CN106635470A - Vehicle body surface water-free deterging antifouling protective spray and preparation method thereof - Google Patents
Vehicle body surface water-free deterging antifouling protective spray and preparation method thereof Download PDFInfo
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- CN106635470A CN106635470A CN201610869113.4A CN201610869113A CN106635470A CN 106635470 A CN106635470 A CN 106635470A CN 201610869113 A CN201610869113 A CN 201610869113A CN 106635470 A CN106635470 A CN 106635470A
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- spray
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- bodywork surface
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/06—Other polishing compositions
- C09G1/14—Other polishing compositions based on non-waxy substances
- C09G1/16—Other polishing compositions based on non-waxy substances on natural or synthetic resins
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
- C11D3/3738—Alkoxylated silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3749—Polyolefins; Halogenated polyolefins; Natural or synthetic rubber; Polyarylolefins or halogenated polyarylolefins
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/004—Surface-active compounds containing F
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/143—Sulfonic acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
Vehicle body surface water-free deterging antifouling protective spray and a preparation method thereof relate to a mixture compound. The spray comprises, by weight, 3-5% of ionic fluorocarbon surfactant, 1-5% of fluorine surfactant, 5-10% of polytetrafluoroethylene micro powder, 5-10% of a degreasing agent, 10-15% of polyether modified brightener, 3-5% of unsaturated fatty alcohol sulfonate, 45-50% of ionized water, and 5-10% of LPG propellant. In use, a whole vehicle body is covered in a mist form and is wiped with sponge or towel, muddy sand is adsorbed, and water on the vehicle body is brought away. After washing, a layer of macromolecular ionic protective film may form on the surface of vehicle paint to protect the vehicle paint, prevent ultraviolet and snow and rain erosion and prevent vehicle paint aging, and good oil stain resistance and dustproof property are provided.
Description
Technical field
The present invention relates to a kind of mixture compound, specially a kind of bodywork surface exempts from water cleaning decontamination soiling protective spray
And preparation method thereof.
Background technology
With the popularization flourished with all kinds vehicle of auto industry, the fast development of carwash industry has been driven.
Traditional car-washing method is exactly to add alkaline detergent solution to rinse with clear water, with open defect:1st, easily make vehicle get rusty, affect just
Order Changshou;2nd, cleaning is less clean or simply cleans car body, washes rear car paint intensely dark;3rd, want to make car paint light such as new necessary
Waxing, increased car-cleaning cost;4th, great lot of water resources is wasted.
Also there is the boundless market space as the car wash trade of one of service trade.In insufficient water sources place or without water
In the case of, will be unable to carry out the cleaning of automobile.In addition, in order to keep automobile case lustrous surface, not only need Jing often to clean,
Waxing is also needed to after the washing, and glazing of then polishing again, complex steps waste time and energy.Waterless carwash had not only been economized on water but also environmentally friendly, can
Meet this demand.
The content of the invention
It is an object of the invention to provide one kind does not hinder automobile finish, integrate the car of cleaning, waxing, glazing and nursing
Exempt from water cleaning decontamination soiling protective spray and preparation method thereof in body surface.
Realizing the technical scheme of above-mentioned purpose is:Bodywork surface exempts from water cleaning decontamination soiling protective spray, it is characterised in that:
Include following components by mass percentage:Ion fluorocarbon surfactant 3%-5%, fluorine surfactant 1%-5%, polytetrafluoroethyl-ne
Alkene micro mist 5%-10%, degreasing agent 5%-10%, polyether-modified brightener 10%-15%, unsaturated fatty alcohol ether sulfonate 3%-5%,
Ionized water 45%-50%, LPG propellant 5%-10%.
No. CAS of the ion fluorocarbon surfactant be: 107852-51-7;No. CAS of fluorine surfactant be:
64422-66-8, molecular formula:(C2H4O)nC27H24O.
No. CAS of the ptfe micropowder be:9002-84-0, molecular formula:(C2F4)n;No. CAS of the degreasing agent
For:25155-30-0, molecular formula:C18H29NaO3S。
No. CAS of the polyether-modified brightener be:9006-65-9, molecular formula:(C2H6OSi)n;The ionized water
No. CAS is:7732-18-5, molecular formula:H2O。
No. CAS of the LPG propellants be:115-10-6, molecular formula:CH3OCH3。
Bodywork surface exempts from the preparation method that water cleans decontamination soiling protective spray, it is characterised in that:Including following technique step
Suddenly:
1)First by corresponding proportioning ion fluorocarbon surfactant, fluorine surfactant, ionized water are injected in agitator and stirred
Uniformly;
2)Again ptfe micropowder, degreasing agent are added by corresponding proportioning, and stirred;
3)Polyether-modified brightener, polyether-modified brightener is added to be stirred simultaneously in adding procedure by corresponding proportioning again
Mix, need to stir after the completion of addition;
4)Unsaturated fatty alcohol ether sulfonate is added, is stirred and is obtained final product spray feed liquid;
5)Spray feed liquid is filled in aerosol container bottle;
6)LPG propellants are filled by corresponding proportioning into the aerosol container bottle for install spray feed liquid, that is, makes a kind of bodywork surface
Exempt from water cleaning decontamination soiling protective spray.
