CN1683484A - Cleaning composition and its use - Google Patents

Cleaning composition and its use Download PDF

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Publication number
CN1683484A
CN1683484A CN 200410017723 CN200410017723A CN1683484A CN 1683484 A CN1683484 A CN 1683484A CN 200410017723 CN200410017723 CN 200410017723 CN 200410017723 A CN200410017723 A CN 200410017723A CN 1683484 A CN1683484 A CN 1683484A
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Prior art keywords
cleaning compositions
alkyl
mixture
active agent
tensio
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Granted
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CN 200410017723
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Chinese (zh)
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CN100465256C (en
Inventor
陆军
童海扬
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HONGLUE INDUSTRY Co Ltd SHANGHAI
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HONGLUE INDUSTRY Co Ltd SHANGHAI
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Priority to CNB2004100177239A priority Critical patent/CN100465256C/en
Publication of CN1683484A publication Critical patent/CN1683484A/en
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Publication of CN100465256C publication Critical patent/CN100465256C/en
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Abstract

The present invention relates to detergent composition and its use. The composition includes at least a kind of surfactant in 1-50 wt%, at least one kind of water soluble polymer thickener in 0.1-20 wt%, at least one kind of oxyalylene compound in 0.001-20 wt%, at least one kind of powdered stuffing in 0.001-20 wt%, and water in at least 20 wt%. The detergent composition may be used in cleaning skin and hair as well as household and industrial articles and has the advantages of high spreading property, good texture, less influence of environment temperature change, etc.

