CN1040051A - Multifunction detergent and preparation method thereof - Google Patents
Multifunction detergent and preparation method thereof Download PDFInfo
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- CN1040051A CN1040051A CN 89104619 CN89104619A CN1040051A CN 1040051 A CN1040051 A CN 1040051A CN 89104619 CN89104619 CN 89104619 CN 89104619 A CN89104619 A CN 89104619A CN 1040051 A CN1040051 A CN 1040051A
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Abstract
A kind of multifunction detergent comprises multiple nonionogenic tenside, organic solvent and auxiliary agent.This multifunction detergent is compared with conventional sanitising agent, removes to have de-sludging, outside the glazing function, also has the removal of impurities bacterium, deodorizing, destatic, prevent dust, mildew-resistant, rust protection etc. are multi-functional, and these functions can once be finished in use.The invention still further relates to a kind of method for preparing this multifunction detergent.
Description
The present invention relates to a kind of multifunction detergent, particularly a kind of sanitising agent with functions such as cleaning, glazing, protections the invention still further relates to the method for preparing this sanitising agent.This multifunction detergent can be widely used in comprising various lacquer paintings, pottery, enamelware, metal, glass, woodwork, plastics, leatheroid, leatherware, synthon, hair, cotton fibre goods, rubber item, the multiple stromal surface of marble, granite product or the like.
Multifunction detergent of the present invention mainly is made up of the nonionic agent of multiple different HLB values and various active agent aid and solvent oil.
Multifunction detergent stability of the present invention is good, has multiple functions such as strong detergency, luminance brightness height, anti-electrostatic, mildew-resistant, antirust, protection against corrosion, removal of impurities bacterium.
At present, commercially available various sanitising agents are of a great variety, powder detergent is arranged, aqueous sanitising agent, paste sanitising agent, solid block sanitising agent etc., but the major ingredient of these sanitising agent prescriptions is single, function is few, use face is narrow, can not use on the matrix face widely.For example the automobile glazing is cured, can only be used for bodywork surface and paint, and all can not use on the matrix such as the plastics in other position such as the car, leather, rubber, glasswork.And for example, carpet cleaner only is suitable for use on this kind fabric of carpet, then can't use indoor furniture and high-grade household electrical appliance etc.Thereby the purposes of existing clean-out system is restricted.
Few in order to overcome existing sanitising agent function, shortcomings such as range of application is narrow, the inventor is through number of research projects for many years, the nonionic agent of having invented with multiple different HLB values carries out composite, and then with multiple other promoting agent, auxiliary agent is in conjunction with method for preparing multifunction detergent and multifunction detergent composition thereof.
One of purpose of the present invention provides a kind of multifunction detergent and preparation method thereof.
Two of purpose of the present invention provides a kind of paste and aqueous multifunction detergent and preparation method thereof.
Three of purpose of the present invention provides a kind of stable performance that is made into by multiple nonionogenic tenside and other promoting agent and auxiliary agent, multifunction detergent of suitable prolonged preservation and preparation method thereof.
Four of purpose of the present invention provide a kind of can be with dirt, remove oil film, removal of impurities bacterium, deodorizing, elimination static, go up light, form protective membrane, dustproof, mildew-resistant, antirust, protection against corrosion, anti-pollution, antifog multi-functional one step completed sanitising agent and preparation method thereof.
For the multifunctionality of determining sanitising agent and can be in the removal dirt ability under the multiple stromal surface condition, at first the dirt content that is touched to be offered a clear explanation, under the dirt condition of complexity, main dirt has: grease, rotten oil, coal ash, dust, crispy rice, swill, the dirt of human body, the bits of various articles for use, calcium phosphate, ferric oxide, pitch, urine, concrete, various residues such as malthoid, magnesia, terrazzo, decorative sheet, plastics, rubber, natural resin, cotton cured, blood stains, and other range proteins or the like.
In order to remove above-mentioned dirt, and reach glazing, anticorrosion, form purposes such as protective membrane, multifunction detergent of the present invention mainly is made up of following component.
