CN103849509A - Glass cleaning agent and preparation method thereof - Google Patents
Glass cleaning agent and preparation method thereof Download PDFInfo
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- CN103849509A CN103849509A CN201210555158.6A CN201210555158A CN103849509A CN 103849509 A CN103849509 A CN 103849509A CN 201210555158 A CN201210555158 A CN 201210555158A CN 103849509 A CN103849509 A CN 103849509A
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- glass cleaner
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- diethylene glycol
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Abstract
The invention relates to a glass cleaning agent. The glass cleaning agent comprises 0.05-10wt% of diethylene glycol, 1-30wt% of monohydric alcohols, 0.1-5wt% of anionic surfactants, 0.05-5wt% of nonionic surfactants, 0.05-5wt% of ampholytic surfactants, 0.1-5wt% of weak base, 0.01-5wt% of essence, 0.01-3wt% of coloring agent and the balance of softened water. The glass cleaning agent has the functions of effectively cleaning stains on the surface of glass and preventing freezing and fog and the like, is environment-friendly and non-toxic, and does not corrode the surface of glass.
Description
Technical field
The present invention relates to a kind of glass cleaner that dirt can effectively be removed and prevent dust, leave no trace, keep glass transparent light.
Background technology
That glass has is smooth, transparent, the advantage such as hardness is high, reasonable price and being widely used on the door and window such as buildings and automobile.But glass surface is easily polluted by the dust of air, oil-containing impurity, has not only affected transparency and aesthetic, also may cause traffic accident because affecting sight line.Therefore, keep glass surface cleaning significant.The structure of glass, glass contains a large amount of silicon-dioxide, is easily corroded by highly basic or organic solvent, causes surface irregularity.And the flying dust of glass surface, oil stain, animal excrements are difficult to clean up with traditional suds.Glass cleaner kind on market is many, some use P contained compounds; Some use weak acid, to other structure generation corrosion; After some cleanings, contamination resistance is not strong.But a technical barrier of existing glass cleaner is glass cleaner in use easily forms new wire, the netted vestige of strip, has had a strong impact on the attractive in appearance and transparency of glass.To this, company has carried out a large amount of research both at home and abroad, uses different nonvolatile organic solvents in glass surface film forming, prevents the appearance of vestige; Use polymer if polyacrylic or poly-epoxy ethanol are as membrane-forming agent.But effect is not very desirable.
Therefore,, in the urgent need to developing a kind of highly-efficient glass clean-out system, after use, do not stay any vestige.
Summary of the invention
The object of the present invention is to provide a kind of novel glass cleaner, it can remove the dirt of glass surface quickly and efficiently, prevent that glass surface from leaving a trace, and give the anti-pollution again of glass surface, quick-drying, short-term antifog, the hydrophilic and performance such as leave no trace, and nontoxic, environmental protection.
Inventor is through further investigation, obtain a kind of glass cleaner, it is made up of diethylene glycol ether, monohydroxy-alcohol, anion surfactant, nonionogenic tenside, amphoterics, weak base, essence, tinting material and softening water, and wherein in this glass cleaner, the content of each component is as follows:
The diethylene glycol ether using in glass cleaner of the present invention can be by following chemical formulation:
Wherein, R
1for hydrogen base, methyl, ethyl or butyl, R
2for methyl, ethyl or butyl; R
1preferably hydrogen base, R
2preferably butyl.
That the diethylene glycol ether using in glass cleaner of the present invention has is lasting, high-efficient cleaning is except effect of glass surface oily pollutant; it is preferably diethylene glycol monobutyl ether; this is because diethylene glycol monobutyl ether not only has effect lasting, that high-efficient cleaning removes glass surface oily pollutant; and its viscosity is larger; volatility is little; can stop the long period and strengthen clean effect at glass surface, and protective glass surface.The consumption of above-mentioned diethylene glycol ether in glass cleaner is preferably 0.05～10 % by weight.
The monohydroxy-alcohol using in glass cleaner of the present invention can be one or more among methyl alcohol, ethanol, Virahol, butanols, octanol and tridecyl alcohol, wherein preferred Virahol, this is because the toxicity of Virahol is little, volatilization is slow, soil removability is strong.The consumption of above-mentioned monohydroxy-alcohol in glass cleaner is preferably 1～30 % by weight.
