CN106635437A - Novel solid detergent for metal surface - Google Patents
Novel solid detergent for metal surface Download PDFInfo
- Publication number
- CN106635437A CN106635437A CN201611159390.2A CN201611159390A CN106635437A CN 106635437 A CN106635437 A CN 106635437A CN 201611159390 A CN201611159390 A CN 201611159390A CN 106635437 A CN106635437 A CN 106635437A
- Authority
- CN
- China
- Prior art keywords
- parts
- powder
- metal surface
- cleaning agent
- kaolin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 53
- 239000002184 metal Substances 0.000 title claims abstract description 53
- 239000013042 solid detergent Substances 0.000 title abstract 4
- 239000000843 powder Substances 0.000 claims abstract description 29
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 26
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 10
- 239000010433 feldspar Substances 0.000 claims abstract description 10
- 235000011187 glycerol Nutrition 0.000 claims abstract description 10
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 10
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims abstract description 10
- 235000010234 sodium benzoate Nutrition 0.000 claims abstract description 10
- 239000004299 sodium benzoate Substances 0.000 claims abstract description 10
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 9
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 9
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 9
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims abstract description 9
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 9
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 9
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 9
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 9
- 239000011734 sodium Substances 0.000 claims abstract description 9
- 239000010457 zeolite Substances 0.000 claims abstract description 9
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 8
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims abstract description 7
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims abstract description 6
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims abstract description 6
- 239000012459 cleaning agent Substances 0.000 claims description 19
- 239000007787 solid Substances 0.000 claims description 16
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 9
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- 229940084030 carboxymethylcellulose calcium Drugs 0.000 claims description 8
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 7
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims 2
- VDGJOQCBCPGFFD-UHFFFAOYSA-N oxygen(2-) silicon(4+) titanium(4+) Chemical compound [Si+4].[O-2].[O-2].[Ti+4] VDGJOQCBCPGFFD-UHFFFAOYSA-N 0.000 claims 1
- 238000002360 preparation method Methods 0.000 abstract description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 abstract 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 abstract 1
- 239000001768 carboxy methyl cellulose Substances 0.000 abstract 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 abstract 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 abstract 1
- 239000002932 luster Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229910021647 smectite Inorganic materials 0.000 abstract 1
- 239000000600 sorbitol Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 26
- 238000007254 oxidation reaction Methods 0.000 description 15
- 230000003647 oxidation Effects 0.000 description 12
- 230000000694 effects Effects 0.000 description 6
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000007743 anodising Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000012937 correction Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- -1 alkali metal salt Chemical class 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002739 metals Chemical group 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- CMXPERZAMAQXSF-UHFFFAOYSA-M sodium;1,4-bis(2-ethylhexoxy)-1,4-dioxobutane-2-sulfonate;1,8-dihydroxyanthracene-9,10-dione Chemical compound [Na+].O=C1C2=CC=CC(O)=C2C(=O)C2=C1C=CC=C2O.CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC CMXPERZAMAQXSF-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
- C11D3/1293—Feldspar; Perlite; Pumice or Portland cement
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/223—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin oxidised
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/16—Metals
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a novel solid detergent for a metal surface. The novel solid detergent is prepared from the following components in parts by weight: 10-25 parts of feldspar powder, 5-15 parts of kieselguhr, 3-5 parts of smectite powder, 10-20 parts of kaolin, 8-18 parts of zeolite powder, 10-25 parts of talcum powder, 5-10 parts of aluminium hydroxide, 15-30 parts of silicon dioxide, 5-10 parts of sodium benzoate, 3-5 parts of polyethylene glycol, 5-10 parts of glycerin, 5-10 parts of sorbitol, 5-10 parts of 2-sodium acylsulfonate, 3-8 parts of carboxymethylcellulose and 6-12 parts of hydroxyethyl cellulose. Compared with the prior art, the novel solid detergent for the metal surface has the significant characteristics that dirt on the metal surface can be effectively removed, the metal surface is protected to be further oxidized, the luster of the metal surface is kept, the preparation technology is simple and the cost is low.
Description
Technical field
The invention belongs to detergent technical field, specifically relates to a kind of metal surface solid cleaning agent.
Background technology
Metal typically has oxygen of the stronger reproducibility easily and in air that redox reaction occurs.And metal can be with
Other metals form galvanic cell in the presence of moist medium so that activity is high to lose electronics, activity it is low obtain electronics, occur
Oxidation reaction.