1 adopts the nonionic agent of multiple different HLB values, carries out compositely, can constitute the additive properties of HLB value like this.Because the emulsification of multiple occasion, aspects such as dispersion, damping, relevant with the HLB value that trickle adjusting obtains, conditions such as polarity temperature according to oil or dirt, need with different HLB values, so select the nonionic surface active agent of different HLB values for use, in addition composite according to its adaptability, the decontamination dirt effect that competence exertion is the highest.The HLB value scope of selecting for use is: 4~5,9~12,14.5,18.2 under multiple matrix and different condition, both otherwise damage, can remove various dirts again, adopt ether oxygen base (R-(EO) n-O-by the stromal surface of decontamination) the multiple nonionic agent of type.Because its stability in hard water is big, to Ca
++, Mg
++Stable, the low bubble of plasma.Composite fully, can demonstrate the synergism effect.
2 under above-mentioned composite structure content, for improving the performance of promoting agent, adopts the various active agent aid, to improve the performance of promoting agent.Contained Ca in dirt composition
++, Mg
++, Fe
++, Al
+++Deng polyvalent cation, these positively charged ions play both keying actions between the dirt fine particle of electronegative matrix and negative charge.This class polyvalent cation bridge is the major reason that dirt adheres to, and these metal ions of chelating are very big to strengthening clean function influence, otherwise these metal ions can produce so-called calcium soap with tensio-active agent, and this calcium soap can cause the detrimentally affect that makes the dirt recontaminate.So select condensed phosphate (STPP) for use, can improve this influence, because condensed phosphate in the place of distance matrix → dirt interface tens dusts, produces the high potential barrier of 100~200KT, so can prevent the pollution and the recontaminate of matrix.Play and increase clean effect.Sequestering power is relevant with pH value, and its pH value of multifunction detergent of the present invention repeatedly is 8~9, at this moment sequestering power the best.
3 in order to prevent the recontaminate of dirt, and carboxymethyl cellulose (CMC) has been adopted in absorption again, it is water-soluble multivalent anions, the concentration height of solution can be used as deflocculant, thickening material in quite wide scope, dispersion agent uses, can make stable emulsifying, strong to the affinity of dirt, dirt can be wrapped, make it to be scattered in the water, play the not effect of recontaminate.
4 in order to improve the affinity of water, the present invention selects high molecular (molecular weight 6000) polyoxyethylene glycol (PEG) for use, because polyoxyethylene glycol and nonionic agent can generate multipolymer, improves the affinity of water, change the proportional quantity of polyoxyethylene glycol, can change affinity arbitrarily water.Simultaneously, macromolecule polyethylene glycol has effects such as emulsification, film forming, glazing.
The more little promoting agent of the polymerization degree of hydrophilic group oxyethyl group in the Soxylat A 25-7 of the different alkyl of 5 employings, its capillary reduction ability is just big more.Thereby surfactivity also just increases.
Add plurality of inorganic salt in 6 prescriptions of the present invention, phosphoric acid salt, silicate, vitriol are arranged, the silicate of wherein selecting for use is to adopt SiO
2/ Na
2The O weight ratio is 2~2.4 hydration polysilicate, can make the Ca in the water
++, Mg
++Ion changes soluble salt into, can play the effect that reduces phosphorous clean-out system simultaneously again.
7 various active agent molecules are made up of hydrophobic group that is insoluble in water and hydrophilic group soluble in water, belong to parents matchmaker's property material, when adding polyoxyethylene glycol, urea, in certain concentration range, assemble having formed so-called micellar molecule or ion aggregate hastily.For the promoting agent solvent that is in the micella state, further obtain mesomorphic state during enrichment, as the jelly state.This cohesion glue has transparence or muddy jelly state.This is relevant with different temperature, is because the relation of phase transition and film function is formed.The temperature of reaction that the present invention selects for use is controlled between 50~70 ℃, forms the opaque cured paste micella aggregate of water.
Selected the urea component for use in 8 prescriptions,, and formed the film colloid, played the effect of solubility promoter again with polyoxyethylene glycol in order that decompose organic dirt.
