CN103142430A - Cleaning agent - Google Patents

Cleaning agent Download PDF

Info

Publication number
CN103142430A
CN103142430A CN2011104119232A CN201110411923A CN103142430A CN 103142430 A CN103142430 A CN 103142430A CN 2011104119232 A CN2011104119232 A CN 2011104119232A CN 201110411923 A CN201110411923 A CN 201110411923A CN 103142430 A CN103142430 A CN 103142430A
Authority
CN
China
Prior art keywords
detergent
peel
sapindi mukouossi
fructus sapindi
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN2011104119232A
Other languages
Chinese (zh)
Other versions
CN103142430B (en
Inventor
梁天赐
本多秀夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yokohama Oils and Fats Industry Co Ltd
Original Assignee
Yokohama Oils and Fats Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yokohama Oils and Fats Industry Co Ltd filed Critical Yokohama Oils and Fats Industry Co Ltd
Priority to CN201110411923.2A priority Critical patent/CN103142430B/en
Publication of CN103142430A publication Critical patent/CN103142430A/en
Application granted granted Critical
Publication of CN103142430B publication Critical patent/CN103142430B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Abstract

The invention provides a cleaning agent. The cleaning agent comprises plant chemical components, can be preserved at a normal temperature, and does not contain components prohibited in America or Japan. Under this premise that the amount of prohibited components in the cleaning agent does not exceed the maximum use amount, the cleaning agent can be used as a preservative and a cleaner. A preparation method of the cleaning agent comprises the following steps of blending soapberry peel and glycerol according to a mass ratio of (1: 9) to (1: 1), and extracting saponin in the soapberry peel by glycerol. The cleaning agent is prepared from the plant chemical components, can be preserved at a normal temperature, and does not contain components prohibited in America or Japan. Under this premise that the amount of prohibited components in the cleaning agent does not exceed the maximum use amount, the cleaning agent has effects of cleaning and corrosion prevention.