Description

A kind of cleaning compositions and uses thereof
Technical field
The present invention relates to a kind of cleaning compositions, relate in particular to and a kind ofly can be applicable to human body skin and hair and meet rheology and the cleaning compositions of aesthetic requirement.
Background technology
As everyone knows, cleaning facial and skin is very important, thorough cleaning skin more to be to use frothing cleaning product.Commercially available frothing cleaning product has the form of paste, gel, emulsion, strip at present, and normal conditions do not contain the frothing cleaning product of fatty acid soaps, because the relation of cost makes product viscosity not enough.Therefore need to use external structure agent-thickening material.
And almost do not have a kind of single thickening material at present, can satisfy application on the rheology and aesthetic view point.For example, alkyl or acyl group oxygen ethylidene compound; Polysaccharide such as derivatived cellulose, guar gum and its derivative etc. are used as thickening to be changed product viscosity for outside temperature and is responsive and does not reach the viscosity requirement, also can influence the foaming properties of product.And the water-soluble polymers thickening material then needs a large amount of addings, makes spreadability and usability variation and add affiliation in a large number.
In known open source literature, the water-soluble polymers of use thickening material is also arranged in the cleaning compositions, but thickening effectiveness is not obvious, make spreadability and usability variation and add affiliation in a large number, and influence foam performance.In cleaning compositions, use the oxyalkylene compound also to have, but can not form stiff lotion, and the lotion of oxyalkylene compound institute thickening is bigger to being subjected to variation of ambient temperature, Gel mile shape promptly appears at low temperatures, and under comparatively high temps, can from flexible pipe, flow out, this is unacceptable.Using ground pigment in cleaning compositions, also is disclosed, but ground pigment can not fully thicken to enough denseness, and adds the rough usability of affiliation generation in a large number.The said products but all can not reach rheology and final the use on requirement.
Summary of the invention
Purpose of the present invention be exactly provide in order to overcome the defective that above-mentioned prior art exists a kind of product spread and texture good, be subjected to variation of ambient temperature influence little, meet cleaning compositions of service requirements and uses thereof.
Purpose of the present invention can be achieved through the following technical solutions:
A kind of cleaning compositions, it is characterized in that, said composition comprises following component and weight content: at least a tensio-active agent 1%-50%, at least a water-soluble polymers thickening material 0.1%-20%, at least a oxyalkylene compound 0.001%-20%, at least a ground pigment 0.001%-20% comprises 20% water at least.
Described tensio-active agent is as whipping agent, and this tensio-active agent is selected from a kind of in nonionogenic tenside, anion surfactant, cats product and the amphoterics or their mixture.
Described tensio-active agent specifically is selected from a kind of in alkyl-sulphate, sulfated alkyl ether, sulfonate, isethionate, taurate, sulfosuccinate, alkyl sulfoacetate, alkyl phosphate salt, alkyl ether phosphate salt, alkyl saccharides, bound to polyglycerol Fatty Alcohol(C12-C14 and C12-C18), carboxylate salt, alkyl ether carboxy acid salt, fatty acid soaps, trimethyl-glycine, tetrahydroglyoxaline, the N-acyl amino hydrochlorate or their mixture.
Described water-soluble polymers thickening material is selected from a kind of in polyose, natural gum, mucopolysaccharide, carboxylic acid polyalcohol, polyacrylic acid, polyacrylic ester, the cross-linked acrylic acid ester copolymer or their mixture.
Described oxyalkylene compound be selected from polyoxyethylene glycol, macrogol ester and/or polypropylene glycol ester, polyglycol ether/or the oxyalkylene diester of the alkoxy-alkyl derivative of polypropylene glycol ether, polyvalent alcohol, glycerine, lipid acid, three esters, with a kind of in the oxyethyl group ethylidene urethane derivant of alkyl chain modification or their mixture.
Described ground pigment is selected from a kind of in the plain microballon of diatomite, kaolin, silicon-dioxide, talcum powder, mica powder, precipitated chalk, aluminium hydroxide, inert fiber, nylon powder, polyethylene powder, polystyrene powder, ptfe micropowder, synthetic wax micro mist, Zinic stearas, the Magnesium Stearate or their mixture.
Described ground pigment is to be the micro mist of 20-500nm through the median size that coats or do not coat.
A kind of purposes of cleaning compositions is characterized in that, this cleaning compositions is as skin, hair cleaning makeup, perhaps family or industrial cleaners.
Compared with prior art, the present invention has the following advantages and beneficial effect:
Meet the acceptable cost requirement, enough formation lotion abilities are arranged, promptly can form enough viscosity, good spreadability and texture are arranged, be convenient to fast and water mixing foaming, and produce fine and close persistent foam, use feeling is good, and pasty consistence is subjected to difference variation little.
Embodiment
The present invention is in concrete enforcement, and tensio-active agent is a kind of at least, is preferably two or more.The relative composition total weight of the tensio-active agent that the present invention relates to is 1%-50%, is preferably 5%-40%, is preferably 10%-30%.The foaming surfactant of mentioning especially has alkyl phosphate and alkyl ether phosphate.For example, by MAP N, MAP H and MAEP that element set chemical industrial company sells, wherein MAP N and MAEP are the mixture of monoesters and dibasic acid esters, and monoester content surpasses 75%, and MAP H is the pure product based on 90% above monoesters.
In the present invention, the water-soluble polymers thickening material is 0.1%-20% with respect to composition total weight, is preferably 0.1%-10%, is preferably 1%-10%.
In the present invention, the oxyalkylene compound is 0.001%-20% with respect to composition total weight, is preferably 0.01%-10%, is preferably 0.1%-5%.
In the present invention, ground pigment is 0.001%-20% with respect to composition total weight, is preferably 0.01%-10%, is preferably 0.1%-8%.
At least 20% the water that comprises the gross weight of relative composition in the present invention.
Following table 1 cited embodiment further describes of the present invention, and wherein embodiment 1~4 is facial cleaning combination:
Table 1 unit: gram
Title Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Embodiment 6 Embodiment 7
Alkyl phosphate salt ??14.7 ????20 ???15 ????8 ??5 ??30 ??35
Lauryl hydroxyl sulphur trimethyl-glycine ??8.0 ????10 ???5 ????2 ??0 ??10 ??15
The cocounut oil diglycollic amide ??4.0 ????4.0 ???4.0 ????4.0 ??4.0 ??4.0 ??4.0
Certain herbaceous plants with big flowers alkyl glucoside ??3.0 ????3.0 ???3.0 ????3.0 ??3.0 ??3.0 ??3.0
Acrylate copolymer ??3.0 ????5.0 ???8 ????5 ??0.1 ??10 ??20
Polyoxyethylene glycol or 6000 pairs of stearates ??0.8 ????3.5 ???2 ????20 ??0.001 ??5 ??1
Diatomite or talcum powder ??1.5 ????5.0 ???20 ????1.5 ??0.001 ??1.5 ??0.01
Glycerine ??2.0 ????2.0 ???2.0 ????2.0 ??2.0 ??2.0 ??2.0
Pearlescent flake ??2.0 ????2.0 ???2.0 ????2.0 ??2.0 ??2.0 ??2.0
Sanitas ??0.2 ????0.5 ???0.2 ????0.1 ??0.3 ??0.2 ??0.1
Water ??60.8 ????45 ???38.8 ????52.4 ??83.598 ??32.3 ??17.89
The pH value ??7.0 ????7.0 ???7.0 ????7.0 ??7.0 ??7.0 ??7.0
Viscosity (25 ℃, Brookfield RVT TB#) ??131000mPas ? ????18400mPas ? ???66000mPas ? ????12000mPas ? ??50000mPas ? ??121000mPas ? ??40400mPas ?
??(2r/min) ????(10r/min) ???(4r/min) ????(10r/min) ??(4r/min) ??(4r/min) ??(5r/min)
Sense organ There are not jelly shape, stiff lotion Flowability is arranged Flowability is arranged Flowability is arranged Flowability is arranged The jelly shape Flowability is arranged

