CN108396324A - A kind of environment-friendly high-efficiency compounding antirust rust remover and preparation method thereof - Google Patents
A kind of environment-friendly high-efficiency compounding antirust rust remover and preparation method thereof Download PDFInfo
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- CN108396324A CN108396324A CN201810127370.XA CN201810127370A CN108396324A CN 108396324 A CN108396324 A CN 108396324A CN 201810127370 A CN201810127370 A CN 201810127370A CN 108396324 A CN108396324 A CN 108396324A
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/04—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors
- C23G1/06—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors
- C23G1/063—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors heterocyclic compounds
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Abstract
The invention discloses a kind of environment-friendly high-efficiencies to compound antirust rust remover and preparation method thereof, includes the raw material of following parts by weight：Compound 20 30 parts of acid solution, 35 parts of surfactant, 13 parts of stearate, environmentally friendly 30 40 parts of organic solvent, 12 parts of corrosion inhibiter, 13 parts of polyethylene glycol, 7 11 parts of antirust emulsion, 12 parts of sodium tripolyphosphate, 35 parts of nanometer additive, 13 parts of graphene, 24 parts of rare earth oxide, 12 parts of hexa.Present composition stability is preferable, can effectively remove metal surface rust staining, while can also form layer protecting film in metal surface; prevent metal from being aoxidized again in a short time; realize derusting, antirust is once completed, product is nontoxic, will not to environment generate pollution；The preparation method of the present invention simultaneously, material cost is relatively low, raw material is easy to get and technique is concise, has higher practical value and good application prospect.
Description
Technical field
The present invention relates to technical fields of mechanical processing, and in particular to a kind of environment-friendly high-efficiency compounding antirust rust remover and its preparation
Method.
Background technology
The weight of metal material and equipment that the whole world is scrapped due to corrosion every year be about the 20% of metal annual output with
On, the processing step that derusting before various anti-corrosion measures is primary is taken to metal product.
One side antirust agent is a kind of synthesis bleeding agent of super grade high efficiency, it can strongly penetrate into iron rust, erosion, in greasy dirt
To easily dispose screw, the rusty stain on snail and erosion, there is infiltration derusting, loosen lubrication, resist burn into protection
The performances such as metal.And one layer of lubricating film can be formed and stored on parts surface, can inhibit moisture and it is many other chemistry at
Corrode caused by part.There are many type of antirust agent on the market, and many antirust agent contain the toxic component for having pollution to environment, right
Human body is harmful.
On the other hand all there is certain undesirable place in some existing derusting technologies, for example construct troublesome and processing not
Thoroughly, article abrasion is easily caused using machinery and artificial derusting and is not easy to thoroughly remove, using its discharge of the method for chemical derusting
Metallic compound pollution is easily caused to water quality, general stainless property is poor, and therefore, it is necessary to research and develop newer technology and production
Product, to promote and improve derusting, antirust technology.
Invention content
In view of the drawbacks of the prior art, the object of the present invention is to provide a kind of environment-friendly high-efficiencies to compound antirust rust remover, this is anti-
Rust remover composition stability of becoming rusty is preferable, can effectively remove metal surface rust staining, while can also form one layer in metal surface
Protective film prevents metal from being aoxidized again in a short time, realizes derusting, antirust is once completed, and product is nontoxic, will not
Pollution is generated to environment；The preparation method of the present invention simultaneously, material cost is relatively low, raw material is easy to get and technique is concise, have compared with
High practical value and good application prospect.
The present invention solves technical problem and adopts the following technical scheme that：
The present invention provides a kind of environment-friendly high-efficiencies to compound antirust rust remover, includes the raw material of following parts by weight：
It compounds 20-30 parts of acid solution, 3-5 parts of surfactant, 1-3 parts of stearate, environmentally friendly 30-40 parts of organic solvent, delay
Lose 1-2 parts of agent, 1-3 parts of polyethylene glycol, 7-11 parts of antirust emulsion, 1-2 parts of sodium tripolyphosphate, 3-5 parts of nanometer additive, graphene
1-3 parts, 2-4 parts of rare earth oxide, 1-2 parts of hexa.
