CN105696008A - Ultrasonic water-based cleaning fluid for hardware products and preparation method thereof - Google Patents
Ultrasonic water-based cleaning fluid for hardware products and preparation method thereof Download PDFInfo
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- CN105696008A CN105696008A CN201610090829.4A CN201610090829A CN105696008A CN 105696008 A CN105696008 A CN 105696008A CN 201610090829 A CN201610090829 A CN 201610090829A CN 105696008 A CN105696008 A CN 105696008A
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/24—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions
- C23G1/26—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions using inhibitors
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
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Abstract
The invention relates to the technical field of chemical products, in particular to ultrasonic water-based cleaning fluid for hardware products. The ultrasonic water-based cleaning fluid for hardware products comprises, by weight, 1-5 parts of dimeric surfactant, 10-20 parts of nonionic surfactant, 1-10 parts of alcohol ether compound, 1-5 parts of alkylol amine compound, 1-5 parts of a builder, 0.1-5 parts of auxiliaries and 60-80 parts of water. The water-based cleaning fluid is low in manufacturing cost, safe, environmentally friendly, efficient, convenient, fast, low in toxicity, and easy to biodegrade and wash away, the residual quantity of the fluid on the surface of metal is extremely low after the fluid is washed away, the metal cannot be corroded, the metal can keep good colour and luster, and the quality of metal products is improved.
Description
Technical field
The present invention relates to chemicals technical field, particularly relate to a kind of hardware products ultrasound wave water-base cleaning liquid and preparation method thereof。
Background technology
It is metallic article requisite process procedure before spraying, plating, hot-dip and following process that metal cleans。Rational cleaning can remove various dirts and the impurity of metal surface attachment effectively, significantly slows down corrosion and the abrasion of metal, enhances product performance, service life and product appearance quality。
Metal cleaner is divided into three major types according to abluent kind, i.e. the aqueous cleaning agent based on surfactant；Semi-aqueous cleaning agent based on surfactant and solvent；Leaning solvent based on gasoline, kerosene, diesel oil or halogenated hydrocarbons。
In the cleaning greasy dirt operation of transportation, machine-building, national defense industry and other relevant departments, traditional method is all adopt the petroleum-type abluents such as gasoline, kerosene, diesel oil to clean machine components。Having well-known advantage with gasoline equal solvent as metal cleaner, degreasing power is strong, clean up。But there is the consumption energy, easy Fire explosion, endanger workers ' health, cause the shortcomings such as environmental pollution。
The halogenated hydrocarbons technology abroad of the difficult combustion such as trichloro ethylene, tetrachloroethylene, carbon tetrachloride, dichloromethane, HFC-143a is considered solvent-borne type metal cleaner presently the most reliably。At present, the abluent that in Chinese market, consumption is maximum is still based on HEP-2 (NPB), trichloro ethylene, dichloromethane equal solvent。Along with the deterioration of global environment, the halogenated hydrocarbon solvent of traditional type is put into restriction gradually and uses hazardous chemical, and the immune system of the mankind, hormonal system and reproductive system are had a degree of murder by poisoning by the toxicity of halogenated hydrocarbons。
The abluent that semi-aqueous cleaning agent is made up of organic solvent, surfactant and water, has taken into account solvent-borne type and the advantage of aqua type metal cleaner, has substantially increased oil removal efficiency。But owing to semi-aqueous cleaning agent is relatively costly, easily at metal residual after rinsing, cause metal erosion, variable color；Organic solvent has a volatility, inflammable and explosive and have toxicity, and moisture exists the danger of burning after being evaporated；The process of waste liquid and the recovery of solvent are difficult problems。These problems limit widely using of half leaning solvent。
