CN102703244A - Environment-friendly cleanser for thick oil scale on pavement of food street and preparation method as well as application thereof - Google Patents
Environment-friendly cleanser for thick oil scale on pavement of food street and preparation method as well as application thereof Download PDFInfo
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- CN102703244A CN102703244A CN2012101898605A CN201210189860A CN102703244A CN 102703244 A CN102703244 A CN 102703244A CN 2012101898605 A CN2012101898605 A CN 2012101898605A CN 201210189860 A CN201210189860 A CN 201210189860A CN 102703244 A CN102703244 A CN 102703244A
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Abstract
The invention relates to an environment-friendly cleanser for thick oil scale on a pavement of a food street. The environment-friendly cleanser consists of the following components in percentage by weight: 1.0-4.0 percent of fatty alcohol polyoxyethylene ether sulfate, 0.5-2.0 percent of linear alkyl benzene sulfonate, 0-6.0 percent of polyoxyethylene octylphenol ether, 0.-4.0 percent of alkyl polyglucoside, 0.5-2.0 percent of fatty alcohol-polyoxyethylene ether, 2.5 percent of triethanolamine, 0.5-2.5 percent of trisodium citrate, 1.0-3.0 percent of oil of mandarin and the balance of tap water. The preparation comprises the following steps of: preparing fatty alcohol polyoxyethylene ether sulfate solution; adding the linear alkyl benzene sulfonate, the polyoxyethylene octylphenol ether, the alkyl polyglucoside, the fatty alcohol-polyoxyethylene ether and the oil of mandarin in sequence at 60-65 DEG C and stirring to dissolve the linear alkyl benzene sulfonate, the polyoxyethylene octylphenol ether, the alkyl polyglucoside, the fatty alcohol-polyoxyethylene ether and the oil of mandarin; cooling to be or below 40 DEG C; and then adding the triethanolamine and the trisodium citrate in sequence and stirring to keep the triethanolamine and the trisodium citrate in a uniform state. The cleanser has the advantages of low cost, high anti-fouling capacity, easiness for promotion, simple preparation process and the like.
Description
Technical field
The present invention relates to the preparation and the applied technical field of clean-out system, be specifically related to the green cleaning agent of road surface, cuisine variety street viscous crude dirt, kitchen oil stain and the ordinary road road surface oil of a kind of nontoxic, low bubble, strong detergency.
Background technology
Along with rapid development of economy, people's the life and the level of consumption progressively improve, and this also impels each city to emerge a large amount of cuisine variety streets to a great extent.And the cuisine variety street is when providing cuisines consumption and amusement and recreation to people; Environment around also giving has caused very big negative impact; Especially near the road surface has had a strong impact on city image because the long-term greasy dirt that adheres to has formed the thick dirt as paint of one deck.
In recent years; Various synthetic greasy dirt detergents are Application and Development in succession; But owing to reason such as surfactant selection or formulation composition be unreasonable; Cleaning performance to dirt is still unsatisfactory, or dirt fully Rapid Cleaning, come off, or poisonous, the inflammable organic solvents such as highly basic such as NaOH, zellon, tetracol phenixin and phenols that add are prone to cause secondary pollution." a kind of ultra concentrated greasy dirt fast cleaning agent and working method thereof " disclosed like Chinese patent document CN101463294A; The clean-out system of being invented is applicable to all kinds of heavy dirty smeary rapid cleanings; But the perishable thing that is cleaned of highly basic NaOH that uses in its prescription; The scavenging solution of discharging also causes environmental pollution easily, has limited its use.Chinese patent document CN1453350A discloses the preparation method of a kind of " scavenger specially for lane in expressway toll gate "; The scavenger specially scale removal of being invented is thorough; Do not corrode the road surface, but the organic solvent kerosene that uses in its prescription is inflammable, explosive and poisonous, operates dangerous.
Along with the deterioration of global environment and the raising of people's environmental protection consciousness; The development of new strong detergency, fast, environmental friendliness, multipurpose high-efficiency grease green cleaning agent safe in utilization, that the preparation method is simple and with low cost have better market prospect; Thereby received investigator's concern, and become the development trend of cleaning industry gradually.
