CN110284143A - A kind of metal cleaner - Google Patents
A kind of metal cleaner Download PDFInfo
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- CN110284143A CN110284143A CN201910748938.4A CN201910748938A CN110284143A CN 110284143 A CN110284143 A CN 110284143A CN 201910748938 A CN201910748938 A CN 201910748938A CN 110284143 A CN110284143 A CN 110284143A
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/24—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions
- C23G1/26—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions using inhibitors
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Abstract
A kind of metal cleaner, including following raw material: sodium dodecyl benzene sulfonate, octyl phenol polyoxyethylene ether, sodium tripolyphosphate, sodium potassium tartrate tetrahydrate, sodium chloride, imidazoline, diethanol amine, antistatic agent, defoaming agent, starch, perlite powder, silicone oil and deionized water.Contain octyl phenol polyoxyethylene ether and lauryl sodium sulfate in metal cleaner provided by the invention, is used in mixed way the polarity dirt that can effectively remove metal surface；Promote the reduction of critical micelle concentration of surfactant by the sodium chloride of addition to promote micelle forma-tion to enable surfactant in the enhancing of the adsorption capacity of dirt and cleaning object surface and by the sodium tripolyphosphate and sodium potassium tartrate tetrahydrate softening of water of addition, so that the washability of surfactant be made to improve；In addition, the silicone oil by addition forms one layer of smooth oil film in metal surface, the anticorrosion ability of imidazoline and diethanol amine is cooperated to improve the corrosion resistance after metal cleaning.
Description
Technical field
The present invention relates to industry cleaning link technical field more particularly to a kind of metal cleaners.
Background technique
In different metalworking procedures, the surface of metal parts can stick various types of for metal material and workpiece
Dirt；The surface of metal material and workpiece is easily adhered after the substances such as greasy dirt when transporting to it, metal material and workpiece
Surface may corrode；Only these dirts are sufficiently cleaned up, could guarantee the processing of metal material and workpiece
Quality；In order to meet metal material and workpiece processing technology requirement, the quality for guaranteeing metal product, the service life used and
The reliability of performance, need before and after intermetallic composite coating and finished product assembling or packaging advance row metal surface degreasing, at scale removal
Reason；It is usually all to make cleaning solution using diesel oil, coal Water Oil Or Gas and cleaned to metal material and workpiece, this not only wastes energy
Source, and there is potential insecurity factors；And current cleaner for metal cleaning effect difference cannot be effectively to metal material
Material and the impurity of work piece surface etc. are purged, in addition, existing cleaner for metal cleaning corrosivity is stronger, it is useless after cleaning
Liquid is toxic to human body, pollution environment etc..
Summary of the invention
(1) goal of the invention
To solve technical problem present in background technique, the present invention proposes a kind of metal cleaner, provided by the invention
Metal cleaner can efficiently be purged the greasy dirt impurity etc. that metal material and work piece surface have, and dirty removal capacities are strong,
It is more environmentally protective and to human body and environmentally friendly.
(2) technical solution
The present invention provides a kind of metal cleaner, the raw material including following parts by weight: sodium dodecyl benzene sulfonate 15-25
Part, 20-30 parts of octyl phenol polyoxyethylene ether, 8-15 parts of sodium tripolyphosphate, 8-15 parts of sodium potassium tartrate tetrahydrate, 5-10 parts of sodium chloride, miaow
0.2-1 parts of oxazoline, 0.2-1 parts of diethanol amine, 0.2-2.5 parts of antistatic agent, 0.2-1.5 parts of defoaming agent, 15-20 parts of starch, treasure
End 8-15 parts of pearl rock powder, 5-8 parts of silicone oil and 50-80 parts of deionized water.
Preferably, above-mentioned metal cleaner, the raw material including following parts by weight: 15 parts of sodium dodecyl benzene sulfonate, octyl
20 parts of phenol polyethenoxy ether, 8 parts of sodium tripolyphosphate, 8 parts of sodium potassium tartrate tetrahydrate, 5 parts of sodium chloride, 0.2 part of imidazoline, diethanol amine
0.2 part, 0.2 part of antistatic agent, 0.2 part of defoaming agent, 15 parts of starch, 8 parts of perlite powder, 5 parts of silicone oil and 50 parts of deionized water.
