CN107815363A - A kind of preparation method of industrial machinery heavy oil pollution cleanser - Google Patents

A kind of preparation method of industrial machinery heavy oil pollution cleanser Download PDF

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Publication number
CN107815363A
CN107815363A CN201711188626.XA CN201711188626A CN107815363A CN 107815363 A CN107815363 A CN 107815363A CN 201711188626 A CN201711188626 A CN 201711188626A CN 107815363 A CN107815363 A CN 107815363A
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CN
China
Prior art keywords
parts
heavy oil
industrial machinery
mixed
revs
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Pending
Application number
CN201711188626.XA
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Chinese (zh)
Inventor
殷德军
陈昊
朱德意
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Wuxi South China New Energy Electric Technology Development Co Ltd
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Wuxi South China New Energy Electric Technology Development Co Ltd
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Priority to CN201711188626.XA priority Critical patent/CN107815363A/en
Publication of CN107815363A publication Critical patent/CN107815363A/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/86Mixtures of anionic, cationic, and non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2041Dihydric alcohols
    • C11D3/2044Dihydric alcohols linear
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2068Ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2086Hydroxy carboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2093Esters; Carbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/30Amines; Substituted amines ; Quaternized amines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/62Quaternary ammonium compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D2111/20

Abstract

The invention discloses a kind of preparation method of industrial machinery heavy oil pollution cleanser, is made up of the grease dirt cleaning agent prepared by this method the component of following parts by weight:30 40 parts of 12 18 parts of diethanol amine, 35 parts of quaternary ammonium compound, 35 parts of ten diamino benzene sulfonic acid sodium, 25 parts of diethylene glycol ether, 13 parts of potassium hydrogen tartrate, 48 parts of citric acid, 27 parts of antioxidant, 8 12 parts of biological disinfectant, 35 parts of surfactant, 37 parts of bergamio, 37 parts of propane diols and deionized water.The grease dirt cleaning agent prepared by the present invention goes that industrial machinery heavy oil dirt ability is strong, nontoxic, non-corrosiveness, and cleaning effect is good, and has good bactericidal effect, does not injure skin;In addition, the fragrant odour of the cleaning agent, can allow user to be in a cheerful frame of mind.