Summary of the invention
Technical problem to be solved by this invention is: for overcoming the deficiency that above-mentioned existing clean-out system exists; Provide that a kind of technology is simple, with low cost, the ability of deoiling is strong, and speed is fast, nontoxic, road surface, the cuisine variety street viscous crude dirt efficient green clean-out system of non-secondary pollution.
The present invention solves its technical problem and adopts following technical scheme:
Road surface, cuisine variety street provided by the invention viscous crude dirt green cleaning agent, its composition by following mass percent constitutes: fatty alcohol polyoxyethylene ether sulfate (AES) 1.0-4.0 %, linear alkylbenzene sulfonate (LAS) 0.5-2.0 %; Polyoxyethylene octylphenol ether (OP-10) 0-6.0 %, alkyl polyglycoside (APG) 0-4.0 %, AEO (AEO-9) 0.5-2.0 %; Trolamine 2.5 %; Trisodium citrate 0.5-2.5 %, mandarin oil 1.0-3.0 %, surplus is a tap water.
The composition that road surface, above-mentioned cuisine variety street viscous crude dirt green cleaning agent can replace with by following mass percent constitutes: fatty alcohol polyoxyethylene ether sulfate 2.0-4.0 %, linear alkylbenzene sulfonate 0.5-1.5 %, polyoxyethylene octylphenol ether 0-6.0 %; Alkyl polyglycoside 0-4.0 %; AEO 0.5-1.5 %, trolamine 2.5 %, trisodium citrate 1.0-2.5 %; Mandarin oil 1.0-2.0 %, surplus is a tap water.
The composition that road surface, above-mentioned cuisine variety street viscous crude dirt green cleaning agent can replace with by following mass percent constitutes: fatty alcohol polyoxyethylene ether sulfate 4.0 %; Linear alkylbenzene sulfonate 1.0 %, alkyl polyglycoside 4.0 %, AEO 1.0 %; Trolamine 2.5 %; Trisodium citrate 2.0 %, mandarin oil 2.0 %, surplus is a tap water.
Road surface, above-mentioned cuisine variety street provided by the invention viscous crude dirt green cleaning agent, it is used to clean the road surface oil of viscous crude dirt, kitchen oil stain or the ordinary road on road surface, cuisine variety street.
Road surface, above-mentioned cuisine variety street provided by the invention viscous crude dirt green cleaning agent, it adopts the method for following steps to process:
(1) slowly fatty alcohol polyoxyethylene ether sulfate is joined in 60-65 ℃ the tap water, be stirred to whole dissolvings after, restir 20 min;
(2) keep 60-65 ℃ of temperature; Under continuously stirring, in the solution that step (1) obtains, add linear alkylbenzene sulfonate, polyoxyethylene octylphenol ether, alkyl polyglycoside, AEO and mandarin oil successively; Continue to stir 1-2 h, till the whole dissolvings of add material;
(3) solution that step (2) is obtained is cooled to≤40 ℃, add trolamine and trisodium citrate then successively, stir 1-2 h to institute add material all dissolving be even attitude, it is described clean-out system.
The preparation method of road surface, above-mentioned cuisine variety street provided by the invention viscous crude dirt green cleaning agent, the clean-out system of its preparation is used to clean the road surface oil of viscous crude dirt, kitchen oil stain or the ordinary road on road surface, cuisine variety street.
The present invention compared with prior art has following main advantage:
The present invention have prescription simply, do not fire not quick-fried, dissolving greasy dirt fast, strong detergency, environmental friendliness, stability and safety and preparation cost is low, do not corrode advantages such as being cleaned road surface.Avoid the use of big, the inflammable and explosive and deleterious organic solvent of volatility; And use from the maturate peel cold press of the red tangerine of rutaceae or some other allied species form, to the harmless mandarin oil of environment and HUMAN HEALTH as secondary solvent, it promptly can be made into the clean-out system that the dirty and kitchen oil stain of road pavement viscous crude etc. all has better cleaning performance after composite with proper amount of surfactant and water.Also avoiding the use of sodium hydroxide and water glass etc. has certain corrosive inorganic base substance, uses mutually environment amenable organic bases trolamine instead.