The anion surfactant using in glass cleaner of the present invention can be one or more among sodium laurylsulfonate, Sodium dodecylbenzene sulfonate, sodium cetanesulfonate, oily acyloxy ethyl sulfonic acid sodium, Aerosol OT and Seconary Alkane Sulphonate Sodium, wherein preferred Seconary Alkane Sulphonate Sodium, this is because Seconary Alkane Sulphonate Sodium has good decontamination, foaming, dispersion, emulsification, the characteristic such as wetting.The consumption of above-mentioned anion surfactant in glass cleaner is preferably 0.1～5 % by weight.
The nonionogenic tenside using in glass cleaner of the present invention can be alkylphenol polyvingl ether, fatty alcohol-polyoxyethylene ether, cithrol, one or more among polyoxyethylene groups alkyl ammonia and fatty acid loss water sorbit ester, wherein preferred fat polyoxyethylenated alcohol, this is because the stability of fatty alcohol-polyoxyethylene ether is high, be not subject to the impact that strong electrolyte exists, be not subject to acid yet, the impact of alkali, can mix use with other type list surface-active agent, consistency is good, in all kinds of SOLVENTS, all there is good solubility, on solid surface, there is not strong adsorption.The consumption of above-mentioned nonionogenic tenside in glass cleaner is preferably 0.05～5 % by weight.
The amphoterics using in glass cleaner of the present invention can be dodecyl oxyethyl group sultaine, dodecyl hydroxypropyl sultaine, dodecyl azochlorosulfonate propyl lycine, myristamide propyl group hydroxypropyl sultaine, decyl hydroxypropyl sultaine, tetradecyl dihydroxy ethyl amine oxide, octadecyl dihydroxy ethyl amine oxide, one or more among the oxidation of stearylamide propyl group and lauroylamidopropyl betaine, wherein preferred lauroylamidopropyl betaine, this is because lauroylamidopropyl betaine has good performance and extremely low pungency, can be extensively and positively charged ion, negatively charged ion, nonionogenic tenside compatibility, there is desirable washing, conditioning, antistatic and germicidal action, there is good flexibility, to skin action temperature and, foam enriches and stablizes, and there is good viscosity adjustment effect.It is 0.05～5 % by weight that the consumption of above-mentioned amphoterics in glass cleaner is preferably preferable amount.
The weak base using in glass cleaner of the present invention can be ammoniacal liquor or thanomin, is preferably ammoniacal liquor, and this is because the potential of hydrogen that ammoniacal liquor can be removed spot and regulate glass cleaner makes it be alkalescence and the soil removability of raising glass cleaner.The consumption of above-mentioned weak base in glass cleaner is preferably 0.1～5 % by weight.
The essence using in glass cleaner of the present invention and tinting material as long as conventional those in this area just, there is no particular limitation.
The preparation method of glass cleaner of the present invention comprises the steps: according to the content of the each component stipulating in described glass cleaner, softening water, diethylene glycol ether and monohydroxy-alcohol are joined in reactor, within the scope of 5 ℃～60 ℃, stir after 5～30 minutes, add successively again anion surfactant, nonionogenic tenside, amphoterics, weak base, essence and tinting material, stir 10～30 minutes to dissolving completely.
The tensio-active agent containing in glass cleaner of the present invention has the effects such as infiltration, infiltration, and can remove well spot.The existence of monohydroxy-alcohol and these organic solvents of diethylene glycol ether, can significantly reduce the freezing point of liquid, thereby play antifreeze effect, prevents the negative impact of low temperature to cleaning performance.Diethylene glycol ether can form layer protective layer at glass surface, prevents that water vapour from forming droplet, guarantees glass transparent.The synergy of three kinds of tensio-active agents, has significantly improved the soil removability of glass cleaner, and can form uniform film at glass surface, prevent wire, strip or netted vestige, thereby it is bright and clean without vestige to make to wash rear glass surface.
Therefore, glass cleaner of the present invention can effectively be removed dirt and the oil stain of glass surface, and other structures are not had to corrosive nature.
Embodiment
Below, based on embodiment, the present invention is specifically described, but these embodiment are illustration of the present invention, the present invention is not limited to these embodiment.
Respectively according to the each component shown in table 1 and table 2 and content thereof, softening water, diethylene glycol ether and monohydroxy-alcohol are joined in reactor, within the scope of 5 ℃～60 ℃, stir after 5～30 minutes, add successively again anion surfactant, nonionogenic tenside, amphoterics, weak base, essence and tinting material, stir 10～30 minutes to dissolving completely, make thus the glass cleaner of embodiment 1～6 and embodiment 7～12.