Description

A kind of preparation method of industrial machinery heavy oil pollution cleanser
Technical field
The present invention relates to a kind of preparation method of industrial machinery heavy oil pollution cleanser, belong to cleaning agent technical field.
Background technology
In industrial machinery production operation, many industrial machinery heavy oil dirts can be usually run into, and most worker exists After being stained with such greasy dirt with it or on hand, general using going the detergent of oil stain to be cleaned, in general detergent is difficult to do Rinsed well to the complete cleaning agent for cleaning and remaining is more difficult, if cleaning is not clean, just influence very much the physical and mental health of people.
The method that tradition degreases mainly has three kinds.1) solvent oil removal process:Using cool wash and vapour degreasing, for clear The organic solvent washed has oil series solvent, fluorination series solvent and fluorine carbon series solvent three major types.Its advantage is the efficiency high that degreases, Shortcoming is that organic solvent typically all has the shortcomings that flash-point is low, toxicity is big, inflammable, contaminative is strong, the Corrosion Protection after cleaning It is poor.2) highly basic oil removal process:It is that price is low using immersion and jet cleaning, its advantage, raw material is easy to get, but alkaline matter corrosivity It is relatively strong, and the oil removing ability only just having been had under higher alkalescence condition.3) surfactant oil removing:Lived according to surface Property the wetting of agent, infiltration, the effect of emulsification, by greasy dirt emulsion dispersion into tiny particle, then make by mechanical (external force) effect Dirt comes off, and reaches oil removing purpose.Although mechanical greasy dirt cleaning agent species at present on the market is various, can not mostly accomplish Clean up completely, and bacteria-eliminating efficacy is poor.
The content of the invention
The defects of the present invention seeks to exist for prior art, provides a kind of preparation of industrial machinery heavy oil pollution cleanser Method.
The present invention to achieve the above object, adopts the following technical scheme that:A kind of preparation of industrial machinery heavy oil pollution cleanser Method, in parts by weight, comprise the following steps:
1) deionized water of 30-40 parts, is taken, is put into reactor, then takes the diethanol amine, the season of 2-6 parts of 4-8 parts Ammonium compound and the citric acid of 6-9 parts, and be poured into reactor mixed successively, mixing speed is 50-70 revs/min, Whipping temp is 20-30 degree, and mixing time is 5-15 minutes, obtains mixed liquor A;
2) the ten diamino benzene sulfonic acid sodium of 2-5 parts and the diethylene glycol ether of 3-7 parts, are slowly added into reactor, and Mixed, mixing speed is 30-50 revs/min, and whipping temp is 25-35 degree, and mixing time is 10-15 minutes, is obtained Mixed liquid B;
3) potassium hydrogen tartrate of 2-5 parts, the biological disinfectant of 5-8 parts, the acetic acid virtue camphor tree of 3-7 parts, are added into mixed liquid B Ester, and mixed, mixing speed is 45-55 revs/min, and whipping temp is 32-40 degree, and mixing time is 5-10 minutes, Obtain mixed liquor C;
4) surfactant, the propane diols of 2-5 parts and the antioxygen of 3-5 parts of 3-5 parts, are added in most backward mixed liquor C Agent, and mixed, mixing speed is 50-60 revs/min, and whipping temp is 55-60 degree, and mixing time is 20-30 minutes, Then normal temperature stands 2-3 hours, and adjusts PH to 6.5-7.5, and the grease dirt cleaning agent of the present invention is finally made.
Further, the surfactant is TX-10, FMES, LAS, AEO-9, TX-10, OP-10, QYL-83C and Y- Any three kinds of mixture in 35.
Further, the biological disinfectant is made up of alginic acid fibre element.
Beneficial effects of the present invention:The heavy oil pollution cleanser prepared by the present invention go industrial machinery heavy oil dirt ability it is strong, Nontoxic, non-corrosiveness, cleaning effect is good, and has good bactericidal effect, does not injure skin;In addition, the smell of the cleaning agent Fragrance, user can be allowed to be in a cheerful frame of mind.
Embodiment
The present invention relates to a kind of industrial machinery heavy oil pollution cleanser, it is made up of the component of following parts by weight:Diethanol amine 4-8 Part, quaternary ammonium compound 2-6 parts, ten diamino benzene sulfonic acid sodium 2-5 parts, diethylene glycol ether 3-7 parts, potassium hydrogen tartrate 2-5 parts, lemon Sour 6-9 parts, antioxidant 3-5 parts, biological disinfectant 5-8 parts, surfactant 3-5 parts, bergamio 3-7 parts, propane diols 2-5 Part and deionized water 30-40 parts.
Wherein, the surfactant is in TX-10, FMES, LAS, AEO-9, TX-10, OP-10, QYL-83C and Y-35 Any three kinds of mixture.Wherein, the biological disinfectant is made up of alginic acid fibre element.