9 for anti-chap, regulates the shortcoming of promoting agent, has adopted glycerine in the prescription, uses as conditioning agent.
10 organic solvents are the brute force best media that degrease.The present invention adopts solvent-refined oil, by emulsifying part solubilising in the promoting agent micella, dirt can be come in the washing lotion.On the other hand,,, do not produce emulsification and form the aqueous solution, be removed by the secondary solubilising in micella because dirt is the surface of solid particulate state attached to matrix to water-soluble dirt.The solvent-refined oil that the present invention adopts be by chemical treatment again rectifying make.Selected rectification temperature scope is 183 ℃ for the initial boiling point temperature, and medium temperature is 195 ℃, and end point temperature is 212 ℃.
11 in order to play the effect of oiliness improver, and the stearic acid in the employing lipid acid can be adsorbed on metal or other stromal surface form tough adsorption film.This adsorption film is the protective membrane effect of playing under the boundary lubricating condition.
12 in order to increase the flexibility to the leather goods fiber, adopts the trolamine component in the present invention's prescription, and this component not only also has soft effect to leather but also to fiber, and absorption H is arranged again
2S gas ability, thus play deodorization functions.Trolamine is good lime soap dispersing agent, prevents the cohesion of calcium soap, keeps the dispersiveness and the washability of calcium soap, prevents recontaminate, can be used as metal and the effect of furniture abrasive simultaneously again.In basic solution, can generate complex compound with tervalent metal ion and play the sequestrant effect.
The silicon emulsion that 13 the present invention adopt is with dimethyl polysiloxane; add promoting agent and trickle silicon dioxide microparticle (2 μ are following); use as dispersion agent; be separated into stable silicon latax through emulsification; this silicon emulsion not only plays light, decontamination, grinding, lubrication, can also play the protective membrane effect; this silicon emulsion is kinds of surface promoting agent and the auxiliary agent that utilizes different HLB values, is dispersed into stable silicon emulsion through emulsification under 60 ℃ temperature.
14 consider the skin that touches the people when using sanitising agent, in order to protect skin, add an amount of fatty acid amide, not only can protect skin, have soft humidification, have again simultaneously thickening, antirust, to the synergy of the stable of calcium soap and enhancing decontamination.
15 other auxiliary agents have biodegradation agent (selecting Citrate trianion for use), can make biological degradation rapid, carry out the oxidation cycle that natural biological is learned in cell, destroy the oxygen enrichment effect in the water, prevent the pollution of the environment.This biodegradation agent consumption seldom generally can.
16 antis can be eliminated the static of stromal surface and play dustproof effect.The present invention selects two kinds of antistatic agents for use, and a kind of is the effect of existing promoting agent, and anti-static electrification is arranged again, as fatty alcohol-polyoxyethylene ether phosphoric acid fat (what select for use is monoester).Another kind is that ASA-50(chemical industry shop is on sale) antistatic agent, it is to the top coat strong adhesion of plastics, keeps the function time of anti-electrostatic long.
It is that anti-leather goods are in the hot and humid mould of generation down that 17 mould inhibitors mainly act on.The kind of selecting for use has 2~3 kinds.For example: acid of benzene potassium and the sodium salt thereof used always in the food, other has two kinds to be mould inhibitor A26 and mould inhibitor CY-1.Mould inhibitor A26 is a N(β β dichloroethylene) the salicylic acid acid amides.This mould inhibitor is effective, safe to the mildew-resistant and the removal of impurities bacterium of leather goods.The mould inhibitor that the present invention adopts also is composite making, and as adopting mildew-resistant CY-1 and mould inhibitor DP, PC is composite to form.
