CN103966031A - Environment-friendly leather cleaning care agent and preparation method thereof - Google Patents
Environment-friendly leather cleaning care agent and preparation method thereof Download PDFInfo
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- CN103966031A CN103966031A CN201410238209.1A CN201410238209A CN103966031A CN 103966031 A CN103966031 A CN 103966031A CN 201410238209 A CN201410238209 A CN 201410238209A CN 103966031 A CN103966031 A CN 103966031A
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Abstract
The invention relates to an environment-friendly leather cleaning care agent and a preparation method thereof. Leather cleaning supplies sold at present markets are single in function and finite in detergency, easily cause leather fiber hardening and hard handfeel, and contain components which easily pollute the environment. The environment-friendly leather cleaning care agent is prepared by mixing fatty alcohol-polyoxyethylene ether, alkyl glycoside, silicone latex, silicon oil emulsion, sodium citrate, glycerin, Kathon, essence and water, wherein the fatty alcohol-polyoxyethylene ether serving as an anionic surfactant and the alkyl glycoside serving as a nonionic surfactant are used as decontamination components. The environment-friendly leather cleaning care agent disclosed by the invention is anti-fouling and waterproof, enables leather to be soft and smooth, assists in resisting leather ageing and surface drying and cracking, and has good biodegradability and a good moisturizing effect; the leather cleaning care agent does not contain organic solvents, so that the production process is environment-friendly; the leather cleaning care agent has a mildew-proof and bacteriostatic effect.
Description
Technical field
the invention belongs to leather cleaning nursing technique field, be specifically related to a kind of environmental-friendly leather cleaning-nursing agent and preparation method thereof.
Background technology
Leatherware is the conventional life product that a kind of consumers in general of being subject to like always, such as corium clothes, leather shoes, sofa, automobile cushion, and the article, particularly corium clothes such as belt, leather gloves, not only fashion is endurable, simultaneously again can warming.But what leatherware adopted is animal skin, as animal skin such as pigskin, ox-hide, sheepskin, snakeskin, fish-skins, process through special process, be different from common textiles etc., it cleans with nursing all will adopt special cleaning-nursing agent.The leather cleaning articles for use of selling in the market, the defect of its formula ubiquity function singleness, clean-out system only has soil-removing action, and detersive power is limited, easily causes that leather fiber hardens, feel hardening; What have also contains organic solvent, very easily causes leather to fade, and often occurs splitting the phenomenons such as slurry, broken face; Or lay particular stress on the upper light effect to leather, contain more grease and wax composition in formula, usually add more organic solvent for dissolving these compositions, in use, easily human body is damaged, stain removal bactericidal effect is general simultaneously, complex manufacturing; Also in some formula, contain the poor nonylphenol class material of biological degradability, even also have the use of plumbous compound, the composition that environment is easily polluted.
Summary of the invention
The object of this invention is to provide a kind of environmental-friendly leather cleaning-nursing agent and preparation method thereof, have leather cleaning and two kinds of functions of nursing concurrently, and use safety, environmental protection.
The technical solution adopted in the present invention is:
The agent of a kind of environmental-friendly leather cleaning-nursing, is characterized in that:
Component by following mass percent is made:
Fatty alcohol-polyoxyethylene ether 1-3%;
Alkyl glycoside 1-3%;
Silicone latex 4-12%;
Silicone oil emulsion 5-12%;
Trisodium Citrate 0.5-2%;
Glycerine 1-5%;
Mould inhibitor 0.1-0.2%;
KF88 0.1-0.2%;
Essence 0.05-0.5%;
Water surplus.
Described fatty alcohol-polyoxyethylene ether is the ethoxylate of straight or branched fatty alcohol, and carbon chain lengths is C
8-14, the average adduct number of EO is 3-10.
Described alkyl glycoside is selected from octyl glucoside, Plantacare 818, lauryl glucoside, myristyl glucoside.
