CN102181330B - Biological cleaning agent and preparation method thereof - Google Patents

Biological cleaning agent and preparation method thereof Download PDF

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Publication number
CN102181330B
CN102181330B CN 201110061237 CN201110061237A CN102181330B CN 102181330 B CN102181330 B CN 102181330B CN 201110061237 CN201110061237 CN 201110061237 CN 201110061237 A CN201110061237 A CN 201110061237A CN 102181330 B CN102181330 B CN 102181330B
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extract
casein
water
add
naoh
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CN102181330A (en
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唐兴旺
唐翊珲
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GUANGZHOU MEIKE BIOLOGICAL TECHNOLOGY CO., LTD.
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唐兴旺
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Abstract

The invention discloses a biological cleaning agent and is characterized in that the biological cleaning agent comprises the following raw materials by weight: 5-10% of soybean protein extract and casein extract, 0.72-1% of NaOH+Na2CO3, 7-10% of glucoside multi-hydroxyl matters, 1-4% of neutral protease, 0.2-0.5% of preservative, 0.2-0.3% of bactericide, 0.4-0.6% of vitamin E, 0.2-0.3% of iso-vitamin C, 0.1-0.2% of fruit green, 0.1-0.2% of retaining agent, 0.1-0.2% of water-soluble food flavor and the balance of deionized water. The biological cleaning agent has active matters with strong cleaning capability and good biodegradation, ensures few residues after cleaning, is safe, healthy, natural and environment-friendly, has long time of storage and is free from deterioration and has simple preparation method.

