CN104278283A - Special water-based cleaning agent for aluminum magnesium alloy - Google Patents
Special water-based cleaning agent for aluminum magnesium alloy Download PDFInfo
- Publication number
- CN104278283A CN104278283A CN201410499635.0A CN201410499635A CN104278283A CN 104278283 A CN104278283 A CN 104278283A CN 201410499635 A CN201410499635 A CN 201410499635A CN 104278283 A CN104278283 A CN 104278283A
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- magnesium alloy
- corrosion inhibitor
- special
- aluminum
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Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/14—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
- C23G1/16—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions using inhibitors
- C23G1/18—Organic inhibitors
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/14—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
- C23G1/22—Light metals
Abstract
The invention discloses a special water-based cleaning agent for aluminum magnesium alloy. The special water-based cleaning agent comprises the following raw materials in parts by weight: 1-6 parts of triethanolamine, 2-10 parts of sodium carbonate, 5-10 parts of sodium bicarbonate, 4-12 parts of heterogeneous alcohol ether, 6-20 parts of alkylolamides, 5-15 parts of a magnesium alloy corrosion inhibitor, 5-10 parts of an aluminum alloy corrosion inhibitor, 8-20 parts of an anionic surfactant, 3-10 parts of hydrophilic alcohol, 0-6 parts of a stabilizer and 50-100 parts of water. The special water-based cleaning agent for aluminum magnesium alloy disclosed by the invention is strong in detersive power, high in cleaning speed, few in residues after being washed, anti-static, and good in corrosion inhibition property, and can prevent the metal from being corroded.
Description
Technical field
The present invention relates to clean-out system technical field, particularly relate to the special-purpose water-based clean-out system of a kind of aluminum magnesium alloy.
Background technology
Metal cleaner is applied very extensive in the industrial production, is usually used in the cleaning before the surface degreasing before and after intermetallic composite coating, scale removal and finished product assembling or packaging.Water base metal cleaning agent is underlying carrier with water, containing tensio-active agent, auxiliary agent etc., containing or containing few organic solvent.Aqueous cleaning agent has following characteristics: (1) good wetting, emulsification, characteristic of solubilizing; (2) preparation and use procedure in substantially pollution-free; (3) to the corrosion-free effect of metallic substance, the original gloss of metal after cleaning, can be kept, there is certain antirust effect; (4) cost performance is higher than organic cleaning solvent; (5) do not burn, security is high.
The water base metal cleaning agent sold in the market is applicable to ferrous metal mostly, be applicable to that non-ferrous metal is especially applicable to magnesium, the aqueous cleaning agent of Aluminum-aluminum alloy only occupies little a part of market, and the magnesium that market is sold, Aluminum-aluminum alloy clean-out system are of a great variety, spread in performance is uneven.Along with magnesium, Aluminum-aluminum alloy are in automobile industry, electron trade, medical device industry, aviation field, the widespread use of optical field etc., the demand of its clean-out system also will be more and more huger.
Existing aqueous cleaning agent rust inhibition is poor, and cleaning performance is not good enough, and cleaning speed is slow, and residual many after washing, poor stability, can not meet the application of aluminum magnesium alloy.
Summary of the invention
The present invention proposes the special-purpose water-based clean-out system of a kind of aluminum magnesium alloy, its strong detergency, cleaning speed is fast, and residual few after washing, antistatic, rust inhibition is good, and metal can be protected not to be corroded.
The present invention proposes the special-purpose water-based clean-out system of a kind of aluminum magnesium alloy, its raw material comprises following component by weight: trolamine 1-6 part, sodium carbonate 2-10 part, sodium bicarbonate 5-10 part, isomery alcohol ether 4-12 part, alkylol amide 6-20 part, magnesium alloy corrosion inhibitor 5-15 part, aluminum alloy corrosion inhibitor 5-10 part, anion surfactant 8-20 part, hydrophilic polyol 3-10 part, stablizer 0-6 part, water 50-100 part.
Preferably, its raw material comprises following component by weight: trolamine 2-5 part, sodium carbonate 3-8 part, sodium bicarbonate 6-8 part, isomery alcohol ether 5-10 part, alkylol amide 10-15 part, magnesium alloy corrosion inhibitor 8-13 part, aluminum alloy corrosion inhibitor 6-9 part, anion surfactant 12-15 part, hydrophilic polyol 6-10 part, stablizer 0-4 part, water 60-80 part.