The preparation method of multifunction detergent of the present invention comprises: above-mentioned raw materials is divided into three big components, i.e. the A group: stearic acid, silicone oil, silicon emulsion, solvent oil, nonionogenic tenside, sulfonation ether; B group: polyoxyethylene glycol, deionized water, tripoly phosphate sodium STPP, sodium phosphate, water glass, urea, trolamine, fatty alkanol amide, carboxymethyl cellulose, glycerine, diethylamine tetraacethyl four sodium; C group: antistatic agent, mould inhibitor, spices, abrasive.The A component is put into the reactor of 300 liter volumetrical Stainless Steel Band chucks, be provided with in the still that the oar formula stirs, revolution is 130~150 rev/mins, chuck leads to steam heating, Heating temperature is no more than 80 ℃, earlier solvent oil is added and begin heating in the reactor, temperature is controlled at 75 ℃ and adds stearic acid then in order, after stearic acid all dissolves, add tensio-active agent, temperature is not less than 75 ℃, become muddy shape in the solvent oil this moment, adds silicone oil, silicon emulsion, sulfonation ether while stirring, continues to stir, and temperature still is controlled between 75~80 ℃.Continue to stir 30 minutes.
It is identical that other gets a same volumetrical reactor structure, add B component raw material, order is earlier deionized water to be added in the still, Heating temperature is 70 ℃, stirring revolution is 150 rev/mins, add trolamine, stir and make its dissolving, add tripoly phosphate sodium STPP, sodium phosphate, water glass, urea, limit edged whipping temp again and can be elevated to 75 ℃, solution is transparence.Add polyoxyethylene glycol, fatty alkanol amide, carboxymethyl cellulose, this moment solution again and be muddy shape.Temperature is not less than 65 ℃, glycerol adding again, this moment, solution still was muddy shape, added diethylamine tetraacethyl four sodium then, this moment the solution shape that is translucent.Continuing to stir remains between 70~75 ℃ temperature, stir and with water pump B component reaction product was squeezed in the reactor of A component then in 1 hour, simultaneous temperature remains between 65~70 ℃, when all squeezing into the reactor of A component, the B component notices that temperature is not less than 65 ℃, and continue to stir, but notice that the B component adds fashionable in A component still, add at twice, promptly adding slowly earlier to stop to add after half and made it reaction stirred about 30~40 minutes, whether have fierce foamed phenomenon, do not add until adding if then continue again if seeing it, after total overall reaction finishes, solution is the muddy shape liquid of emulsus, and this moment, temperature was 65 ℃ ± 2 ℃, then with the raw material of C component, add abrasive in order earlier, stirred 30 minutes, again with antistatic agent, mould inhibitor, and essence.After stirring, squeeze into by pipeline with another Stainless Steel Pump and to carry out packing on the portioning station, the temperature during packing is not less than 55 ℃.Place approximately after the packing and promptly be frozen into cured paste finished product after a few hours.
The component and the consumption of multifunction detergent of the present invention are as follows:
The composition weight umber
Stearic acid 2.5~6
Solvent-refined oil 12~25
Alkylphenol polyoxyethylene HLB value 4~5 2~4
Alkylphenol polyoxyethylene HLB value 9~12 0.8~2
Alkylphenol polyoxyethylene HLB value 14.5~15 0.1~0.2
Alkylphenol polyoxyethylene HLB value 18~19 0.2~1.5
Fatty alcohol-polyoxyethylene ether HLB value 9.4 0.5~2.5
Silicon emulsion 0.6~7
Silicone oil 0.5~5
Tripoly phosphate sodium STPP 1~5
Sodium phosphate 0.3~2.5
Urea 0.2~5
Water glass 0.3~4
Polyoxyethylene glycol 1.5~5
Carboxymethyl cellulose 0.3~4.5
Glycerine 1~2
Dodecyl Soxylat A 25-7 sodium sulfonate 0.2~0.8
Trolamine 0.1~0.9
EDTA4Na(diethylamine tetraacethyl four sodium) 0.1~0.4
Fatty alkanol amide 0.2~0.7
Antistatic agent 0.25~0.6
Mould inhibitor 0.04~0.4
Essence 0.02~0.1
Deionized water 40~350
Abrasive 0~8
The following examples are to further specify of the present invention.
