CN106048630A - Strong water-based metal surface oil contamination cleaning agent and preparing method thereof - Google Patents
Strong water-based metal surface oil contamination cleaning agent and preparing method thereof Download PDFInfo
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- CN106048630A CN106048630A CN201610530452.XA CN201610530452A CN106048630A CN 106048630 A CN106048630 A CN 106048630A CN 201610530452 A CN201610530452 A CN 201610530452A CN 106048630 A CN106048630 A CN 106048630A
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- metal surface
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- greasy dirt
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/14—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
The invention discloses a strong water-based metal surface oil contamination cleaning agent and a preparing method thereof, and relates to the technical field of metal surface treatment. The cleaning agent is composed of, by weight, 2-4 parts of polyoxyethylene cetyl ether, 0.5-1 part of modified sodium lignosulfonate, 2-4 parts of sodium citrate, 1-4 parts of EDTA tetrasodium, 3-6 parts of sodium metasilicate, 4-7 parts of carboxymethyl cellulose, 3-6 parts of ethylene glycol, 1-3 parts of sodium hydroxide and 40-50 parts of deionized water. The cleaning agent is fewer in foam, high in dispersion force and high in cleaning and oil contamination removing capacity, has a good dissolution effect on flora and fauna grease and mineral grease, can effectively remove oil contamination on the metal surface, is low in cleaning temperature and easy to wash, enables the metal surface to be bright, cannot corrode metal, is safe and environment-friendly, and cannot harm the health of an operator.
Description
Technical field
The present invention relates to field of metal surface treatment technology, be specifically related to a kind of powerful water-base metal surface greasy dirt abluent
And preparation method thereof.
Background technology
Metal material and workpiece are in process of manufacture, and its surface is easily adhered the materials such as greasy dirt and is likely to occur
Corrosion.In order to meet the requirement of the processing technique of metal material and workpiece, it is ensured that the quality of metallic article, the life-span of use and
The reliability of performance, needs before and after intermetallic composite coating and finished product assembles or packs at advance row metal surface degreasing, scale removal
Reason.The most traditional mode is to use diesel oil, coal Water Oil Or Gas as cleanout fluid to clean metal material and workpiece, and this is the most unrestrained
Take the energy, and there is potential unsafe factor, it is possible to lead to fire.In recent years, metal cleaner has gradually obtained extensively
General application, it diesel oil substitute, kerosene and gasoline can clean part well.The metal cleaner commonly used at present is still
There are some problems: cleansing power is limited, it is impossible to disposably effectively removing dirt, rust staining, scavenging period is long, and production efficiency is low,
Corrosivity is relatively strong, and the waste liquid after cleaning is toxic to human body, pollutes environment etc..
Summary of the invention
For the deficiencies in the prior art, the invention provides a kind of metal surface cleaning agent, degreasing result is good, and performance is steady
Fixed, corrosion-free to metal.
For realizing object above, the present invention is achieved by the following technical programs:
A kind of powerful water-base metal surface greasy dirt abluent, is made up of the raw material of following weight portion: polyoxyethylene cetyl
Base ether 2-4 part, modified sodium lignosulfonate 0.5-1 part, sodium citrate 2-4 part, EDTA tetra-sodium 1-4 part, sodium metasilicate 3-6 part,
Carboxymethyl cellulose 4-7 part, ethylene glycol 3-6 part, sodium hydroxide 1-3 part, deionized water 40-50 part.
Preferably, described powerful water-base metal surface greasy dirt abluent, it is made up of the raw material of following weight portion: polyoxy second
Alkene cetyl ether 3 parts, modified sodium lignosulfonate 0.7 part, sodium citrate 3 parts, 3 parts of EDTA tetra-sodium, sodium metasilicate 5 parts, carboxylic
Methylcellulose 6 parts, ethylene glycol 5 parts, sodium hydroxide 1.5 parts, deionized water 45 parts.
Preferably, described modified sodium lignosulfonate is crotonamide modified sodium lignosulfonate.
The preparation method of powerful water-base metal surface greasy dirt abluent, step is as follows: by polyoxyethylene cetyl under room temperature
Base ether and carboxymethyl cellulose are added to the water under agitation, sequentially add sodium citrate, EDTA tetra-sodium, metasilicic acid
Sodium, ethylene glycol, stir 5 minutes, adds NaOH and regulates pH to 8-10, stirs 5 minutes, be eventually adding modified sodium lignosulfonate,
Strong stirring is uniform, obtains powerful water-base metal surface greasy dirt abluent.
The method have the benefit that in the present invention, Polyoxyethylene cetyl ether has good moistening, emulsifying and dispersion energy
Power, and modified sodium lignosulfonate synergism, have good dissolution, second two to animal and plant fat and mineral oils and fats
Alcohol can strengthen the abluent solvability to oils and fats, and abluent foam of the present invention is few, dispersion force strong, and cleaning degreasing power is strong,
Can effectively take out metal surface greasy dirt and rust staining, cleaning temperature is low, easily rinses, and makes metal surface light, and does not corrode metal,
Safety and environmental protection, does not endanger the health of operator.
