CN102181330A - Biological cleaning agent and preparation method thereof - Google Patents
Biological cleaning agent and preparation method thereof Download PDFInfo
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- CN102181330A CN102181330A CN2011100612377A CN201110061237A CN102181330A CN 102181330 A CN102181330 A CN 102181330A CN 2011100612377 A CN2011100612377 A CN 2011100612377A CN 201110061237 A CN201110061237 A CN 201110061237A CN 102181330 A CN102181330 A CN 102181330A
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Abstract
The invention discloses a biological cleaning agent and is characterized in that the biological cleaning agent mainly comprises the following raw materials by weight: 5-10% of soybean protein extract and casein extract, 0.72-1% of NaOH+Na2CO3, 7-10% of glucoside multi-hydroxyl matters, 1-4% of neutral protease, 0.2-0.5% of preservative, 0.2-0.3% of bactericide, 0.4-0.6% of vitamin E, 0.2-0.3% of iso-vitamin C, 0.1-0.2% of fruit green, 0.1-0.2% of retaining agent, 0.1-0.2% of water-soluble food flavor and the balance of deionized water. The biological cleaning agent has active matters with strong cleaning capability and good biodegradation, ensures few residues after cleaning, is safe, healthy, natural and environment-friendly, has long time of storage and is free from deterioration and has simple preparation method.
Description
Technical field
The present invention relates to the technology of sanitising agent technical field, particularly a kind of biological cleanser.
Background technology
Common in the market sanitising agent all is by chemical surfactant, Sulfonates, phosphoric acid salt, ammonium salt class, amine oxide, polyprotonic acid, white dyes, pure ethers, ethanol, acetone, dimethoxy ether/butyl ether, Diethylene Glycol butyl ether, sodium-chlor, sulfonic acid, tripoly phosphate sodium STPP, water glass, petroleum benzene, pigment, essence or the like petrochemical industry becomes to be grouped into, and biological degradability is bad, and the cleaning back is residual many, the people is had in various degree injury to thing, and influence safety is with healthy, not environmental protection.
This biological cleanser adopts the natural biological extract to be aided with the biological cleanser that various edible raw materials develop through special process.
Summary of the invention
The purpose of this invention is to provide a kind of biological cleanser, have the actives of powerful cleaning capacity, biological degradability is good, and the cleaning back is residual few, safety and Health, and natural environmental-protective, and also period of storage length is never degenerated.
Further purpose is that its preparation method is simple.
Purpose of the present invention is achieved through the following technical solutions.
A kind of biological cleanser, it is characterized in that described biological cleanser mainly is made up of following weight percentages: soybean protein extract and casein extract 5%～10%, NaOH+Na2CO30.72%～1%, glucosides class poly-hydroxy thing 7%～10%, neutral protease 1%～4%, sanitas 0.2%～0.5%, sterilant 0.2%～0.3%, vitamin-E 0.4%～0.6%, isoascorbic acid 0.2%～0.3%, light green 0.1%～0.2%, retention agent 0.1%～0.2%, water-soluble food flavour 0.1%～0.2%, the deionized water surplus.
The quality proportioning of described soybean protein extract and casein extract is 1: 1; The quality proportioning of described NaOH+Na2CO3 is 1: 3; Described sanitas is made of soluble metyl hydroxybenzoate and soluble propylhydroxybenzoate, and the quality proportioning is 1: 1.
Described neutral protease, molecular weight are 35000-40000.
The described sterilant azanyl imidazoles urea of attaching most importance to, molecular formula is C13H20N8O19, molecular weight is 448.