Description

Detergent
Technical field
The invention relates to the natural detergent with storage stability that is consisted of with vegetalitas chemical composition (Phytochemical).In particular, be about take vegetal composition as main, can preserve at normal temperatures and not comprise the composition that the U.S. or Japan ban use of, or the composition that the restriction that comprises is used does not surpass the detergent of maximum allotment amount.
Background technology
The vegetalitas chemical composition is the general name of the contained material of vegetable food, in the broadest sense, refers to vegetal compound.In recent years, this class contains food that vegetal composition is the nonhazardous of chief component, cosmetics, detergent etc., is just enjoying common people's concern.
Natural prodcuts association (NPA, Natural Products Association) for the providing of the vegetable food of this class etc., the U.S. has worked out following careful Check standard.In raw material, vegetable raw material need account for more than 95%, and, use composition (with reference to non-patent literature 1) except the set composition that bans use of of terrific use, restriction, also can not use composition listed in following table 1.
although the law of Japan is not yet formulated the Valuation Standard of nature cosmetics and organic cosmetics (Organic Cosmetics), but, except the listed composition that bans use of of cosmetics benchmark (with reference to non-patent literature 2), and consumption must not surpass outside maximum allotment quantitative limitation use composition, can not use p-Hydroxybenzoate (Paraben) at present, phenyl phenol (2-phenoxyethanol), sodium benzoate (sodium benzoate), ethanol (alcohol), silica resin (silicone), mineral oil (mineral oil), propylene glycol (propylene glycol) and oil product (oil) are as benchmark.(with reference to the basic free encyclopaedia of the Japanese edition dimension, " organic (organic) cosmetics ").
The present invention in the following description, composition is used in restriction that can non-patent literature 2 is listed, and (102 kinds (have comprised red No. 219, the tar based colorant of yellow No. 204 and the subordinate list 2 in document, listed composition in 3,4)) with " old appointment marker ingredients " be used to claim to represent.
In addition, " organic cosmetics " of the basic free encyclopaedia of relevant the Japanese edition dimension illustrate, take off and are loaded in following webpage:
http://ia.wikipedia.org/wiki/%E3%82%AA%E3%83%BC%E3%82%AC%E3%83%8B%E3%83%83%E3%82%AF%E5%8C%96%E7%B2%A7%E5%93%81
[table 1]
Figure BSA00000635051000021
According to these benchmark, as the detergent that mainly contains vegetal composition, having developed in patent documentation 1 for example is to take in 100% source as alkyl androstanediol (alkyl glucoside) (Chemical formula 1) the made detergent of cocos nucifera oil.But, due to the source for the alkyl androstanediol of cocos nucifera oil be that a kind of source is the semi-synthetic compound of Oleum Cocois and fructose, therefore the detergent of this class can not be called a hundred per cent made by vegetal composition.
Figure BSA00000635051000031
In addition, because the saponin (saponin) that the various plants such as Semen sojae atricolor, Semen Phaseoli comprise after water-soluble, also can produce the foaming effect as Xiang Fei Suds, so can utilize the vegetalitas composition as detergent.For example provide, the tableware kitchen detergent of patent documentation 2 to 4, it is that allotment has a small amount of saponin in the clean composition commonly used such as linear alkylbenzene sulfonate (LAS) (LAS); Or the health cleansing composition of patent documentation 5, wherein comprised saponin that is extracted by Semen sojae atricolor, Germinatus Phragmitis (asparagus) etc.But the detergent of this class only contains the saponin of minute quantity, and neither can being called contained vegetal composition as the detergent of main constituent.
Contain in the plant of saponin in many kinds, the saponin (Chemical formula 2) that the peel of known Fructus Sapindi Mukouossi [English name: Soapberry/ another name: fertile Suds fruit/crude drug name: prolong life skin/formal name used at school: Sapindus Mukorossi/ India works as place name: Ritha, Reetha] comprises shows as has good Biodegradable and efficient cleaning strength.
With critical micella concentration (CMC; Critical Micelle Concentration) as the benchmark of cleaning strength, take some representational boundary activating agents (with reference to non-patent literature 3,4) and sapindoside to make comparisons.This comparative result arranges as table 2, except alkyl poly glucoside (Alkyl polyglucoside) (R=C12) and TX-100, the CMC value of remaining synthetic surfactant is obvious CMC value greater than sapindoside all, so can confirm that sapindoside has good cleaning strength.
[table 2]
Figure BSA00000635051000041
I): with reference to non-patent literature 4
II): with reference to the Japanese edition dimension basic free encyclopaedia " ラ ウ リ Le sulphuric acid Na ト リ ウ system ", take off and be loaded in following webpage
http://ja.wikipedia.org/wiki/%E3%83%A9%E3%82%A6%E3%83%AA%E3%83%AB%E7%A1%AB%E9%85%B8%E3%83%8A%E3%83%88%E3%83%AA%E3%82%A6%E3%83%A0
Figure BSA00000635051000051
So take from peel of Fructus Sapindi Mukouossi De Suds glycosides and be and be used and detergent to numerous species is provided.Can give an example as: patent documentation 6 is to be through allotment pectin (Pectin) and the detergent of ethanol in raw material De Suds glycosides aqueous extraction liquid at peel of Fructus Sapindi Mukouossi; Patent documentation 7 is to contain the skin cleaning agent of the cell activator of Y. flaccida Haw. (Yucca) extract and Fructus Sapindi Mukouossi extract through allotment; Or the detergent of the mixture that contains glycyrrhizic acid (Glycyrrhizin acid), soapbark (Quillaia) extract and Fructus Sapindi Mukouossi extract of patent documentation 8.But these are all has allocated the above-mentioned of ethanol or 1,3 butylene glycol etc. and bans use of composition as the antiseptic person.In addition, although patent documentation 9 has also been developed the extract of allotment peel of Fructus Sapindi Mukouossi and the skin cleaning agent of antiinflammatory, Fructus Sapindi Mukouossi extract used is to extract peel of Fructus Sapindi Mukouossi with ethanol.Therefore, be taken as main constituent gradually and contain although be derived from the composition of peel of Fructus Sapindi Mukouossi, can't obtain not using the detergent of the composition that the U.S. or Japan forbids, so just expecting not use the providing of detergent of the composition that the U.S. or Japan forbids.