Along with the further raising that environmental protection, safety and efficiency etc. are required by people, cleaning field at metal needs to seek the novel detergent product of a kind of safe and environment-friendly, efficient, convenient, low toxicity and easily biological-degradable。
Summary of the invention
The present invention provides a kind of hardware products ultrasound wave water-base cleaning liquid and preparation method thereof for overcoming drawbacks described above, this water-base cleaning liquid low cost of manufacture, safe and environment-friendly, efficient, convenient, low toxicity, easily biological-degradable, easily rinse, after rinsing, the residual quantity in metal surface is extremely low, will not corroding metal, metal can keep good color and luster, improves the quality of metallic article；The preparation method technique of this water-base cleaning liquid is simple, processing ease, and production efficiency is high, and conforming product rate is high, is suitable for large-scale promotion application。
For achieving the above object, the present invention adopts the following technical scheme that。
A kind of hardware products ultrasound wave water-base cleaning liquid, including the raw material of following weight portion:
Preferably, a kind of hardware products ultrasound wave water-base cleaning liquid, including the raw material of following weight portion:
Preferably, a kind of hardware products ultrasound wave water-base cleaning liquid, including the raw material of following weight portion:
Wherein, described Gemini surface active agent is the mixture of the one or more than one of disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, myristyl diphenyl oxide disulfonate, dodecyl diphenyl oxide sodium sulfonate diamides, dodecyloxy diphosphate sodium, lauroyl sodium diacetate, dodecyl adipamide sodium propionate, trilauryl Diethylenetriamine dipropionic acid。
Wherein, described alcohol amine compound compound is the mixture of the one or more than one of N methyldiethanol amine compound, N, N-dimethyl ethanol amines, N-ethyldiethanolamine compound, N-propyl group diethanolamine compound, N butyl diethanol amine compound。
Wherein, described nonionic surfactant is Polyoxyethylene Methyl Glucoside Ether, methyl glucoside polyethenoxy ether, Polyoxyethylene Methyl Glucoside Ether dioleate, cocos nucifera oil acyl monoisopropanolamine compound, myristoyl monoethanolamine compound, sorbitan monooleate, anhydrous sorbitol cetylate, anhydrous sorbitol laurate, glycerol monohydroxystearate, polyoxyethylene alkyl ether ester, isomeric alcohol polyethenoxy ether, fatty acid methyl ester polyoxyethylene ether, glycerol mono-acid stearate, aliphatic acid polyethenoxy acid esters, the mixture of the one or more than one of polyglyceryl fatty acid ester and methyl glycol fatty acid ester。
Wherein, described ether compound is the mixture of the one or more than one of diethylene glycol monomethyl ether, triethylene glycol monomethyl ether, diethylene glycol monobutyl ether, triethylene glycol butyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monopropyl ether, three glycerol list propyl ether, dipropylene, tripropylene glycol butyl ether。
Wherein, described builder is the mixture of the one or more than one of sodium citrate, sodium ethylene diamine tetracetate, nitrilotriacetic acid sodium, sodium metasilicate, complex silicate sodium, modified polyacrylate sodium, poly-aspartate, Oxytarch, carboxymethyl starch。
Wherein, described auxiliary agent includes corrosion inhibiter, and described corrosion inhibiter is the mixture of the one or more than one of thiourea, benzotriazole, mercaptobenzimidazole and alkanolamide。
A kind of preparation method of hardware products ultrasound wave water-base cleaning liquid, including following procedure of processing:
Step A, weigh the material of formula ratio according to formula, be placed individually in different containers；
Step B, add water in reactor, then builder is joined in reactor, stirring while adding so that builder is dispersed in water；
Step C, Gemini surface active agent and nonionic surfactant are added separately in reactor, stirring while adding so that Gemini surface active agent and nonionic surfactant are dispersed in water；
Step D, alcohol amine compound is joined in reactor, stirring while adding so that alcohol amine compound is dispersed in water；