Wherein the concrete weight percent of each raw material is: soybean protein extract and casein extract 10%, NaOH+Na2CO3 1%, glucosides class poly-hydroxy thing 10%, neutral protease 4%, sanitas 0.5%, sterilant 0.3%, vitamin-E 0.6%, isoascorbic acid 0.3%, light green 0.2%, retention agent 0.2%, water-soluble food flavour 0.2%, deionized water 72.7%;
Or soybean protein extract and casein extract 8%, NaOH+Na2CO3 0.95%, glucosides class poly-hydroxy thing 9%, neutral protease 3%, sanitas 0.4%, sterilant 0.3%, vitamin-E 0.6%, isoascorbic acid 0.2%, light green 0.2%, retention agent 0.2%, water-soluble food flavour 0.2%, deionized water 76.85%;
Or soybean protein extract and casein extract 6%, NaOH+Na2CO3 0.85%, glucosides class poly-hydroxy thing 8%, neutral protease 2%, sanitas 0.3%, sterilant 0.2%, vitamin-E 0.4%, isoascorbic acid 0.2%, light green 0.1%, retention agent 0.1%, water-soluble food flavour 0.1%, deionized water 81.75%;
Or soybean protein extract and casein extract 5%, NaOH+Na2CO3 0.75%, glucosides class poly-hydroxy thing 7%, neutral protease 1%, sanitas 0.2%, sterilant 0.2%, vitamin-E 0.4%, isoascorbic acid 0.2%, light green 0.1%, retention agent 0.1%, water-soluble food flavour 0.1%, deionized water 84.95%;
Or soybean protein extract and casein extract 6%, NaOH+Na2CO3 0.72%, glucosides class poly-hydroxy thing 8%, neutral protease 2%, sanitas 0.4%, sterilant 0.3%, vitamin-E 0.4%, isoascorbic acid 0.2%, light green 0.1%, retention agent 0.1%, water-soluble food flavour 0.1%, deionized water 81.86%.
A kind of method for preparing above-mentioned described biological cleanser comprises the following steps:
1) removes ionized water and place, be heated to 76-80 ℃, add NaOH and Na2CO3 in reactor, Deng fully the dissolving after, maintain the temperature at 76-80 ℃, under the 30-60 rev/min of whipped state, evenly slowly add soybean protein and casein bio-extract, add to the transparent glue of full melt into;
2) when temperature keeps 65 ℃, directly add glucosides class poly-hydroxy thing, with 30-60 rev/min of stirring;
3) when temperature drops to 55 ℃, check that PH adds neutral protease when 6-8, stir reaction down then;
4) dissolve sanitas, vitamin-E and isoascorbic acid with ionized water respectively, all add in the reactor, stir;
5) directly add light green and water-soluble food flavour, restir;
6) get Na2CO3 dissolving back and add retention agent, complete molten back adds in the reactor, stirs;
7) deionized water adds in the reactor to total amount 100%, continue to stir 10 minutes, and the check of cooling back, actives is at 15-20%, can.
The present invention compared with prior art has the following advantages:
Soybean protein extract among the present invention, be soybean protein, soya casein, also claim soybean glue, the macromole of forming by multiple L-amino acid, along the protein macromolecule chain, distribution NH2 ,-COO-,-hydrophilic radicals such as CONH-, also distributing hydrophobic grouping as-(CH2-)-, it belongs to amino acid pattern natural surface active agent; Casein extract: Casein also is lactic casein, casein, and casein, casein, its molecular formula C47H48N3NaO7S2, molecular weight 854.02 belongs to the amino acid pattern natural surface active agent equally; Glucosides class poly-hydroxy thing wherein as alkyl-glucoside C8-C16, is the vegetalitas surface-active substance.Other each composition is all harmless fully to environment to thing to the people.Therefore the present invention has following advantage:
1, avoids the injury and the secondary injury of petrochemical industry clean-out system, avoid the pavid psychology of people, thereby slow down stress the chemical hazard generation of chemical cleaner.
2, do not hinder hand, do not hinder object, the cleaning rear surface forms protective film, the protection object prolongs article work-ing life, makes things convenient for the secondary cleaning.
3, curable greasy dirt, dry and comfortable comfortable, simple and efficient, anhydrous cleaning need not be crossed water after the cleaning, and residual quantity is seldom saved a large amount of waters, reduces and pollutes.
4, easy to use, in secondary when cleaning, only need be wiped with wet towel one and get final product, the inconvenience because of water is brought when having changed conventional sanitising agent and cleaning.
5, use range is extensive: the cleaning of multiple crusts such as electrical equipment surface, frosting, glass surface, and whole kitchen, the shallow-layer grease cleaning of lampblack absorber, kitchen range etc. and metope kitchen tools.
