaminants in one operation, so it is effective and easy to control. However, the alkaline degreasing agent must have the ability to be sulphated and emulsified, contain an additive to make it into a colloidal phase, and must be able to be removed from the flush.

A basic material that can be used as an alkali degreasing agent is an alkaline surface active agent. Surfactants reduce surface tension due to their strong wettability at low temperatures and have excellent emulsifying and dispersing capabilities. The alkaline degreasing agent must be able to remove the burnt-on carbon smut from the heat generated by the heat treatment or the acid cleaning process, secondly, to remove grease and oil, thirdly, Since it is necessary to be able to remove phosphates and soap residues produced after the work, the alkali degreasing agent should be selected to satisfy the above-mentioned conditions.

After the degreasing process, the pickling process is performed after two-step water washing. Scale is formed on the surface of iron or steel products manufactured by heat treatment or hot forming. In order to remove such scale, shot blasting is performed before putting into the process, Acid washing is carried out. Since the shot blasting is generally performed in the cold forging process, acid pickling is necessary to increase the surface area of the substrate to increase the formation of the zinc phosphate coating and the coating weight to improve the formability of the cold forging.

After pickling, the zinc phosphate coating process is carried out after rinsing and bathing. The zinc phosphate coating enhances formability during cold forging and helps to adhere soap in the subsequent lubrication process.

The solution used in the zinc phosphate coating process forms a film by attack of the free acid on the steel surface and precipitation of phosphate crystals. Therefore, when some iron is dissolved into the solution, iron and zinc phosphate (Iron and Zinc Phosphate) adhere to the steel surface and form a film. The chemical phenomena involved here are fairly complex, but can be briefly described as follows.

First, due to the interaction between the metal surface and free phosphoric acid, the first acid pickling reaction produces soluble ferrous phosphate (ferrous phosphate / [2Fe (H2PO4) 2]) by the reaction of Fe with phosphoric acid.

Next, zinc phosphate (Zinc Phosphate / [Zn3 (PO4) 2]), which is insoluble due to an increase in local pH at the interface between the metal and the solution, is produced. In solution, Zn (H2PO4) 2 is in equilibrium with insoluble Zn3 (PO4) 2 and H3PO4. Therefore, when reversing the reaction or adding free phosphoric acid to the working solution, the soluble Zinc Phosphate is produced only when the free phosphoric acid is reduced by contact with iron. Therefore, zinc phosphate film treatment is performed as an overall reaction mechanism for deposition of a phosphate film, followed by washing with water and neutralizing (Rinse) process. The neutralization process is a process to increase the effect of the metal soap in the post-process lubrication process. The solution to be used in the neutralization wash must be kept constant by the regular addition. However, even if chemicals are added regularly, the flushing water gradually becomes contaminated and becomes ineffective, and the solution must be discarded regularly. Generally, it is recommended to rehydrate once a week. It is very important to manage the neutralized water wash solution well. Metal soap baths are the most expensive and their management is also important.

After the neutralization process, a metal lubrication process is performed. In the case of cold heading, the reactive soap produces not only the lubrication required for Single Hole Sizing or Drawing of the Calibration Pass, but also the subsequent multi-step heading To provide a suitable residual lubricant.

Metal soaps have been added with life-extending ingredients, which include high grade sodium stearate, corrosion inhibitors, reaction additives to accelerate reactions with phosphate coatings, and salts to overcome water hardening ≪ / RTI >

As described above, the use of the conventional surface treatment agent is not only detrimental to the surface treatment agent itself, but also complicates the treatment process, making it difficult to use the surface treatment agent. Therefore, development of a surface treatment agent that is more environmentally friendly and usable in a simple process is required.

The present invention has been made in order to solve the problems of the prior art as described above, and it is an object of the present invention to provide a method and apparatus for a work machine which can maintain a working environment clean and is not harmful to an operator, The present invention also provides a method for producing a forging lubricant, a method for manufacturing the same, and a method for manufacturing a forged product using the same.

The present invention relates to a process for the preparation of a water-borne admixture comprising 0.5 to 4% by weight of a mixture of 2 to 10% by weight borax, 2 to 10% by weight of potassium carbonate, 4 to 20% by weight of boric acid, sodium hydroxide and potassium hydroxide in a weight ratio of 1: And an additive including a surfactant, an antifoaming agent, and a thickening agent is further added to the forging surface lubricant agent in an amount of 0.1 to 1 wt% based on the total weight of the forging surface lubricant.