Further, step 1)-6)It is both needed to be carried out in the interior of aeration-drying, temperature are for 20 DEG C of -28 DEG C of environment.
Further, step 5)- step 6)Between also to install spray valve additional on aerosol container bottle.
Further, the aerosol container bottle is made up with tinplate of material, is resistant to amounts of pressurized gaseous 15Mpa.
Five kinds of surfactants are added in the dispensing of the present invention:It is ion fluorocarbon surfactant, fluorine surfactant, poly-
Ether is modified brightener, degreasing agent and unsaturated fatty alcohol ether sulfonate.Ion fluorocarbon surfactant has high surface, nothing
Doubt and there is outstanding performance at aspects such as wetting, levellings, and can effectively disperse, emulsify low surfacing, can be with other tables in system
Face activating agent and component are compatible well;Fluorine surfactant outstanding feature the most is:Efficiently, stable, high surface, height
Thermodynamics and chemical stability;Degreasing agent, is a kind of nontoxic anion surfactant, with excellent degreasing power, and
Having reduces well the surface knife of water and wetting, infiltration, emulsifiability;Polyether-modified brightener, is a kind of macromolecule surface
Activating agent, with good water solubility, hydrophobicity and low surface tension;Live on unsaturated fatty alcohol ether sulfonate, this surface
Property agent be the one one-step hydrolysis neutralization by gas phase xanthation by the unrighted acid or ether alcohol compound for blocking, it has height
Foaming power, excellent scourability, and ecological environment-friendlydegradation degradation performance.
Above-mentioned five kinds of surfactants combine, and its chemism is remarkably reinforced, and strengthens dirt-removing power, can be had
Effect dissolves mud etc., effectively antistatic, strengthens biodegradability.
Ptfe micropowder is also added in the dispensing of the present invention, ptfe micropowder is that current surface energy is minimum
A kind of solid material, surface tension only 0.019N/m, almost all of solid material can not all stick to its surface, only table
Face tension force below 0.02N/m liquid could complete wetting its surface, abnormal lubricity and non-stick surface are to other points
The attraction also very little of son, therefore its coefficient of friction is very little, makes the present invention with extremely strong hydrophobic, hydrophobic, antifouling property.
Advantages of the present invention and good effect:(1)It is with low cost, it is easy to operate;(2)Can be formed in surface of vehicle paint after washing
One floor height molecular ion diaphragm, protects car paint, and antiultraviolet, the erosion of rain and snow, anti-car paint are aging, also with preferably anti-
Greasy dirt and dust-proof effect;(3)The present invention utilizes removal of surfactant spot, is gently wiped with wet towel and be can remove, and does not hinder
Car paint;(4)Water dissolves ability of the present invention with superelevation, denseness, permeability, soil release performance, silt covering property and soakage, and
Jing is tested, nontoxic;(5)The present invention integrates cleaning, waxing, glazing and nursing.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention become more apparent, with reference to embodiments, to the present invention
It is further elaborated.It should be appreciated that specific embodiment described herein is not used to only to explain the present invention
Limit the present invention.
Embodiment 1
A kind of bodywork surface exempts from water cleaning decontamination soiling protective spray, by mass percentage including following components:Ion fluorine carbon table
Face activating agent 5%, fluorine surfactant 5%, ptfe micropowder 10%, degreasing agent 10%, polyether-modified brightener 10%, insatiable hunger
With fatty alcohol ether sulfonate 5%, ionized water 50%, LPG propellants 5%.
Embodiment 2
A kind of bodywork surface exempts from water cleaning decontamination soiling protective spray, by mass percentage including following components:Ion fluorine carbon table
Face activating agent 4%, fluorine surfactant 1%, ptfe micropowder 10%, degreasing agent 7%, polyether-modified brightener 15%, insatiable hunger
With fatty alcohol ether sulfonate 3%, ionized water 50%, LPG propellants 10%.
Embodiment 3
A kind of bodywork surface exempts from water cleaning decontamination soiling protective spray, by mass percentage including following components:Ion fluorine carbon table
Face activating agent 3%, fluorine surfactant 5%, ptfe micropowder 7%, degreasing agent 10%, polyether-modified brightener 15%, unsaturation
Fatty alcohol ether sulfonate 5%, ionized water 45%, LPG propellants 10%.