Described silicone latex is the ethylize mixture of three decyl alcohol and decamethylcyclopentaandoxane of the trolamine dodecylbenzene sulfonate, octamethylcyclotetrasiloxane, the polyoxy that mix with arbitrary proportion.
Described silicone oil emulsion is the polydimethylsiloxane containing aminoalkyl, and commodity are called DOW CORNING 5-7070, DOW CORNING 2-8194, TEGO polish ADDITIV ACS, WACKER HC303 or WACKER BELSIL ADM8020VP.
Described mould inhibitor is the ethylene glycol solution of 2-n-octyl group-4-isothiazoline-3-ketone, blending ratio 1:(1-2).
A preparation method for environmental-friendly leather cleaning-nursing agent, is characterized in that:
Realized by following steps:
Step 1: prepare respectively raw material according to following proportioning:
Fatty alcohol-polyoxyethylene ether 1-3%;
Alkyl glycoside 1-3%;
Silicone latex 4-12%;
Silicone oil emulsion 5-12%;
Trisodium Citrate 0.5-2%;
Glycerine 1-5%;
Mould inhibitor 0.1-0.2%;
KF88 0.1-0.2%;
Essence 0.05-0.5%;
Water surplus;
Step 2: heat water to 50 DEG C, add fatty alcohol-polyoxyethylene ether and alkyl glycoside, mix to and be uniformly dissolved, then add silicone latex, silicone oil emulsion and glycerine, then add Trisodium Citrate, mix;
Step 3: reduce below temperature to 40 DEG C, add mould inhibitor, KF88 and essence, be uniformly mixed.
Described fatty alcohol-polyoxyethylene ether is the ethoxylate of straight or branched fatty alcohol, and carbon chain lengths is C
8-14, the average adduct number of EO is 3-10;
Described alkyl glycoside is selected from octyl glucoside, Plantacare 818, lauryl glucoside, myristyl glucoside;
Described silicone latex is the ethylize mixture of three decyl alcohol and decamethylcyclopentaandoxane of the trolamine dodecylbenzene sulfonate, octamethylcyclotetrasiloxane, the polyoxy that mix with arbitrary proportion;
Described silicone oil emulsion is the polydimethylsiloxane containing aminoalkyl, and commodity are called DOW CORNING 5-7070, DOW CORNING 2-8194, TEGO polish ADDITIV ACS, WACKER HC303 or WACKER BELSIL ADM8020VP;
Described mould inhibitor is the ethylene glycol solution of 2-n-octyl group-4-isothiazoline-3-ketone, blending ratio 1:(1-2).
The present invention has the following advantages:
Compared with prior art leather cleaning nursing agent of the present invention has the following advantages:
One, select silicone emulsion for nursing composition, make leather polishing as newly, and effective antifouling waterproof, make leather soft smooth, help the aging and surface drying be full of cracks of antagonism leather;
Two, the stain remover adopting is alkyl glycoside, is a kind of biomass natural surface active agent, belongs to nontoxic or low toxicity material, and biodegradability is good, has good wetting effect, extremely low surface tension, excellent dissolving greasy dirt effect;
Three, not containing organic solvent, free from extraneous odour, harmless, production technique environmental protection, operational safety is simple;
Four, there is fungus-resistant effect.
Embodiment
Below in conjunction with embodiment, the present invention will be described in detail.
The preparation method of a kind of environmental-friendly leather cleaning-nursing agent involved in the present invention, is realized by following steps:
Step 1: prepare respectively raw material according to following proportioning:
Fatty alcohol-polyoxyethylene ether 1-3%;
Alkyl glycoside 1-3%;
Silicone latex 4-12%;
Silicone oil emulsion 5-12%;
Trisodium Citrate 0.5-2%;
Glycerine 1-5%;
Mould inhibitor 0.1-0.2%;
KF88 0.1-0.2%;
Essence 0.05-0.5%;
Water surplus;
Step 2: heat water to 50 DEG C, add fatty alcohol-polyoxyethylene ether and alkyl glycoside, mix to and be uniformly dissolved, then add silicone latex, silicone oil emulsion and glycerine, then add Trisodium Citrate, mix;
Step 3: reduce below temperature to 40 DEG C, add mould inhibitor, KF88 and essence, be uniformly mixed.
