CN105463478A - Metal cleaner material composition and preparation method and application of metal cleaner - Google Patents
Metal cleaner material composition and preparation method and application of metal cleaner Download PDFInfo
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- CN105463478A CN105463478A CN201510873771.6A CN201510873771A CN105463478A CN 105463478 A CN105463478 A CN 105463478A CN 201510873771 A CN201510873771 A CN 201510873771A CN 105463478 A CN105463478 A CN 105463478A
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
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Abstract
The invention discloses a metal cleaner material composition and a preparation method and application of a metal cleaner. The composition comprises water, sodium sulfate, sodium chloride, calcium chloride, polyving akohol, phosphoric acid, starch, titanium dioxide and calcium carbonate. Relative to 100 weight parts of water, the composition comprises, by weight, 5-15 parts of sodium sulfate, 3-10 parts of sodium chloride, 3-10 parts of calcium chloride, 5-15 parts of polyving akohol, 20-50 parts of phosphoric acid, 1-10 parts of starch, 3-15 parts of titanium dioxide and 5-20 parts of calcium carbonate. By means of the design, metal needing to be cleaned can be directly put in the prepared metal cleaner to be soaked, and oil dirt, rust and the like on the surface of the metal can be effectively removed.
Description
Technical field
The present invention relates to the manufacture field of metal cleaning material, particularly, relate to preparation method and the application of a kind of metal cleaner material compositions and metal cleaner.
Background technology
Metal often there will be the phenomenons such as dirty in routine use; especially some greases are very easily infected with on metal; and because needing oil addition etc. in process of production in a lot of situation of equipment of preparation of metals; metallic surface is then made more to become easily infected by grease etc. dirty; and this type of spot is often more difficult clean; general method is difficult to be cleaned out; and also very easily there is the phenomenons such as corrosion after a procedure in metal; therefore need operator to spend a large amount of time and efforts to clean it, thus affect its use.
Therefore, provide one can effective clean metal, and can effectively remove metallic surface corrosion, enhance productivity, reduce the metal cleaner material compositions of maintenance cost and the preparation method of metal cleaner is the problem that the present invention needs solution badly.
Summary of the invention
For above-mentioned prior art, the object of the invention is to overcome in prior art and need oil addition etc. in process of production in a lot of situation of the equipment of preparation of metals, metallic surface is then made more to become easily infected by grease etc. dirty, and this type of spot is often more difficult clean, general method is difficult to be cleaned out, and also very easily there is the phenomenons such as corrosion after a procedure in metal, therefore operator are needed to spend a large amount of time and efforts to clean it, and affect its problem used, thus provide one can effective clean metal, and can effectively remove metallic surface corrosion, enhance productivity, reduce the metal cleaner material compositions of maintenance cost and the preparation method of metal cleaner.
To achieve these goals, the invention provides a kind of metal cleaner material compositions, wherein, described composition comprises water, sodium sulfate, sodium-chlor, calcium chloride, polyvinyl alcohol, phosphoric acid, starch, titanium dioxide and calcium carbonate; Wherein,
Relative to the described water of 100 weight parts, the content of described sodium sulfate is 5-15 weight part, the content of described sodium-chlor is 3-10 weight part, the content of described calcium chloride is 3-10 weight part, the content of described polyvinyl alcohol is 5-15 weight part, and the content of described phosphoric acid is 20-50 weight part, and the content of described starch is 1-10 weight part, the content of described titanium dioxide is 3-15 weight part, and the content of described calcium carbonate is 5-20 weight part.
Present invention also offers a kind of preparation method of metal cleaner, wherein, described preparation method comprises: by metal cleaner obtained after the mixing of water, sodium sulfate, sodium-chlor, calcium chloride, polyvinyl alcohol, phosphoric acid, starch, titanium dioxide and calcium carbonate; Wherein,
Relative to the described water of 100 weight parts, the consumption of described sodium sulfate is 5-15 weight part, the consumption of described sodium-chlor is 3-10 weight part, the consumption of described calcium chloride is 3-10 weight part, the consumption of described polyvinyl alcohol is 5-15 weight part, and the consumption of described phosphoric acid is 20-50 weight part, and the consumption of described starch is 1-10 weight part, the consumption of described titanium dioxide is 3-15 weight part, and the consumption of described calcium carbonate is 5-20 weight part.
Present invention also offers a kind of application of the metal cleaner obtained according to preparation method described above.