Embodiment 4
A kind of bodywork surface exempts from water cleaning decontamination soiling protective spray, by mass percentage including following components:Ion fluorine carbon table
Face activating agent 5%, fluorine surfactant 5%, ptfe micropowder 5%, degreasing agent 5%, polyether-modified brightener 15%, unsaturation
Fatty alcohol ether sulfonate 5%, ionized water 50%, LPG propellants 10%.
No. CAS of ion fluorocarbon surfactant in embodiment 1,2,3,4 be: 107852-51-7;Fluorine surface-active
No. CAS of agent be:64422-66-8, molecular formula:(C2H4O)nC27H24O;No. CAS of ptfe micropowder be:9002-84-
0th, molecular formula:(C2F4)n;No. CAS of degreasing agent be:25155-30-0, molecular formula:C18H29NaO3S;Polyether-modified brightener
No. CAS is:9006-65-9, molecular formula:(C2H6OSi)n;No. CAS of ionized water be:7732-18-5, molecular formula:H2O; LPG
No. CAS of propellant be:115-10-6, molecular formula:CH3OCH3。
The bodywork surface of embodiment 1,2,3,4 exempts from the preparation method that water cleans decontamination soiling protective spray, including following technique step
Suddenly:
1)First ion fluorocarbon surfactant, surfactant, ionized water are injected in agitator by corresponding proportioning and stir equal
It is even;
2)Again ptfe micropowder, degreasing agent are added by corresponding proportioning, and stirred;
3)Polyether-modified brightener, polyether-modified brightener is added to be stirred simultaneously in adding procedure by corresponding proportioning again
Mix, need to stir after the completion of addition;
4)Unsaturated fatty alcohol ether sulfonate is added, is stirred and is obtained final product spray feed liquid;
5)Spray feed liquid is filled in aerosol container bottle, aerosol container bottle is made up with tinplate of material, is resistant to amounts of pressurized gaseous
15Mpa;
6)LPG propellants are filled by corresponding proportioning into the aerosol container bottle for install spray feed liquid, and is added on aerosol container bottle
Dress spray valve, that is, make a kind of bodywork surface and exempt from water cleaning decontamination soiling protective spray.
Step 1)-6)It is both needed to be carried out in the interior of aeration-drying, temperature are for 20 DEG C of -28 DEG C of environment.
The using method of the present invention:
Spray valve is vertically pressed, and away from vehicle body position 20-25 cm distances injection to be painted, makes this product pass through mist
Full vehicle body is covered, then vehicle body is wiped with sponge or towel, adsorb silt, take away vehicle body moisture.
After the completion of being cleaned by this product, vehicle body is cleaner, light, and carwash is after many days, the ash adsorbed on vehicle body
Dust quantity is less, is not only and showed obvious at that time in cleaning without greasy dirt attachment, therefore the cleaning performance of product of the present invention, and can also
Last longer.
Claims (9)
1. bodywork surface exempts from water cleaning decontamination soiling protective spray, it is characterised in that:Include following components by mass percentage:
Ion fluorocarbon surfactant 3%-5%, fluorine surfactant 1%-5%, ptfe micropowder 5%-10%, degreasing agent 5%-10%,
Polyether-modified brightener 10%-15%, unsaturated fatty alcohol ether sulfonate 3%-5%, ionized water 45%-50%, LPG propellant 5%-
10%。
2. bodywork surface according to claim 1 exempts from water cleaning decontamination soiling protective spray, it is characterised in that:The ion
No. CAS of fluorocarbon surfactant be: 107852-51-7;No. CAS of fluorine surfactant be:64422-66-8, molecular formula:
(C2H4O)nC27H24O。
3. bodywork surface according to claim 1 exempts from water cleaning decontamination soiling protective spray, it is characterised in that:Described poly- four
No. CAS of PVF micro mist be:9002-84-0, molecular formula:(C2F4)n;No. CAS of the degreasing agent be:25155-30-0, point
Minor:C18H29NaO3S。
4. bodywork surface according to claim 1 exempts from water cleaning decontamination soiling protective spray, it is characterised in that:The polyethers
No. CAS of modified brightener be:9006-65-9, molecular formula:(C2H6OSi)n;No. CAS of the ionized water be:7732-18-5、
Molecular formula:H2O。
5. bodywork surface according to claim 1 exempts from water cleaning decontamination soiling protective spray, it is characterised in that:The LPG
No. CAS of propellant be:115-10-6, molecular formula:CH3OCH3。
6. the bodywork surface described in claim 1 exempts from the preparation method that water cleans decontamination soiling protective spray, it is characterised in that:Bag
Include following processing step:
1)First by corresponding proportioning ion fluorocarbon surfactant, fluorine surfactant, ionized water are injected in agitator and stirred
Uniformly;
2)Again ptfe micropowder, degreasing agent are added by corresponding proportioning, and stirred;
3)Polyether-modified brightener, polyether-modified brightener is added to be stirred simultaneously in adding procedure by corresponding proportioning again
Mix, need to stir after the completion of addition;
4)Unsaturated fatty alcohol ether sulfonate is added, is stirred and is obtained final product spray feed liquid;
5)Spray feed liquid is filled in aerosol container bottle;
6)LPG propellants are filled by corresponding proportioning into the aerosol container bottle for install spray feed liquid, that is, makes a kind of bodywork surface
Exempt from water cleaning decontamination soiling protective spray.