Embodiment
Biological cleanser of the present invention, mainly form: soybean protein extract and casein extract 5%～10% by following weight percentages, NaOH+Na2CO3 0.72%～1%, glucosides class poly-hydroxy thing 7%～10%, neutral protease 1%～4%, sanitas 0.2%～0.5%, sterilant 0.2%～0.3%, vitamin-E 0.4%～0.6%, isoascorbic acid 0.2%～0.3%, light green 0.1%～0.2%, retention agent 0.1%～0.2%, water-soluble food flavour 0.1%～0.2%, the deionized water surplus.Wherein the quality proportioning of soybean protein extract and casein extract is 1: 1; The quality proportioning of described NaOH+Na2CO3 is 1: 3; Described sanitas is made of soluble metyl hydroxybenzoate and soluble propylhydroxybenzoate, and the quality proportioning is 1: 1; Neutral protease, molecular weight are 35000-40000; The sterilant azanyl imidazoles urea of attaching most importance to, molecular formula is C13H20N8O19, molecular weight is 448.
The embodiment of each proportioning is as follows:
Embodiment 1: soybean protein extract and casein extract 10%, NaOH+Na2CO3 1%, glucosides class poly-hydroxy thing 10%, neutral protease 4%, sanitas 0.5%, sterilant 0.3%, vitamin-E 0.6%, isoascorbic acid 0.3%, light green 0.2%, retention agent 0.2%, water-soluble food flavour 0.2%, deionized water 72.7%;
Embodiment 2: soybean protein extract and casein extract 8%, NaOH+Na2CO3 0.95%, glucosides class poly-hydroxy thing 9%, neutral protease 3%, sanitas 0.4%, sterilant 0.3%, vitamin-E 0.6%, isoascorbic acid 0.2%, light green 0.2%, retention agent 0.2%, water-soluble food flavour 0.2%, deionized water 76.85%;
Embodiment 3: soybean protein extract and casein extract 6%, NaOH+Na2CO3 0.85%, glucosides class poly-hydroxy thing 8%, neutral protease 2%, sanitas 0.3%, sterilant 0.2%, vitamin-E 0.4%, isoascorbic acid 0.2%, light green 0.1%, retention agent 0.1%, water-soluble food flavour 0.1%, deionized water 81.75%;
Embodiment 4: soybean protein extract and casein extract 5%, NaOH+Na2CO3 0.75%, glucosides class poly-hydroxy thing 7%, neutral protease 1%, sanitas 0.2%, sterilant 0.2%, vitamin-E 0.4%, isoascorbic acid 0.2%, light green 0.1%, retention agent 0.1%, water-soluble food flavour 0.1%, deionized water 84.95%;
Embodiment 5: soybean protein extract and casein extract 6%, NaOH+Na2CO3 0.72%, glucosides class poly-hydroxy thing 8%, neutral protease 2%, sanitas 0.4%, sterilant 0.3%, vitamin-E 0.4%, isoascorbic acid 0.2%, light green 0.1%, retention agent 0.1%, water-soluble food flavour 0.1%, deionized water 81.86%.
Specify as follows in above-mentioned each composition:
Soybean protein extract: soybean protein, soya casein also claims soybean glue, the macromole of forming by multiple L-amino acid, along the protein macromolecule chain, distribution NH2 ,-COO-,-hydrophilic radicals such as CONH-, also distributing hydrophobic grouping as-(CH2-)-.Belong to the amino acid pattern natural surface active agent.
Casein extract: Casein also is lactic casein, casein, casein, casein, molecular formula C47H48N3NaO7S2, molecular weight 854.02.
Glucosides class poly-hydroxy thing, alkyl-glucoside, C8-C16, alkyl glucoside vegetalitas surface-active substance.
Soluble metyl hydroxybenzoate, soluble propylhydroxybenzoate: another name: Sodium Methyl Hydroxybenzoate, Sodium propyl p-hydroxybenzoate, molecular formula is C8H8O3, C10H12O3.