Description

A kind of biological cleanser and preparation method thereof
Technical field
The present invention relates to the technology of sanitising agent technical field, particularly a kind of biological cleanser.
Background technology
Common sanitising agent is all by chemical surfactant, Sulfonates in the market, phosphoric acid salt, ammonium salt class, amine oxide, polyprotonic acid, white dyes, pure ethers, ethanol, acetone, dimethoxy ether/butyl ether, Diethylene Glycol butyl ether, sodium-chlor, sulfonic acid, tripoly phosphate sodium STPP, water glass, petroleum benzene, pigment, essence etc. petrochemical industry becomes to be grouped into, and biological degradability is bad, and is residual many after cleaning, the people there is in various degree injury to thing, affects safety and Health, not environmental protection.
This biological cleanser adopts the natural biological extract to be aided with the biological cleanser that various edible raw materials develop through special process.
Summary of the invention
The purpose of this invention is to provide a kind of biological cleanser, have the actives of powerful cleaning capacity, biological degradability is good, and is residual few after cleaning, safety and Health, and natural environmental-protective, and also period of storage length is never degenerated.
Further purpose is that its preparation method is simple.
Purpose of the present invention is achieved through the following technical solutions.
A kind of biological cleanser is characterized in that described biological cleanser is comprised of the raw material of following weight per-cent: soybean protein extract and casein extract 5%～10%, NaOH+Na 2CO 30.72%～1%, glucosides class poly-hydroxy thing 7%～10%, neutral protease 1%～4%, sanitas 0.2%～0.5%, sterilant 0.2%～0.3%, vitamin-E 0.4%～0.6%, isoascorbic acid 0.2%～0.3%, light green 0.1%～0.2%, retention agent 0.1%～0.2%, water-soluble food flavour 0.1%～0.2%, the deionized water surplus.
The quality proportioning of described soybean protein extract and casein extract is 1: 1; Described NaOH+Na 2CO 3The quality proportioning be 1: 3; Described sanitas is made of soluble metyl hydroxybenzoate and soluble propylhydroxybenzoate, and the quality proportioning is 1: 1.
Described neutral protease, molecular weight are 35000-40000.
The described sterilant azanyl imidazoles urea of attaching most importance to, molecular formula is C 13H 20N 8O 19, molecular weight is 592.
Wherein the concrete weight percent of each raw material is: soybean protein extract and casein extract 10%, NaOH+Na 2CO 31%, glucosides class poly-hydroxy thing 10%, neutral protease 4%, sanitas 0.5%, sterilant 0.3%, vitamin-E 0.6%, isoascorbic acid 0.3%, light green 0.2%, retention agent 0.2%, water-soluble food flavour 0.2%, deionized water 72.7%;
Or soybean protein extract and casein extract 6%, NaOH+Na 2CO 30.85%, glucosides class poly-hydroxy thing 8%, neutral protease 2%, sanitas 0.3%, sterilant 0.2%, vitamin-E 0.4%, isoascorbic acid 0.2%, light green 0.1%, retention agent 0.1%, water-soluble food flavour 0.1%, deionized water 81.75%;
Or soybean protein extract and casein extract 5%, NaOH+Na 2CO 30.75%, glucosides class poly-hydroxy thing 7%, neutral protease 1%, sanitas 0.2%, sterilant 0.2%, vitamin-E 0.4%, isoascorbic acid 0.2%, light green 0.1%, retention agent 0.1%, water-soluble food flavour 0.1%, deionized water 84.95%;
A kind of method for preparing biological cleanser described above comprises the following steps:
1) remove ionized water and be placed in reactor, be heated to 76-80 ℃, add NaOH and Na 2CO 3, after waiting dissolving fully, maintain the temperature at 76-80 ℃, under 30-60 rev/min of whipped state, evenly slowly add soybean protein and casein bio-extract, add to the transparent glue of full melt into;
2) when temperature keeps 65 ℃, directly add glucosides class poly-hydroxy thing, with 30-60 rev/min of stirring;
3) when temperature drops to 55 ℃, check that pH adds neutral protease when 6-8, then stir lower reaction;
4) use respectively deionized water dissolving sanitas, vitamin-E and isoascorbic acid, all add in reactor, stir;
5) directly add light green and water-soluble food flavour, then stir;
6) get Na 2CO 3Add retention agent after dissolving, complete add in reactor after molten, stir;
7) deionized water adds in reactor to total amount 100%, continue to stir 10 minutes, and cooling rear check, actives is at 15-20%, can.
The present invention compared with prior art has the following advantages:
Soybean protein extract in the present invention, be soybean protein, soya casein, also claim soybean glue, the macromole that is formed by multiple L-amino acid, along the protein macromolecule chain, distribution NH2 ,-COO-,-hydrophilic radicals such as CONH-, also distributing hydrophobic grouping as-(CH2-)-, it belongs to amino acid pattern natural surface active agent; Casein extract: Casein also is lactic casein, casein, casein, casein, its molecular formula C 47H 48N 3NaO 7S 2, molecular weight 854.02 belongs to the amino acid pattern natural surface active agent equally; Glucosides class poly-hydroxy thing wherein as alkyl-glucoside C8-C16, is the vegetalitas surface-active substance.Other each composition is all fully harmless to environment to thing to the people.Therefore the present invention has following advantage:
1, injury and the secondary injury of avoiding the petrochemical industry clean-out system are avoided people to the pavid psychology of the chemical hazard generation of chemical cleaner, thereby are slowed down stress.
