CN115197787A - Cleaning agent and preparation method and application thereof - Google Patents

Cleaning agent and preparation method and application thereof Download PDF

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Publication number
CN115197787A
CN115197787A CN202210870942.XA CN202210870942A CN115197787A CN 115197787 A CN115197787 A CN 115197787A CN 202210870942 A CN202210870942 A CN 202210870942A CN 115197787 A CN115197787 A CN 115197787A
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Prior art keywords
cleaning agent
parts
cleaning
polydimethylsiloxane
agent according
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CN202210870942.XA
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CN115197787B (en
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陈腾飞
熊炳威
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Guangdong Redsunstar Industry Co ltd
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Guangdong Redsunstar Industry Co ltd
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/662Carbohydrates or derivatives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/02Cleaning by the force of jets or sprays
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2093Esters; Carbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43Solvents

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a cleaning agent and a preparation method and application thereof, wherein the cleaning agent comprises the following raw materials in parts by weight: 5-16 parts of myristyl glucoside, 0-5 parts of soybean oil methyl ester and 0.1-1.5 parts of polydimethylsiloxane. The cleaning agent provided by the invention has the characteristics of high cleaning efficiency and good effect on dirt and the like on vehicles, and has 6H antirust effect on deoiled chains.

Description

Cleaning agent and preparation method and application thereof
Technical Field
The invention belongs to the technical field of sports equipment cleaning, and particularly relates to a cleaning agent, and a preparation method and application thereof.
Background
The chain is an important component of a vehicle, the cleanliness of the chain has a great influence on the power of the vehicle, and various tests on the chain and the cleanliness of the chain in a bicycle show that under the output power of 250 watts, the unclean chain can cause the average loss of the power of the bicycle to be 1-2%, meanwhile, the more dirty the chain is, the greater the loss of the power output is, and under some conditions, one chain which is full of mud can possibly take away 3-5% of the total power output. More importantly, the bicycle chain also meanders through a series of components of the overall drive train, including the sprocket plates, chain guards, cassette sprockets and the unclean chain of the derailleur pulley, which not only wear the power readings, but also damage the drive train.
In view of the above situation, in the prior art, the cleaning of the chain needs to be carried out at a temperature of 80-90 ℃ and also needs to be assisted by ultrasonic waves. However, this method is not suitable for on-line cleaning during riding, and cannot overcome the instant rust return phenomenon of the chain in rainy days.
Therefore, the development of a cleaning agent which is suitable for being used in the riding process and has the advantages of high-efficiency oil sludge and dirt removal and good antirust performance is urgent.
Disclosure of Invention
The present invention is directed to solving at least one of the problems of the prior art described above. Therefore, the cleaning agent provided by the invention has the characteristics of short cleaning time, good effect and 6H antirust effect on the deoiled chain for dirt and the like on a vehicle.
The invention also provides a preparation method of the cleaning agent.
The invention also provides the application of the cleaning agent in vehicle cleaning.
According to one aspect of the invention, the cleaning agent is provided, and the preparation raw materials comprise the following components in parts by weight: 5-16 parts of myristyl glucoside, 0-5 parts of soybean oil methyl ester and 0.1-1.5 parts of polydimethylsiloxane.
According to a preferred embodiment of the present invention, at least the following advantages are provided:
1. the myristyl glucoside adopted in the invention is a mild cleaning active substance, and can absorb and dissolve oil stains in water.
2. The soybean oil methyl ester has low cost, easy degradation and high dissolving capacity, is an environment-friendly solvent with high flash point (360 ℃) and high boiling point (460 ℃), can replace the traditional halohydrocarbon, has the advantages of low VOC, no damage to the ozone layer and the like, is a solvent with excellent comprehensive performance, and has obvious effects of dissolving oil stains and cleaning carbon black, dust and solid particles.
3. The polydimethylsiloxane is a hydrophobic organic silicon material, can generate a hydrophobic film layer after the chain is cleaned, has obvious brightening and lubricating effects, has waterproof and wear-resistant effects, and can effectively prevent the chain from rusting for a short time.
In some embodiments of the present invention, the raw materials for preparing the cleaning agent comprise, by weight: 2 to 4 parts of soybean oil methyl ester and 0.5 to 1.5 parts of polydimethylsiloxane.
In some preferred embodiments of the present invention, the preparation raw materials of the cleaning agent comprise, by weight: 8 to 12 parts of myristyl glucoside and 0.5 to 1.5 parts of polydimethylsiloxane.
Under the emulsification, penetration and solubilization action of the surface activity of the myristyl glucoside, and the strong penetration and dissolution of a soybean oil methyl ester solvent, the cleaning agent system can thoroughly remove dirt such as petroleum dirt, clay, soil, road dirt, white stripes and the like at a very high speed, and cannot damage high-end surfaces, plastics or rubber. When the chain is cleaned, the polydimethylsiloxane forms a film layer which has the effects of brightness, lubrication, water resistance and wear resistance on the metal surfaces of the chain and the like, and can effectively prevent the chain from rusting back for a short time.
In some embodiments of the present invention, a cleaning agent is provided, which comprises the following raw materials by weight: 5-16 parts of myristyl glucoside and 1-1.5 parts of polydimethylsiloxane.
In some embodiments of the present invention, a cleaning agent is provided, which comprises the following raw materials by weight: 14-16 parts of myristyl glucoside and 4-5 parts of soybean oil methyl ester.
In some preferred embodiments of the present invention, the preparation of the raw materials comprises, in parts by weight: 14-16 parts of myristyl glucoside and 4-5 parts of soybean oil methyl ester.
In some embodiments of the present invention, the raw material for preparing the cleaning agent further comprises water.
The second aspect of the present invention provides a method for preparing the above cleaning agent, comprising: mixing the myristyl glucoside, the methyl ester of soybean oil, and the polydimethylsiloxane.
In some preferred embodiments of the invention, the stirring speed is 45 to 80r/min.
In some preferred embodiments of the present invention, the preparation method of the cleaning agent comprises: the myristyl glucoside, the methyl ester of soybean oil, and polydimethylsiloxane were sequentially added to water to prepare an aqueous dispersion.
In some preferred embodiments of the invention, the moisture is added twice.