Described fatty alcohol-polyoxyethylene ether is the ethoxylate of straight or branched fatty alcohol, and carbon chain lengths is C
8-14, the average adduct number of EO is 3-10;
Described alkyl glycoside is selected from octyl glucoside, Plantacare 818, lauryl glucoside, myristyl glucoside;
Described silicone latex is the ethylize mixture of three decyl alcohol and decamethylcyclopentaandoxane of the trolamine dodecylbenzene sulfonate, octamethylcyclotetrasiloxane, the polyoxy that mix with arbitrary proportion;
Described silicone oil emulsion is the polydimethylsiloxane containing aminoalkyl, and commodity are called DOW CORNING 5-7070, DOW CORNING 2-8194, TEGO polish ADDITIV ACS, WACKER HC303 or WACKER BELSIL ADM8020VP;
Described mould inhibitor is the ethylene glycol solution of 2-n-octyl group-4-isothiazoline-3-ketone, blending ratio 1:(1-2).(n represents n-octyl)
Embodiment 1:
Step 1: prepare respectively raw material according to following proportioning:
Fatty alcohol-polyoxyethylene ether 1%;
Alkyl glycoside 1%;
Silicone latex 4%;
Silicone oil emulsion 5%;
Trisodium Citrate 0.5%;
Glycerine 1%;
Mould inhibitor 0.1%;
KF88 0.1%;
Essence 0.05%;
Water surplus;
Step 2: heat water to 50 DEG C, add fatty alcohol-polyoxyethylene ether and alkyl glycoside, mix to and be uniformly dissolved, then add silicone latex, silicone oil emulsion and glycerine, then add Trisodium Citrate, mix;
Step 3: reduce below temperature to 40 DEG C, add mould inhibitor, KF88 and essence, be uniformly mixed.
Described fatty alcohol-polyoxyethylene ether is the ethoxylate of straight or branched fatty alcohol, and carbon chain lengths is C
8-14, the average adduct number of EO is 3-10;
Described alkyl glycoside is selected from octyl glucoside, Plantacare 818;
Described silicone latex is the ethylize mixture of three decyl alcohol and decamethylcyclopentaandoxane of the trolamine dodecylbenzene sulfonate, octamethylcyclotetrasiloxane, the polyoxy that mix with the mass ratio of 1:1:1:1;
Described silicone oil emulsion is the polydimethylsiloxane containing aminoalkyl, commodity DOW CORNING 5-7070 by name or DOW CORNING 2-8194;
Described mould inhibitor is the ethylene glycol solution of 2-n-octyl group-4-isothiazoline-3-ketone, blending ratio 1:1.(n represents n-octyl)
Embodiment 2:
Step 1: prepare respectively raw material according to following proportioning:
Fatty alcohol-polyoxyethylene ether 2%;
Alkyl glycoside 2%;
Silicone latex 8%;
Silicone oil emulsion 8%;
Trisodium Citrate 1%;
Glycerine 3%;
Mould inhibitor 0.15%;
KF88 0.15%;
Essence 0.3%;
Water surplus;
Step 2: heat water to 50 DEG C, add fatty alcohol-polyoxyethylene ether and alkyl glycoside, mix to and be uniformly dissolved, then add silicone latex, silicone oil emulsion and glycerine, then add Trisodium Citrate, mix;
Step 3: reduce below temperature to 40 DEG C, add mould inhibitor, KF88 and essence, be uniformly mixed.