2, do not hinder hand, do not hinder object, the cleaning rear surface forms protective film, the protection object extends article work-ing life, facilitates the secondary cleaning.
3, curable greasy dirt, dry and comfortable comfortable, simple and efficient, anhydrous cleaning need not be crossed water after cleaning, and residual quantity is seldom saved a large amount of waters, reduces and pollutes.
4, easy to use, only need get final product with wet towel one wiping the inconvenience because water is brought when having changed conventional sanitising agent cleaning during the secondary cleaning.
5, use range is extensive: the cleaning of the multiple crusts such as electrical equipment surface, frosting, glass surface, and whole kitchen, the shallow-layer grease cleaning of lampblack absorber, kitchen range etc. and metope kitchen tools.
Embodiment
Biological cleanser of the present invention is comprised of the raw material of following weight per-cent: soybean protein extract and casein extract 5%～10%, NaOH+Na 2CO 30.72%～1%, glucosides class poly-hydroxy thing 7%～10%, neutral protease 1%～4%, sanitas 0.2%～0.5%, sterilant 0.2%～0.3%, vitamin-E 0.4%～0.6%, isoascorbic acid 0.2%～0.3%, light green 0.1%～0.2%, retention agent 0.1%～0.2%, water-soluble food flavour 0.1%～0.2%, the deionized water surplus.Wherein the quality proportioning of soybean protein extract and casein extract is 1: 1; Described NaOH+Na 2CO 3The quality proportioning be 1: 3; Described sanitas is made of soluble metyl hydroxybenzoate and soluble propylhydroxybenzoate, and the quality proportioning is 1: 1; Neutral protease, molecular weight are 35000-40000; The sterilant azanyl imidazoles urea of attaching most importance to, molecular formula is C 13H 20N 8O 19, molecular weight is 592.
The embodiment of each proportioning is as follows:
Embodiment 1: soybean protein extract and casein extract 10%, NaOH+Na2CO3 1%, glucosides class poly-hydroxy thing 10%, neutral protease 4%, sanitas 0.5%, sterilant 0.3%, vitamin-E 0.6%, isoascorbic acid 0.3%, light green 0.2%, retention agent 0.2%, water-soluble food flavour 0.2%, deionized water 72.7%;
Embodiment 2: soybean protein extract and casein extract 6%, NaOH+Na2CO3 0.85%, glucosides class poly-hydroxy thing 8%, neutral protease 2%, sanitas 0.3%, sterilant 0.2%, vitamin-E 0.4%, isoascorbic acid 0.2%, light green 0.1%, retention agent 0.1%, water-soluble food flavour 0.1%, deionized water 81.75%;
Embodiment 3: soybean protein extract and casein extract 5%, NaOH+Na2CO3 0.75%, glucosides class poly-hydroxy thing 7%, neutral protease 1%, sanitas 0.2%, sterilant 0.2%, vitamin-E 0.4%, isoascorbic acid 0.2%, light green 0.1%, retention agent 0.1%, water-soluble food flavour 0.1%, deionized water 84.95%;
Be described as follows in above-mentioned each composition:
Soybean protein extract: soybean protein, soya casein also claims soybean glue, the macromole that is formed by multiple L-amino acid, along the protein macromolecule chain, distribution NH2 ,-COO-,-hydrophilic radicals such as CONH-, also distributing hydrophobic grouping as-(CH2-)-.Belong to the amino acid pattern natural surface active agent.
Casein extract: Casein also is lactic casein, casein, casein, casein, molecular formula C 47H 48N 3NaO 7S 2, molecular weight 854.02.
Glucosides class poly-hydroxy thing, alkyl-glucoside, C 8-C 16, alkyl glucoside vegetalitas surface-active substance.
Soluble metyl hydroxybenzoate, soluble propylhydroxybenzoate: another name: Sodium Methyl Hydroxybenzoate, Sodium propyl p-hydroxybenzoate, molecular formula is C 8H 8O 3, C 10H 12O 3
Neutral protease: another name, serrapeptass, Serratiopeptidase reaches elder generation, Seradase, Neutralproteinase, Neutrase, molecular weight is at 35000-40000.Neutral protease, 200,000 units, 45-55 ℃, PH6.0-8.0
The sanitas azanyl imidazoles urea of attaching most importance to, molecular formula is C 13H 20N 8O 19, molecular weight is 448.
Vitamin-E, VE calls and is that tocopherol, molecular formula are C 29H 50O 2, molecular weight 430.69.
Isoascorbic acid, different VC calls and is that SODIUM ISOVITAMIN C, molecular formula are C 6H 7NaO 6.H 2O。
The preparation method of biological cleanser of the present invention:
1,70% deionized water that weighs of getting total amount is heated to 76-80 ℃ in reactor, add NaOH+ part Na 2CO 3, after waiting dissolving fully, maintain the temperature at 76-80 ℃, under 30-60 rev/min of whipped state, evenly slowly add soybean protein and casein bio-extract.Add to the transparent glue of full melt into approximately 30 minutes.
2, when temperature keeps 65 ℃, directly add alkyl-glucoside (C 8-C 16), 30-60 rev/min of stirring.
3, when temperature drops to 55 ℃, check that pH adds neutral protease when 6-8, then reacted 30 minutes under 30 rev/mins of stirrings.
4, separately respectively with pure water dissolving soluble metyl hydroxybenzoate ten soluble propylhydroxybenzoates-A and diazonium alkyl imidazole urea (G-II), vitamin-E and isoascorbic acid, all add in reactor 30 rev/mins of stirrings.
5, directly add light green and water-soluble food flavour, 30 rev/mins of stirrings.
6, get small part Na 2CO 3, add retention agent also to be complexing agent EDTA-4Na after dissolving, complete add in reactor 30 rev/mins of stirrings after molten.
7, add again deionized water and enter in reactor to total amount 100%, continue to stir 10 minutes, cooling rear check, actives is at 15-20%, can.