Pass through technique scheme, water, sodium sulfate, sodium-chlor, calcium chloride, polyvinyl alcohol, phosphoric acid, starch, titanium dioxide and calcium carbonate are obtained metal cleaner according to after the mixing of certain ratio by the present invention, and soak needing the metal of cleaning to be directly placed in above-mentioned obtained metal cleaner, effectively can remove the greasy dirt and corrosion etc. of metallic surface, thus the maintenance cost greatly reduced for this metal, improve service efficiency and production efficiency.
Other features and advantages of the present invention are described in detail in embodiment part subsequently.
Embodiment
Below the specific embodiment of the present invention is described in detail.Should be understood that, embodiment described herein, only for instruction and explanation of the present invention, is not limited to the present invention.
The invention provides a kind of metal cleaner material compositions, wherein, described composition comprises water, sodium sulfate, sodium-chlor, calcium chloride, polyvinyl alcohol, phosphoric acid, starch, titanium dioxide and calcium carbonate; Wherein,
Relative to the described water of 100 weight parts, the content of described sodium sulfate is 5-15 weight part, the content of described sodium-chlor is 3-10 weight part, the content of described calcium chloride is 3-10 weight part, the content of described polyvinyl alcohol is 5-15 weight part, and the content of described phosphoric acid is 20-50 weight part, and the content of described starch is 1-10 weight part, the content of described titanium dioxide is 3-15 weight part, and the content of described calcium carbonate is 5-20 weight part.
Above-mentioned design is by obtaining metal cleaner by water, sodium sulfate, sodium-chlor, calcium chloride, polyvinyl alcohol, phosphoric acid, starch, titanium dioxide and calcium carbonate according to after the mixing of certain ratio, and soak needing the metal of cleaning to be directly placed in above-mentioned obtained metal cleaner, effectively can remove the greasy dirt and corrosion etc. of metallic surface, thus the maintenance cost greatly reduced for this metal, improve service efficiency and production efficiency.
One of the present invention preferred embodiment in, in order to make the degreasing of the metal cleaner obtained and erosion better effects if of derusting, relative to the described water of 100 weight parts, the content of described sodium sulfate is 8-12 weight part, the content of described sodium-chlor is 5-8 weight part, the content of described calcium chloride is 5-8 weight part, the content of described polyvinyl alcohol is 8-12 weight part, the content of described phosphoric acid is 30-40 weight part, the content of described starch is 3-7 weight part, the content of described titanium dioxide is 5-10 weight part, and the content of described calcium carbonate is 10-15 weight part.
Certainly, in order to make more easily to mix between each material, one of the present invention more preferred embodiment in, the particle diameter of described titanium dioxide and described calcium carbonate is not more than 0.5mm.
Present invention also offers a kind of preparation method of metal cleaner, wherein, described preparation method comprises: by metal cleaner obtained after the mixing of water, sodium sulfate, sodium-chlor, calcium chloride, polyvinyl alcohol, phosphoric acid, starch, titanium dioxide and calcium carbonate; Wherein,
Relative to the described water of 100 weight parts, the consumption of described sodium sulfate is 5-15 weight part, the consumption of described sodium-chlor is 3-10 weight part, the consumption of described calcium chloride is 3-10 weight part, the consumption of described polyvinyl alcohol is 5-15 weight part, and the consumption of described phosphoric acid is 20-50 weight part, and the consumption of described starch is 1-10 weight part, the consumption of described titanium dioxide is 3-15 weight part, and the consumption of described calcium carbonate is 5-20 weight part.
Similarly, one of the present invention preferred embodiment in, relative to the described water of 100 weight parts, the consumption of described sodium sulfate is 8-12 weight part, and the consumption of described sodium-chlor is 5-8 weight part, the consumption of described calcium chloride is 5-8 weight part, the consumption of described polyvinyl alcohol is 8-12 weight part, and the consumption of described phosphoric acid is 30-40 weight part, and the consumption of described starch is 3-7 weight part, the consumption of described titanium dioxide is 5-10 weight part, and the consumption of described calcium carbonate is 10-15 weight part.
Certainly, one of the present invention more preferred embodiment in, the particle diameter of described titanium dioxide and described calcium carbonate is not more than 0.5mm.
The mode that described mixing process can adopt according to this area routine operates, such as, one of the present invention preferred embodiment in, in order to make mixed effect better, mixing velocity is faster, and described mixing process is that to be placed in temperature be uniformly mixed under the condition of 40-80 DEG C.