Detailed description of the invention
For making the purpose of the embodiment of the present invention, technical scheme and advantage clearer, below in conjunction with the embodiment of the present invention,
Technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is the present invention one
Divide embodiment rather than whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art are not making
The every other embodiment obtained under creative work premise, broadly falls into the scope of protection of the invention.
Embodiment 1:
A kind of powerful water-base metal surface greasy dirt abluent, is made up of the raw material of following weight portion: polyoxyethylene cetyl
3 parts of base ether, crotonamide modified sodium lignosulfonate 0.7 part, sodium citrate 3 parts, 3 parts of EDTA tetra-sodium, sodium metasilicate 5 parts, carboxylic
Methylcellulose 6 parts, ethylene glycol 5 parts, sodium hydroxide 1.5 parts, deionized water 45 parts.
The preparation method of powerful water-base metal surface greasy dirt abluent, step is as follows: by polyoxyethylene cetyl under room temperature
Base ether and carboxymethyl cellulose are added to the water under agitation, sequentially add sodium citrate, EDTA tetra-sodium, metasilicic acid
Sodium, ethylene glycol, stir 5 minutes, adds NaOH and regulates pH to 9, stirs 5 minutes, be eventually adding crotonamide modified lignin resin sulphur
Acid sodium, strong stirring is uniform, obtains powerful water-base metal surface greasy dirt abluent.
Embodiment 2:
A kind of powerful water-base metal surface greasy dirt abluent, is made up of the raw material of following weight portion: polyoxyethylene cetyl
2 parts of base ether, crotonamide modified sodium lignosulfonate 1 part, sodium citrate 2 parts, 4 parts of EDTA tetra-sodium, sodium metasilicate 3 parts, carboxylic first
Base cellulose 7 parts, ethylene glycol 3 parts, sodium hydroxide 3 parts, deionized water 40 parts.
The preparation method of powerful water-base metal surface greasy dirt abluent, step is as follows: by polyoxyethylene cetyl under room temperature
Base ether and carboxymethyl cellulose are added to the water under agitation, sequentially add sodium citrate, EDTA tetra-sodium, metasilicic acid
Sodium, ethylene glycol, stir 5 minutes, stirs 5 minutes, is eventually adding crotonamide modified sodium lignosulfonate, and strong stirring is uniform,
Obtain powerful water-base metal surface greasy dirt abluent.
Embodiment 3:
A kind of powerful water-base metal surface greasy dirt abluent, is made up of the raw material of following weight portion: polyoxyethylene cetyl
4 parts of base ether, crotonamide modified sodium lignosulfonate 0.5 part, sodium citrate 4 parts, 1 part of EDTA tetra-sodium, sodium metasilicate 6 parts, carboxylic
Methylcellulose 4 parts, ethylene glycol 6 parts, sodium hydroxide 1 part, deionized water 50 parts.
The preparation method of powerful water-base metal surface greasy dirt abluent, step is as follows: by polyoxyethylene cetyl under room temperature
Base ether and hydroxymethyl cellulose are added to the water under agitation, sequentially add sodium citrate, EDTA tetra-sodium, metasilicic acid
Sodium, ethylene glycol, stir 5 minutes, stirs 5 minutes, is eventually adding crotonamide modified sodium lignosulfonate, and strong stirring is uniform,
Obtain powerful water-base metal surface greasy dirt abluent.
Embodiment 4:
A kind of powerful water-base metal surface greasy dirt abluent, is made up of the raw material of following weight portion: polyoxyethylene cetyl
3 parts of base ether, crotonamide modified sodium lignosulfonate 1 part, sodium citrate 2 parts, 3 parts of EDTA tetra-sodium, sodium metasilicate 4 parts, carboxylic first
Base cellulose 5 parts, ethylene glycol 4 parts, sodium hydroxide 2 parts, deionized water 48 parts.
The preparation method of powerful water-base metal surface greasy dirt abluent, step is as follows: by polyoxyethylene cetyl under room temperature
Base ether and carboxymethyl cellulose are added to the water under agitation, sequentially add sodium citrate, EDTA tetra-sodium, metasilicic acid
Sodium, ethylene glycol, stir 5 minutes, stirs 5 minutes, is eventually adding crotonamide modified sodium lignosulfonate, and strong stirring is uniform,
Obtain powerful water-base metal surface greasy dirt abluent.
To sum up, the embodiment of the present invention has the advantages that in the present invention, abluent foam is few, dispersion force strong, cleaning
Degreasing power is strong, and animal and plant fat and mineral oils and fats are had good dissolution, it is possible to effectively remove metal surface oil
Dirt, cleaning temperature is low, easily rinses, and makes metal surface light, and does not corrode metal, and safety and environmental protection does not endanger the health of operator.