Preferably, above-mentioned metal cleaner, the raw material including following parts by weight: 18 parts of sodium dodecyl benzene sulfonate, octyl
23 parts of phenol polyethenoxy ether, 10 parts of sodium tripolyphosphate, 10 parts of sodium potassium tartrate tetrahydrate, 7 parts of sodium chloride, 0.4 part of imidazoline, diethanol amine
0.4 part, 1.2 parts of antistatic agent, 0.6 part of defoaming agent, 17 parts of starch, 10 parts of perlite powder, 6 parts of silicone oil and deionized water 65
Part.
Preferably, above-mentioned metal cleaner, the raw material including following parts by weight: 22 parts of sodium dodecyl benzene sulfonate, octyl
27 parts of phenol polyethenoxy ether, 12 parts of sodium tripolyphosphate, 12 parts of sodium potassium tartrate tetrahydrate, 9 parts of sodium chloride, 0.6 part of imidazoline, diethanol amine
0.6 part, 2.0 parts of antistatic agent, 1.1 parts of defoaming agent, 18 parts of starch, 12 parts of perlite powder, 7 parts of silicone oil and deionized water 75
Part.
Preferably, above-mentioned metal cleaner, the raw material including following parts by weight: 25 parts of sodium dodecyl benzene sulfonate, octyl
30 parts of phenol polyethenoxy ether, 15 parts of sodium tripolyphosphate, 15 parts of sodium potassium tartrate tetrahydrate, 10 parts of sodium chloride, 01 part of imidazoline, diethanol amine
1 part, 2.5 parts of antistatic agent, 1.5 parts of defoaming agent, 20 parts of starch, 15 parts of perlite powder, 8 parts of silicone oil and 80 parts of deionized water.
Preferably, the particle diameter of starch is 40-80 microns.
Preferably, the particle diameter of perlite powder is 300-600 microns.
Preferably, defoaming agent is polyoxyethylene polyoxypropylene pentaerythrite ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polyoxy third
One of alkene glycerin ether and polyoxyethylene polyoxypropylene glycerin ether are a variety of.
Preferably, antistatic agent includes alkylolamides phosphate kalium salt.
Preferably, the production method of above-mentioned metal cleaner, comprising the following specific steps
S1, perlite powder and silicone oil are weighed by weight be uniformly mixed, obtain mixture A；
S2, deionized water is weighed by weight and is heated to 30-45 DEG C, obtain warm water B；
S3, starch is weighed by weight and is added in warm water B, obtain mixture C after evenly mixing；
S4, sodium dodecyl benzene sulfonate, octyl phenol polyoxyethylene ether, sodium tripolyphosphate, potassium tartrate are weighed by weight
Sodium, sodium chloride, imidazoline and diethanol amine are simultaneously added in mixture C one by one, are uniformly mixing to obtain mixture D；
S5, antistatic agent is weighed by weight and defoaming agent is separately added into mixture D, be uniformly mixing to obtain mixture E；
S6, it mixture E is cooled to room temperature to mechanism obtains metal cleaner F.