Agitation condition can be not construed as limiting, certainly, one of the present invention preferred embodiment in, the stir speed (S.S.) of whipping process is 100-200r/min, and churning time is 10-30min.
Present invention also offers a kind of application of the metal cleaner obtained according to preparation method described above.
Below will be described the present invention by embodiment.In following examples, described sodium sulfate, described sodium-chlor, described calcium chloride, described polyvinyl alcohol, described phosphoric acid, described starch, described titanium dioxide and described calcium carbonate are conventional commercial product.
Embodiment 1
It is 40 DEG C that the mixing of 100g water, 8g sodium sulfate, 5g sodium-chlor, 5g calcium chloride, 8g polyvinyl alcohol, 30g phosphoric acid, 3g starch, 5g titanium dioxide and 10g calcium carbonate is placed on temperature, stir speed (S.S.) is stir 10min under the condition of 100r/min, obtained metal cleaner A1.
Embodiment 2
It is 80 DEG C that the mixing of 100g water, 12g sodium sulfate, 8g sodium-chlor, 8g calcium chloride, 12g polyvinyl alcohol, 40g phosphoric acid, 7g starch, 10g titanium dioxide and 15g calcium carbonate is placed on temperature, stir speed (S.S.) is stir 30min under the condition of 200r/min, obtained metal cleaner A2.
Embodiment 3
It is 60 DEG C that the mixing of 100g water, 10g sodium sulfate, 6g sodium-chlor, 6g calcium chloride, 10g polyvinyl alcohol, 35g phosphoric acid, 5g starch, 8g titanium dioxide and 12g calcium carbonate is placed on temperature, stir speed (S.S.) is stir 20min under the condition of 150r/min, obtained metal cleaner A3.
Embodiment 4
Be prepared according to the preparation method of embodiment 1, unlike, the consumption of described sodium sulfate is 5g, and the consumption of described sodium-chlor is 3g, and the consumption of described calcium chloride is 3g, the consumption of described polyvinyl alcohol is 5g, the consumption of described phosphoric acid is 20g, and the consumption of described starch is 1g, and the consumption of described titanium dioxide is 3g, the consumption of described calcium carbonate is 5g, obtained metal cleaner A4.
Embodiment 5
Be prepared according to the preparation method of embodiment 2, unlike, the consumption of described sodium sulfate is 15g, and the consumption of described sodium-chlor is 10g, and the consumption of described calcium chloride is 10g, the consumption of described polyvinyl alcohol is 15g, the consumption of described phosphoric acid is 50g, and the consumption of described starch is 10g, and the consumption of described titanium dioxide is 15g, the consumption of described calcium carbonate is 20g, obtained metal cleaner A5.
Comparative example 1
Be prepared according to the preparation method of embodiment 3, unlike, the consumption of described sodium sulfate is 2g, and the consumption of described sodium-chlor is 1g, and the consumption of described calcium chloride is 1g, the consumption of described polyvinyl alcohol is 2g, the consumption of described phosphoric acid is 10g, and the consumption of described starch is 0.5g, and the consumption of described titanium dioxide is 1g, the consumption of described calcium carbonate is 2g, obtained metal cleaner D1.
Comparative example 2
Be prepared according to the preparation method of embodiment 3, unlike, the consumption of described sodium sulfate is 30g, and the consumption of described sodium-chlor is 20g, and the consumption of described calcium chloride is 20g, the consumption of described polyvinyl alcohol is 30g, the consumption of described phosphoric acid is 80g, and the consumption of described starch is 20g, and the consumption of described titanium dioxide is 30g, the consumption of described calcium carbonate is 40g, obtained metal cleaner D2.
Test case
Iron plate surface with greasy dirt and corrosion is placed in after above-mentioned A1-A5, D1 and D2 soak 2h and takes out above-mentioned iron plate, and detect iron plate surface clearness, the result obtained is as shown in table 1.
Table 1
Numbering | Surface clearness |
A1 | Without greasy dirt, non-corroding |
A2 | Without greasy dirt, non-corroding |
A3 | Without greasy dirt, non-corroding |
A4 | Without obvious greasy dirt and corrosion |
A5 | Without obvious greasy dirt and corrosion |
D1 | Obvious greasy dirt and corrosion |
D2 | Obvious greasy dirt and corrosion |
More than describe the preferred embodiment of the present invention in detail; but the present invention is not limited to the detail in above-mentioned embodiment, within the scope of technical conceive of the present invention; can carry out multiple simple variant to technical scheme of the present invention, these simple variant all belong to protection scope of the present invention.