The present invention mainly is applicable near the viscous crude dirt on road surface, cuisine variety street, takes into account the cleaning of kitchen grease and other road surface oil.
Embodiment
Below in conjunction with embodiment the present invention is described further, but is not limited to following said content.
Embodiment 1: road surface, a kind of cuisine variety street viscous crude dirt green cleaning agent and preparation method thereof
The mass percent of this each component of clean-out system is: AES 3.0 %, LAS 1.5 %, OP-10 6.0 %, AEO-9 1.5 %, trolamine 2.5 %, trisodium citrate 2.5 %, mandarin oil 2.0 %, tap water 81.0 %.Wherein, AES and LAS are AS, and OP-10, APG and AEO-9 are nonionogenic tenside, have wetting, emulsification and cleaning function; Trolamine is mainly done the pH regulator agent; Trisodium citrate plays sequestering action; Mainly as secondary solvent, it obtains from the maturate peel cold press of the red tangerine of rutaceae or some other allied species mandarin oil, so harmless to environment and HUMAN HEALTH.Tensio-active agent and secondary solvent used in the present embodiment are commercial article.
The preparation technology of this prescription is:
(1) constantly stirs down slowly AES is joined in 60-65 ℃ the prescription reaction water gaging,, stir 20 min to all dissolvings;
(2) keep 60-65 ℃ of temperature, under continuously stirring, add LAS, OP-10, APG and AEO-9 tensio-active agent and mandarin oil secondary solvent successively, stir 1-2 h, till all dissolving;
(3) be cooled to 40 ℃ of next coming in order and add trolamine and trisodium citrate, it is even to sample to stir 1-2 h.
Making sample is light yellow transparent uniform solution, with reference to the TP of " liquid kitchen oil stain clean-out system national standard ", the detersive power of sample is made an experiment, and its detersive power reaches 95.6 %.
Embodiment 2: road surface, a kind of cuisine variety street viscous crude dirt green cleaning agent and preparation method thereof
The mass percent of this each component of clean-out system is: AES 4.0 %, LAS 1.0 %, APG 4.0 %, AEO-9 1.0 %, trolamine 2.5 %, trisodium citrate 2.0 %, mandarin oil 2.0 %, tap water 83.5 %.
The prescription production technique is with embodiment 1.Making sample is light yellow transparent settled solution, no demixing phenomenon.With reference to the TP of " liquid kitchen oil stain clean-out system national standard ", the detersive power of sample is made an experiment, its detersive power reaches 94.9 %.
Embodiment 3: road surface, a kind of cuisine variety street viscous crude dirt green cleaning agent and preparation method thereof
The mass percent of this each component of clean-out system is: AES 4.0 %, LAS 1.0 %, OP-10 6.0 %, AEO-9 1.5 %, trolamine 2.5 %, trisodium citrate 2.0 %, mandarin oil 2.0 %, tap water 81.0 %.
The prescription production technique is with embodiment 1.Making sample is the yellow transparent settled solution, no demixing phenomenon.With reference to the TP of " liquid kitchen oil stain clean-out system national standard ", the detersive power of sample is made an experiment, its detersive power reaches 92.3 %.
Embodiment 4: road surface, a kind of cuisine variety street viscous crude dirt green cleaning agent and preparation method thereof
The mass percent of this each component of clean-out system is: AES 2.0 %, LAS 2.0 %, OP-10 1.5%, APG 3.0 %, AEO-9 0.5 %, trolamine 2.5 %, trisodium citrate 2.5 %, mandarin oil 1.0 %, tap water 85.0 %.
The prescription production technique is with embodiment 1.Make sample for having a little white transparent settled solution, no demixing phenomenon.With reference to the TP of " liquid kitchen oil stain clean-out system national standard ", the detersive power of sample is made an experiment, its detersive power reaches 72.8 %.