Table 1
The glass cleaner of embodiment 1～6 gained is as clear as crystal, no suspended substance, and there is light fragrance.
The salad oil that takes a morsel, is evenly coated in glass surface with slide glass, then cleans glass with above-mentioned glass cleaner, found that, cleaning performance is remarkable, and glass surface is residual without greasy dirt.
To above-mentioned glass cleaner measuring stability 1 month at 4 ℃, 35 ℃ respectively, result glass cleaner is without precipitation or metachromatism.
Table 2
The glass cleaner of embodiment 7～12 gained is as clear as crystal, no suspended substance, and there is light fragrance.The salad oil that takes a morsel, is evenly coated in glass surface with slide glass, then cleans glass with above-mentioned glass cleaner, found that, glass surface is cleaned totally, only has superfine little thread or short-term vestige.
Industrial applicibility
Glass cleaner of the present invention can effectively be removed dirt and the oil stain of glass surface, and other structures are not had to corrosive nature.
Claims (10)
1. a glass cleaner, it is made up of diethylene glycol ether, monohydroxy-alcohol, anion surfactant, nonionogenic tenside, amphoterics, weak base, essence, tinting material and softening water, and wherein in this glass cleaner, the content of each component is as follows:
2. glass cleaner according to claim 1, wherein, described diethylene glycol ether is by following chemical formulation:
Wherein R
1for hydrogen base, methyl, ethyl or butyl, R
2for methyl, ethyl or butyl.
3. glass cleaner according to claim 1 and 2, wherein, described diethylene glycol ether is diethylene glycol monobutyl ether.
4. glass cleaner according to claim 1 and 2, wherein, described monohydroxy-alcohol is one or more among methyl alcohol, ethanol, Virahol, butanols, octanol and tridecyl alcohol.
5. glass cleaner according to claim 1 and 2, wherein, described monohydroxy-alcohol is Virahol.
6. glass cleaner according to claim 1 and 2, wherein, described anion surfactant is one or more among sodium laurylsulfonate, Sodium dodecylbenzene sulfonate, sodium cetanesulfonate, oily acyloxy ethyl sulfonic acid sodium, Aerosol OT and Seconary Alkane Sulphonate Sodium.
7. glass cleaner according to claim 1 and 2, wherein, described nonionogenic tenside is one or more among alkylphenol polyvingl ether, fatty alcohol-polyoxyethylene ether, cithrol, polyoxyethylene groups alkyl ammonia and fatty acid loss water sorbit ester.
8. glass cleaner according to claim 1 and 2, wherein, described amphoterics is one or more among dodecyl oxyethyl group sultaine, dodecyl hydroxypropyl sultaine, dodecyl azochlorosulfonate propyl lycine, myristamide propyl group hydroxypropyl sultaine, decyl hydroxypropyl sultaine, tetradecyl dihydroxy ethyl amine oxide, octadecyl dihydroxy ethyl amine oxide, the oxidation of stearylamide propyl group and lauroylamidopropyl betaine.
9. glass cleaner according to claim 1 and 2, wherein, described weak base is ammoniacal liquor or thanomin.
10. the preparation method of the glass cleaner described in claim 1～9 any one, it comprises the steps: according to the content of the each component stipulating in described glass cleaner, softening water, diethylene glycol ether and monohydroxy-alcohol are joined in reactor, within the scope of 5 ℃～60 ℃, stir after 5～30 minutes, add successively again anion surfactant, nonionogenic tenside, amphoterics, weak base, essence and tinting material, stir 10～30 minutes to dissolving completely.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210555158.6A CN103849509A (en) | 2012-12-06 | 2012-12-06 | Glass cleaning agent and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210555158.6A CN103849509A (en) | 2012-12-06 | 2012-12-06 | Glass cleaning agent and preparation method thereof |
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| CN103849509A true CN103849509A (en) | 2014-06-11 |