Embodiment 1
The prescription and the method for making that prepare cured paste sanitising agent are as follows:
The composition weight umber
Stearic acid 2.5
Solvent-refined oil 12
Nonionic surface active agent:
Polyoxyethylene nonylphenol ether (HLB value 10~12) 2
Polyoxyethylene nonylphenol ether (HLB value 18~19) 0.2
Polyoxyethylene nonylphenol ether (HLB value 14~15) 0.1
Octadecyl polyoxyethylenated alcohol (HLB value 9.4) 1.2
Silicon emulsion 0.6
Silicone oil 5
Tripoly phosphate sodium STPP 1
Tertiary sodium phosphate (12 crystal water) 0.3
Starso (9 crystal water) 2
Urea 3
Polyoxyethylene glycol (molecular weight 6000) 1.5
Carboxymethyl cellulose 0.3
Glycerine 1
Dodecyl Soxylat A 25-7 sodium sulfonate 0.3
Trolamine 0.4
Diethylamine tetraacethyl four sodium 0.1
Fatty alkanol amide 0.2
Antistatic agent
Nine alkyl alcohol Soxylat A 25-7 list phosphoric acid fat 0.15
ASA-50 0.1
Mould inhibitor
Sodium Benzoate 0.1
Mould inhibitor-A
260.3
(chemical name dichloroethenyl salicylamide)
Spices peppermint essence 0.02
Abrasive zirconium silicate (granularity 2 μ following 88~92%) 0.3
Deionized water 40
In having the stainless steel cauldron of strap clamp cover of agitator, 300 liters put into solvent oil, then in the logical steam heating of chuck, agitator stirs with 130~150 rev/mins of rotating speeds, makes heating and temperature control at 75 ℃, is sequentially added into stearic acid then after stearic acid all dissolves, add tensio-active agent, temperature is not less than 75 ℃, and become muddy shape in the solvent oil this moment, adds silicone oil, silicon emulsion, sulfonation ether while stirring, continue to stir, temperature still is controlled between 75~80 ℃.Continue to stir 30 minutes.
Other get a same volumetrical reactor and structure identical, add B component raw material successively, promptly earlier deionized water is added in the still, Heating temperature is 70 ℃, stirring revolution is 150 rev/mins, order of addition(of ingredients) makes its dissolving for adding the trolamine stirring, add tripoly phosphate sodium STPP, sodium phosphate, water glass, urea, the stirring of limit edged again, temperature can be elevated to 75 ℃, and (seeing its solution is transparence, add polyoxyethylene glycol, fatty alkanol amide, carboxymethyl cellulose again, this moment, solution was muddy shape.Temperature is not less than 65 ℃, glycerol adding again, this moment, solution was muddy shape, added diethylamine tetraacethyl four sodium then, this moment the solution shape that is translucent.Continuing to stir remains between 70 ℃ and 75 ℃ temperature, stir after 1 hour and to squeeze into water pump that simultaneous temperature remains between 65~70 ℃ in the A reactor, when all squeezing into A group reaction still, the B component notices that temperature is not less than 65 ℃, and continue to stir, but notice that the B component adds fashionable in A component still, add at twice, promptly add slowly earlier to stop to add after half and make it stirring reaction and saw it in about 30~40 minutes whether fierce foamed phenomenon is arranged, then continue to stir if having, then do not continue again to add until adding if having.After total overall reaction finished, solution was the muddy shape liquid of emulsus, and this moment, temperature was 65 ℃ ± 2 ℃, with the raw material of C component, in order, added abrasive earlier then, stirred 30 minutes, again with antistatic agent, mould inhibitor, reach essence.After stirring, squeeze into by pipeline with another Stainless Steel Pump and to carry out packing on the portioning station, the temperature during packing is not less than 55 ℃.Place approximately after the packing and promptly be frozen into cured paste finished product after a few hours.