Preferably, the environment-friendly high-efficiency compounding antirust rust remover includes the raw material of following parts by weight：
Compound 25 parts of acid solution, 4 parts of surfactant, 2 parts of stearate, environmentally friendly 35 parts of organic solvent, 1.5 parts of corrosion inhibiter,
2 parts of polyethylene glycol, 9 parts of antirust emulsion, 1.5 parts of sodium tripolyphosphate, 4 parts of nanometer additive, 2 parts of graphene, rare earth oxide 3
Part, 1.5 parts of hexa.
Preferably, the compounding acid solution is by acetic acid, tartaric acid, coco-nut oil fatty acid, oxalic acid, salicylic acid according to weight
Measure ratio 2:1:1:2:1 mixing is added to the water, and proportioning is at the solution that mass fraction is 25-35%.
Preferably, the surfactant is alkanolamide, fatty alcohol polyoxyethylene ether and neopelex, is pressed
According to weight ratio 2:1:The mixture of 1 composition.
Preferably, the stearate is zinc stearate, magnesium stearate, calcium stearate according to weight ratio 3:1:1 composition
Mixture；
The antirust emulsion is vinylacetate, acrylic acid accounts for, n-BMA, epoxy resin are according to weight ratio 2:3:
1:The mixture of 4 compositions.
Preferably, the environmentally friendly organic solvent is dimethyl ether, ethyl alcohol, isoamyl alcohol according to weight ratio 5:2:1 group
At mixture.
Preferably, the corrosion inhibiter is methenamine, tungstates, lignosulfonate, cetylamine according to weight ratio 3:1:
2:The mixture of 4 compositions.
Preferably, the nanometer additive is nano zine oxide, nano-titanium dioxide, nano ceramics micro mist according to weight ratio
2:1:The mixture of 1 composition；
The rare earth oxide is the mixture of one or more of lanthanum, cerium, praseodymium, neodymium oxides.
The present invention also provides the preparation methods that a kind of environment-friendly high-efficiency compounds antirust rust remover, include the following steps：
Step 1 weighs each component raw material as required；
Step 2, will compound acid solution, graphene, rare earth oxide, nanometer additive mix be added it is anti-with blender
It answers in kettle, is stirred 20-30 minutes at being 35-45 DEG C in temperature, speed of agitator 200-300r/min obtains mixture A；
Antirust emulsion is mixed environmentally friendly organic solvent and is sent into reaction kettle by step 3, and stirring and dissolving is anti-at being 50-60 DEG C in temperature
It answers 10-20 minutes, adds surfactant, stearate, corrosion inhibiter, polyethylene glycol, sodium tripolyphosphate, hexa-methylene four
Amine continues stirring 10-20 minutes, and speed of agitator 600-700r/min obtains mixture B；
Mixture B prepared by step 4, mixture A prepared by step 2 and step 3 is added in homogenizer, is 45- in temperature
55 DEG C, homogenization pressure 10-14MPa, speed of agitator be homogeneous 7-9 minutes under 7000-8000 r/min, it is cooling canned to obtain
The environment-friendly high-efficiency of the present invention compounds antirust rust remover.
Preferably, the preparation process of the environment-friendly high-efficiency compounding antirust rust remover is：
Step 1 weighs each component raw material as required；
Step 2, will compound acid solution, graphene, rare earth oxide, nanometer additive mix be added it is anti-with blender
It answers in kettle, is stirred 25 minutes at being 40 DEG C in temperature, speed of agitator 250r/min obtains mixture A；
Antirust emulsion is mixed environmentally friendly organic solvent and is sent into reaction kettle by step 3, and stirring and dissolving is reacted at being 55 DEG C in temperature
15 minutes, surfactant, stearate, corrosion inhibiter, polyethylene glycol, sodium tripolyphosphate, hexa are added, is continued
Stirring 15 minutes, speed of agitator 650r/min obtains mixture B；
Mixture B prepared by step 4, mixture A prepared by step 2 and step 3 is added in homogenizer, is 50 in temperature
DEG C, homogenization pressure 12MPa, speed of agitator be homogeneous 8 minutes under 7500r/min, the cooling canned environmental protection for obtaining the present invention is high
Effect compounding antirust rust remover.