Very easily corrupt at normal temperatures owing to extracting De Suds glycosides from plant with water, carry out the preservation of Leng KURA so usually add the glycerol (Glycerin) with antiseptic effect.But, utilize as detergent, wish and can preserve at normal temperatures, so need to add the antiseptic such as sorbate (Sorbate), p-Hydroxybenzoate (Paraben), benzoate (Benzoate).But, because the meetings such as sorbate and nitrite reaction in environment become carcinogen, thus the problem of safety is arranged, and hydroxybenzoate and benzoate are also the above-mentioned compositions that bans use of.
Glycerol has antiseptic effect and nontoxic, and can produce hydration heat (heat of hydration) after contact skin, so often be used in commercially available warming massage agent.Also have, also use the raw material as the Temperature Susceptibility skin cleaning agent of patent documentation 10 to 15.But, these detergents also used ethylene oxide etc. above-mentioned ban use of composition.
At present, fail to obtain so to preserve at normal temperatures take the vegetalitas composition as main, and do not comprise the composition that the U.S. or Japan ban use of in formula, do not surpass under the state of maximum allotment amount at the composition that the restriction that comprises is used, take into account the detergent of cleaning strength and anti-corrosive properties.
The inventor of this case waits in the present invention, is to make up nontoxic composition take the vegetalitas composition as main, attempts to provide the detergent that can preserve at normal temperatures.In patent documentation 16, a kind of composition for oral cavity has been proposed, its the made tea powder of the so nontoxic vegetalitas composition of combination, as the peel of Fructus Sapindi Mukouossi of vegetalitas blowing agent component, and the sweetener that consists of of vegetalitas composition in, also allocate glycerol and make.But because be used for the oral cavity, the allotment amount of peel of Fructus Sapindi Mukouossi is few, cleans effect and insufficient, and the storage stability during the allotment amount of unpredictable increase peel of Fructus Sapindi Mukouossi.
[prior art document]
[patent documentation]
[patent documentation 1] U.S. patent of invention US2010/0056416 communique
[patent documentation 2] Japanese kokai publication hei 10-324893 communique
[patent documentation 3] Japanese kokai publication hei 10-147796 communique
[patent documentation 4] Japanese kokai publication hei 10-45566 communique
No. the 3226225th, [patent documentation 5] Japanese patent of invention
No. WO2006/00741, [patent documentation 6] international open handbook
No. the 3904336th, [patent documentation 7] Japanese patent of invention
[patent documentation 8] TOHKEMY 2007-326806 communique
[patent documentation 9] Japanese kokai publication hei 9-263531 communique
[patent documentation 10] TOHKEMY 2010-106258 communique
[patent documentation 11] TOHKEMY 2010-100577 communique
[patent documentation 12] TOHKEMY 2010-37269 communique
No. the 3589514th, [patent documentation 13] Japanese patent of invention
[patent documentation 14] TOHKEMY 2003-300839 communique
[patent documentation 15] Japanese kokai publication hei 9-227361 communique
No. the 3287658th, [patent documentation 16] Japanese patent of invention
[non-patent literature]
[non-patent literature 1] Clinics in Dermatology, 2001, Volume 19, and issue 4, pp371-374
[non-patent literature 2] cosmetics benchmark (equalling into 12 on JIUYUE 29, No. the 331st, Health and human services department bulletin)
[non-patent literature 3] The Journal of Physical Chemistry B, 2009, Volume113, Issue 2, pp.474-481.
[non-patent literature 4] Bulletin of the Chemical Society of Japan, 1961, Volume 24, No.2, pp.233-237.
Summary of the invention
(problem that invention will solve)
Problem of the present invention is to provide a kind of detergent, it is consisted of with the vegetalitas chemical composition, can preserve at normal temperatures, and do not comprise the U.S. or the composition that bans use of of Japan, in addition, do not surpass under the state of maximum allotment amount at the composition that the restriction that comprises is used, make the detergent that cleaning strength and anti-corrosive properties can get both.
(solving the means of problem)
After the inventor of this case waits and studies intensively in order to reach above-mentioned purpose, found that and the mass ratio of peel of Fructus Sapindi Mukouossi and glycerol is allocated as the ratio of 1: 9 to 1: 1, extract by glycerol and be included in peel of Fructus Sapindi Mukouossi De Suds glycosides, can make by the vegetalitas chemical composition made, can preserve at normal temperatures, and do not comprise the U.S. or the composition that bans use of of Japan, in addition, do not surpass under the state of maximum allotment amount at the composition that the restriction that comprises is used, take into account the detergent of cleaning strength and anti-corrosive properties, thereby completed the present invention.
Detergent of the present invention when extraction is got the Suds glycosides from peel of Fructus Sapindi Mukouossi, does not adopt the water or the methanol that used in the past, but adopts glycerol, thereby improved anti-corrosive properties, can preserve at normal temperatures yet.In addition, owing to using glycerol, detergent presents warm effect, has also improved cleaning strength.
That is to say, the present invention is about the detergent put down in writing in following (1) to (7) etc.
(1) a kind of detergent, its mass ratio with peel of Fructus Sapindi Mukouossi and glycerol is allocated as the ratio of 1: 9 to 1: 1, and extracts in peel of Fructus Sapindi Mukouossi contained De Suds glycosides (Saponin) by glycerol and make.
(2) detergent of putting down in writing as above-mentioned (1) item wherein, directly comprises peel of Fructus Sapindi Mukouossi as exfoliation material (scrub), or after extraction is got out the Suds glycosides, peel of Fructus Sapindi Mukouossi is removed.
(3) detergent of putting down in writing as above-mentioned (1) or (2) item wherein, adds the plant extract with antiseptic property.
(4) detergent of putting down in writing as any one of above-mentioned (1) to (3) item, wherein, plant extract is that phenol coefficient (Phenol Coefficient) is 1 above person.
(5) detergent of putting down in writing as any one of above-mentioned (1) to (4) item, wherein, plant extract is selected from from more than one of citral (Citral), geraniol (Geraniol), eugenol (Eugenol) or thyme camphor (Thymol).