Above-mentioned technical proposal of the invention has following beneficial technical effect:
Added with the octyl phenol polyoxyethylene ether for belonging to nonionic surfactant in metal cleaner produced by the present invention
And belong to anionic, it is used in mixed way the polarity dirt that can effectively remove metal surface
Dirt；In addition, added with the sodium chloride for belonging to neutral electrolyte salt in metal cleaner；There is no washing energy for sodium chloride itself
Power, but the reduction of critical micelle concentration of surfactant can be promoted in their addition aqueous surfactant solutions to promote micella shape
At the raising of, surface-active, and the surface tension of aqueous surfactant solution can be made to reduce, make surfactant in dirt and clear
The adsorption capacity enhancing for washing body surface, so that the washability of surfactant be made to improve；
Starch is added in metal cleaner produced by the present invention；The surfactant adsorbed in starch powder particle, can
The washability to the greasy dirt of metal surface can be effectively improved in cleaning；Silicone oil is adsorbed in perlite powder；Using gold
When category cleaning agent is cleaned, starch and perlite powder contact with metal surface and generate friction to improve surfactant
To the cleaning effect of metal surface rusty stain；
The metal surface of imidazoline and the diethanol amine absorption added in metal cleaner produced by the present invention after cleaning,
Metallic material corrosion can effectively be prevented or slowed down；The silicone oil adsorbed in perlite powder simultaneously releases, in metal surface
One layer of smooth oil film is formed, cooperates the anticorrosion ability of imidazoline and diethanol amine, and then can be after metal cleaning to metal watch
Face has certain corrosion resistance；
The sodium tripolyphosphate and sodium potassium tartrate tetrahydrate energy softening of water added in metal cleaner produced by the present invention, and can incite somebody to action
The metal cation to serve as a connection between electronegative dirt particles chelates to form soluble stabilization complex salt, and then destroys metal
Electrostatic structure between surface smut, and cooperate the antistatic agent of addition to improve the dirt-removing power of metal cleaner；Pass through addition
Defoaming agent can suppress or eliminate the foam that generates in metal cleaner preparation and use process, improve the equal of reagent solution
Even property and then the dirt-removing power for improving solution；Metal cleaner produced by the present invention is more green to human body and environmentally friendly
Environmental protection.
Specific embodiment
In order to make the objectives, technical solutions and advantages of the present invention clearer, With reference to embodiment, to this
Invention is further described.It should be understood that these descriptions are merely illustrative, and it is not intended to limit the scope of the invention.This
Outside, in the following description, descriptions of well-known structures and technologies are omitted, so as not to unnecessarily obscure the concept of the present invention.
Embodiment 1
A kind of metal cleaner proposed by the present invention, the raw material including following parts by weight: 15 parts of sodium dodecyl benzene sulfonate,
20 parts of octyl phenol polyoxyethylene ether, 8 parts of sodium tripolyphosphate, 8 parts of sodium potassium tartrate tetrahydrate, 5 parts of sodium chloride, 0.2 part of imidazoline, diethanol
0.2 part of amine, 0.2 part of antistatic agent, 0.2 part of defoaming agent, 15 parts of starch, 8 parts of perlite powder, 5 parts of silicone oil and deionized water 50
Part.
In an alternative embodiment, the particle diameter of starch is 40 microns.
In an alternative embodiment, the particle diameter of perlite powder is 300 microns.
In an alternative embodiment, defoaming agent is polyoxyethylene polyoxypropylene pentaerythrite ether, polyoxyethylene polyoxy
One of propyl alcohol amidogen ether, polypropylene glycerol aether and polyoxyethylene polyoxypropylene glycerin ether are a variety of.
In an alternative embodiment, antistatic agent includes alkylolamides phosphate kalium salt.
A kind of production method for metal cleaner that the present invention also proposes, comprising the following specific steps
S1, perlite powder and silicone oil are weighed by weight be uniformly mixed, obtain mixture A；
S2, deionized water is weighed by weight and is heated to 30 DEG C, obtain warm water B；
S3, starch is weighed by weight and is added in warm water B, obtain mixture C after evenly mixing；
S4, sodium dodecyl benzene sulfonate, octyl phenol polyoxyethylene ether, sodium tripolyphosphate, potassium tartrate are weighed by weight
Sodium, sodium chloride, imidazoline and diethanol amine are simultaneously added in mixture C one by one, are uniformly mixing to obtain mixture D；
S5, antistatic agent is weighed by weight and defoaming agent is separately added into mixture D, be uniformly mixing to obtain mixture E；
S6, it mixture E is cooled to room temperature to mechanism obtains metal cleaner F.