Embodiment 5: road surface, a kind of cuisine variety street viscous crude dirt green cleaning agent and preparation method thereof
The mass percent of this each component of clean-out system is: AES 3.0 %, LAS 0.5 %, APG 4.0 %, AEO-9 0.5 %, trolamine 2.5 %, trisodium citrate 1.0 %, mandarin oil 1.0 %, tap water 87.5 %.
The prescription production technique is with embodiment 1.Make sample for having a little the yellow transparent settled solution, no demixing phenomenon.With reference to the TP of " liquid kitchen oil stain clean-out system national standard ", the detersive power of sample is made an experiment, its detersive power reaches 95.3 %.
Embodiment 6: road surface, a kind of cuisine variety street viscous crude dirt green cleaning agent and preparation method thereof
The mass percent of this each component of clean-out system is: AES 1.0 %, LAS 2.0 %, OP-10 3.0 %, APG 2.0 %, AEO-9 2.0 %, trolamine 2.5 %, trisodium citrate 0.5 %, mandarin oil 3.0 %, tap water 84.0 %.
The prescription production technique is with embodiment 1.Making sample is light yellow slightly turbid solution, no demixing phenomenon.With reference to the TP of " liquid kitchen oil stain clean-out system national standard ", the detersive power of sample is made an experiment, its detersive power reaches 90.3 %.
Embodiment 7: road surface, a kind of cuisine variety street viscous crude dirt green cleaning agent and preparation method thereof
The mass percent of this each component of clean-out system is: AES 2.0 %, LAS 0.5 %, OP-10 4.5 %, APG 1.0 %, AEO-9 0.8 %, trolamine 2.5 %, trisodium citrate 1.5 %, mandarin oil 1.5 %, tap water 85.7 %.
The prescription production technique is with embodiment 1.Make sample and be the transparent settled solution that slightly is white in color, no demixing phenomenon.With reference to the TP of " liquid kitchen oil stain clean-out system national standard ", the detersive power of sample is made an experiment, its detersive power reaches 71.9 %.
Further use clean-out system " brave and fierce Mr. " and the sample among the embodiment 1 ~ 7 to carry out the contrast experiment of outward appearance and detersive power in commercially available kitchen more.Commercially available clean-out system is a colourless transparent solution, and the bottom sinks after leaving standstill has a little throw out.With reference to the TP of " liquid kitchen oil stain clean-out system national standard ", the detersive power of sample is made an experiment, its detersive power is 87.5 %.
The clean-out system that the foregoing description 1-7 is prepared, it is used to clean the road surface oil of viscous crude dirt, kitchen oil stain or the ordinary road on road surface, cuisine variety street.
Embodiment 8: the method for use of road surface, a kind of cuisine variety street viscous crude dirt green cleaning agent
When the road surface oil of viscous crude dirt, kitchen oil stain or the ordinary road of cleaning the road surface, cuisine variety street, its method of use is: pour the clean-out system that makes into watering can, when cleaning area hour can be used the watering can of watering flowers; When cleaning area is big, preferably use the atomizer of spraying insecticide.Before using clean-out system, shake earlier watering can or atomizer fully.During use clean-out system directly is sprayed onto on the ground of grease spot, requires to cover fully road surface oil, soak 5-10 min, water sprinkles and washes then.If road surface viscous crude dirt is thicker, can repeats to spray the road surface and clean several times, until cleaning up.For stain, suggestion soak the back with harder brush (cleaning the brush of toilet like family expenses) scrub repeatedly several down, and then water cleans and gets final product.
Grease dirt cleaning agent suggestion consumption: per 4 ~ 6 m
2Spot is cleaned with the prepared clean-out system of 100 g.
When prepared clean-out system is used to remove oil smoke and kitchen grease, 1 to 5 times of dilutable water, concrete concentration is looked cleaning area and greasy dirt adhere firmly degree and is decided.With wiping clean with scrub-brush behind clean-out system sprinkling and wetting grease 10 ~ 15 min, use flushing with clean water then, reusable in case of necessity.