Compared with prior art, the present invention has following advantageous effect：
（1）A kind of environment-friendly high-efficiency of the present invention compounds antirust rust remover, and the compounding acid solution of use is mainly acetic acid, winestone
Acid, coco-nut oil fatty acid, oxalic acid, salicylic acid, a few person's compound actions of one side can be gone effectively with the reaction of metal surface rust
Except the corrosion substance of metal surface, the brightness of metal surface is improved, while avoiding the deep-etching of inorganic acid such as hydrochloric acid sulfuric acid
Property may protect metal device significantly to the corrosion on normal metal surface.
（2）A kind of environment-friendly high-efficiency compounding antirust rust remover addition surfactant of the present invention is mainly alkanolamide, fat
Fat alcohol polyoxyethylene ether and neopelex, cooperation compounding acid solution can increase the activity of metal surface, improve
Derust effect, increases the using effect of this product.
（3）A kind of environment-friendly high-efficiency of the present invention compounds antirust rust remover, and it is vinylacetate, propylene to be added to antirust emulsion
Acid accounts for, n-BMA, epoxy resin, can metal surface forms layer protecting film again after use, reduce
Metal and extraneous contact, have completely cut off oxygen, have reduced the generation of oxidation reaction, reached good rust-proof effect.
（4）A kind of environment-friendly high-efficiency solvent for using of compounding antirust rust remover of the present invention for dimethyl ether, ethyl alcohol,
Isoamyl alcohol, it is capable of providing good solubility property to side name, and secondly a few person's mixtures, substantially nonirritant, avoids other
The toxic and harmful gas that organic solvent may volatilize substantially increases the environmental-protecting performance of product.
（5）The nanometer additive that a kind of environment-friendly high-efficiency compounding antirust rust remover of the present invention uses, it is predominantly nano oxidized
Zinc, nano-titanium dioxide, nano ceramics micro mist, one side can coordinate antirust emulsion to form fatal film in metal surface
Layer, reaches good rust-proof effect, and secondly several persons also have certain bactericidal effect, and the generation of the mildew effectively avoided carries significantly
The high self-cleaning performance of product.
（6）On the one hand a kind of graphene of environment-friendly high-efficiency compounding antirust rust remover addition of the present invention can improve product
Heat conductivility can effectively improve derusting performance on the other hand due to the electron interaction on its surface；The corrosion inhibiter master of addition
Compounding yogurt liquid can be effectively reduced for methenamine, tungstates, lignosulfonate, cetylamine may be to normal metal table
On the one hand the corrosion in face reduces the waste of product, substantially increase rust removing function, on the other hand prevents other rust removers
The side effect that may be brought.
（7）A kind of environment-friendly high-efficiency compounding antirust rust remover composition stability of the present invention is preferable, can effectively remove gold
Metal surface rust staining, while layer protecting film can also be formed in metal surface, it prevents metal from being aoxidized again in a short time, realizes
Derusting, antirust are once completed, and product is nontoxic, will not generate pollution to environment；The preparation method of the present invention simultaneously, material
Material cost is relatively low, raw material is easy to get and technique is concise, has higher practical value and good application prospect.
Specific implementation mode
With reference to specific embodiment, technical scheme in the embodiment of the invention is clearly and completely described, shows
So, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the reality in the present invention
Example is applied, every other embodiment obtained by those of ordinary skill in the art without making creative efforts all belongs to
In the scope of protection of the invention.
Embodiment 1.
A kind of environment-friendly high-efficiency of the present embodiment compounds antirust rust remover, includes the raw material of following parts by weight：
It compounds 20 parts of acid solution, 3 parts of surfactant, 1 part of stearate, environmentally friendly 30 parts of organic solvent, 1 part of corrosion inhibiter, gather
1 part of ethylene glycol, 7 parts of antirust emulsion, 1 part of sodium tripolyphosphate, 3 parts of nanometer additive, 1 part of graphene, 2 parts of rare earth oxide, six
1 part of methenamine.