Described fatty alcohol-polyoxyethylene ether is the ethoxylate of straight or branched fatty alcohol, and carbon chain lengths is C
8-14, the average adduct number of EO is 3-10;
Described alkyl glycoside is selected from Plantacare 818, lauryl glucoside;
Described silicone latex is the ethylize mixture of three decyl alcohol and decamethylcyclopentaandoxane of the trolamine dodecylbenzene sulfonate, octamethylcyclotetrasiloxane, the polyoxy that mix with the mass ratio of 1:1:1:1;
Described silicone oil emulsion is the polydimethylsiloxane containing aminoalkyl, commodity TEGO polish ADDITIV ACS by name or WACKER HC30;
Described mould inhibitor is the ethylene glycol solution of 2-n-octyl group-4-isothiazoline-3-ketone, blending ratio 1:1.(n represents n-octyl)
Embodiment 3:
Step 1: prepare respectively raw material according to following proportioning:
Fatty alcohol-polyoxyethylene ether 3%;
Alkyl glycoside 3%;
Silicone latex 12%;
Silicone oil emulsion 12%;
Trisodium Citrate 2%;
Glycerine 5%;
Mould inhibitor 0.2%;
KF88 0.2%;
Essence 0.5%;
Water surplus;
Step 2: heat water to 50 DEG C, add fatty alcohol-polyoxyethylene ether and alkyl glycoside, mix to and be uniformly dissolved, then add silicone latex, silicone oil emulsion and glycerine, then add Trisodium Citrate, mix;
Step 3: reduce below temperature to 40 DEG C, add mould inhibitor, KF88 and essence, be uniformly mixed.
Described fatty alcohol-polyoxyethylene ether is the ethoxylate of straight or branched fatty alcohol, and carbon chain lengths is C
8-14, the average adduct number of EO is 3-10;
Described alkyl glycoside is selected from lauryl glucoside, myristyl glucoside;
Described silicone latex is the ethylize mixture of three decyl alcohol and decamethylcyclopentaandoxane of the trolamine dodecylbenzene sulfonate, octamethylcyclotetrasiloxane, the polyoxy that mix with the mass ratio of 1:1:1:1;
Described silicone oil emulsion is the polydimethylsiloxane containing aminoalkyl, commodity WACKER HC303 by name or WACKER BELSIL ADM8020VP;
Described mould inhibitor is the ethylene glycol solution of 2-n-octyl group-4-isothiazoline-3-ketone, blending ratio 1:2.(n represents n-octyl)
Be below the performance test explanation of cleaning-nursing agent involved in the present invention:
Experiment 1:
Test this contrivance and the commercial product performance comparison aspect glossiness and feel.
1) the black ox-hide of buying is cleaned up with 95% ethanol, dry, be divided into grid of the same area stand-by;
2) contrivance and commercial product are smeared respectively evenly in different grid ox-hides surface, 10 people evaluate group glossiness and the feel on each ox-hide grid surface are given a mark.
Standards of grading: 1-10 divides, 1 be divided into minimum, 10 be divided into the highest.The blank ox-hide grid glossiness of not smearing cleaning-nursing agent is 1 point, and feel is 1 point.
As follows by the 10 people mean value evaluation result of giving a mark:
Experiment 2:
Test this contrivance and commercial product in the contrast to coloured leather fadedness energy.
Contrivance and commercial product are embrocated respectively in coloured leather surface with absorbent cotton, wiping 10 times, observes dyeing situation on absorbent cotton, as following table:
It is cited that content of the present invention is not limited to embodiment, and the conversion of any equivalence that those of ordinary skill in the art take technical solution of the present invention by reading specification sheets of the present invention, is claim of the present invention and contains.
Claims (8)
1. an environmental-friendly leather cleaning-nursing agent, is characterized in that:
Component by following mass percent is made:
Fatty alcohol-polyoxyethylene ether 1-3%;
Alkyl glycoside 1-3%;
Silicone latex 4-12%;
Silicone oil emulsion 5-12%;
Trisodium Citrate 0.5-2%;
Glycerine 1-5%;
Mould inhibitor 0.1-0.2%;
KF88 0.1-0.2%;
Essence 0.05-0.5%;
Water surplus.