Preferably, its raw material comprises following component by weight: trolamine 3.5 parts, 5 parts, sodium carbonate, sodium bicarbonate 7 parts, isomery alcohol ether 8 parts, alkylol amide 13 parts, magnesium alloy corrosion inhibitor 10 parts, aluminum alloy corrosion inhibitor 8 parts, anion surfactant 13 parts, hydrophilic polyol 7 parts, stablizer 3 parts, 65 parts, water.
Preferably, described isomery alcohol ether is a kind of or multiple combination in isomery ten polyoxyethylenated alcohol, isomery undecyl alcohol Soxylat A 25-7, isomerous tridecanol polyoxyethylene ether.
Preferably, described alkylol amide is one or more the combination in lauroyl monoethanolamine, lauroyl diethanolamine, Monoethanolamine Oleate, oleic acid diethanolamine, stearyl diethanolamine, stearyl monoethanolamine, coconut oleoyl monoethanolamine, coconut oleoyl diethanolamine.
Preferably, described hydrophilic polyol is one or more the combination in ethanol, Virahol, glycerine, 1,2-PD, ethylene glycol, propyl alcohol, polyoxyethylene glycol.
Preferably, described aluminum alloy corrosion inhibitor is the combination of a kind of in tetraethoxysilane, methyltrimethoxy silane or two kinds.
Preferably, described stablizer is one or more the combination in γ-aminopropyl triethoxysilane, γ-methacryloxypropyl trimethoxy silane, γ-glycydoxy Trimethoxy silane.
In the present invention, trolamine both can play the etch-proof effect of protection aluminum magnesium alloy as tensio-active agent, can provide stable pH value again, sodium carbonate and sodium bicarbonate, as having the effect regulating pH while alkaline cleaner, coordinate with trolamine and maintain the stable of clean-out system pH; The effect that isomery alcohol ether has dispersion greasy dirt as nonionogenic tenside and protects metal not to be corroded; Alkylol amide has the performances such as decontamination, lubrication, thickening, emulsification, foam stabilization, joins in addition in clean-out system and also has anlistatig effect; Hydrophilic polyol can work in coordination with other raw material dissolving greasy dirt He regulate this formula as solubilizing agent and tensio-active agent, enable the performance of each raw material strengthen and improve; According to the clean-out system strong detergency that above-mentioned raw materials and proportioning obtain, cleaning speed is fast, and usage quantity is few, and residual few after washing, antistatic, rust inhibition is good, and metal can be protected not to be corroded.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail; should understand; embodiment is only for illustration of the present invention, instead of for limiting the present invention, any amendment, equivalent replacement etc. made on basis of the present invention is all in protection scope of the present invention.
In a particular embodiment, the special-purpose water-based clean-out system of aluminum magnesium alloy of the present invention, in its raw material, the weight part of trolamine can be 1.3, 1.8, 2, 2.3, 2.6, 3, 4, 4.5, 5, 5.3, 5.8 parts, the weight part of sodium carbonate can be 2.5, 3, 3.6, 4, 4.5, 5, 5.8, 7, 7.3, 8, 8.5, 9, 9.3 parts, the weight part of sodium bicarbonate can be 5.6, 6, 6.3, 7, 8, 8.5, 9, 9.1, 9.7 parts, the weight part of isomery alcohol ether can be 4.5, 5, 5.6, 6, 6.7, 7, 7.4, 8, 8.3, 9, 9.8, 10, 10.5, 11, 11.4 parts, the weight part of alkylol amide can be 6.5, 7, 7.3, 8, 8.4, 9, 9.6, 10, 10.5, 11, 11.5, 12, 12.5, 13, 14, 15.7, 17, 18, 18.4, 19, 19.2 parts, the weight part of magnesium alloy corrosion inhibitor can be 5.6, 6, 6.3, 7, 7.4, 8, 8.5, 9, 9.6, 10, 10.5, 11, 11.8, 13, 13.5, 14, 14.2 parts, the weight part of aluminum alloy corrosion inhibitor can be 5.4, 6, 6.3, 7, 7.2, 8, 8.5, 9, 9.3 parts, the weight part of anion surfactant can be 8.5, 9, 10, 11, 12.3, 13, 14.5, 15, 16, 16.7, 17, 17.4, 18, 18.6, 19, 19.3 parts, the weight part of hydrophilic polyol can be 4, 4.5, 5, 5.2, 6, 6.3, 7, 7.2, 8, 8.4, 9, 9.3 parts, the weight part of stablizer can be 0.6, 0.9, 1, 1.2, 1.3, 1.5, 1.6, 2, 3, 3.5, 3.7, 4, 4.1, 4.6, 5, 5.4 parts, the weight part of water can be 55, 56, 58, 59.4, 61, 63, 68, 70, 75, 78, 79.5, 81, 83, 84.5, 86, 87, 88, 89.3, 90, 92.5, 93.6, 95, 97, 98.3 parts.