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| CN201210555158.6A Pending CN103849509A (en) | 2012-12-06 | 2012-12-06 | Glass cleaning agent and preparation method thereof |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104152290A (en) * | 2014-08-01 | 2014-11-19 | 无棣华信石油技术服务有限公司 | Cleaning agent for thickened oil conveying pipelines and preparation method thereof |
| CN104178364A (en) * | 2014-09-19 | 2014-12-03 | 山东华亚环保科技有限公司 | Glass detergent |
| CN104178374A (en) * | 2014-09-19 | 2014-12-03 | 山东华亚环保科技有限公司 | High-efficiency glass detergent |
| CN104388206A (en) * | 2014-10-30 | 2015-03-04 | 青岛昌安达药业有限公司 | Glass cleaner |
| CN105296169A (en) * | 2015-12-02 | 2016-02-03 | 苏州龙腾万里化工科技有限公司 | Efficient decontamination glass cleaner |
| CN105419972A (en) * | 2015-12-24 | 2016-03-23 | 东莞市安美润滑科技有限公司 | High-cleanliness degree corrosion-resistant water-based optical glass cleaning compound and application method thereof |
| CN105567446A (en) * | 2016-02-22 | 2016-05-11 | 苏州龙腾万里化工科技有限公司 | Glass cleaning agent |
| CN107955744A (en) * | 2017-11-29 | 2018-04-24 | 惠州市清洋实业有限公司 | A kind of production method of cleaning solution before glass thinning |
| CN108753482A (en) * | 2018-06-21 | 2018-11-06 | 深圳达诚清洗剂有限公司 | A kind of finished glass cleaning agent and preparation method thereof |
| CN109704554A (en) * | 2019-01-28 | 2019-05-03 | 深圳市普盛旺科技有限公司 | A kind of removing surface layer of glass stress aqueous dose |
| CN110592605A (en) * | 2018-12-17 | 2019-12-20 | 江苏斯尔邦石化有限公司 | Heavy oil stain cleaning agent for metal surface |
| CN111471536A (en) * | 2020-05-13 | 2020-07-31 | 深圳市众望丽华实业有限公司 | Water-based cleaning agent used after optical glass screen printing and application thereof |
| CN115975737A (en) * | 2022-12-13 | 2023-04-18 | 新疆金雪驰科技股份有限公司 | Multifunctional environment-friendly aromatic glass water composition and preparation method thereof |
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| CN1076476A (en) * | 1992-02-07 | 1993-09-22 | 克罗洛斯公司 | Reduce the hard surface cleaner of resistates |
| WO1997033963A1 (en) * | 1996-03-14 | 1997-09-18 | The Procter & Gamble Company | Glass cleaner compositions having good filming/streaking characteristics containing amine oxide polymers functionality |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104152290A (en) * | 2014-08-01 | 2014-11-19 | 无棣华信石油技术服务有限公司 | Cleaning agent for thickened oil conveying pipelines and preparation method thereof |
| CN104178364A (en) * | 2014-09-19 | 2014-12-03 | 山东华亚环保科技有限公司 | Glass detergent |
| CN104178374A (en) * | 2014-09-19 | 2014-12-03 | 山东华亚环保科技有限公司 | High-efficiency glass detergent |
| CN104388206A (en) * | 2014-10-30 | 2015-03-04 | 青岛昌安达药业有限公司 | Glass cleaner |
| CN105296169A (en) * | 2015-12-02 | 2016-02-03 | 苏州龙腾万里化工科技有限公司 | Efficient decontamination glass cleaner |
| CN105419972A (en) * | 2015-12-24 | 2016-03-23 | 东莞市安美润滑科技有限公司 | High-cleanliness degree corrosion-resistant water-based optical glass cleaning compound and application method thereof |
| CN105567446A (en) * | 2016-02-22 | 2016-05-11 | 苏州龙腾万里化工科技有限公司 | Glass cleaning agent |
| CN107955744A (en) * | 2017-11-29 | 2018-04-24 | 惠州市清洋实业有限公司 | A kind of production method of cleaning solution before glass thinning |
| CN108753482A (en) * | 2018-06-21 | 2018-11-06 | 深圳达诚清洗剂有限公司 | A kind of finished glass cleaning agent and preparation method thereof |
| CN110592605A (en) * | 2018-12-17 | 2019-12-20 | 江苏斯尔邦石化有限公司 | Heavy oil stain cleaning agent for metal surface |
| CN109704554A (en) * | 2019-01-28 | 2019-05-03 | 深圳市普盛旺科技有限公司 | A kind of removing surface layer of glass stress aqueous dose |
| CN111471536A (en) * | 2020-05-13 | 2020-07-31 | 深圳市众望丽华实业有限公司 | Water-based cleaning agent used after optical glass screen printing and application thereof |
| CN115975737A (en) * | 2022-12-13 | 2023-04-18 | 新疆金雪驰科技股份有限公司 | Multifunctional environment-friendly aromatic glass water composition and preparation method thereof |
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Application publication date: 20140611 |