Step E, ether compound is joined in reactor, stirring while adding so that ether compound is dispersed in water；
Step F, auxiliary agent is joined in reactor, stirring while adding so that auxiliary agent is dispersed in water and forms final multicomponent mixed liquor, get product。
The invention have the benefit that
A kind of hardware products ultrasound wave water-base cleaning liquid of the present invention, including the raw material of following weight portion: Gemini surface active agent 1～5 part, nonionic surfactant 10～20 parts, ether compound 1～10 part, alcohol amine compound 1～5 part, builder 1～5 part, auxiliary agent 0.1～5 part, 60～80 parts of water；This water-base cleaning liquid low cost of manufacture, safe and environment-friendly, efficient, convenient, low toxicity, easily biological-degradable, easily rinsing, after rinsing, the residual quantity in metal surface is extremely low, will not corroding metal, metal can keep good color and luster, improves the quality of metallic article；
The preparation method of a kind of hardware products ultrasound wave water-base cleaning liquid of the present invention, including following procedure of processing: step A, weigh the material of formula ratio according to formula, is placed individually in different containers；Step B, add water in reactor, then builder is joined in reactor, stirring while adding so that builder is dispersed in water；Step C, Gemini surface active agent and nonionic surfactant are added separately in reactor, stirring while adding so that Gemini surface active agent and nonionic surfactant are dispersed in water；Step D, alcohol amine compound is joined in reactor, stirring while adding so that alcohol amine compound is dispersed in water；Step E, ether compound is joined in reactor, stirring while adding so that ether compound is dispersed in water；Step F, auxiliary agent is joined in reactor, stirring while adding so that auxiliary agent is dispersed in water and forms final multicomponent mixed liquor, get product；The preparation method technique of this water-base cleaning liquid is simple, processing ease, and production efficiency is high, and conforming product rate is high, is suitable for large-scale promotion application。
In sum, the water-base cleaning liquid application of the present invention is compound prescription technology, improve cleaning force and the Safety and Environmental Protection of ablution, reduce the consumption of ablution, ablution is prone to degraded, solves metallic article and cleans before spraying, plating, hot-dip and following process, meets biodegradable, efficiently, people is nontoxic, environmental sound, ozone layer is lossless, the not composite request such as phosphate-containing and nonyl phenol ethyl salt。
(1) Gemini surface active agent that the present invention uses has less critical micelle concentration (CMC), generally low than corresponding monomcric surfactant 1～2 even low 3～4 orders of magnitude, the surface tension of the more effective reduction water of energy, there is less C20 value (making water surface tension reduce the concentration of required surfactant during 0.02N/m) and higher calcium stability, be suitable for hard water environment。
(2) builder that the present invention uses is phosphorus-free adjuvant, stops on the one hand the environmental problems such as the body eutrophication that causes due to phosphorous assistant, reduces builder consumption on the other hand, improve ablution cleansing power。
(3) surfactant that the present invention uses is for being readily biodegradable type surfactant, to human non-toxic, and environmental sound, ozone layer is lossless, belong to biodegradable environmental protection abluent。
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further illustrated, and this is presently preferred embodiments of the present invention。
Embodiment 1。
A kind of hardware products ultrasound wave water-base cleaning liquid of the present invention, including the raw material of following weight portion:
The Gemini surface active agent of the present embodiment is disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate。
The alcohol amine compound compound of the present embodiment is N methyldiethanol amine compound。
The nonionic surfactant of the present embodiment is Polyoxyethylene Methyl Glucoside Ether。
The ether compound of the present embodiment is diethylene glycol monomethyl ether。