(6) detergent of putting down in writing as any one of above-mentioned (1) to (5) item wherein, is added with peel of Fructus Sapindi Mukouossi exfoliation material in addition.
(7) detergent of putting down in writing as any one of (1) to (6) item wherein, also comprises water-soluble biological polymer, moisturizing composition, antioxidant, physiologically active ingredient or natural perfume material.
(effect of invention)
The prepared detergent of the present invention is made by the vegetalitas chemical composition, can preserve at normal temperatures, and not comprise the U.S. or the Japanese composition that bans use of, in addition, do not surpass under the state of maximum allotment amount at the composition that the restriction that comprises is used, take into account the detergent of cleaning strength and anti-corrosive properties.The made detergent of the cleaning strength of detergent of the present invention and similar synthesizing/semi-synthetic surfactant is in a ratio of not a halfpenny the worse, owing to having warm effect, and the function that also can have the skin warming to clean.In addition, the detergent that also can be used as nontoxic cleaning tableware etc. uses.
Description of drawings
Fig. 1 shows the antiseptic effect figure (embodiment 1 to 3) under the room temperature preservation.
Fig. 2 shows the clean design sketch (embodiment 1) of detergent.
Fig. 3 shows the antiseptic effect figure (comparative example 1 to 5) under the room temperature preservation.
Fig. 4 shows the antiseptic effect figure (comparative example 6 to 10) under the room temperature preservation.
The specific embodiment
" detergent " of the present invention is that vegetalitas composition (Phytochemical) take peel of Fructus Sapindi Mukouossi or vegetalitas glycerol etc. is as main, has the storage stability that to preserve under room temperature, and do not comprise above-mentioned at the U.S. or the Japanese composition that bans use of, in addition, do not surpass under the state of maximum allotment amount at the composition that the restriction that comprises is used, can take into account the detergent of cleaning strength and anti-corrosive properties.
" banning use of composition " of mentioning in this case explanation, " composition is used in restriction ", refer to composition represented in above-mentioned [prior art] (the cited compositions such as non-patent literature 1,2, table 1), restriction uses " the maximum allotment amount " of composition cited as non-patent literature 2, means maximum adjustable in the cosmetics of 100g.For example, take thyme camphor as example, for " be not used in the cosmetics of mucosa, after using with water cleaning person " or " be not used in the cosmetics of mucosa, after using not with water cleaning person " each 100g, adjustable maximum allotment amount is 0.05g.(with reference to non-patent literature 2).
So the present invention " detergent ", so long as the mass ratio of peel of Fructus Sapindi Mukouossi and glycerol is allocated as the ratio of 1: 9 to 1: 1, extract contained De Suds glycosides in peel of Fructus Sapindi Mukouossi and the detergent made gets final product with glycerol, also can contain for mammalss such as the mankind is other nontoxic composition.
About extract the method for peel of Fructus Sapindi Mukouossi Zhong Suds glycosides with glycerol, can use over known the whole bag of tricks, but the present invention is preferably by being immersed in dry/peel of Fructus Sapindi Mukouossi after pulverizing the method such as extract in glycerol.
" peel of Fructus Sapindi Mukouossi " that comprises in " detergent " of the present invention, no matter be to use commercially available product, or the peel that will take from the mature fruit of gathering on tree directly or after dry uses, and is all good.
In " detergent " of the present invention, this " peel of Fructus Sapindi Mukouossi " preferably is allocated as 10 to 50 % by weight.
In " detergent " of the present invention, the peel of Fructus Sapindi Mukouossi during directly the extraction of Han You Suds glycosides is completed or extracted is as the exfoliation material.In this case, peel of Fructus Sapindi Mukouossi is 20 to 40 % by weight, is preferably 20 to 30 % by weight, more preferably 20 to 25 % by weight.
After the extraction of , Zai Suds glycosides is completed in addition, also can wait by filtration and remove the Fructus Sapindi Mukouossi residue.In this case, the peel of Fructus Sapindi Mukouossi that adds in glycerol is 30 to 50 % by weight, is preferably 30 to 40 % by weight, or 30 to 35 % by weight more preferably.
In addition, " glycerol " that comprises in " detergent " of the present invention preferably selected the vegetalitas glycerol, can use commercially available product etc.This " glycerol " is allocated as 50 to 98 % by weight in " detergent " of the present invention, be preferably 70 to 80 % by weight, or 75 % by weight more preferably.
" detergent " of the present invention also can also add " plant extract " with antiseptic property.This " plant extract " be commercially available product, voluntarily from the plantation plant with known the whole bag of tricks of past extracted taker, chemosynthesis person all can.
This " plant extract " though addition different and different according to the kind of substance, but in " detergent " of the present invention, adding becomes 0 to 5 % by weight, be preferably 0.05 to 2 % by weight, 0.05 to 0.5 % by weight more preferably, if the composition that restriction is used, addition need be no more than maximum allotment amount.
" plant extract " of the present invention, the numerical value of preferred phenol coefficient is the plant extract more than 1 because adding the antiseptic effect of the property taken advantage of ground promotion lotion.The larger antibacterial ability of the numerical value of phenol coefficient is higher.Be preferably the numerical value that uses the phenol coefficient shown in more than one tables 3 and be the plant extract of citral more than 5, geraniol, eugenol, thyme camphor etc.
In addition, thyme camphor is not used by U.S. food both FAD (FDA) restriction, for be considered as the plant extract of spendable natural material by U.S. natural prodcuts association (NPA).(with reference to list of references 1,2)
List of references 1:Natural Products Associations Standard and Certification for Personal Care Products, 2010.9.1., The Natural Standard
List of references 2:Natural Products Associations Standard and Certification for Personal Care Products, Appendix I, Illustrative " Positive list " of ingredients.
[table 3]
Figure BSA00000635051000101