Claims (8)

1. cleaning compositions, it is characterized in that, said composition comprises following component and weight content: at least a tensio-active agent 1%-50%, at least a water-soluble polymers thickening material 0.1%-20%, at least a oxyalkylene compound 0.001%-20%, at least a ground pigment 0.001%-20% comprises 20% water at least.
2. cleaning compositions according to claim 1, it is characterized in that, described tensio-active agent is as whipping agent, and this tensio-active agent is selected from a kind of in nonionogenic tenside, anion surfactant, cats product and the amphoterics or their mixture.
3. cleaning compositions according to claim 2; it is characterized in that described tensio-active agent specifically is selected from a kind of in alkyl-sulphate, sulfated alkyl ether, sulfonate, isethionate, taurate, sulfosuccinate, alkyl sulfoacetate, alkyl phosphate salt, alkyl ether phosphate salt, alkyl saccharides, bound to polyglycerol Fatty Alcohol(C12-C14 and C12-C18), carboxylate salt, alkyl ether carboxy acid salt, fatty acid soaps, trimethyl-glycine, tetrahydroglyoxaline, the N-acyl amino hydrochlorate or their mixture.
4. cleaning compositions according to claim 1, it is characterized in that described water-soluble polymers thickening material is selected from a kind of in polyose, natural gum, mucopolysaccharide, carboxylic acid polyalcohol, polyacrylic acid, polyacrylic ester, the cross-linked acrylic acid ester copolymer or their mixture.
5. cleaning compositions according to claim 1, it is characterized in that, described oxyalkylene compound be selected from polyoxyethylene glycol, macrogol ester and/or polypropylene glycol ester, polyglycol ether/or the oxyalkylene diester of the alkoxy-alkyl derivative of polypropylene glycol ether, polyvalent alcohol, glycerine, lipid acid, three esters, with a kind of in the oxyethyl group ethylidene urethane derivant of alkyl chain modification or their mixture.
6. cleaning compositions according to claim 1, it is characterized in that described ground pigment is selected from a kind of in the plain microballon of diatomite, kaolin, silicon-dioxide, talcum powder, mica powder, precipitated chalk, aluminium hydroxide, inert fiber, nylon powder, polyethylene powder, polystyrene powder, ptfe micropowder, synthetic wax micro mist, Zinic stearas, the Magnesium Stearate or their mixture.
7. according to claim 1 or 6 described cleaning compositions, it is characterized in that described ground pigment is to be the micro mist of 20-500nm through the median size that coats or do not coat.
8. the purposes of the described cleaning compositions of claim 1 is characterized in that, this cleaning compositions is as skin, hair cleaning makeup, perhaps family or industrial cleaners.
CNB2004100177239A 2004-04-16 2004-04-16 Cleaning composition and its use Expired - Lifetime CN100465256C (en)