Neutral protease: another name, serrapeptass, Serratiopeptidase reaches elder generation, Seradase, Neutralproteinase, Neutrase, molecular weight is at 35000-40000.Neutral protease, 200,000 units, 45-55 ℃, PH6.0-8.0
The sanitas azanyl imidazoles urea of attaching most importance to, molecular formula is C13H20N8O19, molecular weight is 448.
Vitamin-E, VE calls and is that tocopherol, molecular formula are C29H50O2, molecular weight 430.69.
Isoascorbic acid, different VC calls and is that SODIUM ISOVITAMIN C, molecular formula are C6H7NaO6.H2O.
The preparation method of biological cleanser of the present invention:
1,70% deionized water that weighs of getting total amount is heated to 76-80 ℃ in reactor, adds NaOH+ part Na2CO3, Deng fully the dissolving after, maintain the temperature at 76-80 ℃, under the 30-60 rev/min of whipped state, evenly slowly add soybean protein and casein bio-extract.Add to the transparent glue of full melt into about 30 minutes.
2, when temperature keeps 65 ℃, directly add alkyl-glucoside (C8-C16), 30-60 rev/min of stirring.
3, when temperature drops to 55 ℃, check that PH adds neutral protease when 6-8,30 rev/mins of stirrings were reacted 30 minutes down then.
4, dissolve soluble metyl hydroxybenzoate+soluble propylhydroxybenzoate-A and diazonium alkyl imidazole urea (G-II), vitamin-E and isoascorbic acid with pure water respectively separately, all add in the reactor, 30 rev/mins of stirrings.
5, directly add light green and water-soluble food flavour, 30 rev/mins of stirrings.
6, get small part Na2CO3, the dissolving back adds retention agent and also is complexing agent EDTA-4Na, and complete molten back adds in the reactor 30 rev/mins of stirrings.
7, add deionized water again and go in the reactor, continue to stir 10 minutes to total amount 100%, the check of cooling back, actives is at 15-20%, can.
Claims (10)
1. biological cleanser is characterized in that described biological cleanser mainly is made up of following weight percentages:
Soybean protein extract and casein extract 5%～10%, NaOH+Na2CO3 0.72%～1%, glucosides class poly-hydroxy thing 7%～10%, neutral protease 1%～4%, sanitas 0.2%～0.5%, sterilant 0.2%～0.3%, vitamin-E 0.4%～0.6%, isoascorbic acid 0.2%～0.3%, light green 0.1%～0.2%, retention agent 0.1%～0.2%, water-soluble food flavour 0.1%～0.2%, deionized water surplus.
2. biological cleanser according to claim 1 is characterized in that: the quality proportioning of described soybean protein extract and casein extract is 1: 1; The quality proportioning of described NaOH+Na2CO3 is 1: 3; Described sanitas is made of soluble metyl hydroxybenzoate and soluble propylhydroxybenzoate, and the quality proportioning is 1: 1.
3. biological cleanser according to claim 1 is characterized in that: described neutral protease, molecular weight are 35000-40000.
4. biological cleanser according to claim 1 is characterized in that: the described sterilant azanyl imidazoles urea of attaching most importance to, and molecular formula is C13H20N8O19, molecular weight is 448.
5. according to the described biological cleanser of each claim of claim 1-4, it is characterized in that: soybean protein extract and casein extract 10%, NaOH+Na2CO
31%, glucosides class poly-hydroxy thing 10%, neutral protease 4%, sanitas 0.5%, sterilant 0.3%, vitamin-E 0.6%, isoascorbic acid 0.3%, light green 0.2%, retention agent 0.2%, water-soluble food flavour 0.2%, deionized water 72.7%.
6. according to the described biological cleanser of each claim of claim 1-4, it is characterized in that: soybean protein extract and casein extract 8%, NaOH+Na2CO
30.95%, glucosides class poly-hydroxy thing 9%, neutral protease 3%, sanitas 0.4%, sterilant 0.3%, vitamin-E 0.6%, isoascorbic acid 0.2%, light green 0.2%, retention agent 0.2%, water-soluble food flavour 0.2%, deionized water 76.85%.