The oxidation processes of metal are that metal surface acts on and the oxide-film of formation protectiveness with oxygen or oxidant, prevent metal
Corrosion.Method for oxidation has thermal oxidation method, alkaline oxygenated method, acidic oxidation method (ferrous metal) and chemical oxidization method, anodic oxygen
Change method (non-ferrous metal) etc..Now it is described below：
1) chemical oxidation method is primarily adapted for use in the oxidation processes of non-ferrous metal (such as aluminium, copper, magnesium and their alloy).
Processing method is put in part in the solution for preparing, at a certain temperature Jing after the oxidation reaction of certain hour, then shape
The operations such as into layer protecting film then cleaned and drying.
2) part is immersed in deployed solution when alkaline oxygenated method is processed is heated to 135 DEG C～155 DEG C, during process
Between length depend on part in carbon content height.After metal parts is oxidation-treated, then with 60 DEG C～80 DEG C of content
Rinse for 15g/L～20g/L suds, the time is 2min～5min, it is then clean simultaneously with cold water and hot water injection respectively
Dry up or dry 5min～10min (temperature is 80 DEG C～90 DEG C).
3) acidic oxidation method will part be placed in acid solution and processed.Compare with alkaline oxygenated method, acidic oxidation
Method is relatively inexpensive, the diaphragm that metal surface is generated after process, and corrosion resistance and mechanical strength exceed alkaline oxygenated process
The performance of generated film afterwards, therefore be widely used.
4) metallic article is heated to 600 DEG C～650 DEG C by thermal oxidation method, is then processed with vapours and reducing agent.Also
A kind of method is that metallic article is immersed in the alkali metal salt of about 300 DEG C of melting to be processed
5) anodizing anodizing is another kind of method of non-ferrous metal oxidation.It is that metal parts is made into sun
Pole, makes its surface form the process of oxide-film using electrolysis.This oxide-film can both play the passivating film between metal and film
Effect, can increase coating and intermetallic adhesion again, reduce the infiltration of moisture, so as to extend the service life of coating,
It is widely used in the bottom of japanning.
But no matter which kind of method, handled result has have certain harm to metal surface, causes metal surface to be continued
Aoxidize and tarnish.
Although patent document CN01823835, CN201010212838, CN201110024703, CN201410265252 are
There is the patent of oneself to metal surface, but these cleaning agents more or less can have certain to metal, particularly precious metal surface
Harm, so needing a kind of not only safety but also efficient cleaning agent on market.
The content of the invention
In view of this, the technical problem to be solved in the present invention is to provide a kind of metal surface solid cleaning agent, this
The cleaning agent that invention is provided not only can efficiently remove the dirt of metal surface, and can be effectively kept metal surface
Gloss, while may also operate as preventing the further oxidation of metal surface.
To reach above-mentioned purpose, following technical scheme is this invention takes：
A kind of metal surface solid cleaning agent, it is in parts by weight, composed of the following components：Feldspar powder 10～25, silicon
Diatomaceous earth 5～15, montmorillonite powder 3～5, kaolin 10～20, zeolite powder 8～18, talcum powder 10～25, aluminium hydroxide 5～10, two
Silica 15～30, Sodium Benzoate 5～10, polyethylene glycol 3～5, glycerine 5～10, sorbierite 5～10,2- acyloxy key sulfonic acid
Sodium 5～10, carboxymethylcellulose calcium 3～8, hydroxyethyl cellulose 6～12
Described metal surface solid cleaning agent preparation technology is：By proportioning, after each component ground and mixed, stirring
Finished product is obtained by after being uniformly dispersed.
The present invention principle be：
(1) special space adsorption structure.The grounds travels such as feldspar powder, diatomite, montmorillonite powder have good space to tie
Structure, the Si in their tetrahedrons4+Can be by A13+Displacement, and the Si in octahedron4+、A13+Can be by Fe3+、Fe2+、Zn2+、Mn2 +、Li+Deng displacement.As a result the chemical composition and interlayer negative electricity He of series of complex are defined.The electric charge of crystal lattice is in a basic balance,
And generate charge difference after replacing.Make the chemical bond in chip and crystal layer more be partial to ionic bond, make crystal layer that there is absorption sun
The ability of ion.The dirt of metal surface has certain electric charge, is easily captured by space structure and is removed.