Embodiment 1:
The preparation method of above-mentioned heavy oil pollution cleanser, in parts by weight, comprise the following steps:
1), take 30 parts of deionized water, be put into reactor, then take 4 parts diethanol amine, 2 parts of quaternary ammonium compound With 6 parts of citric acid, and it is poured into reactor is mixed successively, mixing speed is 50 revs/min, whipping temp 20 Degree, mixing time are 5 minutes, obtain mixed liquor A;
2) 2 parts of ten diamino benzene sulfonic acid sodium and 3 parts of diethylene glycol ether, are slowly added into reactor, and are carried out Mix, mixing speed is 30 revs/min, and whipping temp is 25 degree, and mixing time is 10 minutes, obtains mixed liquid B;
3) 2 parts of potassium hydrogen tartrate, 5 parts of biological disinfectant, 3 parts of bergamio, is added into mixed liquid B, and Mixed, mixing speed is 45 revs/min, and whipping temp is 32 degree, and mixing time is 5 minutes, obtains mixed liquor C;
4) 3 parts of surfactant, 2 parts of propane diols and 3 parts of antioxidant, is added in most backward mixed liquor C, and Mixed, mixing speed is 50 revs/min, and whipping temp is 55 degree, and mixing time is 20 minutes, and then normal temperature stands 2 Hour, and PH to 6.5 is adjusted, the grease dirt cleaning agent of the present invention is finally made.
In use, first drenching hand, then take 1ml or so grease dirt cleaning agent to be placed in hand and clean, industrial machinery greasy dirt Clearance is up to more than 90%, and degerming rate is up to more than 92%.
Embodiment 2:
The preparation method of above-mentioned heavy oil pollution cleanser, in parts by weight, comprise the following steps:
1), take 36 parts of deionized water, be put into reactor, then take 6 parts diethanol amine, 4 parts of quaternary ammonium compound Citric acid with 7, and is poured into reactor is mixed successively, and mixing speed is 60 revs/min, whipping temp 25 Degree, mixing time are 10 minutes, obtain mixed liquor A;
2) 3 parts of ten diamino benzene sulfonic acid sodium and 5 parts of diethylene glycol ether, are slowly added into reactor, and are carried out Mix, mixing speed is 40 revs/min, and whipping temp is 30 degree, and mixing time is 12 minutes, obtains mixed liquid B;
3) 4 parts of potassium hydrogen tartrate, 6 parts of biological disinfectant, 5 parts of bergamio, is added into mixed liquid B, and Mixed, mixing speed is 50 revs/min, and whipping temp is 37 degree, and mixing time is 8 minutes, obtains mixed liquor C;
4) 4 parts of surfactant, 4 parts of propane diols and 4 parts of antioxidant, is added in most backward mixed liquor C, and Mixed, mixing speed is 55 revs/min, and whipping temp is 58 degree, and mixing time is 25 minutes, and then normal temperature is stood 2.5 hours, and PH to 7 is adjusted, the grease dirt cleaning agent of the present invention is finally made.
In use, first drenching hand, then take 1ml or so grease dirt cleaning agent to be placed in hand and clean, industrial machinery greasy dirt Clearance is up to more than 96%, and degerming rate is up to more than 97%.
Embodiment 3:
The preparation method of above-mentioned heavy oil pollution cleanser, in parts by weight, comprise the following steps:
1), take 40 parts of deionized water, be put into reactor, then take 8 parts diethanol amine, 6 parts of quaternary ammonium compound With 9 parts of citric acid, and it is poured into reactor is mixed successively, mixing speed is 70 revs/min, whipping temp 30 Degree, mixing time are 15 minutes, obtain mixed liquor A;
2) 5 parts of ten diamino benzene sulfonic acid sodium and 7 parts of diethylene glycol ether, are slowly added into reactor, and are carried out Mix, mixing speed is 50 revs/min, and whipping temp is 35 degree, and mixing time is 15 minutes, obtains mixed liquid B;
3) 5 parts of potassium hydrogen tartrate, 8 parts of biological disinfectant, 7 parts of bergamio, is added into mixed liquid B, and Mixed, mixing speed is 55 revs/min, and whipping temp is 40 degree, and mixing time is 10 minutes, obtains mixed liquor C;
4) 5 parts of surfactant, 5 parts of propane diols and 5 parts of antioxidant, is added in most backward mixed liquor C, and Mixed, mixing speed is 60 revs/min, and whipping temp is 60 degree, and mixing time is 30 minutes, and then normal temperature stands 3 Hour, and PH to 7.5 is adjusted, the grease dirt cleaning agent of the present invention is finally made.
In use, first drenching hand, then take 1ml or so grease dirt cleaning agent to be placed in hand and clean, industrial machinery greasy dirt Clearance is up to more than 99%, and degerming rate is up to more than 99%.
The foregoing is only presently preferred embodiments of the present invention, be not intended to limit the invention, it is all the present invention spirit and Within principle, any modification, equivalent substitution and improvements made etc., it should be included in the scope of the protection.