Embodiment 2
A kind of metal cleaner proposed by the present invention, the raw material including following parts by weight: 18 parts of sodium dodecyl benzene sulfonate,
23 parts of octyl phenol polyoxyethylene ether, 10 parts of sodium tripolyphosphate, 10 parts of sodium potassium tartrate tetrahydrate, 7 parts of sodium chloride, 0.4 part of imidazoline, diethyl
0.4 part of hydramine, 1.2 parts of antistatic agent, 0.6 part of defoaming agent, 17 parts of starch, 10 parts of perlite powder, 6 parts of silicone oil and deionized water
65 parts.
In an alternative embodiment, the particle diameter of starch is 50 microns.
In an alternative embodiment, the particle diameter of perlite powder is 400 microns.
In an alternative embodiment, defoaming agent is polyoxyethylene polyoxypropylene pentaerythrite ether, polyoxyethylene polyoxy
One of propyl alcohol amidogen ether, polypropylene glycerol aether and polyoxyethylene polyoxypropylene glycerin ether are a variety of.
In an alternative embodiment, antistatic agent includes alkylolamides phosphate kalium salt.
A kind of production method for metal cleaner that the present invention also proposes, comprising the following specific steps
S1, perlite powder and silicone oil are weighed by weight be uniformly mixed, obtain mixture A；
S2, deionized water is weighed by weight and is heated to 35 DEG C, obtain warm water B；
S3, starch is weighed by weight and is added in warm water B, obtain mixture C after evenly mixing；
S4, sodium dodecyl benzene sulfonate, octyl phenol polyoxyethylene ether, sodium tripolyphosphate, potassium tartrate are weighed by weight
Sodium, sodium chloride, imidazoline and diethanol amine are simultaneously added in mixture C one by one, are uniformly mixing to obtain mixture D；
S5, antistatic agent is weighed by weight and defoaming agent is separately added into mixture D, be uniformly mixing to obtain mixture E；
S6, it mixture E is cooled to room temperature to mechanism obtains metal cleaner F.
Embodiment 3
A kind of metal cleaner proposed by the present invention, the raw material including following parts by weight: 22 parts of sodium dodecyl benzene sulfonate,
27 parts of octyl phenol polyoxyethylene ether, 12 parts of sodium tripolyphosphate, 12 parts of sodium potassium tartrate tetrahydrate, 9 parts of sodium chloride, 0.6 part of imidazoline, diethyl
0.6 part of hydramine, 2.0 parts of antistatic agent, 1.1 parts of defoaming agent, 18 parts of starch, 12 parts of perlite powder, 7 parts of silicone oil and deionized water
75 parts.
In an alternative embodiment, the particle diameter of starch is 65 microns.
In an alternative embodiment, the particle diameter of perlite powder is 500 microns.
In an alternative embodiment, defoaming agent is polyoxyethylene polyoxypropylene pentaerythrite ether, polyoxyethylene polyoxy
One of propyl alcohol amidogen ether, polypropylene glycerol aether and polyoxyethylene polyoxypropylene glycerin ether are a variety of.
In an alternative embodiment, antistatic agent includes alkylolamides phosphate kalium salt.
A kind of production method for metal cleaner that the present invention also proposes, comprising the following specific steps
S1, perlite powder and silicone oil are weighed by weight be uniformly mixed, obtain mixture A；
S2, deionized water is weighed by weight and is heated to 40 DEG C, obtain warm water B；
S3, starch is weighed by weight and is added in warm water B, obtain mixture C after evenly mixing；
S4, sodium dodecyl benzene sulfonate, octyl phenol polyoxyethylene ether, sodium tripolyphosphate, potassium tartrate are weighed by weight
Sodium, sodium chloride, imidazoline and diethanol amine are simultaneously added in mixture C one by one, are uniformly mixing to obtain mixture D；
S5, antistatic agent is weighed by weight and defoaming agent is separately added into mixture D, be uniformly mixing to obtain mixture E；
S6, it mixture E is cooled to room temperature to mechanism obtains metal cleaner F.