(2) good similar intermiscibility.Sodium Benzoate, polyethylene glycol, glycerine, sorbierite equal solvent and metal surface dirt
With good similitude.The similar material of every molecular structure, is all easy to mutual phased soln.Due to molecule polarity whether
It is similar that very big is affected on dissolubility, so, the similar principle that mixes can be understood as again " polar molecule is soluble in polar solvent,
Nonpolar molecule is soluble in non-polar solven ", such that it is able to be removed well to metal surface.
Compared with prior art, the present invention has the advantages that：
(1) present invention not only can effectively remove the dirt of metal surface, and continue oxygen with protection metal surface
Change, and keep the gloss of metal surface；
(2) preparation process is simple, it is with low cost.
Specific embodiment
Describe embodiments of the present invention in detail below with reference to specific embodiment, whereby how skill is applied to the present invention
Art means solving technical problem, and reach technique effect realize that process can fully understand and implement according to this.
If not specializing, the conventional hand that the technological means employed in embodiment is well known to those skilled in the art
Section, the raw material for being adopted also is available commercial.The various processes and method not described in detail are as known in the art
Conventional method.
Embodiment 1
A kind of metal surface solid cleaning agent, it is in parts by weight, composed of the following components：
Feldspar powder 10, diatomite 5, montmorillonite powder 3, kaolin 10,
Zeolite powder 8, talcum powder 10, aluminium hydroxide 5, silica 15, Sodium Benzoate 5,
Polyethylene glycol 3, glycerine 5, sorbierite 5,2- acyloxy keys sodium sulfonate 5,
Carboxymethylcellulose calcium 3, hydroxyethyl cellulose 6
Embodiment 2
A kind of metal surface solid cleaning agent, it is in parts by weight, composed of the following components：
Feldspar powder 18, diatomite 10, montmorillonite powder 4, kaolin 15,
Zeolite powder 13, talcum powder 17, aluminium hydroxide 7, silica 23, Sodium Benzoate 8,
Polyethylene glycol 4, glycerine 8, sorbierite 7,2- acyloxy keys sodium sulfonate 7,
Carboxymethylcellulose calcium 6, hydroxyethyl cellulose 9
Embodiment 3
A kind of metal surface solid cleaning agent, it is in parts by weight, composed of the following components：
Feldspar powder 25, diatomite 15, montmorillonite powder 5, kaolin 20,
Zeolite powder 18, talcum powder 25, aluminium hydroxide 10, silica 30,
Sodium Benzoate 10, polyethylene glycol 5, glycerine 10, sorbierite 10,
2- acyloxy keys sodium sulfonate 10, carboxymethylcellulose calcium 8, hydroxyethyl cellulose 12
In order to be able to the effect for directly reflecting this product, below using certain metal as research object, carry out treatment effect and test
Card.
Table 1 below is to carry out glossiness correction data before and after the solid cleaning agent addition of metal surface.
Specifically the metal surface solid cleaning agent of example 1～3 is applied to into certain metal surface and has been cleaned repeatedly 1～2 hour
After carry out glossiness and be measured.
The solid cleaning agent of table 1 is applied to the correction data of glossiness before and after certain metal surface
As it can be seen from table 1 the solid cleaning agent through example 1～3 is applied to glossiness before and after certain metal surface and can reach
To more than 85%.So, the dirt of metal surface not only can be effectively removed after this product process, and with protection metal watch
Face continues to aoxidize, and keeps the gloss of metal surface, and its practicality is stronger.
Finally it should be noted that above example is only to illustrative and not limiting technical scheme, although reference
Above-described embodiment has been described in detail to the present invention, it will be appreciated by those skilled in the art that still can carry out to the present invention
Modification or equivalent, any modification or partial replacement without departing from the spirit and scope of the present invention, it all should cover
In scope of the presently claimed invention.
Claims (4)
1. a kind of metal surface solid cleaning agent, in parts by weight, composed of the following components：
Feldspar powder 10～25, diatomite 5～15, montmorillonite powder 3～5, kaolin 10～20, zeolite powder 8～18, talcum powder 10～
25th, aluminium hydroxide 5～10, silica 1 5～30, Sodium Benzoate 5～10, polyethylene glycol 3～5, glycerine 5～10, sorbierite 5
～10,2- acyloxy key sodium sulfonate 5～10, carboxymethylcellulose calcium 3～8, hydroxyethyl cellulose 6～12.