In some preferred embodiments of the invention, the first addition is half of the water added prior to the addition of myristyl glucoside.
In some preferred embodiments of the invention, the two additions, the second addition being the addition of the remaining water after the addition of the polydimethylsiloxane.
In some embodiments of the invention, the temperature of the mixing is 15 to 40 ℃.
In some preferred embodiments of the invention, the temperature of the mixing is 25 to 35 ℃.
In some embodiments of the invention, the time of mixing is 15-50min.
In some preferred embodiments of the present invention, the mixing time is 25 to 35min.
A third aspect of the invention proposes the use of the above-mentioned cleaning agent for cleaning vehicles.
In some embodiments of the invention, the vehicle comprises: one of a motorcycle, sports car, recreational vehicle, scooter, truck, and automobile.
In some embodiments of the invention, the vehicle cleaning comprises cleaning of a vehicle chain.
The cleaning agent can remove heavy petroleum dirt, clay, mud, road dirt, white stripes and the like on the surfaces of chains of vehicles such as automobiles and the like or on the surfaces of plastics or rubber.
Detailed Description
The concept and technical effects of the present invention will be clearly and completely described below in conjunction with the embodiments to fully understand the objects, features and effects of the present invention. It is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments, and those skilled in the art can obtain other embodiments without inventive effort based on the embodiments of the present invention, and all embodiments are within the protection scope of the present invention. The test methods used in the examples are all conventional methods unless otherwise specified; the materials, reagents and the like used are commercially available reagents and materials unless otherwise specified. If not specifically stated, the same ingredients of each example and comparative example were purchased from the same manufacturer and the same batch; the corresponding parameters were the same as in example 3 unless otherwise specified.
In the description of the present invention, reference to the description of the terms "one embodiment," "some embodiments," "an illustrative embodiment," "an example," "a specific example," or "some examples," etc., means that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the present invention. In this specification, the schematic representations of the terms used above do not necessarily refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples. In the description of the present invention, the meaning of "about" means plus or minus 2% unless otherwise specified.
Example 1
The embodiment prepares a cleaning agent, and the specific process is as follows:
preparing 77.5 parts of water by weight, adding about 60% of water by weight into a mixing tank, heating to 40 ℃, sequentially adding 16 parts of myristyl glucoside and 1.5 parts of polydimethylsiloxane under stirring, sequentially adding, and adding the next material after each material is completely dissolved; adding the rest water, and stirring for 50min to obtain semitransparent emulsion.
The materials are all industrial grade products reaching the standard.
Example 2
The embodiment prepares a cleaning agent, and the specific process is as follows:
adding 68.8 parts of water into a mixing tank by weight, heating to 30 ℃, sequentially adding 10 parts of myristyl glucoside (from Shanghai Kaiyu) under stirring, 3 parts of soybean oil methyl ester (CAS: 67784-80-9, from Guangdong Wengjiang chemical reagent Co., ltd.) and 1 part of polydimethylsiloxane (CAS: 9016-00-6, from Jinan Zhongkuai New Material Co., ltd.), sequentially adding, and adding the next material after each material is completely dissolved; stirring for 30min to obtain translucent emulsion. If the production is not done in the order of addition, unpredictable appearances such as delamination, bleeding, sedimentation, etc. will result.
The materials are all industrial grade products up to the standard.
Example 3
The embodiment prepares the cleaning agent, and the specific process is as follows:
adding 68.8 parts of water into a mixing tank by weight, heating to 30 ℃, sequentially adding 10 parts of octyl glucoside, 3 parts of soybean oil methyl ester and 1 part of polydimethylsiloxane under a stirring state, sequentially adding, and adding the next material after each material is completely dissolved; stirring for 30min to obtain translucent emulsion. Adding the materials out of the order of addition during production can result in unpredictable appearances such as delamination, precipitation, sedimentation, and the like.
The materials are all industrial grade products reaching the standard.
Comparative example 1
This comparative example, which differs from example 2 in that myristyl glucoside is absent, was prepared under the same conditions.
Comparative example 2
The cleaning agent of this comparative example was:
application No.: CN201210403711.4 "cleaning agent for cleaning chain".
Comparative example 3
The cleaning agent of this comparative example was:
application No.: cn201510374694.X "chain cleaning agent composition and preparation method thereof.
Comparative example 4
This comparative example, which differs from example 2 in that polydimethylsiloxane was absent and the other conditions were the same, prepared a cleaning agent.
Comparative example 5
This comparative example, which is different from example 2 in that myristyl glucoside in example 2 is replaced with octyl glucoside, was prepared as a cleaning agent, and the other conditions were the same.
Test example 1
In this test example, the cleaning agents prepared in examples 1 to 3 and comparative examples 1 to 5 were tested by the following specific methods: randomly selecting 10 normal limit riding racing cars on a competition site, wherein the chain cleaning mode is online normal-temperature spray scrubbing, and the scrubbing time is unified to 1min; after cleaning, the chain is wiped dry by a dry cloth, and the surface of the chain is visually checked to see whether oil dirt, stubborn particles, soil, rust and color change exist.
Comparative cleaning effect is as follows:
Figure BDA0003761238370000061
the comparative example 1 does not contain myristyl glucoside, so that the cleaning action force on oil stains is weakened, and the cleaning and rust prevention synergistic effect of the three components in the example 2 is obvious, so that the cleanliness is high, and the rust prevention effect is excellent; comparative example 4 defaulted to polydimethylsiloxane, resulting in a decrease in the cleaning effect and rust prevention effect of the cleaning agent; comparative example 5 replacing myristyl glucoside in example 2 with octyl glucoside did not absorb and dissolve the oil stain, resulting in the production of oil slick on the surface after cleaning.
Test example 2
The cleaning agent is in a proportioning range, is practical and convenient, has high cleaning and rust-proof efficiency, does not need heating, ultrasonic wave or special cleaning equipment, and can be sprayed once.
The embodiments of the present invention have been described in detail, but the present invention is not limited to the embodiments, and various changes can be made without departing from the gist of the present invention within the knowledge of those skilled in the art. Furthermore, the embodiments of the present invention and the features of the embodiments may be combined with each other without conflict.