Embodiment 4
A kind of metal cleaner proposed by the present invention, the raw material including following parts by weight: 25 parts of sodium dodecyl benzene sulfonate,
30 parts of octyl phenol polyoxyethylene ether, 15 parts of sodium tripolyphosphate, 15 parts of sodium potassium tartrate tetrahydrate, 10 parts of sodium chloride, 01 part of imidazoline, diethyl
1 part of hydramine, 2.5 parts of antistatic agent, 1.5 parts of defoaming agent, 20 parts of starch, 15 parts of perlite powder, 8 parts of silicone oil and deionized water 80
Part.
In an alternative embodiment, the particle diameter of starch is 80 microns.
In an alternative embodiment, the particle diameter of perlite powder is 600 microns.
In an alternative embodiment, defoaming agent is polyoxyethylene polyoxypropylene pentaerythrite ether, polyoxyethylene polyoxy
One of propyl alcohol amidogen ether, polypropylene glycerol aether and polyoxyethylene polyoxypropylene glycerin ether are a variety of.
In an alternative embodiment, antistatic agent includes alkylolamides phosphate kalium salt.
A kind of production method for metal cleaner that the present invention also proposes, comprising the following specific steps
S1, perlite powder and silicone oil are weighed by weight be uniformly mixed, obtain mixture A；
S2, deionized water is weighed by weight and is heated to 45 DEG C, obtain warm water B；
S3, starch is weighed by weight and is added in warm water B, obtain mixture C after evenly mixing；
S4, sodium dodecyl benzene sulfonate, octyl phenol polyoxyethylene ether, sodium tripolyphosphate, potassium tartrate are weighed by weight
Sodium, sodium chloride, imidazoline and diethanol amine are simultaneously added in mixture C one by one, are uniformly mixing to obtain mixture D；
S5, antistatic agent is weighed by weight and defoaming agent is separately added into mixture D, be uniformly mixing to obtain mixture E；
S6, it mixture E is cooled to room temperature to mechanism obtains metal cleaner F.
It should be understood that above-mentioned specific embodiment of the invention is used only for exemplary illustration or explains of the invention
Principle, but not to limit the present invention.Therefore, that is done without departing from the spirit and scope of the present invention is any
Modification, equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.In addition, appended claims purport of the present invention
Covering the whole variations fallen into attached claim scope and boundary or this range and the equivalent form on boundary and is repairing
Change example.
Claims (10)
1. a kind of metal cleaner, which is characterized in that the raw material including following parts by weight: 15-25 parts of sodium dodecyl benzene sulfonate,
20-30 parts of octyl phenol polyoxyethylene ether, 8-15 parts of sodium tripolyphosphate, 8-15 parts of sodium potassium tartrate tetrahydrate, 5-10 parts of sodium chloride, imidazoline
0.2-1 parts, 0.2-1 parts of diethanol amine, 0.2-2.5 parts of antistatic agent, 0.2-1.5 parts of defoaming agent, 15-20 parts of starch, perlite
8-15 parts of powder, 5-8 parts of silicone oil and 50-80 parts of deionized water.
2. metal cleaner according to claim 1, which is characterized in that the raw material including following parts by weight: dodecyl
15 parts of phenyl-hydrogen-sulfate sodium, 20 parts of octyl phenol polyoxyethylene ether, 8 parts of sodium tripolyphosphate, 8 parts of sodium potassium tartrate tetrahydrate, 5 parts of sodium chloride, imidazoles
0.2 part of quinoline, 0.2 part of diethanol amine, 0.2 part of antistatic agent, 0.2 part of defoaming agent, 15 parts of starch, 8 parts of perlite powder, silicone oil 5
Part and 50 parts of deionized water.
3. metal cleaner according to claim 1, which is characterized in that the raw material including following parts by weight: dodecyl
18 parts of phenyl-hydrogen-sulfate sodium, 23 parts of octyl phenol polyoxyethylene ether, 10 parts of sodium tripolyphosphate, 10 parts of sodium potassium tartrate tetrahydrate, 7 parts of sodium chloride, miaow
0.4 part of oxazoline, 0.4 part of diethanol amine, 1.2 parts of antistatic agent, 0.6 part of defoaming agent, 17 parts of starch, 10 parts of perlite powder, silicon
6 parts and 65 parts of deionized water of oil.
4. metal cleaner according to claim 1, which is characterized in that the raw material including following parts by weight: dodecyl
22 parts of phenyl-hydrogen-sulfate sodium, 27 parts of octyl phenol polyoxyethylene ether, 12 parts of sodium tripolyphosphate, 12 parts of sodium potassium tartrate tetrahydrate, 9 parts of sodium chloride, miaow
0.6 part of oxazoline, 0.6 part of diethanol amine, 2.0 parts of antistatic agent, 1.1 parts of defoaming agent, 18 parts of starch, 12 parts of perlite powder, silicon
7 parts and 75 parts of deionized water of oil.
5. metal cleaner according to claim 1, which is characterized in that the raw material including following parts by weight: dodecyl
25 parts of phenyl-hydrogen-sulfate sodium, 30 parts of octyl phenol polyoxyethylene ether, 15 parts of sodium tripolyphosphate, 15 parts of sodium potassium tartrate tetrahydrate, 10 parts of sodium chloride, miaow
01 part of oxazoline, 1 part of diethanol amine, 2.5 parts of antistatic agent, 1.5 parts of defoaming agent, 20 parts of starch, 15 parts of perlite powder, silicone oil 8
Part and 80 parts of deionized water.
6. metal cleaner according to claim 1, which is characterized in that the particle diameter of starch is 40-80 microns.
7. metal cleaner according to claim 1, which is characterized in that the particle diameter of perlite powder is 300-600
Micron.
8. metal cleaner according to claim 1, which is characterized in that defoaming agent is polyoxyethylene polyoxypropylene Ji Wusi
One of alcohol ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether and polyoxyethylene polyoxypropylene glycerin ether are more
Kind.
9. metal cleaner according to claim 1, which is characterized in that antistatic agent includes alkylolamides phosphate potassium
Salt.
10. -9 described in any item metal cleaners according to claim 1, which is characterized in that the production method of metal cleaner,
Comprising the following specific steps
S1, perlite powder and silicone oil are weighed by weight be uniformly mixed, obtain mixture A；
S2, deionized water is weighed by weight and is heated to 30-45 DEG C, obtain warm water B；
S3, starch is weighed by weight and is added in warm water B, obtain mixture C after evenly mixing；
S4, sodium dodecyl benzene sulfonate, octyl phenol polyoxyethylene ether, sodium tripolyphosphate, sodium potassium tartrate tetrahydrate, chlorine are weighed by weight
Change sodium, imidazoline and diethanol amine and be added in mixture C one by one, is uniformly mixing to obtain mixture D；
S5, antistatic agent is weighed by weight and defoaming agent is separately added into mixture D, be uniformly mixing to obtain mixture E；
S6, it mixture E is cooled to room temperature to mechanism obtains metal cleaner F.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910748938.4A CN110284143A (en) | 2019-08-14 | 2019-08-14 | A kind of metal cleaner |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910748938.4A CN110284143A (en) | 2019-08-14 | 2019-08-14 | A kind of metal cleaner |
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| CN110284143A true CN110284143A (en) | 2019-09-27 |
Family
ID=68025193
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| CN112139133A (en) * | 2020-08-27 | 2020-12-29 | 广西灵水林化有限公司 | Integrated treatment method for scale removal and wastewater of tannin extract production evaporation system |
| CN114107999A (en) * | 2021-11-29 | 2022-03-01 | 厦门普诺尔新材料科技有限公司 | Plane grinding cleaning agent and preparation method thereof |
| CN115247266A (en) * | 2021-10-01 | 2022-10-28 | 哈尔滨市力安特科技发展有限责任公司 | Antirust traceless steel metal cleaning solution and preparation method thereof |
| CN115287129A (en) * | 2022-08-03 | 2022-11-04 | 益阳市明正宏电子有限公司 | Preparation method of neutral water-based cleaning agent for cleaning PCB |
| CN116554729A (en) * | 2023-05-10 | 2023-08-08 | 孚玉山房(北京)文化有限公司 | Color ink easy to clean and preparation method thereof |
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Application publication date: 20190927 |
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