Embodiment 2
The preparation method is with embodiment 1, and its cured paste sanitising agent prescription is as follows:
The composition weight umber
Stearic acid 6
Solvent-refined oil 25
Tensio-active agent
Polyoxyethylene nonylphenol ether (HLB value 10~12) 1
Polyoxyethylene nonylphenol ether (HLB value 18~19) 1.5
Octadecyl polyoxyethylenated alcohol (HLB value 9.4) 2.5
Silicon emulsion 7
Silicone oil 0.5
Tripoly phosphate sodium STPP 5
Tertiary sodium phosphate (containing 12 crystal water) 2.5
Water glass (containing 9 crystal water) 4
Urea 5
Polyoxyethylene glycol (molecular weight 6000) 5
Carboxymethyl cellulose 4.5
Glycerine 2
Sulfonation ether 1
Trolamine 0.9
EDTA four sodium 0.4
Antistatic agent ASA-50 0.6
Sanitas:
Sodium Benzoate 0.04
Spices: lemon flavour 0.1
Abrasive: (white carbon black (2~4 μ are more than 90%) 4
Deionized water 65
Embodiment 3
The preparation method is with embodiment 1, and its cured paste sanitising agent prescription is as follows:
The composition weight umber
Stearic acid 4
Solvent-refined oil 17.5
Tensio-active agent:
Polyoxyethylene nonylphenol ether (HLB value 10~12) 1.5
Polyoxyethylene nonylphenol ether (HLB value 18~19) 1
Octadecyl polyoxyethylenated alcohol (HLB value 9.4) 2
Silicon emulsion 6
Silicone oil 0.6
Tripoly phosphate sodium STPP 4.5
Sodium phosphate (12 crystal water) 2
Water glass (9 crystal water) 3.3
Urea 4.5
Polyoxyethylene glycol 2.8
Carboxymethyl cellulose 3.2
Glycerine 1.8
EDTA four sodium 0.1
Trolamine 0.6
Mould inhibitor
Sodium Benzoate 0.2
Sodium azide 0.1
Antistatic agent ASA-50 0.4
Spices: menthol 0.05
Lemon flavour 0.05
Deionized water 107
Embodiment 4
The preparation method is with embodiment 1, but the sanitising agent of present embodiment preparation is a liquid state, and its prescription is as follows:
The component parts by weight
Solvent oil 5
Stearic acid 1
Tensio-active agent:
Polyoxyethylene nonylphenol ether HLB value 10~12 0.8
Polyoxyethylene nonylphenol ether HLB value 18~19 0.4
Octadecyl polyoxyethylenated alcohol HLB value 9.4 0.5
Silicon emulsion 1.6
Sulfonation ether 0.2
Trolamine 0.1
Glycerine 0.5
Methylcellulose gum 1.2
Tripoly phosphate sodium STPP 1
Sodium phosphate 0.4
Water glass 0.3
Urea 1.5
ASA-50 antistatic agent 0.04
Sodium Benzoate 0.05
Deionized water 350
Spices 0.04
Should be understood that top narration and embodiment just further specify of the present invention, and unrestricted the present invention, any improvement that does not exceed spirit and scope of the invention all within the scope of the present invention.
Claims (9)
1, a kind of multifunction detergent, this sanitising agent comprises:
2.5~6 parts of stearic acid
12~25 parts of solvent-refined oils
Nonionogenic tenside:
Alkylphenol polyoxyethylene HLB value 4~5 2~4 part
Alkylphenol polyoxyethylene HLB value 9~12 0.8~2 part
Alkylphenol polyoxyethylene HLB value 14.5~15 0.1~0.2 part
Alkylphenol polyoxyethylene HLB value 18~19 0.2~1.5 part
9.4 0.5~2.5 parts of fatty alcohol-polyoxyethylene ether HLB values
0.6~7 part of silicon emulsion
0.5~5 part of silicone oil
1~5 part of tripoly phosphate sodium STPP
0.3~2.5 part of sodium phosphate
0.2~5 part in urea
0.3~4 part of water glass
1.5~5 parts of polyoxyethylene glycol
0.3~4.5 part of carboxymethyl cellulose
1~2 part of glycerine
0.2~0.8 part of dodecyl Soxylat A 25-7 sodium sulfonate
0.1~0.9 part of trolamine
0.1~0.4 part of EDTA4Na (diethylamine tetraacethyl four sodium)
0.2~0.7 part of fatty alkanol amide
0.25~0.6 part of antistatic agent
0.04~0.4 part of mould inhibitor
0.02~0.1 part in essence
40~350 parts of deionized waters
0~8 part of abrasive
Said umber is parts by weight.