It is important to emphasize, the foregoing description only be for clearly the present invention is described and is done for example, and be not to the qualification fully of embodiment with the cleaning agent formula composition.The those of ordinary skill in affiliated field can also be made other multi-form change on the basis of above-mentioned explanation; Here can't also need not all embodiments are provided embodiment, but the conspicuous change of being amplified out thus still is in protection scope of the present invention.
The correlation data of the foregoing description 1 ~ 7 prepared cleaning agent formula composition and detersive power thereof and commercially available " brave and fierce Mr. " detersive power is seen table 1.Commercially available " brave and fierce Mr. " outward appearance is a water white transparency, and its composition and prescription thereof are unknown, and under equal experiment condition, the detersive power that is somebody's turn to do " brave and fierce Mr. " is 87.5%.
Subordinate list
Table 1 cleaning agent formula is formed and the detersive power data
| Form | Instance 1 | Instance 2 | Instance 3 | Instance 4 | Instance 5 | Instance 6 | Instance 7 |
| Fatty alcohol polyoxyethylene ether sulfate (AES) | 3.0 | 4.0 | 4.0 | 2.0 | 3.0 | 1.0 | 2.0 |
| Linear alkylbenzene sulfonate (LAS) | 1.5 | 1.0 | 1.0 | 2.0 | 0.5 | 2.0 | 0.5 |
| Polyoxyethylene octylphenol ether (OP-10) | 6.0 | 0 | 6.0 | 1.5 | 0 | 3.0 | 4.5 |
| Alkyl polyglycoside (APG) | 0 | 4.0 | 0 | 3.0 | 4.0 | 2.0 | 1.0 |
| AEO (AEO-9) | 1.5 | 1.0 | 1.5 | 0.5 | 0.5 | 2.0 | 0.8 |
| Trolamine | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 |
| Trisodium citrate | 2.5 | 2.0 | 2.0 | 2.5 | 1.0 | 0.5 | 1.5 |
| Mandarin oil | 2.0 | 2.0 | 2.0 | 1.0 | 1.0 | 3.0 | 1.5 |
| Tap water | 81.0 | 83.5 | 81.0 | 85.0 | 87.5 | 84.0 | 85.7 |
| Outward appearance | Light yellow transparent | Light yellow transparent | Yellow transparent | It is transparent to have a little white | Have a little yellow transparent | Light yellow slightly muddy | It is transparent to have a little white |
| Detersive power (%) | 95.6 | 94.9 | 92.3 | 72.8 | 95.3 | 90.3 | 71.9 |
Claims (6)
1. road surface, cuisine variety street viscous crude dirt green cleaning agent is characterized in that said clean-out system is made up of the composition of following mass percent: fatty alcohol polyoxyethylene ether sulfate 1.0-4.0 %, linear alkylbenzene sulfonate 0.5-2.0 %; Polyoxyethylene octylphenol ether 0-6.0 %, alkyl polyglycoside 0-4.0 %, AEO 0.5-2.0 %; Trolamine 2.5 %; Trisodium citrate 0.5-2.5 %, mandarin oil 1.0-3.0 %, surplus is a tap water.
2. according to road surface, the said cuisine variety street of claim 1 viscous crude dirt green cleaning agent, it is characterized in that the composition that said clean-out system replaces with by following mass percent is constituted: fatty alcohol polyoxyethylene ether sulfate 2.0-4.0 %, linear alkylbenzene sulfonate 0.5-1.5 %; Polyoxyethylene octylphenol ether 0-6.0 %, alkyl polyglycoside 0-4.0 %, AEO 0.5-1.5 %; Trolamine 2.5 %; Trisodium citrate 1.0-2.5 %, mandarin oil 1.0-2.0 %, surplus is a tap water.
3. according to road surface, the said cuisine variety street of claim 2 viscous crude dirt green cleaning agent, it is characterized in that said clean-out system is made up of the composition of following mass percent: fatty alcohol polyoxyethylene ether sulfate 4.0 %, linear alkylbenzene sulfonate 1.0 %; Alkyl polyglycoside 4.0 %; AEO 1.0 %, trolamine 2.5 %, trisodium citrate 2.0 %; Mandarin oil 2.0 %, surplus is a tap water.