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CN100465256C CN100465256C (en) 2009-03-04

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102430364A (en) * 2011-09-09 2012-05-02 中交武汉港湾工程设计研究院有限公司 Composite stratum waste soil improving foam additive
CN103897856A (en) * 2012-12-28 2014-07-02 青岛锦涟鑫商贸有限公司 Preparation method of liquid detergent
CN103961271A (en) * 2014-01-08 2014-08-06 片仔癀(上海)生物科技研发有限公司 Cleansing cream and preparation method thereof
CN104450240A (en) * 2014-11-11 2015-03-25 大连工业大学 Diatomite laundry detergent and preparation method thereof
CN105255595A (en) * 2014-07-17 2016-01-20 葛以东 Washing powder formula
CN106434025A (en) * 2016-09-14 2017-02-22 芜湖成德龙过滤设备有限公司 Sleeve sterilization agent and preparation method thereof
CN106635437A (en) * 2016-12-15 2017-05-10 佛山慧创正元新材料科技有限公司 Novel solid detergent for metal surface
CN106635470A (en) * 2016-09-30 2017-05-10 东莞市蓝鲸化工科技有限公司 Vehicle body surface water-free deterging antifouling protective spray and preparation method thereof
WO2017100979A1 (en) * 2015-12-14 2017-06-22 L'oreal Composition for treating keratin fibers comprising hydrophobic silica aerogel particles, crosslinked copolymer, clay, and surfactant
CN109475474A (en) * 2016-07-14 2019-03-15 荷兰联合利华有限公司 Foamed cleaning composition for local application
CN110393692A (en) * 2019-09-04 2019-11-01 广东丸美生物技术股份有限公司 Wire drawing plant thickener and its preparation method and application

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1069880A (en) * 1991-08-31 1993-03-17 岳阳市日用化工总厂 Bile element shampoo
DE69431793T2 (en) * 1993-09-24 2003-07-03 Kao Corp DETERGENT COMPOSITION

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102430364A (en) * 2011-09-09 2012-05-02 中交武汉港湾工程设计研究院有限公司 Composite stratum waste soil improving foam additive
CN102430364B (en) * 2011-09-09 2014-07-09 中交武汉港湾工程设计研究院有限公司 Composite stratum waste soil improving foam additive
CN103897856A (en) * 2012-12-28 2014-07-02 青岛锦涟鑫商贸有限公司 Preparation method of liquid detergent
CN103961271B (en) * 2014-01-08 2017-01-25 片仔癀(上海)生物科技研发有限公司 Cleansing cream and preparation method thereof
CN103961271A (en) * 2014-01-08 2014-08-06 片仔癀(上海)生物科技研发有限公司 Cleansing cream and preparation method thereof
CN105255595A (en) * 2014-07-17 2016-01-20 葛以东 Washing powder formula
CN104450240A (en) * 2014-11-11 2015-03-25 大连工业大学 Diatomite laundry detergent and preparation method thereof
CN104450240B (en) * 2014-11-11 2018-08-03 大连工业大学 A kind of diatomite liquid detergent and preparation method thereof
WO2017100979A1 (en) * 2015-12-14 2017-06-22 L'oreal Composition for treating keratin fibers comprising hydrophobic silica aerogel particles, crosslinked copolymer, clay, and surfactant
CN109475474A (en) * 2016-07-14 2019-03-15 荷兰联合利华有限公司 Foamed cleaning composition for local application
CN106434025A (en) * 2016-09-14 2017-02-22 芜湖成德龙过滤设备有限公司 Sleeve sterilization agent and preparation method thereof
CN106635470A (en) * 2016-09-30 2017-05-10 东莞市蓝鲸化工科技有限公司 Vehicle body surface water-free deterging antifouling protective spray and preparation method thereof
CN106635437A (en) * 2016-12-15 2017-05-10 佛山慧创正元新材料科技有限公司 Novel solid detergent for metal surface
CN110393692A (en) * 2019-09-04 2019-11-01 广东丸美生物技术股份有限公司 Wire drawing plant thickener and its preparation method and application

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