" detergent " of the present invention can be and comprise with peel of Fructus Sapindi Mukouossi conduct " exfoliation material " person itself, also can be interpolation peel of Fructus Sapindi Mukouossi Plant Powder in addition and minces as " exfoliation material " person.The Plant Powder of this class Semen Armeniacae Amarum powder (Fructus Pruni seed powder), Semen Maydis powder, bran powder, Semen Juglandis grain, Semen Phaseoli, analysis for soybean powder, Rhizoma amorphophalli powder and the zostera marina etc. as ground product such as Semen Armeniacae Amarums of to give an example of mincing.In addition, salt etc. also can be used as the exfoliation material and uses.
These exfoliation materials can use separately the peel of Fructus Sapindi Mukouossi itself for Cui Qu Suds glycosides, and, even added combination these Plant Powders person of mincing, also can be after getting except peel of Fructus Sapindi Mukouossi, then the Plant Powder that adds separately these minces.In this case, after available centrifuge (for example rotating speed 4000rpm, more than 1 hour) etc. makes the peel of Fructus Sapindi Mukouossi sedimentation, supernatant is refiltered etc. with metallic screen cloth (being of a size of the screen cloth that can pass through less than 850 μ m persons), to remove peel.
When " detergent " of the present invention comprised these exfoliation material, content was 1 to 30 % by weight with respect to " detergent " of the present invention, be preferably 5 to 20 % by weight, more preferably 5 to 10 % by weight.
" detergent " of the present invention can also also contain the natural perfume materials such as the physiologically active ingredients such as moisturizing composition, the amino acidses such as water-soluble biological polymer, amino acids such as natural surfactant, hyaluronic acid sodium (Sodium Hyaluronate) such as lecithin (lecithin) and jasmine (Jasmine).
Below embodiments of the invention are done more specifically explanation.But the present invention is not defined as these embodiment.
(embodiment)
In embodiment 1 to 3, peel of Fructus Sapindi Mukouossi was carried out vacuum drying with vacuum drier (V-30 type, Japan makes limited company of institute) at 50 ℃, 6 hours.Dried peel is pulverized with home-use pulverizer (MILL MIXER-FM50, SUN limited company), and sieved with metallic screen cloth (mesh 850 μ m).Resulting peel of Fructus Sapindi Mukouossi (drying) fine powder is added/is stirred in glycerol (room temperature), after making abundant dispersion, optionally add the listed plant extract of table 4 and stir.Resulting solution is placed more than 2 days at normal temperatures Cui Qu Chu Suds glycosides.The formula of each embodiment is recorded in table 4.
[table 4]
Figure BSA00000635051000121
As shown in Figure 1, it is identical with the state of reference examples (detergent of embodiment 3 was preserved a day after modulation at normal temperatures) that the preservation state of the detergent of each embodiment (preserving more than 1 month at normal temperatures) all remains, and corrupt/precipitation does not occur.
In addition, as shown in Figure 2, (1): be stained with the greasy dirt of paying on bicycle chain with palm, (2): the schematic diagram of greasy dirt, (3): after the detergent with embodiment 1 is washed (2) middle palm by rubbing with the hands, (4): after water cleaned, result had shown that the detergent of embodiment 1 has good clean effect.Embodiment 2 and 3 has also shown the cleaning strength identical with embodiment 1.
If with gently the rubbing on palm of the detergent of embodiment 1, the surface temperature of skin can be raised to 36.4 ℃ or be raised to 35.0 ℃ from 33.4 ℃ from 34.6 ℃, and temperature has risen more than 1.5 ℃, really shows the warm effect (n=2) of detergent.Embodiment 2 and 3 has also shown the warm effect identical with embodiment 1.The surface temperature of skin is to record with Raytek (registered trade mark) MINITEMP infra-red thermometer (non-contact type Portable thermometer).
[comparative example 1 to 5]
Use peel of Fructus Sapindi Mukouossi (drying) fine powder identical with embodiment to add/be stirred in water (room temperature) and after making abundant dispersion, optionally the listed tackifier of interpolation table 5, antiseptic etc. and stir.After placing at normal temperatures resulting solution more than 4 days, the Fructus Sapindi Mukouossi fine powder is filtered from extract/removes.The component list of resulting solution is recorded in table 5.
[table 5]
Figure BSA00000635051000131
As shown in Figure 3, corruption has occured in comparative example 1 to 5 (preserving more than 1 month at normal temperatures).Comparative example 1 has become suspension through corruption.In addition, comparative example 2 to 5 can be confirmed to precipitate.The Fructus Sapindi Mukouossi powder aqueous solution of example (Fructus Sapindi Mukouossi: water=16: 84) be the just modulation person of completing in contrast.
[comparative example 6 to 9]
Use peel of Fructus Sapindi Mukouossi (drying) fine powder identical with embodiment, soak in methanol (room temperature) after 3 days, insoluble Fructus Sapindi Mukouossi fine powder is filtered/removes.Use again vaporizer (evaporator) to remove methanol from the filtrate of gained, obtain the refining De Suds glycosides powder of Wei.The Suds glycosides powder that makes is added/be stirred to (room temperature) in water, after making abundant dispersion, optionally add the listed tackifier of table 6 or antiseptic etc., and stir.The component list of resulting solution is recorded in table 6.
[table 6]
Figure BSA00000635051000141
As shown in Figure 4, corruption has occured in comparative example 6 to 9 (preserving more than 1 month at normal temperatures).Comparative example 9 is corrupt and become suspension.In addition, comparative example 6,7,8,10 can confirm to precipitate.Li De Suds glycosides powder aqueous solution (Suds glycosides powder in contrast: water=4: 96) be the just modulation person of completing.
(utilizability on industry)
According to the present invention, can provide a kind of made by the vegetalitas chemical composition, can preserve at normal temperatures, and do not comprise the U.S. or the composition that bans use of of Japan, in addition, do not surpass under the state of maximum allotment amount at the composition that the restriction that comprises is used, take into account simultaneously the detergent of cleaning strength and anti-corrosive properties.Detergent of the present invention, can use the healths such as shampoo, bath oil of cleaning use as skin with or clean the nontoxic detergent of the use such as tableware.