2, sanitising agent according to claim 1, wherein the nonionogenic tenside alkylphenol polyoxyethylene is a polyoxyethylene nonylphenol ether.
3, sanitising agent according to claim 1, wherein fatty alcohol-polyoxyethylene ether is the octadecyl polyoxyethylenated alcohol.
4, sanitising agent according to claim 1, wherein the initial boiling point of solvent-refined oil is 183 ℃, final boiling point is 212 ℃.
5, sanitising agent according to claim 1, wherein antistatic agent is selected from nine alkyl polyoxyethylene ether phosplate and ASA-50.
6, sanitising agent according to claim 1, wherein mould inhibitor is selected from Sodium Benzoate, sodium azide, dichloroethylene salicylic amide.
7, sanitising agent according to claim 1, wherein essence is selected from menthol, lemon flavour.
8, sanitising agent according to claim 1, wherein abrasive is selected from zirconium silicate.White carbon black, silica gel.
9, a kind of method for preparing multifunction detergent, this method comprise that (A) in the jacketed type reactor that stirs and heat, adds solvent-refined oil, temperature is controlled at 75 ℃, and stirring revolution is 130~150 rev/mins, adds stearic acid then, after stearic acid all dissolves, add tensio-active agent, temperature is not less than 75 ℃, become muddy shape in the solvent oil this moment, adds silicone oil, silicon emulsion while stirring, sulfonation ether, continue to stir, temperature still is controlled between 75~80 ℃, continues to stir 30 minutes; (B) get the together reactor of spline structure in addition, deionized water is added in the still, Heating temperature is 70 ℃, stirring revolution is 150 rev/mins, order of addition(of ingredients), trolamine adds the back stirring and makes its dissolving, add tripoly phosphate sodium STPP, sodium phosphate, water glass, urea again, the limit edged stirs, and temperature can be elevated to 75 ℃, and seeing its solution is transparence, add polyoxyethylene glycol again, fatty alkanol amide, carboxymethyl cellulose, this moment, solution was muddy shape, temperature is not less than 65 ℃, glycerol adding again, this moment, solution was muddy shape, added diethylamine tetraacethyl four sodium then, at this moment, the solution shape that is translucent.Continue stirring temperature is remained between 70 ℃ and 75 ℃, stir after 1 hour and squeeze in (A) reactor, between simultaneous temperature keeps 65~70 ℃ with water pump; (C) final product in (B) is all squeezed in the reactor of (A), kept (A) temperature of reaction kettle to be not less than 65 ℃, and continue to stir; (D) add abrasive then, stirred 30 minutes, again with antistatic agent, mould inhibitor, and essence, after stirring, squeeze into by pipeline with another Stainless Steel Pump and to carry out packing on the portioning station, the temperature during packing is not less than 55 ℃.
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CN 89104619 CN1040051A (en) | 1989-07-12 | 1989-07-12 | Multifunction detergent and preparation method thereof |
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CN106675854A (en) * | 2016-12-15 | 2017-05-17 | 佛山慧创正元新材料科技有限公司 | Improved commemorative coin solid detergent |
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CN107794139A (en) * | 2017-09-08 | 2018-03-13 | 安徽万利达羽绒制品有限公司 | A kind of drake feather degreasing reagent and preparation method thereof |
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CN108822983A (en) * | 2018-07-24 | 2018-11-16 | 合肥市大卓电力有限责任公司 | A kind of power equipment grease dirt cleaning agent |
CN110951398A (en) * | 2018-09-27 | 2020-04-03 | 南通品德清洁科技有限公司 | Decontaminating and curing brightener for stone |
CN110129144A (en) * | 2019-05-31 | 2019-08-16 | 深圳市润贝化工有限公司 | A kind of aircraft passenger compartment leather cleaning glazing agent |
CN112877145A (en) * | 2021-01-14 | 2021-06-01 | 台州智子科技有限公司 | Cleaning agent for plastic shell of fitness equipment |
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