It should be noted that in this article, the relational terms of such as first and second or the like is used merely to a reality
Body or operation separate with another entity or operating space, and deposit between not necessarily requiring or imply these entities or operating
Relation or order in any this reality.And, term " includes ", " comprising " or its any other variant are intended to
Comprising of nonexcludability, so that include that the process of a series of key element, method, article or equipment not only include that those are wanted
Element, but also include other key elements being not expressly set out, or also include for this process, method, article or equipment
Intrinsic key element.In the case of there is no more restriction, statement " including ... " key element limited, it is not excluded that
Including process, method, article or the equipment of described key element there is also other identical element.
Above example only in order to technical scheme to be described, is not intended to limit;Although with reference to previous embodiment
The present invention is described in detail, it will be understood by those within the art that: it still can be to aforementioned each enforcement
Technical scheme described in example is modified, or wherein portion of techniques feature is carried out equivalent;And these amendment or
Replace, do not make the essence of appropriate technical solution depart from the spirit and scope of various embodiments of the present invention technical scheme.
Claims (4)
1. a powerful water-base metal surface greasy dirt abluent, it is characterised in that be made up of the raw material of following weight portion: polyoxy second
Alkene cetyl ether 2-4 part, modified sodium lignosulfonate 0.5-1 part, sodium citrate 2-4 part, EDTA tetra-sodium 1-4 part, metasilicic acid
Sodium 3-6 part, carboxymethyl cellulose 4-7 part, ethylene glycol 3-6 part, sodium hydroxide 1-3 part, deionized water 40-50 part.
2. powerful water-base metal surface greasy dirt abluent as claimed in claim 1, it is characterised in that former by following weight portion
Material composition: Polyoxyethylene cetyl ether 3 parts, modified sodium lignosulfonate 0.7 part, sodium citrate 3 parts, 3 parts of EDTA tetra-sodium, partially
Sodium silicate 5 parts, carboxymethyl cellulose 6 parts, ethylene glycol 5 parts, sodium hydroxide 1.5 parts, deionized water 45 parts.
3. powerful water-base metal surface greasy dirt abluent as claimed in claim 2, it is characterised in that described modified lignin resin sulphur
Acid sodium is crotonamide modified sodium lignosulfonate.
4. a preparation method for the powerful water-base metal surface greasy dirt abluent as described in claim 1-3 is arbitrary, its feature
Being, step is as follows: Polyoxyethylene cetyl ether and carboxymethyl cellulose are added to the water under agitation under room temperature,
Sequentially add sodium citrate, EDTA tetra-sodium, sodium metasilicate, ethylene glycol, stir 5 minutes, add NaOH and regulate pH to 8-10, stir
Mixing 5 minutes, be eventually adding modified sodium lignosulfonate, strong stirring is uniform, obtains powerful water-base metal surface greasy dirt abluent.
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108018131A (en) * | 2017-12-15 | 2018-05-11 | 芜湖衣码通信息科技有限公司 | Quick Response Code braider spends greasy dirt detergent and preparation method thereof |
CN108359535A (en) * | 2018-02-23 | 2018-08-03 | 甘肃添彩纸品包装科技开发有限公司 | A kind of processing method of surface and oil contaminant strength remover |
CN112064045A (en) * | 2020-09-14 | 2020-12-11 | 苏州鸿宇工业清洗技术有限公司 | Copper alkaline bright cleaning agent and preparation method thereof |
CN112981423A (en) * | 2019-12-02 | 2021-06-18 | 娄底市鼎宏自动化科技有限公司 | Surface oil stain treatment agent for mining machinery |
CN115852381A (en) * | 2022-10-19 | 2023-03-28 | 广州市联诺化工科技有限公司 | High-pressure spray cleaning agent for automatic line spraying and preparation method thereof |
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CN101407916A (en) * | 2008-11-13 | 2009-04-15 | 常熟华冶薄板有限公司 | Low-alkali non-phosphate degreasing agent |
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JP2008214459A (en) * | 2007-03-02 | 2008-09-18 | Kao Corp | Method for cleaning hard surface |
CN101407916A (en) * | 2008-11-13 | 2009-04-15 | 常熟华冶薄板有限公司 | Low-alkali non-phosphate degreasing agent |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108018131A (en) * | 2017-12-15 | 2018-05-11 | 芜湖衣码通信息科技有限公司 | Quick Response Code braider spends greasy dirt detergent and preparation method thereof |
CN108359535A (en) * | 2018-02-23 | 2018-08-03 | 甘肃添彩纸品包装科技开发有限公司 | A kind of processing method of surface and oil contaminant strength remover |
CN112981423A (en) * | 2019-12-02 | 2021-06-18 | 娄底市鼎宏自动化科技有限公司 | Surface oil stain treatment agent for mining machinery |
CN112064045A (en) * | 2020-09-14 | 2020-12-11 | 苏州鸿宇工业清洗技术有限公司 | Copper alkaline bright cleaning agent and preparation method thereof |
CN115852381A (en) * | 2022-10-19 | 2023-03-28 | 广州市联诺化工科技有限公司 | High-pressure spray cleaning agent for automatic line spraying and preparation method thereof |
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Application publication date: 20161026 |