Claims (10)

1. The cleaning agent is characterized by comprising the following preparation raw materials in parts by weight: 5-16 parts of myristyl glucoside, 0-5 parts of soybean oil methyl ester and 0.1-1.5 parts of polydimethylsiloxane.
2. The cleaning agent according to claim 1, wherein the raw materials for preparation comprise, in parts by weight: 2 to 4 parts of soybean oil methyl ester and 0.5 to 1.5 parts of polydimethylsiloxane.
3. The cleaning agent according to claim 1, wherein the raw materials for preparation comprise, in parts by weight: 5-16 parts of myristyl glucoside and 1-1.5 parts of polydimethylsiloxane.
4. The cleaning agent according to claim 1, wherein the raw materials for preparation comprise, in parts by weight: soybean oil methyl ester 0.5-1.5 weight portions and polydimethyl siloxane 0.1-0.2 weight portions.
5. The cleaning agent according to claim 1, wherein the raw material for preparing the cleaning agent further comprises water.
6. The method for producing a cleaning agent according to any one of claims 1 to 5, comprising: mixing the myristyl glucoside, the methyl ester of soybean oil, and the polydimethylsiloxane.
7. The method for producing a cleaning agent according to claim 6, wherein the mixing temperature is 15 to 40 ℃.
8. The method for preparing the cleaning agent according to claim 6, wherein the mixing time is 15-50min.
9. Use of a cleaning agent according to any of claims 1 to 5 for cleaning vehicles.
10. Use of a cleaning agent according to claim 9 in car cleaning, characterized in that the car cleaning comprises cleaning of a car chain.
CN202210870942.XA 2022-07-22 2022-07-22 Cleaning agent and preparation method and application thereof Active CN115197787B (en)

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CN108690758A (en) * 2018-05-28 2018-10-23 广州卡士德汽车用品有限公司 A kind of engine chamber Rapid Cleaning maintaining agent and preparation method thereof
CN108893208A (en) * 2018-07-31 2018-11-27 江苏今日卫生用品有限公司 A kind of antifreeze vehicle bath of glass and preparation method thereof
KR102128505B1 (en) * 2020-02-11 2020-07-01 이국초 Multifunctional detergent and Manufacturing mehtod thereof
CN111961539A (en) * 2020-09-22 2020-11-20 哈尔滨铁路石化销售有限公司 Brake valve cleaning fluid and preparation method thereof
JP7067823B1 (en) * 2021-10-26 2022-05-16 合同会社M&D企画 Detergent composition

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