The forging can be a hot forging or an on-tightening.

Further, the present invention is characterized in that the forged product is preheated, the preheated forgings are dried by impregnating or spray coating the forging surface lubricant of claim 1, followed by heat treatment and pressing.

The present invention also relates to a process for the preparation of a mixture comprising 0.5 to 4% by weight of a mixture of 2 to 10% by weight of borax, 2 to 10% by weight of potassium carbonate, 4 to 20% by weight of boric acid, sodium hydroxide and potassium hydroxide in a weight ratio of 1: A first step of dissolving 2 to 10% by weight of borax in the residual water obtained by preliminarily calculating the respective component contents in the forging surface lubricant;

A second step of dissolving 0.5 to 4% by weight of a mixture of 2 to 10% by weight of potassium carbonate, 4 to 20% by weight of boric acid, sodium hydroxide and potassium hydroxide in a weight ratio of 1: 1 in the solution of the first step;

And a third step of mixing 0.1 to 1% by weight of an additive including a surfactant, a defoaming agent and a thickening agent as additives for modifying the surface properties of the forging lubricant, to the total weight of the forging lubricant, to provide.

The lubricating surface treatment agent for forging according to the present invention is colorless and transparent and does not use a black or white lubricating material having particles such as graphite, zirconium oxide, boron nitride, silicon dioxide, zinc oxide, aluminum oxide, titanium dioxide and the like, Since the pH is 6 ~ 9 neutral and weakly alkaline in the previous strong alkali, the working environment is clean and 100% water-soluble, so the cleaning and working environment of the product is clean and the hazard to the operator is greatly reduced.

In addition, heat resistance and lubricity are superior to conventional colored lubricants, surface conditions after heat treatment are uniform, and product quality is excellent. In addition, by preheating the forged material, applying the lubrication agent, and then drying the material, the pigment is hardly volatilized during the forging operation, and the lubrication of the forging product and the mold is enhanced. High strength and corrosion resistance of the forgings, and it is possible to obtain a high-precision product, and it has an excellent effect on the prolongation of the life of the mold by the mold protection and the rust prevention of the forgings, Lt; RTI ID = 0.0 > C, < / RTI >

Hereinafter, the present invention will be described in detail.

The present invention relates to a colorless transparent eco-friendly surface lubricant for use in hot and warm tanks, a method for producing the same, and a method for producing a forged product using the same.

Accordingly, the present invention relates to a process for the preparation of a mixture comprising 0.5 to 4% by weight of a mixture of 2 to 10% by weight borax, 2 to 10% by weight of potassium carbonate, 4 to 20% by weight of boric acid, sodium hydroxide and potassium hydroxide in a weight ratio of 1: An additive including a surfactant, an antifoaming agent and a thickener is added to the forging lubricant containing water in an amount of 0.1 to 1 wt% based on the total weight of the forging lubricant.

The borax is used in an amount of 2 to 10% by weight. When the content of the borax is less than 2% by weight, the effect of lubricity is insignificant. When the content of borax exceeds 10% by weight, the borax is not dissolved well in water.

When the content is less than 2% by weight, potassium is less than boron (boron component in boric acid) and the lubricity is lowered. When the content is more than 10% by weight, boron There is a problem that the surface of the treatment agent can be corroded because the potassium is excessively increased to lower the lubricity and become strong alkali.

The boric acid is used in an amount of 4 to 20% by weight. When the content of the boric acid is less than 4% by weight, the effect of lubricity is weakened. When the content is more than 10% by weight, the boric acid is not dissolved well in water.

The amount of the compound selected from the group consisting of sodium hydroxide, potassium hydroxide and a combination thereof is 0.5-4% by weight. When the content is less than 0.5% by weight, boric acid can not be dissolved in water. When the content is more than 4% by weight, It becomes strong alkaline, and the surface of the treatment agent can be corroded.

The forging lubricant may further contain 0.1 to 1% by weight of at least one additive selected from the group consisting of a surfactant, a defoamer, and a thickener. The surfactant may be selected from, for example, polyethylene glycol, polypropylene glycol, polyethylene glycol nonyl (or octyl) phenyl ether, polypropylene glycol nonyl (or octyl) phenyl ether, ) phenyl ether, Block Copolymer, Polyethylene glycol allkyl ether, Polyethylene glycol fatty acid ester, and the like. Examples of the thickening agent include water-soluble Cellurose, such as Hydroxy ethyl cellurose, Hydroxypropyl methyl cellurose, Carboxy methyl cellurose, and Gellatine, Arabic gum, Dextrine, Alpha starch And the like.