It should be noted that in addition, each concrete technical characteristic described in above-mentioned embodiment, in reconcilable situation, can be combined by any suitable mode, in order to avoid unnecessary repetition, the present invention illustrates no longer separately to various possible array mode.
In addition, also can carry out arbitrary combination between various different embodiment of the present invention, as long as it is without prejudice to thought of the present invention, it should be considered as content disclosed in this invention equally.
Claims (9)
1. a metal cleaner material compositions, is characterized in that, described composition comprises water, sodium sulfate, sodium-chlor, calcium chloride, polyvinyl alcohol, phosphoric acid, starch, titanium dioxide and calcium carbonate; Wherein,
Relative to the described water of 100 weight parts, the content of described sodium sulfate is 5-15 weight part, the content of described sodium-chlor is 3-10 weight part, the content of described calcium chloride is 3-10 weight part, the content of described polyvinyl alcohol is 5-15 weight part, and the content of described phosphoric acid is 20-50 weight part, and the content of described starch is 1-10 weight part, the content of described titanium dioxide is 3-15 weight part, and the content of described calcium carbonate is 5-20 weight part.
2. composition according to claim 1, wherein, relative to the described water of 100 weight parts, the content of described sodium sulfate is 8-12 weight part, and the content of described sodium-chlor is 5-8 weight part, the content of described calcium chloride is 5-8 weight part, the content of described polyvinyl alcohol is 8-12 weight part, and the content of described phosphoric acid is 30-40 weight part, and the content of described starch is 3-7 weight part, the content of described titanium dioxide is 5-10 weight part, and the content of described calcium carbonate is 10-15 weight part.
3. composition according to claim 1 and 2, wherein, the particle diameter of described titanium dioxide and described calcium carbonate is not more than 0.5mm.
4. a preparation method for metal cleaner, is characterized in that, described preparation method comprises: by metal cleaner obtained after the mixing of water, sodium sulfate, sodium-chlor, calcium chloride, polyvinyl alcohol, phosphoric acid, starch, titanium dioxide and calcium carbonate; Wherein,
Relative to the described water of 100 weight parts, the consumption of described sodium sulfate is 5-15 weight part, the consumption of described sodium-chlor is 3-10 weight part, the consumption of described calcium chloride is 3-10 weight part, the consumption of described polyvinyl alcohol is 5-15 weight part, and the consumption of described phosphoric acid is 20-50 weight part, and the consumption of described starch is 1-10 weight part, the consumption of described titanium dioxide is 3-15 weight part, and the consumption of described calcium carbonate is 5-20 weight part.
5. preparation method according to claim 4, wherein, relative to the described water of 100 weight parts, the consumption of described sodium sulfate is 8-12 weight part, and the consumption of described sodium-chlor is 5-8 weight part, the consumption of described calcium chloride is 5-8 weight part, the consumption of described polyvinyl alcohol is 8-12 weight part, and the consumption of described phosphoric acid is 30-40 weight part, and the consumption of described starch is 3-7 weight part, the consumption of described titanium dioxide is 5-10 weight part, and the consumption of described calcium carbonate is 10-15 weight part.
6. the preparation method according to claim 4 or 5, wherein, the particle diameter of described titanium dioxide and described calcium carbonate is not more than 0.5mm.
7. the preparation method according to claim 4 or 5, wherein, described mixing process is that to be placed in temperature be uniformly mixed under the condition of 40-80 DEG C.
8. preparation method according to claim 7, wherein, the stir speed (S.S.) of whipping process is 100-200r/min, and churning time is 10-30min.
9. the application of the metal cleaner obtained according to the preparation method in claim 4-8 described in any one.
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CN108385119A (en) * | 2018-04-13 | 2018-08-10 | 苏州锐耐洁电子科技新材料有限公司 | A kind of metal cleaner and preparation method thereof |
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CN1696262A (en) * | 2004-05-13 | 2005-11-16 | 崔生 | Phosphorus free Nano Hyperconcentrated liquid detergent |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN108385119A (en) * | 2018-04-13 | 2018-08-10 | 苏州锐耐洁电子科技新材料有限公司 | A kind of metal cleaner and preparation method thereof |
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Application publication date: 20160406 |