7. according to the described biological cleanser of each claim of claim 1-4, it is characterized in that: soybean protein extract and casein extract 6%, NaOH+Na2CO
30.85%, glucosides class poly-hydroxy thing 8%, neutral protease 2%, sanitas 0.3%, sterilant 0.2%, vitamin-E 0.4%, isoascorbic acid 0.2%, light green 0.1%, retention agent 0.1%, water-soluble food flavour 0.1%, deionized water 81.75%.
8. according to the described biological cleanser of each claim of claim 1-4, it is characterized in that: soybean protein extract and casein extract 5%, NaOH+Na2CO
30.75%, glucosides class poly-hydroxy thing 7%, neutral protease 1%, sanitas 0.2%, sterilant 0.2%, vitamin-E 0.4%, isoascorbic acid 0.2%, light green 0.1%, retention agent 0.1%, water-soluble food flavour 0.1%, deionized water 84.95%.
9. according to the described biological cleanser of each claim of claim 1-4, it is characterized in that: soybean protein extract and casein extract 6%, NaOH+Na2CO
30.72%, glucosides class poly-hydroxy thing 8%, neutral protease 2%, sanitas 0.4%, sterilant 0.3%, vitamin-E 0.4%, isoascorbic acid 0.2%, light green 0.1%, retention agent 0.1%, water-soluble food flavour 0.1%, deionized water 81.86%.
10. one kind prepares above-mentioned each method according to the described biological cleanser of claim, comprises the following steps:
1) removes ionized water and place, be heated to 76-80 ℃, add NaOH and Na2CO in reactor
3, wait fully dissolving after, maintain the temperature at 76-80 ℃, under the 30-60 rev/min of whipped state, evenly slowly add soybean protein and casein bio-extract, add to the transparent glue of full melt into;
2) when temperature keeps 65 ℃, directly add glucosides class poly-hydroxy thing, with 30-60 rev/min of stirring;
3) when temperature drops to 55 ℃, check that PH adds neutral protease when 6-8, stir reaction down then;
4) dissolve sanitas, vitamin-E and isoascorbic acid with ionized water respectively, all add in the reactor, stir;
5) directly add light green and water-soluble food flavour, restir;
6) get Na2CO3 dissolving back and add retention agent, complete molten back adds in the reactor, stirs;
7) deionized water adds in the reactor to total amount 100%, continue to stir 10 minutes, and the check of cooling back, actives is at 15-20%, can.
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| CN 201110061237 CN102181330B (en) | 2011-03-14 | 2011-03-14 | Biological cleaning agent and preparation method thereof |
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| CN102181330B CN102181330B (en) | 2013-06-05 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104450225A (en) * | 2014-11-03 | 2015-03-25 | 唐翊珲 | Pesticide residue scavenging agent and preparation method thereof |
| CN104789395A (en) * | 2015-04-30 | 2015-07-22 | 王英英 | Environment-friendly bactericidal detergent and preparation method thereof |
| CN106753842A (en) * | 2016-12-16 | 2017-05-31 | 全椒祥瑞塑胶有限公司 | A kind of plastic cement cleaning agent |
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| US7396808B1 (en) * | 2007-06-20 | 2008-07-08 | The Clorox Company | Natural cleaning compositions |
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| WO2008134343A1 (en) * | 2007-04-30 | 2008-11-06 | Danisco Us Inc., Genencor Division | Use of protein hydrolysates to stabilize metalloprotease detergent formulations |
| US7396808B1 (en) * | 2007-06-20 | 2008-07-08 | The Clorox Company | Natural cleaning compositions |
| CN101245291A (en) * | 2008-03-10 | 2008-08-20 | 赵玉春 | Biological cleanser |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104450225A (en) * | 2014-11-03 | 2015-03-25 | 唐翊珲 | Pesticide residue scavenging agent and preparation method thereof |
| CN104789395A (en) * | 2015-04-30 | 2015-07-22 | 王英英 | Environment-friendly bactericidal detergent and preparation method thereof |
| CN106753842A (en) * | 2016-12-16 | 2017-05-31 | 全椒祥瑞塑胶有限公司 | A kind of plastic cement cleaning agent |
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| CN102181330B (en) | 2013-06-05 |
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