In general, forging is a simple method in which forging is performed at a temperature higher than the temperature at which the recrystallization progresses in the material is performed at a temperature for hot forging and recrystallization, and the forging of the present invention is referred to as hot forging, have.

The surface lubricant for forging has a total solid content of 5 to 30% by weight and a neutral or weakly alkaline pH of 6 to 9.

When a surface lubricating agent is used, the total solid content can be adjusted by diluting the total solid content with water according to the characteristics of the forging product manufacturing process, and preferably, it can be diluted to 3.0 to 12.0 wt%.

In addition, the present invention is characterized in that 2 to 10% by weight of borax is dissolved in a residual amount of water, 2 to 10% by weight of potassium carbonate, 4 to 20% by weight of boric acid, 0.5 to 4% by weight of a compound selected from the group consisting of potassium hydroxide, potassium hydroxide and a combination thereof is dissolved.

In addition to the preparation method, 0.1 to 1% by weight of one or more additives selected from the group consisting of surfactants, antifoaming agents and thickening agents can be further dissolved. Examples of surfactants, antifoaming agents and thickening agents are as described above.

The method for producing the surface lubricating agent for forgings of the present invention proceeds largely in three steps.

In the first step, water dissolves 2 to 10% by weight of borax in the weight percent of the balance, excluding the total amount of the total components previously calculated.

In the second step, 2 to 10 wt% of potassium carbonate, 4 to 20 wt% of boric acid, and 0.5 to 4 wt% of a compound selected from sodium hydroxide, potassium hydroxide and a combination thereof are added to the solution in this order. The order of addition and dissolution must be observed. This is because when potassium carbonate is dissolved first, the boric acid dissolves, and potassium and boron react first to form a potassium / boron compound. When a compound selected from sodium hydroxide, potassium hydroxide and a combination thereof is added first, boron and sodium are reacted first to form a sodium / boron compound, which results in a loss of lubricity, and there is a problem in that a compound selected from sodium hydroxide, potassium hydroxide, Is added to completely insolubilize some insoluble boric acid.

In the third step, a surface-leveling surfactant, a water-soluble antifoaming agent, a water-soluble thickener, and the like are added as a general additive for modifying the physical properties of the surface to prepare a colorless transparent environmentally friendly surface lubricant used in hot and warm tanks. The kind of the additive is as described above.

In addition, the present invention is characterized in that the forged product is preheated and the preheated forgings are dried by impregnating or spray coating the surface lubricating agent for forging according to the present invention or the forging surface lubricating agent according to the manufacturing method of the present invention, And a method for producing such a forged product.

When a surface lubricating agent is used, the total solid content can be adjusted by diluting the total solid content with water according to the characteristics of the forging product manufacturing process, and preferably, it can be diluted to 3.0 to 12.0 wt%. It is preferable to coat the surface of the material so that the surface area of the forging material, that is, the weight of about 1.5 to 12.0 g / m < 2 >, during the process of impregnating or spray coating the lubricant.

Hereinafter, the present invention will be described in more detail by way of examples.

<Examples>

Example 1

300 g of borax was dissolved in 6.8 kg of water. To the solution was added 800 g of potassium carbonate, 1.8 kg of boric acid and 300 g of sodium hydroxide in succession to dissolve. In addition, 50 g of surfactant for surface leveling, 30 g of water-soluble defoamer and 20 g of water-soluble thickener were added to prepare a colorless transparent environmentally friendly surface lubricant for use in hot and warm tanks.

Example 2

800 g of borax was dissolved in 8.2 kg of water. To the solution, 300 g of potassium carbonate, 0.6 kg of boric acid and 100 g of potassium hydroxide were dissolved in succession. In addition, 50 g of surfactant for surface leveling, 30 g of water-soluble defoamer and 20 g of water-soluble thickener were added to prepare a colorless transparent environmentally friendly surface lubricant for use in hot and warm tanks.

Example 3

600 g of borax was dissolved in 7.3 kg of water. To the solution was added a mixture of 700 g of potassium carbonate, 1.2 kg of boric acid, 100 g of sodium hydroxide and 100 g of potassium hydroxide in succession to dissolve. In addition, 50 g of surfactant for surface leveling, 30 g of water-soluble defoamer and 20 g of water-soluble thickener were added to prepare a colorless transparent environmentally friendly surface lubricant for use in hot and warm tanks.