4. the application of road surface, the said cuisine variety street of arbitrary claim viscous crude dirt green cleaning agent in claim 1 to the claim 3 is characterized in that being used to cleaning the road surface oil of viscous crude dirt, kitchen oil stain or the ordinary road on road surface, cuisine variety street.
5. the preparation method of road surface, the said cuisine variety street of arbitrary claim viscous crude dirt green cleaning agent in the claim 1 to 3 is characterized in that adopting the method for following steps:
(1) slowly fatty alcohol polyoxyethylene ether sulfate is joined in 60-65 ℃ the tap water, be stirred to whole dissolvings after, restir 20 min;
(2) keep 60-65 ℃ of temperature; Under continuously stirring, in the solution that step (1) obtains, add linear alkylbenzene sulfonate, polyoxyethylene octylphenol ether, alkyl polyglycoside, AEO and mandarin oil successively; Continue to stir 1-2 h, till the whole dissolvings of add material;
(3) solution that step (2) is obtained is cooled to≤40 ℃, add trolamine and trisodium citrate then successively, stir 1-2 h to institute add material all dissolving be even attitude, it is described clean-out system.
6. application by the said clean-out system of claim 5 preparation is characterized in that being used to cleaning the road surface oil of viscous crude dirt, kitchen oil stain or the ordinary road on road surface, cuisine variety street.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2012101898605A CN102703244B (en) | 2012-06-11 | 2012-06-11 | Environment-friendly cleanser for thick oil scale on pavement of food street and preparation method as well as application thereof |
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| CN2012101898605A CN102703244B (en) | 2012-06-11 | 2012-06-11 | Environment-friendly cleanser for thick oil scale on pavement of food street and preparation method as well as application thereof |
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Cited By (5)
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| CN103045401A (en) * | 2013-01-19 | 2013-04-17 | 重庆暄洁环保产业（集团）股份有限公司 | Water-base oil dirt cleaning agent and preparation method thereof |
| CN103242971A (en) * | 2013-05-03 | 2013-08-14 | 武汉理工大学 | Green efficient thick oil dirt nearly-neutral water-based cleaning agent without adding any acid-base |
| CN103320238A (en) * | 2013-07-02 | 2013-09-25 | 武汉理工大学 | Water-based cleaning agent with weak acidity for removing thick oil dirt, and preparation method thereof |
| CN111139145A (en) * | 2019-12-26 | 2020-05-12 | 仁创生态环保科技股份有限公司 | Oil stain cleaning agent and preparation method and application thereof |
| CN114891572A (en) * | 2022-04-28 | 2022-08-12 | 广东丽臣奥威实业有限公司 | Concentrated surfactant composition and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103045401A (en) * | 2013-01-19 | 2013-04-17 | 重庆暄洁环保产业（集团）股份有限公司 | Water-base oil dirt cleaning agent and preparation method thereof |
| CN103045401B (en) * | 2013-01-19 | 2014-12-24 | 重庆新安洁景观园林环保股份有限公司 | Water-base oil dirt cleaning agent and preparation method thereof |
| CN103242971A (en) * | 2013-05-03 | 2013-08-14 | 武汉理工大学 | Green efficient thick oil dirt nearly-neutral water-based cleaning agent without adding any acid-base |
| CN103242971B (en) * | 2013-05-03 | 2015-02-04 | 武汉理工大学 | Green efficient thick oil dirt nearly-neutral water-based cleaning agent without adding any acid-base |
| CN103320238A (en) * | 2013-07-02 | 2013-09-25 | 武汉理工大学 | Water-based cleaning agent with weak acidity for removing thick oil dirt, and preparation method thereof |
| CN111139145A (en) * | 2019-12-26 | 2020-05-12 | 仁创生态环保科技股份有限公司 | Oil stain cleaning agent and preparation method and application thereof |
| CN114891572A (en) * | 2022-04-28 | 2022-08-12 | 广东丽臣奥威实业有限公司 | Concentrated surfactant composition and preparation method thereof |
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