The builder of the present embodiment is sodium citrate。
The auxiliary agent of the present embodiment includes corrosion inhibiter, and described corrosion inhibiter is thiourea。
A kind of preparation method of hardware products ultrasound wave water-base cleaning liquid, including following procedure of processing:
Step A, weigh the material of formula ratio according to formula, be placed individually in different containers；
Step B, add water in reactor, then builder is joined in reactor, stirring while adding so that builder is dispersed in water；
Step C, Gemini surface active agent and nonionic surfactant are added separately in reactor, stirring while adding so that Gemini surface active agent and nonionic surfactant are dispersed in water；
Step D, alcohol amine compound is joined in reactor, stirring while adding so that alcohol amine compound is dispersed in water；
Step E, ether compound is joined in reactor, stirring while adding so that ether compound is dispersed in water；
Step F, auxiliary agent is joined in reactor, stirring while adding so that auxiliary agent is dispersed in water and forms final multicomponent mixed liquor, get product。
Embodiment 2。
A kind of hardware products ultrasound wave water-base cleaning liquid of the present invention, including the raw material of following weight portion:
The Gemini surface active agent of the present embodiment is myristyl diphenyl oxide disulfonate。
The alcohol amine compound compound of the present embodiment is N, N-dimethyl ethanol amines。
The nonionic surfactant of the present embodiment is methyl glucoside polyethenoxy ether。
The ether compound of the present embodiment is triethylene glycol monomethyl ether。
The builder of the present embodiment is sodium ethylene diamine tetracetate。
The auxiliary agent of the present embodiment includes corrosion inhibiter, and described corrosion inhibiter is benzotriazole。
A kind of preparation method of hardware products ultrasound wave water-base cleaning liquid, including following procedure of processing:
Step A, weigh the material of formula ratio according to formula, be placed individually in different containers；
Step B, add water in reactor, then builder is joined in reactor, stirring while adding so that builder is dispersed in water；
Step C, Gemini surface active agent and nonionic surfactant are added separately in reactor, stirring while adding so that Gemini surface active agent and nonionic surfactant are dispersed in water；
Step D, alcohol amine compound is joined in reactor, stirring while adding so that alcohol amine compound is dispersed in water；
Step E, ether compound is joined in reactor, stirring while adding so that ether compound is dispersed in water；
Step F, auxiliary agent is joined in reactor, stirring while adding so that auxiliary agent is dispersed in water and forms final multicomponent mixed liquor, get product。
Embodiment 3。
A kind of hardware products ultrasound wave water-base cleaning liquid of the present invention, including the raw material of following weight portion:
The Gemini surface active agent of the present embodiment is the mixture of dodecyl diphenyl oxide sodium sulfonate diamides, dodecyloxy diphosphate sodium。
The alcohol amine compound compound of the present embodiment is the mixture of N-ethyldiethanolamine compound, N-propyl group diethanolamine compound。
The nonionic surfactant of the present embodiment is the mixture of Polyoxyethylene Methyl Glucoside Ether dioleate, cocos nucifera oil acyl monoisopropanolamine compound。
The ether compound of the present embodiment is the mixture of diethylene glycol monobutyl ether, triethylene glycol butyl ether。
The builder of the present embodiment is the mixture of nitrilotriacetic acid sodium, sodium metasilicate。
The auxiliary agent of the present embodiment includes corrosion inhibiter, and described corrosion inhibiter is the mixture of mercaptobenzimidazole and alkanolamide。
A kind of preparation method of hardware products ultrasound wave water-base cleaning liquid, including following procedure of processing:
Step A, weigh the material of formula ratio according to formula, be placed individually in different containers；
Step B, add water in reactor, then builder is joined in reactor, stirring while adding so that builder is dispersed in water；