Claims (3)

  1. A kind of 1. preparation method of industrial machinery heavy oil pollution cleanser, it is characterised in that in parts by weight, including following step Suddenly:
    1), take the deionized water of 30-40 parts, be put into reactor, then take the diethanol amine of 4-8 parts, 2-6 parts it is quaternized Thing and the citric acid of 6-9 parts, and be poured into reactor mixed successively, mixing speed is 50-70 revs/min, stirring Temperature is 20-30 degree, and mixing time is 5-15 minutes, obtains mixed liquor A;
    2) the ten diamino benzene sulfonic acid sodium of 2-5 parts and the diethylene glycol ether of 3-7 parts, are slowly added into reactor, and is carried out Mix, mixing speed is 30-50 revs/min, and whipping temp is 25-35 degree, and mixing time is 10-15 minutes, is mixed Liquid B;
    3) potassium hydrogen tartrate of 2-5 parts, the biological disinfectant of 5-8 parts, the bergamio of 3-7 parts, are added into mixed liquid B, And mixed, mixing speed is 45-55 revs/min, and whipping temp is 32-40 degree, and mixing time is 5-10 minutes, is obtained Mixed liquor C;
    4) surfactant, the propane diols of 2-5 parts and the antioxidant of 3-5 parts of 3-5 parts, are added in most backward mixed liquor C, And mixed, mixing speed is 50-60 revs/min, and whipping temp is 55-60 degree, and mixing time is 20-30 minutes, so Normal temperature stands 2-3 hours afterwards, and adjusts PH to 6.5-7.5, and the grease dirt cleaning agent of the present invention is finally made.
  2. A kind of 2. preparation method of industrial machinery heavy oil pollution cleanser as claimed in claim 1, it is characterised in that the surface Activating agent is any three kinds of mixture in TX-10, FMES, LAS, AEO-9, TX-10, OP-10, QYL-83C and Y-35.
  3. A kind of 3. preparation method of industrial machinery heavy oil pollution cleanser as claimed in claim 1, it is characterised in that the biology Bacteria remover is made up of alginic acid fibre element.
CN201711188626.XA 2017-11-24 2017-11-24 A kind of preparation method of industrial machinery heavy oil pollution cleanser Pending CN107815363A (en)

Priority Applications (1)

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CN201711188626.XA CN107815363A (en) 2017-11-24 2017-11-24 A kind of preparation method of industrial machinery heavy oil pollution cleanser

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Application Number Priority Date Filing Date Title
CN201711188626.XA CN107815363A (en) 2017-11-24 2017-11-24 A kind of preparation method of industrial machinery heavy oil pollution cleanser

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CN107815363A true CN107815363A (en) 2018-03-20

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1021506A1 (en) * 1997-10-03 2000-07-26 The Procter & Gamble Company Peroxygen bleach-containing compositions comprising a particular chelating agent system
CN104946426A (en) * 2015-07-02 2015-09-30 康玉东 Range hood cleaner and preparation method thereof
CN105419969A (en) * 2015-12-16 2016-03-23 无锡吉进环保科技有限公司 Preparation method of industrial heavy oil stain cleaner

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1021506A1 (en) * 1997-10-03 2000-07-26 The Procter & Gamble Company Peroxygen bleach-containing compositions comprising a particular chelating agent system
CN104946426A (en) * 2015-07-02 2015-09-30 康玉东 Range hood cleaner and preparation method thereof
CN105419969A (en) * 2015-12-16 2016-03-23 无锡吉进环保科技有限公司 Preparation method of industrial heavy oil stain cleaner

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Application publication date: 20180320