Embodiment 1
The special-purpose water-based clean-out system of aluminum magnesium alloy of the present invention, its raw material comprises following component by weight: trolamine 1 part, 10 parts, sodium carbonate, sodium bicarbonate 5 parts, isomery alcohol ether 12 parts, alkylol amide 6 parts, magnesium alloy corrosion inhibitor 5 parts, aluminum alloy corrosion inhibitor 10 parts, anion surfactant 20 parts, hydrophilic polyol 3 parts, γ-aminopropyl triethoxysilane 1 part, γ-methacryloxypropyl trimethoxy silane 3 parts, γ-glycydoxy Trimethoxy silane 2 parts, 50 parts, water.
Embodiment 2
The special-purpose water-based clean-out system of aluminum magnesium alloy of the present invention, its raw material comprises following component by weight: trolamine 6 parts, 2 parts, sodium carbonate, sodium bicarbonate 10 parts, isomery ten polyoxyethylenated alcohol 4 parts, stearyl monoethanolamine 5 parts, coconut oleoyl diethanolamine 15 parts, magnesium alloy corrosion inhibitor 15 parts, tetraethoxysilane 5 parts, anion surfactant 8 parts, ethanol 10 parts, stablizer 0 part, 100 parts, water.
Embodiment 3
The special-purpose water-based clean-out system of aluminum magnesium alloy of the present invention, its raw material comprises following component by weight: trolamine 3.5 parts, 5 parts, sodium carbonate, sodium bicarbonate 7 parts, isomery undecyl alcohol Soxylat A 25-7 2 parts, isomerous tridecanol polyoxyethylene ether 3 parts, isomery ten polyoxyethylenated alcohol 3 parts, Monoethanolamine Oleate 13 parts, magnesium alloy corrosion inhibitor 10 parts, methyltrimethoxy silane 6 parts, tetraethoxysilane 2 parts, anion surfactant 13 parts, 1, 2-propylene glycol 1 part, polyoxyethylene glycol 2 parts, Virahol 4 parts, γ-methacryloxypropyl trimethoxy silane 3 parts, 65 parts, water.
Embodiment 4
The special-purpose water-based clean-out system of aluminum magnesium alloy of the present invention, its raw material comprises following component by weight: trolamine 3.5 parts, 6.7 parts, sodium carbonate, sodium bicarbonate 8.3 parts, isomery alcohol ether 9 parts, alkylol amide 11 parts, magnesium alloy corrosion inhibitor 8 parts, aluminum alloy corrosion inhibitor 5.9 parts, anion surfactant 13.6 parts, hydrophilic polyol 7 parts, stablizer 3 parts, 80 parts, water;
Wherein, described isomery alcohol ether is isomery ten polyoxyethylenated alcohol; Described alkylol amide is stearyl diethanolamine; Described hydrophilic polyol is ethylene glycol; Described aluminum alloy corrosion inhibitor is tetraethoxysilane; Described stablizer is γ-aminopropyl triethoxysilane.
Embodiment 5
The special-purpose water-based clean-out system of aluminum magnesium alloy of the present invention, its raw material comprises following component by weight: trolamine 2.2 parts, 5.6 parts, sodium carbonate, sodium bicarbonate 9 parts, isomery alcohol ether 5.8 parts, alkylol amide 12 parts, magnesium alloy corrosion inhibitor 7 parts, aluminum alloy corrosion inhibitor 8.3 parts, anion surfactant 15 parts, hydrophilic polyol 3.8 parts, stablizer 2.6 parts, 87 parts, water;
Wherein, described isomery alcohol ether is the combination of isomery ten polyoxyethylenated alcohol, isomery undecyl alcohol Soxylat A 25-7, isomerous tridecanol polyoxyethylene ether; Described alkylol amide is the combination of lauroyl monoethanolamine, lauroyl diethanolamine, Monoethanolamine Oleate, oleic acid diethanolamine, stearyl diethanolamine, stearyl monoethanolamine, coconut oleoyl monoethanolamine, coconut oleoyl diethanolamine; Described hydrophilic polyol is the combination of ethanol, Virahol, glycerine, 1,2-PD, ethylene glycol, propyl alcohol, polyoxyethylene glycol; Described aluminum alloy corrosion inhibitor is the combination of tetraethoxysilane, methyltrimethoxy silane; Described stablizer is the combination of γ-aminopropyl triethoxysilane, γ-methacryloxypropyl trimethoxy silane, γ-glycydoxy Trimethoxy silane.