Compounding acid solution in the present embodiment be by acetic acid, tartaric acid, coco-nut oil fatty acid, oxalic acid, salicylic acid according to
Weight ratio 2:1:1:2:1 mixing is added to the water, the solution that proportioning is 25% at mass fraction.
Surfactant in the present embodiment is alkanolamide, fatty alcohol polyoxyethylene ether and neopelex,
According to weight ratio 2:1:The mixture of 1 composition.
Stearate in the present embodiment is zinc stearate, magnesium stearate, calcium stearate according to weight ratio 3:1:1 composition
Mixture；
The antirust emulsion is vinylacetate, acrylic acid accounts for, n-BMA, epoxy resin are according to weight ratio 2:3:
1:The mixture of 4 compositions.
Environmentally friendly organic solvent in the present embodiment is dimethyl ether, ethyl alcohol, isoamyl alcohol according to weight ratio 5:2:1 group
At mixture.
Corrosion inhibiter in the present embodiment is methenamine, tungstates, lignosulfonate, cetylamine according to weight ratio 3:1:
2:The mixture of 4 compositions.
Nanometer additive in the present embodiment is nano zine oxide, nano-titanium dioxide, nano ceramics micro mist according to weight
Than 2:1:The mixture of 1 composition；
The rare earth oxide is the mixture of one or more of lanthanum, cerium, praseodymium, neodymium oxides.
A kind of preparation method of environment-friendly high-efficiency compounding antirust rust remover of the present embodiment, includes the following steps：
Step 1 weighs each component raw material as required；
Step 2, will compound acid solution, graphene, rare earth oxide, nanometer additive mix be added it is anti-with blender
It answers in kettle, is stirred 20 minutes at being 35 DEG C in temperature, speed of agitator 200r/min obtains mixture A；
Antirust emulsion is mixed environmentally friendly organic solvent and is sent into reaction kettle by step 3, and stirring and dissolving is reacted at being 50 DEG C in temperature
10 minutes, surfactant, stearate, corrosion inhibiter, polyethylene glycol, sodium tripolyphosphate, hexa are added, is continued
Stirring 10 minutes, speed of agitator 600r/min obtains mixture B；
Mixture B prepared by step 4, mixture A prepared by step 2 and step 3 is added in homogenizer, is 45 in temperature
DEG C, homogenization pressure 10MPa, speed of agitator be homogeneous 7 minutes under 7000r/min, the cooling canned environmental protection for obtaining the present invention is high
Effect compounding antirust rust remover.
Embodiment 2.
A kind of environment-friendly high-efficiency of the present embodiment compounds antirust rust remover, includes the raw material of following parts by weight：
It compounds 30 parts of acid solution, 5 parts of surfactant, 3 parts of stearate, environmentally friendly 40 parts of organic solvent, 2 parts of corrosion inhibiter, gather
3 parts of ethylene glycol, 11 parts of antirust emulsion, 2 parts of sodium tripolyphosphate, 5 parts of nanometer additive, 3 parts of graphene, 4 parts of rare earth oxide, six
2 parts of methenamine.
Compounding acid solution in the present embodiment be by acetic acid, tartaric acid, coco-nut oil fatty acid, oxalic acid, salicylic acid according to
Weight ratio 2:1:1:2:1 mixing is added to the water, the solution that proportioning is 35% at mass fraction.
Surfactant in the present embodiment is alkanolamide, fatty alcohol polyoxyethylene ether and neopelex,
According to weight ratio 2:1:The mixture of 1 composition.
Stearate in the present embodiment is zinc stearate, magnesium stearate, calcium stearate according to weight ratio 3:1:1 composition
Mixture；
The antirust emulsion is vinylacetate, acrylic acid accounts for, n-BMA, epoxy resin are according to weight ratio 2:3:
1:The mixture of 4 compositions.
Environmentally friendly organic solvent in the present embodiment is dimethyl ether, ethyl alcohol, isoamyl alcohol according to weight ratio 5:2:1 group
At mixture.
Corrosion inhibiter in the present embodiment is methenamine, tungstates, lignosulfonate, cetylamine according to weight ratio 3:1:
2:The mixture of 4 compositions.