Claims (8)

1. biological cleanser is characterized in that described biological cleanser is comprised of the raw material of following weight per-cent:
Soybean protein extract and casein extract 5%～10%, NaOH+Na 2CO 30.72%～1%, glucosides class poly-hydroxy thing 7%～10%, neutral protease 1%～4%, sanitas 0.2%～0.5%, sterilant 0.2%～0.3%, vitamin-E 0.4%～0.6%, isoascorbic acid 0.2%～0.3%, light green 0.1%～0.2%, retention agent 0.1%～0.2%, water-soluble food flavour 0.1%～0.2%, the deionized water surplus.
2. biological cleanser according to claim 1, it is characterized in that: the quality proportioning of described soybean protein extract and casein extract is 1: 1; Described NaOH+Na 2CO 3The quality proportioning be 1: 3; Described sanitas is made of soluble metyl hydroxybenzoate and soluble propylhydroxybenzoate, and the quality proportioning is 1: 1.
3. biological cleanser according to claim 1, it is characterized in that: described neutral protease, molecular weight are 35000-40000.
4. biological cleanser according to claim 1 is characterized in that: the described sterilant azanyl imidazoles urea of attaching most importance to, molecular formula is C 13H 20N 8O 19, molecular weight is 592.
5. according to claim 1-4 described biological cleansers of any one claim, is characterized in that: soybean protein extract and casein extract 10%, NaOH+Na 2CO 31%, glucosides class poly-hydroxy thing 10%, neutral protease 4%, sanitas 0.5%, sterilant 0.3%, vitamin-E 0.6%, isoascorbic acid 0.3%, light green 0.2%, retention agent 0.2%, water-soluble food flavour 0.2%, deionized water 72.7%.
6. according to claim 1-4 described biological cleansers of any one claim, is characterized in that: soybean protein extract and casein extract 6%, NaOH+Na 2CO 30.85%, glucosides class poly-hydroxy thing 8%, neutral protease 2%, sanitas 0.3%, sterilant 0.2%, vitamin-E 0.4%, isoascorbic acid 0.2%, light green 0.1%, retention agent 0.1%, water-soluble food flavour 0.1%, deionized water 81.75%.
7. according to claim 1-4 described biological cleansers of any one claim, is characterized in that: soybean protein extract and casein extract 5%, NaOH+Na 2CO 30.75%, glucosides class poly-hydroxy thing 7%, neutral protease 1%, sanitas 0.2%, sterilant 0.2%, vitamin-E 0.4%, isoascorbic acid 0.2%, light green 0.1%, retention agent 0.1%, water-soluble food flavour 0.1%, deionized water 84.95%.
8. a method for preparing the described biological cleanser of above-mentioned any one claim, comprise the following steps:
1) remove ionized water and be placed in reactor, be heated to 76-80 ℃, add NaOH and Na 2CO 3, after waiting dissolving fully, maintain the temperature at 76-80 ℃, under 30-60 rev/min of whipped state, evenly slowly add soybean protein and casein bio-extract, add to the transparent glue of full melt into;
2) when temperature keeps 65 ℃, directly add glucosides class poly-hydroxy thing, with 30-60 rev/min of stirring;
3) when temperature drops to 55 ℃, check that pH adds neutral protease when 6-8, then stir lower reaction;
4) use respectively deionized water dissolving sanitas, vitamin-E and isoascorbic acid, all add in reactor, stir;
5) directly add light green and water-soluble food flavour, then stir;
6) get Na 2CO 3Add retention agent after dissolving, complete add in reactor after molten, stir;
7) deionized water adds in reactor to total amount 100%, continue to stir 10 minutes, and cooling rear check, actives is at 15-20%, can.
CN 201110061237 2011-03-14 2011-03-14 Biological cleaning agent and preparation method thereof Active CN102181330B (en)

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Families Citing this family (3)

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Publication number Priority date Publication date Assignee Title
CN104450225B (en) * 2014-11-03 2018-04-27 唐翊珲 A kind of pesticide residue scavenging agent and preparation method thereof
CN104789395A (en) * 2015-04-30 2015-07-22 王英英 Environment-friendly bactericidal detergent and preparation method thereof
CN106753842A (en) * 2016-12-16 2017-05-31 全椒祥瑞塑胶有限公司 A kind of plastic cement cleaning agent

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7396808B1 (en) * 2007-06-20 2008-07-08 The Clorox Company Natural cleaning compositions
CN101245291A (en) * 2008-03-10 2008-08-20 赵玉春 Biological cleanser
WO2008134343A1 (en) * 2007-04-30 2008-11-06 Danisco Us Inc., Genencor Division Use of protein hydrolysates to stabilize metalloprotease detergent formulations

Patent Citations (3)

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Publication number Priority date Publication date Assignee Title
WO2008134343A1 (en) * 2007-04-30 2008-11-06 Danisco Us Inc., Genencor Division Use of protein hydrolysates to stabilize metalloprotease detergent formulations
US7396808B1 (en) * 2007-06-20 2008-07-08 The Clorox Company Natural cleaning compositions
CN101245291A (en) * 2008-03-10 2008-08-20 赵玉春 Biological cleanser

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