Applicant states, above content is in conjunction with concrete preferred implementation further description made for the present invention, can not assert that specific embodiment of the invention is confined to these explanations.For general technical staff of the technical field of the invention, without departing from the inventive concept of the premise, some simple deduction or replace can also be made, all should be considered as belonging to protection scope of the present invention.
Claims (8)
1. the special-purpose water-based clean-out system of aluminum magnesium alloy, it is characterized in that, its raw material comprises following component by weight: trolamine 1-6 part, sodium carbonate 2-10 part, sodium bicarbonate 5-10 part, isomery alcohol ether 4-12 part, alkylol amide 6-20 part, magnesium alloy corrosion inhibitor 5-15 part, aluminum alloy corrosion inhibitor 5-10 part, anion surfactant 8-20 part, hydrophilic polyol 3-10 part, stablizer 0-6 part, water 50-100 part.
2. the special-purpose water-based clean-out system of aluminum magnesium alloy according to claim 1, it is characterized in that, its raw material comprises following component by weight: trolamine 2-5 part, sodium carbonate 3-8 part, sodium bicarbonate 6-8 part, isomery alcohol ether 5-10 part, alkylol amide 10-15 part, magnesium alloy corrosion inhibitor 8-13 part, aluminum alloy corrosion inhibitor 6-9 part, anion surfactant 12-15 part, hydrophilic polyol 6-10 part, stablizer 0-4 part, water 60-80 part.
3. the special-purpose water-based clean-out system of aluminum magnesium alloy according to claim 1 or 2, it is characterized in that, its raw material comprises following component by weight: trolamine 3.5 parts, 5 parts, sodium carbonate, sodium bicarbonate 7 parts, isomery alcohol ether 8 parts, alkylol amide 13 parts, magnesium alloy corrosion inhibitor 10 parts, aluminum alloy corrosion inhibitor 8 parts, anion surfactant 13 parts, hydrophilic polyol 7 parts, stablizer 3 parts, 65 parts, water.
4. the special-purpose water-based clean-out system of aluminum magnesium alloy according to any one of claim 1-3, it is characterized in that, described isomery alcohol ether is a kind of or multiple combination in isomery ten polyoxyethylenated alcohol, isomery undecyl alcohol Soxylat A 25-7, isomerous tridecanol polyoxyethylene ether.
5. the special-purpose water-based clean-out system of aluminum magnesium alloy according to any one of claim 1-4, it is characterized in that, described alkylol amide is one or more the combination in lauroyl monoethanolamine, lauroyl diethanolamine, Monoethanolamine Oleate, oleic acid diethanolamine, stearyl diethanolamine, stearyl monoethanolamine, coconut oleoyl monoethanolamine, coconut oleoyl diethanolamine.
6. the special-purpose water-based clean-out system of aluminum magnesium alloy according to any one of claim 1-5, is characterized in that, described hydrophilic polyol is one or more the combination in ethanol, Virahol, glycerine, 1,2-PD, ethylene glycol, propyl alcohol, polyoxyethylene glycol.
7. the special-purpose water-based clean-out system of aluminum magnesium alloy according to any one of claim 1-6, is characterized in that, described aluminum alloy corrosion inhibitor is the combination of a kind of in tetraethoxysilane, methyltrimethoxy silane or two kinds.
8. the special-purpose water-based clean-out system of aluminum magnesium alloy according to any one of claim 1-7, it is characterized in that, described stablizer is one or more the combination in γ-aminopropyl triethoxysilane, γ-methacryloxypropyl trimethoxy silane, γ-glycydoxy Trimethoxy silane.