Nanometer additive in the present embodiment is nano zine oxide, nano-titanium dioxide, nano ceramics micro mist according to weight
Than 2:1:The mixture of 1 composition；
The rare earth oxide is the mixture of one or more of lanthanum, cerium, praseodymium, neodymium oxides.
A kind of preparation method of environment-friendly high-efficiency compounding antirust rust remover of the present embodiment, includes the following steps：
Step 1 weighs each component raw material as required；
Step 2, will compound acid solution, graphene, rare earth oxide, nanometer additive mix be added it is anti-with blender
It answers in kettle, is stirred 30 minutes at being 45 DEG C in temperature, speed of agitator 300r/min obtains mixture A；
Antirust emulsion is mixed environmentally friendly organic solvent and is sent into reaction kettle by step 3, and stirring and dissolving is reacted at being 60 DEG C in temperature
20 minutes, surfactant, stearate, corrosion inhibiter, polyethylene glycol, sodium tripolyphosphate, hexa are added, is continued
Stirring 20 minutes, speed of agitator 700r/min obtains mixture B；
Mixture B prepared by step 4, mixture A prepared by step 2 and step 3 is added in homogenizer, is 55 in temperature
DEG C, homogenization pressure 14MPa, speed of agitator be homogeneous 9 minutes under 8000 r/min, it is cooling canned to obtain the environmental protection of the present invention
Highly efficiency compositional antirust rust remover.
Embodiment 3.
A kind of environment-friendly high-efficiency of the present embodiment compounds antirust rust remover, includes the raw material of following parts by weight：
Compound 25 parts of acid solution, 4 parts of surfactant, 2 parts of stearate, environmentally friendly 35 parts of organic solvent, 1.5 parts of corrosion inhibiter,
2 parts of polyethylene glycol, 9 parts of antirust emulsion, 1.5 parts of sodium tripolyphosphate, 4 parts of nanometer additive, 2 parts of graphene, rare earth oxide 3
Part, 1.5 parts of hexa.
Compounding acid solution in the present embodiment be by acetic acid, tartaric acid, coco-nut oil fatty acid, oxalic acid, salicylic acid according to
Weight ratio 2:1:1:2:1 mixing is added to the water, the solution that proportioning is 30% at mass fraction.
Surfactant in the present embodiment is alkanolamide, fatty alcohol polyoxyethylene ether and neopelex,
According to weight ratio 2:1:The mixture of 1 composition.
Stearate in the present embodiment is zinc stearate, magnesium stearate, calcium stearate according to weight ratio 3:1:1 composition
Mixture；
The antirust emulsion is vinylacetate, acrylic acid accounts for, n-BMA, epoxy resin are according to weight ratio 2:3:
1:The mixture of 4 compositions.
Environmentally friendly organic solvent in the present embodiment is dimethyl ether, ethyl alcohol, isoamyl alcohol according to weight ratio 5:2:1 group
At mixture.
Corrosion inhibiter in the present embodiment is methenamine, tungstates, lignosulfonate, cetylamine according to weight ratio 3:1:
2:The mixture of 4 compositions.
Nanometer additive in the present embodiment is nano zine oxide, nano-titanium dioxide, nano ceramics micro mist according to weight
Than 2:1:The mixture of 1 composition；
The rare earth oxide is the mixture of one or more of lanthanum, cerium, praseodymium, neodymium oxides.
A kind of preparation method of environment-friendly high-efficiency compounding antirust rust remover of the present embodiment, includes the following steps：
Step 1 weighs each component raw material as required；
Step 2, will compound acid solution, graphene, rare earth oxide, nanometer additive mix be added it is anti-with blender
It answers in kettle, is stirred 25 minutes at being 40 DEG C in temperature, speed of agitator 250r/min obtains mixture A；
Antirust emulsion is mixed environmentally friendly organic solvent and is sent into reaction kettle by step 3, and stirring and dissolving is reacted at being 55 DEG C in temperature
15 minutes, surfactant, stearate, corrosion inhibiter, polyethylene glycol, sodium tripolyphosphate, hexa are added, is continued
Stirring 15 minutes, speed of agitator 650r/min obtains mixture B；
Mixture B prepared by step 4, mixture A prepared by step 2 and step 3 is added in homogenizer, is 50 in temperature
DEG C, homogenization pressure 12MPa, speed of agitator be homogeneous 8 minutes under 7500r/min, the cooling canned environmental protection for obtaining the present invention is high
Effect compounding antirust rust remover.