Step C, Gemini surface active agent and nonionic surfactant are added separately in reactor, stirring while adding so that Gemini surface active agent and nonionic surfactant are dispersed in water；
Step D, alcohol amine compound is joined in reactor, stirring while adding so that alcohol Anhua compound is dispersed in water；
Step E, ether compound is joined in reactor, stirring while adding so that ether compound is dispersed in water；
Step F, auxiliary agent is joined in reactor, stirring while adding so that auxiliary agent is dispersed in water and forms final multicomponent mixed liquor, get product。
Embodiment 4。
A kind of hardware products ultrasound wave water-base cleaning liquid of the present invention, including the raw material of following weight portion:
The Gemini surface active agent of the present embodiment is the mixture of dodecyloxy diphosphate sodium, lauroyl sodium diacetate, dodecyl adipamide sodium propionate。
The alcohol amine compound compound of the present embodiment is the mixture of N, N-dimethyl ethanol amines, N-ethyldiethanolamine compound, N butyl diethanol amine compound。
The nonionic surfactant of the present embodiment is the mixture of myristoyl monoethanolamine compound, sorbitan monooleate, anhydrous sorbitol cetylate, anhydrous sorbitol laurate。
The ether compound of the present embodiment is the mixture of dipropylene glycol monomethyl ether, dipropylene glycol monopropyl ether, three glycerol list propyl ether。
The builder of the present embodiment is the mixture of complex silicate sodium, modified polyacrylate sodium, poly-aspartate。
The auxiliary agent of the present embodiment includes corrosion inhibiter, and described corrosion inhibiter is the mixture of thiourea, benzotriazole, mercaptobenzimidazole。
A kind of preparation method of hardware products ultrasound wave water-base cleaning liquid, including following procedure of processing:
Step A, weigh the material of formula ratio according to formula, be placed individually in different containers；
Step B, add water in reactor, then builder is joined in reactor, stirring while adding so that builder is dispersed in water；
Step C, Gemini surface active agent and nonionic surfactant are added separately in reactor, stirring while adding so that Gemini surface active agent and nonionic surfactant are dispersed in water；
Step D, alcohol amine compound is joined in reactor, stirring while adding so that alcohol amine compound is dispersed in water；
Step E, ether compound is joined in reactor, stirring while adding so that ether compound is dispersed in water；
Step F, auxiliary agent is joined in reactor, stirring while adding so that auxiliary agent is dispersed in water and forms final multicomponent mixed liquor, get product。
Embodiment 5。
A kind of hardware products ultrasound wave water-base cleaning liquid of the present invention, including the raw material of following weight portion:
The Gemini surface active agent of the present embodiment is the mixture of disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, myristyl diphenyl oxide disulfonate, dodecyl diphenyl oxide sodium sulfonate diamides, dodecyloxy diphosphate sodium, lauroyl sodium diacetate, dodecyl adipamide sodium propionate, trilauryl Diethylenetriamine dipropionic acid。
The alcohol amine compound compound of the present embodiment is the mixture of N methyldiethanol amine compound, N, N-dimethyl ethanol amines, N-ethyldiethanolamine compound, N-propyl group diethanolamine compound, N butyl diethanol amine compound。
The nonionic surfactant of the present embodiment is Polyoxyethylene Methyl Glucoside Ether, methyl glucoside polyethenoxy ether, Polyoxyethylene Methyl Glucoside Ether dioleate, cocos nucifera oil acyl monoisopropanolamine compound, myristoyl monoethanolamine compound, sorbitan monooleate, anhydrous sorbitol cetylate, anhydrous sorbitol laurate, glycerol monohydroxystearate, polyoxyethylene alkyl ether ester, isomeric alcohol polyethenoxy ether, fatty acid methyl ester polyoxyethylene ether, glycerol mono-acid stearate, aliphatic acid polyethenoxy acid esters, the mixture of polyglyceryl fatty acid ester and methyl glycol fatty acid ester。
The ether compound of the present embodiment is the mixture of diethylene glycol monomethyl ether, triethylene glycol monomethyl ether, diethylene glycol monobutyl ether, triethylene glycol butyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monopropyl ether, three glycerol list propyl ether, dipropylene, tripropylene glycol butyl ether。