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| CN201410499635.0A CN104278283A (en) | 2014-09-25 | 2014-09-25 | Special water-based cleaning agent for aluminum magnesium alloy |
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| CN201410499635.0A CN104278283A (en) | 2014-09-25 | 2014-09-25 | Special water-based cleaning agent for aluminum magnesium alloy |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104862716A (en) * | 2015-04-29 | 2015-08-26 | 安徽长城输送机械制造有限公司 | Phosphorus-water-base-free metal cleaning agent |
| CN104862724A (en) * | 2015-04-29 | 2015-08-26 | 安徽长城输送机械制造有限公司 | Metal cleaning agent |
| CN104928695A (en) * | 2015-04-29 | 2015-09-23 | 安徽长城输送机械制造有限公司 | Steel material surface scrubbing liquid |
| CN106119873A (en) * | 2016-07-29 | 2016-11-16 | 南京科润工业介质股份有限公司 | A kind of die-cast aluminium shell cleaning showers agent being applied under supertension |
| CN106367764A (en) * | 2016-10-13 | 2017-02-01 | 武汉杰生润滑科技有限公司 | Water-based detergent for aluminum alloy |
| CN106381203A (en) * | 2016-08-29 | 2017-02-08 | 江苏富兰克化学有限公司 | Metal cutting fluid, preparation method and use system thereof |
| CN106947979A (en) * | 2017-03-22 | 2017-07-14 | 广州亦盛环保科技有限公司 | A kind of magnadure cleaning agent |
| CN107130253A (en) * | 2017-06-28 | 2017-09-05 | 华杰 | A kind of aluminum alloy cleaning agent |
| CN107326375A (en) * | 2017-06-29 | 2017-11-07 | 顾渊 | One Albatra metal cleaning agent |
| CN107937157A (en) * | 2017-12-26 | 2018-04-20 | 邓艳 | A kind of kitchen ventilator cleaning agent |
| CN110938827A (en) * | 2019-12-11 | 2020-03-31 | 富兰克润滑科技（太仓）有限公司 | Magnesium alloy cleaning agent with excellent cleaning and anti-corrosion effects and method |
| CN115287039A (en) * | 2022-01-28 | 2022-11-04 | 延边群益科技发展有限责任公司 | Odor agent and preparation method and application thereof |
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| CN104862716B (en) * | 2015-04-29 | 2018-04-27 | 安徽美腾特种电缆材料有限公司 | A kind of Phosphorus-Free Water-Based Cleaning Agent for Metals |
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| CN104928695A (en) * | 2015-04-29 | 2015-09-23 | 安徽长城输送机械制造有限公司 | Steel material surface scrubbing liquid |
| CN104862716A (en) * | 2015-04-29 | 2015-08-26 | 安徽长城输送机械制造有限公司 | Phosphorus-water-base-free metal cleaning agent |
| CN106119873A (en) * | 2016-07-29 | 2016-11-16 | 南京科润工业介质股份有限公司 | A kind of die-cast aluminium shell cleaning showers agent being applied under supertension |
| CN106119873B (en) * | 2016-07-29 | 2018-06-29 | 南京科润工业介质股份有限公司 | A kind of die-cast aluminium shell cleaning showers agent applied under super-pressure |
| CN106381203A (en) * | 2016-08-29 | 2017-02-08 | 江苏富兰克化学有限公司 | Metal cutting fluid, preparation method and use system thereof |
| CN106367764A (en) * | 2016-10-13 | 2017-02-01 | 武汉杰生润滑科技有限公司 | Water-based detergent for aluminum alloy |
| CN106947979A (en) * | 2017-03-22 | 2017-07-14 | 广州亦盛环保科技有限公司 | A kind of magnadure cleaning agent |
| CN107130253A (en) * | 2017-06-28 | 2017-09-05 | 华杰 | A kind of aluminum alloy cleaning agent |
| CN107326375A (en) * | 2017-06-29 | 2017-11-07 | 顾渊 | One Albatra metal cleaning agent |
| CN107937157A (en) * | 2017-12-26 | 2018-04-20 | 邓艳 | A kind of kitchen ventilator cleaning agent |
| CN110938827A (en) * | 2019-12-11 | 2020-03-31 | 富兰克润滑科技（太仓）有限公司 | Magnesium alloy cleaning agent with excellent cleaning and anti-corrosion effects and method |
| CN115287039A (en) * | 2022-01-28 | 2022-11-04 | 延边群益科技发展有限责任公司 | Odor agent and preparation method and application thereof |
| CN115287039B (en) * | 2022-01-28 | 2024-04-05 | 延边群益科技发展有限责任公司 | Odor agent and preparation method and application thereof |
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Application publication date: 20150114 |