2. a kind of environmental-friendly leather cleaning-nursing according to claim 1 agent, is characterized in that:
Described fatty alcohol-polyoxyethylene ether is the ethoxylate of straight or branched fatty alcohol, and carbon chain lengths is C
8-14, the average adduct number of EO is 3-10.
3. a kind of environmental-friendly leather cleaning-nursing according to claim 2 agent, is characterized in that:
Described alkyl glycoside is selected from octyl glucoside, Plantacare 818, lauryl glucoside, myristyl glucoside.
4. a kind of environmental-friendly leather cleaning-nursing according to claim 3 agent, is characterized in that:
Described silicone latex is the ethylize mixture of three decyl alcohol and decamethylcyclopentaandoxane of the trolamine dodecylbenzene sulfonate, octamethylcyclotetrasiloxane, the polyoxy that mix with arbitrary proportion.
5. a kind of environmental-friendly leather cleaning-nursing according to claim 4 agent, is characterized in that:
Described silicone oil emulsion is the polydimethylsiloxane containing aminoalkyl, and commodity are called DOW CORNING 5-7070, DOW CORNING 2-8194, TEGO polish ADDITIV ACS, WACKER HC303 or WACKER BELSIL ADM8020VP.
6. a kind of environmental-friendly leather cleaning-nursing according to claim 5 agent, is characterized in that:
Described mould inhibitor is the ethylene glycol solution of 2-n-octyl group-4-isothiazoline-3-ketone, blending ratio 1:(1-2).
7. a preparation method for environmental-friendly leather cleaning-nursing agent, is characterized in that:
Realized by following steps:
Step 1: prepare respectively raw material according to following proportioning:
Fatty alcohol-polyoxyethylene ether 1-3%;
Alkyl glycoside 1-3%;
Silicone latex 4-12%;
Silicone oil emulsion 5-12%;
Trisodium Citrate 0.5-2%;
Glycerine 1-5%;
Mould inhibitor 0.1-0.2%;
KF88 0.1-0.2%;
Essence 0.05-0.5%;
Water surplus;
Step 2: heat water to 50 DEG C, add fatty alcohol-polyoxyethylene ether and alkyl glycoside, mix to and be uniformly dissolved, then add silicone latex, silicone oil emulsion and glycerine, then add Trisodium Citrate, mix;
Step 3: reduce below temperature to 40 DEG C, add mould inhibitor, KF88 and essence, be uniformly mixed.
8. the preparation method of a kind of environmental-friendly leather cleaning-nursing according to claim 7 agent, is characterized in that:
Described fatty alcohol-polyoxyethylene ether is the ethoxylate of straight or branched fatty alcohol, and carbon chain lengths is C
8-14, the average adduct number of EO is 3-10;
Described alkyl glycoside is selected from octyl glucoside, Plantacare 818, lauryl glucoside, myristyl glucoside;
Described silicone latex is the ethylize mixture of three decyl alcohol and decamethylcyclopentaandoxane of the trolamine dodecylbenzene sulfonate, octamethylcyclotetrasiloxane, the polyoxy that mix with arbitrary proportion;
Described silicone oil emulsion is the polydimethylsiloxane containing aminoalkyl, and commodity are called DOW CORNING 5-7070, DOW CORNING 2-8194, TEGO polish ADDITIV ACS, WACKER HC303 or WACKER BELSIL ADM8020VP;
Described mould inhibitor is the ethylene glycol solution of 2-n-octyl group-4-isothiazoline-3-ketone, blending ratio 1:(1-2).