The builder of the present embodiment is the mixture of sodium citrate, sodium ethylene diamine tetracetate, nitrilotriacetic acid sodium, sodium metasilicate, complex silicate sodium, modified polyacrylate sodium, poly-aspartate, Oxytarch, carboxymethyl starch。
The auxiliary agent of the present embodiment includes corrosion inhibiter, and described corrosion inhibiter is the mixture of thiourea, benzotriazole, mercaptobenzimidazole and alkanolamide。
A kind of preparation method of hardware products ultrasound wave water-base cleaning liquid, including following procedure of processing:
Step A, weigh the material of formula ratio according to formula, be placed individually in different containers；
Step B, add water in reactor, then builder is joined in reactor, stirring while adding so that builder is dispersed in water；
Step C, Gemini surface active agent and nonionic surfactant are added separately in reactor, stirring while adding so that Gemini surface active agent and nonionic surfactant are dispersed in water；
Step D, alcohol amine compound is joined in reactor, stirring while adding so that alcohol Anhua compound is dispersed in water；
Step E, ether compound is joined in reactor, stirring while adding so that ether compound is dispersed in water；
Step F, auxiliary agent is joined in reactor, stirring while adding so that auxiliary agent is dispersed in water and forms final multicomponent mixed liquor, get product。
Finally should be noted that; above example is only in order to illustrate technical scheme; but not limiting the scope of the invention; although having made to explain to the present invention with reference to preferred embodiment; it will be understood by those within the art that; technical scheme can be modified or equivalent replacement, without deviating from the spirit and scope of technical solution of the present invention。
Claims (10)
1. a hardware products ultrasound wave water-base cleaning liquid, it is characterised in that: include the raw material of following weight portion:
2. a kind of hardware products ultrasound wave water-base cleaning liquid according to claim 1, it is characterised in that: include the raw material of following weight portion:
3. a kind of hardware products ultrasound wave water-base cleaning liquid according to claim 1, it is characterised in that: include the raw material of following weight portion:
4. a kind of hardware products ultrasound wave water-base cleaning liquid according to claim 1, it is characterised in that: described Gemini surface active agent is the mixture of the one or more than one of disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, myristyl diphenyl oxide disulfonate, dodecyl diphenyl oxide sodium sulfonate diamides, dodecyloxy diphosphate sodium, lauroyl sodium diacetate, dodecyl adipamide sodium propionate, trilauryl Diethylenetriamine dipropionic acid。
5. a kind of hardware products ultrasound wave water-base cleaning liquid according to claim 1, it is characterized in that: described alcohol amine compound compound is the mixture of the one or more than one of N methyldiethanol amine compound, N, N-dimethyl ethanol amines, N-ethyldiethanolamine compound, N-propyl group diethanolamine compound, N butyl diethanol amine compound。
6. a kind of hardware products ultrasound wave water-base cleaning liquid according to claim 1, it is characterized in that: described nonionic surfactant is Polyoxyethylene Methyl Glucoside Ether, methyl glucoside polyethenoxy ether, Polyoxyethylene Methyl Glucoside Ether dioleate, cocos nucifera oil acyl monoisopropanolamine compound, myristoyl monoethanolamine compound, sorbitan monooleate, anhydrous sorbitol cetylate, anhydrous sorbitol laurate, glycerol monohydroxystearate, polyoxyethylene alkyl ether ester, isomeric alcohol polyethenoxy ether, fatty acid methyl ester polyoxyethylene ether, glycerol mono-acid stearate, aliphatic acid polyethenoxy acid esters, the mixture of the one or more than one of polyglyceryl fatty acid ester and methyl glycol fatty acid ester。
7. a kind of hardware products ultrasound wave water-base cleaning liquid according to claim 1, it is characterised in that: described ether compound is the mixture of the one or more than one of diethylene glycol monomethyl ether, triethylene glycol monomethyl ether, diethylene glycol monobutyl ether, triethylene glycol butyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monopropyl ether, three glycerol list propyl ether, dipropylene, tripropylene glycol butyl ether。