2. a kind of metal surface solid cleaning agent according to claim 1, in parts by weight, by following components group
Into：
Feldspar powder 10, diatomite 5, montmorillonite powder 3, kaolin 10, zeolite powder 8, talcum powder 10, aluminium hydroxide 5, silica
15th, Sodium Benzoate 5, polyethylene glycol 3, glycerine 5, sorbierite 5,2- acyloxy keys sodium sulfonate 5, carboxymethylcellulose calcium 3, ethoxy are fine
Dimension element 6.
3. a kind of metal surface solid cleaning agent according to claim 1, in parts by weight, by following components group
Into：
Feldspar powder 18, diatomite 10, montmorillonite powder 4, kaolin 15, zeolite powder 13, talcum powder 17, aluminium hydroxide 7, silica
23rd, Sodium Benzoate 8, polyethylene glycol 4, glycerine 8, sorbierite 7,2- acyloxy keys sodium sulfonate 7, carboxymethylcellulose calcium 6, ethoxy are fine
Dimension element 9.
4. a kind of metal surface solid cleaning agent according to claim 1, in parts by weight, by following components group
Into：
Feldspar powder 25, diatomite 15, montmorillonite powder 5, kaolin 20, zeolite powder 18, talcum powder 25, aluminium hydroxide 10, titanium dioxide
Silicon 30, Sodium Benzoate 10, polyethylene glycol 5, glycerine 10, sorbierite 10,2- acyloxy keys sodium sulfonate 10, carboxymethylcellulose calcium 8, hydroxyl
Ethyl cellulose 12.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107987986A (en) * | 2017-12-19 | 2018-05-04 | 山东联星能源集团有限公司 | The flexible detergent and application method of a kind of high performance military helmet |
| CN108048252A (en) * | 2017-12-06 | 2018-05-18 | 常州朋悦纺织品有限公司 | A kind of preparation method of bathtub cleaning agent |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1040051A (en) * | 1989-07-12 | 1990-02-28 | 金颖逵 | Multifunction detergent and preparation method thereof |
| CN1683484A (en) * | 2004-04-16 | 2005-10-19 | 上海宏略实业有限公司 | Cleaning composition and its use |
| CN101880608A (en) * | 2010-06-28 | 2010-11-10 | 深圳市成为生物科技有限公司 | Natural solid cleaning agent |
| CN102864031A (en) * | 2012-10-16 | 2013-01-09 | 宁波御坊堂生物科技有限公司 | Powerful kitchenware detergent and preparation method thereof |
| CN104404538A (en) * | 2014-11-07 | 2015-03-11 | 合肥大安印刷有限责任公司 | Metal surface cleaning agent capable of strongly removing scales and preparation method thereof |
| CN105176708A (en) * | 2015-09-18 | 2015-12-23 | 颍上县龙裕扬工贸有限公司 | Soak solution for cleaning screws of plastic extruder |
| CN106011909A (en) * | 2016-05-31 | 2016-10-12 | 无锡伊佩克科技有限公司 | Metal surface cleaning agent and preparation method thereof |
-
2016
- 2016-12-15 CN CN201611159390.2A patent/CN106635437A/en not_active Withdrawn
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1040051A (en) * | 1989-07-12 | 1990-02-28 | 金颖逵 | Multifunction detergent and preparation method thereof |
| CN1683484A (en) * | 2004-04-16 | 2005-10-19 | 上海宏略实业有限公司 | Cleaning composition and its use |
| CN101880608A (en) * | 2010-06-28 | 2010-11-10 | 深圳市成为生物科技有限公司 | Natural solid cleaning agent |
| CN102864031A (en) * | 2012-10-16 | 2013-01-09 | 宁波御坊堂生物科技有限公司 | Powerful kitchenware detergent and preparation method thereof |
| CN104404538A (en) * | 2014-11-07 | 2015-03-11 | 合肥大安印刷有限责任公司 | Metal surface cleaning agent capable of strongly removing scales and preparation method thereof |
| CN105176708A (en) * | 2015-09-18 | 2015-12-23 | 颍上县龙裕扬工贸有限公司 | Soak solution for cleaning screws of plastic extruder |
| CN106011909A (en) * | 2016-05-31 | 2016-10-12 | 无锡伊佩克科技有限公司 | Metal surface cleaning agent and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108048252A (en) * | 2017-12-06 | 2018-05-18 | 常州朋悦纺织品有限公司 | A kind of preparation method of bathtub cleaning agent |
| CN107987986A (en) * | 2017-12-19 | 2018-05-04 | 山东联星能源集团有限公司 | The flexible detergent and application method of a kind of high performance military helmet |
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