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| CN104358149A (en) * | 2014-10-25 | 2015-02-18 | 合肥市安山涂层织物有限公司 | Rapid moistening and diffusing synthetic leather penetrant and preparing method thereof |
| CN104531914A (en) * | 2014-12-17 | 2015-04-22 | 广东菲安妮皮具股份有限公司 | Leather softening agent |
| CN104911041A (en) * | 2015-07-08 | 2015-09-16 | 姚雳 | Cleaning agent for decorative material of automotive upholstery leather product |
| CN105296198A (en) * | 2015-09-29 | 2016-02-03 | 崔晓雪 | Environment-friendly repair type shoe washing solution and preparation method thereof |
| CN105349274A (en) * | 2015-10-30 | 2016-02-24 | 明光市良宇家俬有限公司 | Leather sofa detergent for improving softness |
| CN105441202A (en) * | 2015-12-26 | 2016-03-30 | 中国船舶重工集团公司第七一八研究所 | Nano-emulsion composition for leather cleaning care and preparation method thereof |
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| CN104358149A (en) * | 2014-10-25 | 2015-02-18 | 合肥市安山涂层织物有限公司 | Rapid moistening and diffusing synthetic leather penetrant and preparing method thereof |
| CN104531914B (en) * | 2014-12-17 | 2018-01-16 | 广东菲安妮皮具股份有限公司 | A kind of bating agent |
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| CN107690493B (en) * | 2015-05-18 | 2020-11-06 | 尼克瓦格斯有限公司 | Cloth and fabric treatment method |
| CN107690493A (en) * | 2015-05-18 | 2018-02-13 | 尼克瓦格斯有限公司 | The processing method of cloth and fabric |
| CN104911041A (en) * | 2015-07-08 | 2015-09-16 | 姚雳 | Cleaning agent for decorative material of automotive upholstery leather product |
| CN105296198A (en) * | 2015-09-29 | 2016-02-03 | 崔晓雪 | Environment-friendly repair type shoe washing solution and preparation method thereof |
| CN105349274A (en) * | 2015-10-30 | 2016-02-24 | 明光市良宇家俬有限公司 | Leather sofa detergent for improving softness |
| CN105441202A (en) * | 2015-12-26 | 2016-03-30 | 中国船舶重工集团公司第七一八研究所 | Nano-emulsion composition for leather cleaning care and preparation method thereof |
| CN105441202B (en) * | 2015-12-26 | 2019-04-16 | 中国船舶重工集团公司第七一八研究所 | A kind of leather cleaning nursing nano emulsion composition and preparation method thereof |
| CN106434040A (en) * | 2016-09-27 | 2017-02-22 | 枣阳市华威硅氟材料有限公司 | Flexible leather detergent containing hydroxyl silicone oil |
| CN106520395A (en) * | 2016-10-14 | 2017-03-22 | 无锡市华诚印染剂厂 | Environment-friendly water soluble detergent |
| CN110305996A (en) * | 2018-04-04 | 2019-10-08 | 徐雄剑 | Leather care products |
| CN110305996B (en) * | 2018-04-04 | 2022-02-01 | 广州卡士德汽车用品有限公司 | Leather care agent |
| CN108728256A (en) * | 2018-07-03 | 2018-11-02 | 阜南县富昌恒业工艺品有限公司 | A kind of Wood craft surface cleaning agent |
| CN109402306A (en) * | 2018-11-19 | 2019-03-01 | 张昌盛 | Animal hide protective agent and preparation method thereof |
| CN109402306B (en) * | 2018-11-19 | 2021-02-12 | 张昌盛 | Animal skin protective agent and preparation method thereof |
| CN111020070A (en) * | 2019-12-20 | 2020-04-17 | 佛山科学技术学院 | Suede leather surface waterproof and dustproof agent |
| CN112662486A (en) * | 2020-12-30 | 2021-04-16 | 北京绿伞化学股份有限公司 | Solvent-free water-based fire-fighting boot ultrasonic cleaning agent and preparation method and application thereof |
| CN115109873A (en) * | 2022-02-28 | 2022-09-27 | 福建省永建皮革科技股份有限公司 | Softening agent and method for preparing leather with high softness by using same |
| CN115109873B (en) * | 2022-02-28 | 2024-02-27 | 福建省永建皮革科技股份有限公司 | Softening agent and method for preparing leather with high softness by using same |
| CN115197787A (en) * | 2022-07-22 | 2022-10-18 | 广东红日星实业有限公司 | Cleaning agent and preparation method and application thereof |
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Application publication date: 20140806 |