7. bodywork surface according to claim 6 exempts from the preparation method that water cleans decontamination soiling protective spray, and its feature exists
In:Step 1)-6)It is both needed to be carried out in the interior of aeration-drying, temperature are for 20 DEG C of -28 DEG C of environment.
8. the bodywork surface according to claim 6 or 7 exempts from the preparation method that water cleans decontamination soiling protective spray, its feature
It is:Step 5)- step 6)Between also to install spray valve additional on aerosol container bottle.
9. bodywork surface according to claim 8 exempts from the preparation method that water cleans decontamination soiling protective spray, and its feature exists
In:The aerosol container bottle is made up with tinplate of material, is resistant to amounts of pressurized gaseous 15Mpa.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201610869113.4A CN106635470A (en) | 2016-09-30 | 2016-09-30 | Vehicle body surface water-free deterging antifouling protective spray and preparation method thereof |
Applications Claiming Priority (1)
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CN201610869113.4A CN106635470A (en) | 2016-09-30 | 2016-09-30 | Vehicle body surface water-free deterging antifouling protective spray and preparation method thereof |
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Family
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CN201610869113.4A Pending CN106635470A (en) | 2016-09-30 | 2016-09-30 | Vehicle body surface water-free deterging antifouling protective spray and preparation method thereof |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108300597A (en) * | 2018-03-01 | 2018-07-20 | 奥普家居股份有限公司 | A kind of antifouling cleaning agent |
CN111088122A (en) * | 2019-12-25 | 2020-05-01 | 北京桂华悦洗科技有限公司 | Anhydrous car washing liquid and preparation method thereof |
CN111304018A (en) * | 2020-03-26 | 2020-06-19 | 北京京蝠环保科技有限公司 | Scrubbing-free car washing powder |
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WO2002053695A2 (en) * | 2001-01-05 | 2002-07-11 | Henkel Kommanditgesellschaft Auf Aktien | Portion of washing agent, rinsing agent or cleaning agent, containing surfactants |
CN1683484A (en) * | 2004-04-16 | 2005-10-19 | 上海宏略实业有限公司 | Cleaning composition and its use |
CN104194964A (en) * | 2014-07-30 | 2014-12-10 | 南昌印仁贸易有限公司 | Automobile glass cleaner and preparation method thereof |
CN104745322A (en) * | 2013-12-30 | 2015-07-01 | 华中科技大学 | Phosphorus-free automobile cleaning solution and preparation method thereof |
CN104974859A (en) * | 2015-06-29 | 2015-10-14 | 陈士县 | Anhydrous car washing liquid |
CN105505642A (en) * | 2015-12-16 | 2016-04-20 | 重庆嗨馒头网络科技有限公司 | Water-saving car washing method |
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WO2002053695A2 (en) * | 2001-01-05 | 2002-07-11 | Henkel Kommanditgesellschaft Auf Aktien | Portion of washing agent, rinsing agent or cleaning agent, containing surfactants |
CN1683484A (en) * | 2004-04-16 | 2005-10-19 | 上海宏略实业有限公司 | Cleaning composition and its use |
CN104745322A (en) * | 2013-12-30 | 2015-07-01 | 华中科技大学 | Phosphorus-free automobile cleaning solution and preparation method thereof |
CN104194964A (en) * | 2014-07-30 | 2014-12-10 | 南昌印仁贸易有限公司 | Automobile glass cleaner and preparation method thereof |
CN104974859A (en) * | 2015-06-29 | 2015-10-14 | 陈士县 | Anhydrous car washing liquid |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN108300597A (en) * | 2018-03-01 | 2018-07-20 | 奥普家居股份有限公司 | A kind of antifouling cleaning agent |
CN111088122A (en) * | 2019-12-25 | 2020-05-01 | 北京桂华悦洗科技有限公司 | Anhydrous car washing liquid and preparation method thereof |
CN111088122B (en) * | 2019-12-25 | 2021-07-16 | 北京桂华悦洗科技有限公司 | Anhydrous car washing liquid and preparation method thereof |
CN111304018A (en) * | 2020-03-26 | 2020-06-19 | 北京京蝠环保科技有限公司 | Scrubbing-free car washing powder |
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