Example 4

To 8 kg of water, 700 g of potassium carbonate, 1.2 kg of boric acid and 100 g of potassium hydroxide were dissolved in succession. In addition, 50 g of surfactant for surface leveling, 30 g of water-soluble defoamer and 20 g of water-soluble thickener were added to prepare a colorless transparent environmentally friendly surface lubricant for use in hot and warm tanks.

Comparative Example 1 and Comparative Example 2

Existing forging surface lubricants having the components and contents shown in the following Table 1 were prepared. The content of each component is expressed in parts by weight.

ingredient Comparative Example 1 Comparative Example 2 Purified water 100 100 Triton-X100 0.1 5.0 BYK-024 * 2 0.1 0.3 Silicate (47%) Potassium silicate 20 Sodium metasilicate 20 MoS2 25 black smoke 10 20 Tinso 10 Alcoprint-PTF * 3 1.5 0.6 Solid content (%) 15.9 38.7 Sum 132 181

Property evaluation

The properties of the lubricants of Examples 1 to 4 and Comparative Examples 1 and 2 were evaluated, and the results are shown in Table 2 below.

Example 1 Example 2 Example 3 Example 4 Comparative Example 1 Comparative Example 2 standard Solid content (%) 32 18 27 20 15.9 38.7 5 ~ 45 Leveling
Coating property Great Great Great Great Great Great Good or better Lubricity Great Great Great Great Great Great Good or better sedimentation
stability Transparent solution Transparent solution Transparent solution Transparent solution Great Great Good or better Bubble cast
(minute) No bubbles No bubbles No bubbles No bubbles Within 5 minutes Within 3 minutes Within 3 minutes Pigment
Ferric acid No pigment No pigment No pigment No pigment Great Great Good or better pH (25 캜) 7.2 7.3 7.3 7.2 12.8 14.0 or higher - color Colorless Colorless Colorless Colorless black black -

As shown in Table 2, it can be seen that Examples 1 to 4 exhibit neutral pH and colorlessness whilst satisfying all of the standards for solid content, leveling coating property, lubricity, sedimentation stability, defoaming property and pigment volatility have.

The above description is merely illustrative of the technical idea of the present patent. Those skilled in the art will appreciate that various modifications and changes may be made without departing from the essential characteristics of the present invention.

In addition, the embodiments disclosed in this patent are intended to illustrate rather than limit the technical idea of the present patent, and the scope of the technical idea of the present patent is not limited by these embodiments.

Therefore, the scope of protection of the present invention should be construed according to the following claims, and all technical ideas within the scope of equivalents should be interpreted as being included in the scope of the present patent.

Claims (4)

0.5 to 4% by weight of a mixture of 2 to 10% by weight of borax, 2 to 10% by weight of potassium carbonate, 4 to 20% by weight of boric acid, sodium hydroxide and potassium hydroxide in a weight ratio of 1: 1, The surface lubrication treating agent for forging according to claim 1, further comprising 0.1 to 1 wt% of an additive including a surfactant, a defoaming agent and a thickening agent in the silent surface lubricant, based on the total weight of the forging lubricant.
The method according to claim 1,
Wherein the forging is hot forging or hot forging.
Characterized in that the forged product is preheated and the preheated forgings are dried by impregnating or spray coating the forging surface lubricant of claim 1, followed by heat treatment and pressing.
0.5 to 4% by weight of a mixture of 2 to 10% by weight of borax, 2 to 10% by weight of potassium carbonate, 4 to 20% by weight of boric acid, sodium hydroxide and potassium hydroxide in a weight ratio of 1: 1, A first step of dissolving 2 to 10% by weight of borax in the water of the remaining amount obtained by preliminarily calculating the content of each component in the silent surface lubricant;
A second step of dissolving 0.5 to 4% by weight of a mixture of 2 to 10% by weight of potassium carbonate, 4 to 20% by weight of boric acid, sodium hydroxide and potassium hydroxide in a weight ratio of 1: 1 in the solution of the first step;
And a third step of mixing 0.1 to 1% by weight of an additive including a surfactant, a defoaming agent, and a thickening agent as additives for modifying the surface properties of the forging surface lubricant, based on the total weight of the forging surface lubricant, &Lt; / RTI &gt;