Claims (7)

1. a detergent, is characterized in that, is the ratio of 1: 9 to 1: 1 that the mass ratio of peel of Fructus Sapindi Mukouossi and glycerol is allocated as, and make with contained Suds glycosides in glycerol extraction peel of Fructus Sapindi Mukouossi.
2. detergent as claimed in claim 1, is characterized in that, directly comprises peel of Fructus Sapindi Mukouossi as the exfoliation material, or after Cui Qu Chu Suds glycosides, peel of Fructus Sapindi Mukouossi is removed.
3. detergent as claimed in claim 1 or 2, is characterized in that, is added with the plant extract with antiseptic property.
4. detergent as described in any one in claims 1 to 3, is characterized in that, plant extract is the above person of phenol coefficient 1.
5. detergent as described in any one in claim 1 to 4, is characterized in that, plant extract is selected from more than one in citral, geraniol, eugenol or thyme camphor.
6. detergent as described in any one in claim 1 to 5, is characterized in that, is added with peel of Fructus Sapindi Mukouossi exfoliation material in addition.
7. detergent as described in any one in claim 1 to 6, is characterized in that, also comprises water-soluble biological polymer, moisturizing composition, antioxidant, physiologically active ingredient or natural perfume material.
CN201110411923.2A 2011-12-07 2011-12-07 Cleaning agent Active CN103142430B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201110411923.2A CN103142430B (en) 2011-12-07 2011-12-07 Cleaning agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201110411923.2A CN103142430B (en) 2011-12-07 2011-12-07 Cleaning agent