8. a kind of hardware products ultrasound wave water-base cleaning liquid according to claim 1, it is characterised in that: described builder is the mixture of the one or more than one of sodium citrate, sodium ethylene diamine tetracetate, nitrilotriacetic acid sodium, sodium metasilicate, complex silicate sodium, modified polyacrylate sodium, poly-aspartate, Oxytarch, carboxymethyl starch。
9. a kind of hardware products ultrasound wave water-base cleaning liquid according to claim 1, it is characterised in that: described auxiliary agent includes corrosion inhibiter, and described corrosion inhibiter is the mixture of the one or more than one of thiourea, benzotriazole, mercaptobenzimidazole and alkanolamide。
10. the preparation method of a kind of hardware products ultrasound wave water-base cleaning liquid as described in claim 1-9 any one, it is characterised in that: include following procedure of processing:
Step A, weigh the material of formula ratio according to formula, be placed individually in different containers；
Step B, add water in reactor, then builder is joined in reactor, stirring while adding so that builder is dispersed in water；
Step C, Gemini surface active agent and nonionic surfactant are added separately in reactor, stirring while adding so that Gemini surface active agent and nonionic surfactant are dispersed in water；
Step D, alcohol amine compound is joined in reactor, stirring while adding so that alcohol amine compound is dispersed in water；
Step E, ether compound is joined in reactor, stirring while adding so that ether compound is dispersed in water；
Step F, auxiliary agent is joined in reactor, stirring while adding so that auxiliary agent is dispersed in water and forms final multicomponent mixed liquor, get product。
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Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102002722A (en) * | 2009-08-28 | 2011-04-06 | 比亚迪股份有限公司 | Stainless steel cleaner and stainless steel cleaning method |
| CN102492952A (en) * | 2011-11-18 | 2012-06-13 | 东莞市东辉贸易有限公司 | Phosphorus-free degreasing powder, production process and phosphorus-free degreasing process thereof |
| CN102560510A (en) * | 2010-12-10 | 2012-07-11 | 安集微电子（上海）有限公司 | Cleaning solution for metal corrosion resistance |
| CN103510100A (en) * | 2013-09-26 | 2014-01-15 | 杨桂望 | Metal cleaning agent |
| CN104141145A (en) * | 2014-07-30 | 2014-11-12 | 青岛启源振东电气有限公司 | Efficient cleaning agent for metal equipment |
| CN104388966A (en) * | 2014-12-03 | 2015-03-04 | 谭建忠 | Normal temperature water-based antirust cleaning agent |
| CN104480482A (en) * | 2014-12-25 | 2015-04-01 | 常熟市苏搪化工设备制造有限公司 | Special cleaning solution for slightly alkaline chemical equipment |
| CN105040005A (en) * | 2015-07-24 | 2015-11-11 | 苏州华冲精密机械有限公司 | Water-based cleaning agents for automobile parts and preparation method for water-based cleaning agents |
-
2016
- 2016-02-18 CN CN201610090829.4A patent/CN105696008B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102002722A (en) * | 2009-08-28 | 2011-04-06 | 比亚迪股份有限公司 | Stainless steel cleaner and stainless steel cleaning method |
| CN102560510A (en) * | 2010-12-10 | 2012-07-11 | 安集微电子（上海）有限公司 | Cleaning solution for metal corrosion resistance |
| CN102492952A (en) * | 2011-11-18 | 2012-06-13 | 东莞市东辉贸易有限公司 | Phosphorus-free degreasing powder, production process and phosphorus-free degreasing process thereof |
| CN103510100A (en) * | 2013-09-26 | 2014-01-15 | 杨桂望 | Metal cleaning agent |
| CN104141145A (en) * | 2014-07-30 | 2014-11-12 | 青岛启源振东电气有限公司 | Efficient cleaning agent for metal equipment |
| CN104388966A (en) * | 2014-12-03 | 2015-03-04 | 谭建忠 | Normal temperature water-based antirust cleaning agent |
| CN104480482A (en) * | 2014-12-25 | 2015-04-01 | 常熟市苏搪化工设备制造有限公司 | Special cleaning solution for slightly alkaline chemical equipment |
| CN105040005A (en) * | 2015-07-24 | 2015-11-11 | 苏州华冲精密机械有限公司 | Water-based cleaning agents for automobile parts and preparation method for water-based cleaning agents |
Non-Patent Citations (4)
| Title |
|---|
| 徐宝财等: "《洗涤剂配方设计》", 30 April 2010, 北京：化学工业出版社 * |
| 王福海等: "《硬脂酸及脂肪酸衍生物生产工艺》", 31 July 1991, 中国轻工业出版社 * |
| 王雨: "含双子表面活性剂的金属清洗剂的研制", 《第九届全国化学工艺学术年会》 * |
| 章永年等: "《液体洗涤剂（第2版）》", 30 September 2000, 中国轻工业出版社 * |
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