A kind of environment-friendly high-efficiency compounding antirust rust remover composition stability of the present invention is preferable, can effectively remove metal watch
Face rust staining, while layer protecting film can also be formed in metal surface, it prevents metal from being aoxidized again in a short time, realizes and remove
Rust, antirust are once completed, and product is nontoxic, will not generate pollution to environment；Simultaneously the present invention preparation method, material at
This relatively low, raw material is easy to get and technique is concise, has higher practical value and good application prospect.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Profit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent requirements of the claims
Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiment being appreciated that.
Claims (10)
1. a kind of environment-friendly high-efficiency compounds antirust rust remover, which is characterized in that include the raw material of following parts by weight：
It compounds 20-30 parts of acid solution, 3-5 parts of surfactant, 1-3 parts of stearate, environmentally friendly 30-40 parts of organic solvent, delay
Lose 1-2 parts of agent, 1-3 parts of polyethylene glycol, 7-11 parts of antirust emulsion, 1-2 parts of sodium tripolyphosphate, 3-5 parts of nanometer additive, graphene
1-3 parts, 2-4 parts of rare earth oxide, 1-2 parts of hexa.
2. a kind of environment-friendly high-efficiency according to claim 1 compounds antirust rust remover, which is characterized in that the environment-friendly high-efficiency is multiple
Include the raw material of following parts by weight with antirust rust remover：
Compound 25 parts of acid solution, 4 parts of surfactant, 2 parts of stearate, environmentally friendly 35 parts of organic solvent, 1.5 parts of corrosion inhibiter,
2 parts of polyethylene glycol, 9 parts of antirust emulsion, 1.5 parts of sodium tripolyphosphate, 4 parts of nanometer additive, 2 parts of graphene, rare earth oxide 3
Part, 1.5 parts of hexa.
3. a kind of environment-friendly high-efficiency according to claim 1 or 2 compounds antirust rust remover, which is characterized in that the compounding acid
Property solution be by acetic acid, tartaric acid, coco-nut oil fatty acid, oxalic acid, salicylic acid according to weight ratio 2:1:1:2:Water is added in 1 mixing
In, proportioning is at the solution that mass fraction is 25-35%.
4. a kind of environment-friendly high-efficiency according to claim 1 or 2 compounds antirust rust remover, which is characterized in that live on the surface
Property agent be alkanolamide, fatty alcohol polyoxyethylene ether and neopelex, according to weight ratio 2:1:The mixing of 1 composition
Object.
5. a kind of environment-friendly high-efficiency according to claim 1 or 2 compounds antirust rust remover, which is characterized in that the stearic acid
Salt is zinc stearate, magnesium stearate, calcium stearate according to weight ratio 3:1:The mixture of 1 composition；
The antirust emulsion is vinylacetate, acrylic acid accounts for, n-BMA, epoxy resin are according to weight ratio 2:3:
1:The mixture of 4 compositions.
6. a kind of environment-friendly high-efficiency according to claim 1 or 2 compounds antirust rust remover, which is characterized in that the environmental protection has
Solvent is dimethyl ether, ethyl alcohol, isoamyl alcohol according to weight ratio 5:2:The mixture of 1 composition.
7. a kind of environment-friendly high-efficiency according to claim 1 or 2 compounds antirust rust remover, which is characterized in that the corrosion inhibiter
It is methenamine, tungstates, lignosulfonate, cetylamine according to weight ratio 3:1:2:The mixture of 4 compositions.
8. a kind of environment-friendly high-efficiency according to claim 1 or 2 compounds antirust rust remover, which is characterized in that the nanometer adds
Add that object is nano zine oxide, nano-titanium dioxide, nano ceramics micro mist is according to weight ratio 2:1:The mixture of 1 composition；
The rare earth oxide is the mixture of one or more of lanthanum, cerium, praseodymium, neodymium oxides.