Publications (2)

Publication Number Publication Date
CN103142430A true CN103142430A (en) 2013-06-12
CN103142430B CN103142430B (en) 2015-07-15

Family

ID=48540950

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201110411923.2A Active CN103142430B (en) 2011-12-07 2011-12-07 Cleaning agent

Country Status (1)

Country Link
CN (1) CN103142430B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106943415A (en) * 2017-03-31 2017-07-14 牡丹江医学院 A kind of externally-applied medicinal composition for preventing and treating pruitus and its production and use
CN112210445A (en) * 2020-09-30 2021-01-12 山东华熙海御生物医药有限公司 Hyaluronic acid cleaning solution and preparation method thereof
CN115197787A (en) * 2022-07-22 2022-10-18 广东红日星实业有限公司 Cleaning agent and preparation method and application thereof

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0733632A (en) * 1993-07-16 1995-02-03 Sunstar Inc Oral composition containing tea power
CN1240640A (en) * 1999-06-25 2000-01-12 张展洪 Sapindus mukorossi pulp shampoo and its preparing process
CN1344537A (en) * 2001-02-14 2002-04-17 上海白猫有限公司 Scurf-eliminating and itch-stopping shampoo of Chinese soapberry seed
CN1935820A (en) * 2006-10-14 2007-03-28 合肥新新石化助剂有限公司 Method for preparing total saponin of sapindusmukerossi
CN102021086A (en) * 2009-09-17 2011-04-20 中国林业科学研究院亚热带林业研究所 Natural plant detergent and preparation method thereof
CN102038793A (en) * 2010-09-27 2011-05-04 南京泽朗医药科技有限公司 Preparation method of soapberry saponin
CN102241725A (en) * 2010-05-13 2011-11-16 福建源华林业生物科技有限公司 Water extraction preparation method of daily chemical sapindoside
US20110293760A1 (en) * 2009-06-10 2011-12-01 Heng-Jui Hsu Method for extracting substances from soapberry fruit and seed and products made therefrom

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0733632A (en) * 1993-07-16 1995-02-03 Sunstar Inc Oral composition containing tea power
CN1240640A (en) * 1999-06-25 2000-01-12 张展洪 Sapindus mukorossi pulp shampoo and its preparing process
CN1344537A (en) * 2001-02-14 2002-04-17 上海白猫有限公司 Scurf-eliminating and itch-stopping shampoo of Chinese soapberry seed
CN1935820A (en) * 2006-10-14 2007-03-28 合肥新新石化助剂有限公司 Method for preparing total saponin of sapindusmukerossi
US20110293760A1 (en) * 2009-06-10 2011-12-01 Heng-Jui Hsu Method for extracting substances from soapberry fruit and seed and products made therefrom
CN102021086A (en) * 2009-09-17 2011-04-20 中国林业科学研究院亚热带林业研究所 Natural plant detergent and preparation method thereof
CN102241725A (en) * 2010-05-13 2011-11-16 福建源华林业生物科技有限公司 Water extraction preparation method of daily chemical sapindoside
CN102038793A (en) * 2010-09-27 2011-05-04 南京泽朗医药科技有限公司 Preparation method of soapberry saponin

Non-Patent Citations (10)