9. a kind of method preparing environment-friendly high-efficiency compounding antirust rust remover as claimed in claim 1 or 2, which is characterized in that packet
Include following steps：
Step 1 weighs each component raw material as required；
Step 2, will compound acid solution, graphene, rare earth oxide, nanometer additive mix be added it is anti-with blender
It answers in kettle, is stirred 20-30 minutes at being 35-45 DEG C in temperature, speed of agitator 200-300r/min obtains mixture A；
Antirust emulsion is mixed environmentally friendly organic solvent and is sent into reaction kettle by step 3, and stirring and dissolving is anti-at being 50-60 DEG C in temperature
It answers 10-20 minutes, adds surfactant, stearate, corrosion inhibiter, polyethylene glycol, sodium tripolyphosphate, hexa-methylene four
Amine continues stirring 10-20 minutes, and speed of agitator 600-700r/min obtains mixture B；
Mixture B prepared by step 4, mixture A prepared by step 2 and step 3 is added in homogenizer, is 45- in temperature
55 DEG C, homogenization pressure 10-14MPa, speed of agitator be homogeneous 7-9 minutes under 7000-8000 r/min, it is cooling canned to obtain
The environment-friendly high-efficiency of the present invention compounds antirust rust remover.
10. a kind of preparation method of environment-friendly high-efficiency compounding antirust rust remover according to claim 9, which is characterized in that institute
Stating preparation process is：
Step 1 weighs each component raw material as required；
Step 2, will compound acid solution, graphene, rare earth oxide, nanometer additive mix be added it is anti-with blender
It answers in kettle, is stirred 25 minutes at being 40 DEG C in temperature, speed of agitator 250r/min obtains mixture A；
Antirust emulsion is mixed environmentally friendly organic solvent and is sent into reaction kettle by step 3, and stirring and dissolving is reacted at being 55 DEG C in temperature
15 minutes, surfactant, stearate, corrosion inhibiter, polyethylene glycol, sodium tripolyphosphate, hexa are added, is continued
Stirring 15 minutes, speed of agitator 650r/min obtains mixture B；
Mixture B prepared by step 4, mixture A prepared by step 2 and step 3 is added in homogenizer, is 50 in temperature
DEG C, homogenization pressure 12MPa, speed of agitator be homogeneous 8 minutes under 7500r/min, the cooling canned environmental protection for obtaining the present invention is high
Effect compounding antirust rust remover.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109574262A (en) * | 2019-01-02 | 2019-04-05 | 深圳中天烯源科技有限公司 | Carbene environment-friendly type descaling and derusting anticorrosion antirust liquid and its preparation method and application |
| CN110284143A (en) * | 2019-08-14 | 2019-09-27 | 重庆市联坤科技开发有限责任公司 | A kind of metal cleaner |
| BE1028533B1 (en) * | 2020-08-24 | 2022-09-08 | Chaohu Guoli Hangbiao Equipment Co Ltd | METHOD OF IMPROVING THE CORROSION RESISTANCE OF A NAVIGATION FLOAT LAMP HOLDER |
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| CN104313606A (en) * | 2014-10-08 | 2015-01-28 | 安徽奥丰汽车配件有限公司 | Cleaning solution for metal surface oil and rust removal |
| CN107447222A (en) * | 2016-05-31 | 2017-12-08 | 皮方艳 | A kind of metal antirusting agent |
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| CN109574262A (en) * | 2019-01-02 | 2019-04-05 | 深圳中天烯源科技有限公司 | Carbene environment-friendly type descaling and derusting anticorrosion antirust liquid and its preparation method and application |
| CN110284143A (en) * | 2019-08-14 | 2019-09-27 | 重庆市联坤科技开发有限责任公司 | A kind of metal cleaner |
| BE1028533B1 (en) * | 2020-08-24 | 2022-09-08 | Chaohu Guoli Hangbiao Equipment Co Ltd | METHOD OF IMPROVING THE CORROSION RESISTANCE OF A NAVIGATION FLOAT LAMP HOLDER |
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Application publication date: 20180814 |