* Cited by examiner, † Cited by third party
Title
张蕾: "无患子在化妆品中的开发与应用", 《2006年中国化妆品学术研讨会论文集 》, 31 December 2006 (2006-12-31), pages 194 - 196 *
朱亚红,等: "无患子皂苷粗提物提取方法比较", 《浙江农业科学》, vol. 2008, no. 2, 31 December 2008 (2008-12-31), pages 247 - 248 *
武士威,等: "无患子餐具洗涤剂的研制", 《电力环境保护》, vol. 25, no. 3, 30 June 2009 (2009-06-30), pages 29 - 31 *
段纪东,等: "无患子提取物的泡沫性能研究", 《辽宁化工》, vol. 36, no. 9, 30 September 2007 (2007-09-30), pages 595 - 597 *
沈国军,等: "对无患子提取液洗涤性能的研究", 《中国园艺文摘》, vol. 2009, no. 1, 31 December 2009 (2009-12-31), pages 47 - 48 *
田辉,等: "无患子提取液安全性实验研究", 《公共卫生与预防医学》, vol. 20, no. 3, 31 December 2009 (2009-12-31), pages 84 - 85 *
赵丽: "《美容化妆品学》", 31 May 2005, article "防腐剂", pages: 45-46 *
饶厚曾,等: "无患子皂苷提取工艺研究", 《江西科学》, vol. 20, no. 1, 31 March 2002 (2002-03-31), pages 55 - 58 *
魏凤玉,等: "天然无患子皂苷的提取分离", 《安徽化工》, vol. 33, no. 3, 30 June 2007 (2007-06-30), pages 15 - 17 *
黄素梅,等: "无患子的研究现状及其开发利用", 《林业科技开发》, vol. 23, no. 6, 31 December 2009 (2009-12-31), pages 1 - 5 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106943415A (en) * 2017-03-31 2017-07-14 牡丹江医学院 A kind of externally-applied medicinal composition for preventing and treating pruitus and its production and use
CN106943415B (en) * 2017-03-31 2019-12-27 牡丹江医学院 External pharmaceutical composition for preventing and treating skin itch and preparation method and application thereof
CN112210445A (en) * 2020-09-30 2021-01-12 山东华熙海御生物医药有限公司 Hyaluronic acid cleaning solution and preparation method thereof
CN115197787A (en) * 2022-07-22 2022-10-18 广东红日星实业有限公司 Cleaning agent and preparation method and application thereof
CN115197787B (en) * 2022-07-22 2023-07-07 广东红日星实业有限公司 Cleaning agent and preparation method and application thereof

Also Published As

Publication number Publication date
CN103142430B (en) 2015-07-15

Similar Documents

Publication Publication Date Title
JP5616188B2 (en) Washing soap
CN103637940B (en) A kind of bath gel
CN102090999A (en) Eatable lipstick
CN108324679A (en) Turbid dew composition and preparation method are arranged in no anti-corrosion makeup removing
KR20120052012A (en) Depilatory shampoo composition including natural material
CN101961298B (en) Moisturizing composition
CN103735467B (en) A kind of natural plant shower gel and preparation method thereof
CN106727151A (en) A kind of mildy wash and preparation method thereof
CN103142430B (en) Cleaning agent
CN109106621A (en) Cleansing composition and its preparation method and application
CN102743310A (en) Skin external-use agentia combination containing lotus extract and dark plum extract serving as effective components and having antioxidant activity
CN112430510B (en) Bacteriostatic detergent containing plant surfactant and preparation method thereof
KR101615027B1 (en) Natural detergent composition and preparation method thereof
CN103720637A (en) Natural plant shampoo and hair conditioner and preparation methods thereof
CN105342943A (en) Gel containing Chinese herbal medicine extract and preparation method of gel
TW201102108A (en) A natural facial-cleaning component
CN106511144A (en) Eye and lip makeup remover and preparation method thereof
CN106367245A (en) Natural biological laundry soap
KR20170099098A (en) Cosmetic composition for cleansing having herb extracts and preparing method of the same
CN105168032A (en) Pure natural composite hand-protection emulsion and preparation method thereof
TWI467013B (en) Cleaning agent
KR20100003955A (en) Cosmetic composition for moisturizing effect on the skin
CN104367510A (en) Natural extract body wash and preparation method thereof
CN109609299A (en) A kind of nanometer of soapberry soap and preparation method thereof
CN104173271A (en) Nostoc commune Vauch extract and preparation method and application thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant