KR20070006061A - Metal cleaner - Google Patents
Metal cleaner Download PDFInfo
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- KR20070006061A KR20070006061A KR1020050061054A KR20050061054A KR20070006061A KR 20070006061 A KR20070006061 A KR 20070006061A KR 1020050061054 A KR1020050061054 A KR 1020050061054A KR 20050061054 A KR20050061054 A KR 20050061054A KR 20070006061 A KR20070006061 A KR 20070006061A
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 80
- 239000002184 metal Substances 0.000 title claims abstract description 80
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Natural products OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 claims abstract description 10
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000012153 distilled water Substances 0.000 claims abstract description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 10
- 238000004140 cleaning Methods 0.000 claims description 8
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 5
- 230000009965 odorless effect Effects 0.000 claims description 2
- 230000035515 penetration Effects 0.000 claims description 2
- 239000003599 detergent Substances 0.000 claims 1
- 229910001220 stainless steel Inorganic materials 0.000 abstract description 9
- 239000010935 stainless steel Substances 0.000 abstract description 9
- PXRKCOCTEMYUEG-UHFFFAOYSA-N 5-aminoisoindole-1,3-dione Chemical compound NC1=CC=C2C(=O)NC(=O)C2=C1 PXRKCOCTEMYUEG-UHFFFAOYSA-N 0.000 abstract 1
- 229910017665 NH4HF2 Inorganic materials 0.000 abstract 1
- 230000002411 adverse Effects 0.000 abstract 1
- 230000008595 infiltration Effects 0.000 abstract 1
- 238000001764 infiltration Methods 0.000 abstract 1
- 239000002689 soil Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 13
- 239000012459 cleaning agent Substances 0.000 description 11
- 238000011109 contamination Methods 0.000 description 11
- 239000000126 substance Substances 0.000 description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 239000000356 contaminant Substances 0.000 description 4
- 230000006378 damage Effects 0.000 description 4
- 229920002430 Fibre-reinforced plastic Polymers 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000000645 desinfectant Substances 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 239000011151 fibre-reinforced plastic Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- -1 Hsinchu Substances 0.000 description 2
- 239000004902 Softening Agent Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 208000002193 Pain Diseases 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/263—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/261—Alcohols; Phenols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/265—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/16—Metals
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
Description
도 1a 내지 도 1d는 본 발명의 금속 세정제가 금속 표면에 도포되어 오염된 이물질을 제거시키는 공정도.1A to 1D are process diagrams in which the metal cleaner of the present invention is applied to a metal surface to remove contaminated foreign substances.
본 발명은 오염된 금속 표면에 대해 간단히 분사 도포하여 이물질을 제거할 수 있는 금속 세정제에 관한 것으로, 보다 상세하게는 스테인리스나 신주 등과 같은 금속 제품의 표면에 신속히 침투해서 작은 양으로도 오염된 녹물이나 찌든 때 등을 쉽게 제거하여 금속 본래의 품위와 광택을 되살려 줄 수 있는 금속 세정제에 관한 것이다.The present invention relates to a metal cleaner that can remove foreign matter by simply spraying on a contaminated metal surface, and more particularly, it is quickly penetrated into the surface of a metal product such as stainless steel or scavenger and contaminated in small amounts. The present invention relates to a metal cleaner that can easily remove stains and restore the original quality and gloss of metal.
통상 금속 제품이 오염되는 형태를 보면, 대기 중의 수분과 이물질이 금속 표면에 접촉되어 산화작용을 일으킴으로서 금속 본질의 형태를 잃게 되거나, 또는 사람의 지문이나 기타 오염물이 접촉하여 금속 표면이 변색되어 그 색을 잃어버리게 된다.In general, when the metal product is contaminated, the moisture and foreign substances in the air come into contact with the metal surface and cause oxidation, thereby losing the shape of the metal, or by discoloring the metal surface due to human fingerprints or other contaminants. The color is lost.
아울러 이와 같이 오염된 금속 표면을 깨끗하게 세정하여 금속 특유의 광택을 되살리고자 할 때 다양한 조성물의 세정제가 사용되고 있는데, 대부분의 세정제는 강산 성분이 높아 조금이라도 도포되는 양이 많을 경우 금속 표면을 부식시켜 정상적으로 깨끗한 세척상태를 얻기가 힘들었으며, 또한 그 양이 적을 경우에는 세척력이 떨어져 작업 자체가 상대적으로 힘들어질 수 있다.In addition, various compositions of cleaners are used to clean the contaminated metal surface to restore the gloss of metal. Most of the cleaners have a strong acid content, so if a large amount is applied to the metal surface, it will corrode the surface of the metal. It was difficult to obtain a clean cleaning state, and if the amount is small, the washing power may be low and the work itself may be relatively difficult.
특히, 지금까지 소개된 금속 제품의 오염 세척용 세정제는 광택은 좋으나 세척한 금속 제품의 연마효과가 장기적으로 지속되면, 금속 제품 본연(특유)의 색상과 질감을 잃기 쉬울 뿐만 아니라 오염을 제거하기 위해서는 오랜 시간과 많은 노동력이 필요하고, 조성물에 포함된 유지성분으로 인해 화재가 발생될 위험도 대단히 많은 등의 불편이 있었다.In particular, the cleaning agents for the contamination of metal products introduced so far have good gloss, but if the polishing effect of the washed metal products lasts for a long time, it is not only easy to lose the color and texture of the metal product, but also to remove the contamination. It takes a long time and a lot of labor, and due to the oil and fat contained in the composition, there is a great risk of fire.
본 발명은 스테인리스나 신주 등과 같은 금속 제품의 오염된 녹물이나 찌든 때 등을 비교적 적은 양으로도 세척력이 좋아 쉽게 제거할 수 있어 금속 본래의 품위와 광택을 되살려 줄 수 있으며, 또한 물분해도가 좋아 자연 친화적인 세척제로 인체에는 해가 없어 누구나 쉽고 안전하게 세척 작업할 수 있는 금속 세정제를 제공함에 그 목적이 있다.The present invention can be easily removed even with a relatively small amount of contaminated rust or splatter of metal products such as stainless steel or Hsinchu, so as to restore the original quality and luster of the metal, and also good water decomposition nature Its purpose is to provide a metal cleaner that can be cleaned easily and safely by anyone because it is harmless to human body.
상기의 목적을 달성하기 위한 본 발명의 금속 세정제는 다용도 금속 세정제 중량100%의 주성분으로서, 기본적으로 수용성 소독제인 불화암모늄(NH4HF2) 중량3-5%와, 인체에 무해하며 용액의 응고제인 구연산(C6H8O7-H2O) 중량2-4%와, 연화 및 세척제인 부틸세로솔브(C4H9OCH2CH2OH) 중량1-3%와, 물(증류수) 중량88-91%를 포함하여 조성된 것을 특징으로 한다.The metal cleaner of the present invention for achieving the above object is a main component of 100% by weight of a multi-purpose metal cleaner, basically 3 to 5% by weight of ammonium fluoride (NH 4 HF 2 ) as a water-soluble disinfectant, harmless to the human body and a solution coagulant Phosphoric citric acid (C 6 H 8 O 7 -H 2 O) weight 2-4%, softening and cleaning agent butyl vertical solver (C 4 H 9 OCH 2 CH 2 OH) weight 1-3%, water (distilled water) It is characterized by including the weight 88-91%.
이하에서는 본 발명의 구성 및 작용을 바람직한 실시예의 첨부 도면을 참조하여 상세히 설명한다.Hereinafter, the configuration and operation of the present invention will be described in detail with reference to the accompanying drawings of preferred embodiments.
본 발명의 금속 세정제는 스테인리스, 신주, 니켈과 같은 금속 제품의 표면에 발생되는 오염물질(이물질)을 신속히 침투하여 쉽게 분해시켜 깨끗하게 세정시킴으로서 금속 본래의 광택을 살려줄 수 있으며, 미량으로도 신뢰성 있는 세정상태가 유지될 수 있어 누구나 쉽게 사용 가능한 세정성분으로 이루어진다.Metal cleaning agent of the present invention can quickly penetrate contaminants (foreign substances) generated on the surface of metal products such as stainless steel, Hsinchu, nickel, and easily disintegrate to clean, thereby maintaining the original gloss of the metal, reliable even in small amounts The cleaning state can be maintained and consists of cleaning components that can be easily used by anyone.
이는 기본적으로 수용성 소독제인 불화암모늄(NH4HF2)(Ammonium Bi Fluoride) 중량4-6%와, 인체에 무해하며 용액의 응고제인 구연산(C6H8O7-H2O) (Citric Acid) 중량2-4%와, 특히 무색무취로 금속에 손상을 주지 않으면서 침투력이 좋아 세척후 금속 표면의 광택과 매끄러움을 유지시켜 줄 수 있도록 연화 및 세척제로서 부틸셀로솔브(C4H9OCH2CH2OH)(Butyl Cellosolve) 중량1-3%와, 물(증류수) 중량88-91%를 포함하여 금속 세정제가 조성되며, 필요에 따라 물의 첨가량을 줄이고 기타 소량의 글리콜(C2H6O2)(Glycol) 중량0.5-1.5%를 포함하여 조성될 수 있다.This is basically 4 to 6% by weight of water soluble disinfectant (NH 4 HF 2 ) (Ammonium Bi Fluoride), and citric acid (C 6 H 8 O 7 -H 2 O) (Ci H. ) Butyl Cellosolve (C 4 H 9 OCH) as a softening and cleaning agent to maintain the gloss and smoothness of the metal surface after washing due to its excellent penetration without damaging the metal with 2-4% by weight, especially colorless and odorless. 2 CH 2 OH) (Butyl Cellosolve) and 1-3% of water and 88-91% of water (distilled water), metal cleaner is formed, reducing the amount of water and other small amount of glycol (C 2 H 6 O 2 ) (Glycol) may comprise a weight of 0.5-1.5%.
즉, 본 발명에 따른 다용도 금속 세정제는 스테인리스나 신주, 니켈 등과 같 은 금속 제품의 표면에 신속히 침투해서 작은 양으로도 간단하게 거품이 발생되어 오염된 녹물이나 찌든 때 등을 쉽게 제거될 수 있도록, 특히 인체에 무해하면서 화재의 위험이 없는 수용성의 조성물로 이루어진다. 이는 도 1a 내지 도 1d에서 보는 것과 같이 이물질이 오염된 금속 표면에 대해 본 발명의 금속 세정제를 분사하면, 금속 표면으로 세정제가 도포 침투되어 거품이 발생되고 이를 마른 헝겊이나 스폰지로 닦아줌으로서 금속 표면의 이물질(때)를 깨끗하게 세척시켜 금속 본래의 품위와 광택을 회복시킬 수 있다.In other words, the multi-purpose metal cleaner according to the present invention can quickly penetrate the surface of metal products such as stainless steel, Hsinchu, nickel, etc., so that bubbles can be easily generated even in a small amount to easily remove contaminated green water or stinging. In particular, it is made of a water-soluble composition that is harmless to the human body and has no danger of fire. When the metal cleaner of the present invention is sprayed on a metal surface contaminated with foreign substances, as shown in FIGS. 1A to 1D, the metal cleaner is applied to the metal surface to penetrate and generate bubbles, and then wipe it with a dry cloth or sponge. You can wash the foreign matter of the clean and restore the original quality and gloss of the metal.
위와 같은 조성물로 이루어지는 본 발명의 금속 세정제의 제조공정을 바람직한 일 실시예를 통해 상세히 설명한다.The manufacturing process of the metal cleaner of the present invention made of the composition as described above will be described in detail through a preferred embodiment.
<실시예><Example>
우선 섬유강화플라스틱(FRP) 탱크에 본 발명의 금속 세정제 중량100%를 기준으로 물(H2O)을 중량89%로 계량한 후 교반기를 통해 일정시간 회전시키며, 작동되고 있는 상기 탱크에 불화암모늄(NH4HF2)을 분진이 날리지 않도록 중량5% 넣고 20분 정도 교반시킨다.First, water (H 2 O) is weighed at 89% by weight based on 100% by weight of the metal cleaner of the present invention in a fiber-reinforced plastic (FRP) tank, and then rotated for a predetermined time through an agitator. Add (NH 4 HF 2 ) 5% by weight so that dust does not fly off and stir for about 20 minutes.
특히 탱크로 사용되는 FRP(Fiberglass Reinforced Plastic)는 통상 엔지니어링 플라스틱이라 하며, 장력강도와 내충격성과 함께 난연성 및 내식성이 우수한 성질을 갖고 있으며, 물은 불순물이거의 없는 증류수를 사용함이 바람직하다. 아울러 불화암모늄은 무색의 침상 결정체로서 수용성이며 소독제로서 널리 이용되고 있는 물질이다.In particular, FRP (Fiberglass Reinforced Plastic) used as a tank is generally called an engineering plastic, and has excellent properties of flame retardancy and corrosion resistance along with tensile strength and impact resistance, and it is preferable to use distilled water with almost no impurities. In addition, ammonium fluoride is a colorless acicular crystal that is water-soluble and widely used as a disinfectant.
그리고 불화암모늄(NH4HF2)을 충분히 교반시킨 후, 구연산(Citric acid)을 상기 불화암모늄과 같은 방법으로 서서히 붓고(넣고) 20분 정도 교반시킨다. 상기 불화암모늄은 미량으로도 제품 표면에 침투시 정밀한 부식성을 가지므로 전체 조성물 중량100%에서 중량4-6%을 넘지 않도록 한다.After sufficiently stirring ammonium fluoride (NH 4 HF 2 ), citric acid is slowly poured into the same method as the ammonium fluoride and stirred for about 20 minutes. The ammonium fluoride has a fine corrosiveness when penetrated into the product surface even in a small amount so as not to exceed 4-6% by weight of the total composition.
아울러 상기 구연산은 식용이 가능할 정도로 인체에 무해하며, 특히 구연산에 포함된 전해질인 나트륨염은 칼슘을 해리도가 낮은 칼슘염으로 포착하기 때문에 용액의 응고 저지에 사용되며, 이는 본 발명의 세정제 사용시 금속 제품의 표면에 구연산의 나트륨이 증발후에 미량 잔류될 수 있으므로 반드시 린스작업을 추가적으로 실시함이 바람직하다. 이는 본 발명의 세정제가 용해제가 아니라 이물질을 박리시키는 작용을 하는 제품이기 때문에 이물질을 제거한 후에는 반드시 린스작업을 필요로 한다.In addition, the citric acid is harmless to the human body to be edible, in particular, sodium salt, an electrolyte contained in citric acid, is used to prevent coagulation of the solution because it traps calcium as a calcium salt having a low dissociation degree, which is a metal product when the cleaning agent of the present invention is used. Sodium citrate may remain on the surface of the traces after evaporation, so it is desirable to carry out additional rinsing. This is because the cleaning agent of the present invention is not a dissolving agent but a product that functions to peel off foreign substances, it is necessary to rinse after removing the foreign substances.
그리고 물 속에 소량으로 불화암모늄과 구연산이 용해되어 교반된 위의 용액이 잘 녹았는지 확인한 후, 부틸셀로솔브(C4H9OCH2CH2OH) 중량2%를 넣고 상대적으로 짧은 시간 약 10분 정도 교반시킨다.After a small amount of ammonium fluoride and citric acid were dissolved in water to confirm that the agitated solution was well dissolved, 2% by weight of butyl cellosolve (C 4 H 9 OCH 2 CH 2 OH) was added and a relatively short time was about 10%. Stir for minutes.
특히 부틸셀로솔브는 본 발명의 세정제에서 계면활성제 역할을 하게 되는데, 이는 계면활성제가 우수한 분산, 유화 및 세정능력을 지니고 있어 물과 잘 혼합될 수 있고 물을 연화시킬 수 있어 세척효과를 높일 수 있으며, 특히 금속 표면에 오염된 이물질 및 부유물질 등을 쉽게 용해하여 제거할 수 있을 뿐만 아니라 스케일 방지 및 세척기능을 갖도록 한다.In particular, butyl cellosolve serves as a surfactant in the cleaning agent of the present invention, which can have a good dispersion, emulsification and cleaning ability of the surfactant can be mixed well with water and soften the water can increase the cleaning effect In particular, it is possible to easily dissolve and remove contaminants and suspended substances contaminated on the metal surface, as well as to prevent scale and wash.
즉, 본 발명의 금속 세정제에 적용되어 계면활성제로서 역할을 하게 되는 부틸셀로솔브는 휘발성이 강하고 세척능력이 뛰어나 오염물을 흡착함과 동시에 함께 휘발함으로서, 세척작업에서 물로 헹궈내는 등의 후처리작업을 필요로 하지 않기에 세척작업을 보다 간편하고 용이하게 할 수 있다.That is, the butyl cellosolve applied to the metal cleaner of the present invention serves as a surfactant has a high volatility and excellent washing ability, so as to adsorb contaminants and volatilize at the same time, the post-treatment work such as rinsing with water in the washing operation Since it does not require the cleaning operation can be made easier and easier.
그리고 부틸셀로솔브와 별도로 알코올류인 글리콜을 극소량 첨가하는데, 이는 선택적으로 적용시킬 수 있으며 교반시간은 상대적으로 긴 30분 정도 실시하며 그 첨가량도 중량1% 정도로 그친다. 이는 식물성 산 정화제로서 조성물의 농도를 묽은 상태로 희석함과 동시에 혼합으로 발생되는 독성을 제거하는 역할을 하게 된다.In addition to the butyl cellosolve, a very small amount of alcohol, glycol, is added. This can be selectively applied, and the stirring time is performed for about 30 minutes, and the addition amount is only about 1% by weight. It is a vegetable acid purifier, which dilutes the concentration of the composition in a diluted state and at the same time serves to remove the toxicity caused by mixing.
또한 조성물에 대한 교반을 충분히 시킨 후 배수구에서 충진하여 리싸이클링을 실시하며(30분 후가 바람직함), 용기 주입구에 필터링을 하고 최종적으로 충진시킴으로서 본 발명의 금속 세정제가 제조될 수 있다.In addition, the metal cleaning agent of the present invention may be prepared by sufficiently stirring the composition and then filling the drain hole to recycle (preferably after 30 minutes), filtering the container inlet and finally filling it.
한편, 상기의 실시예를 포함한 다양한 실시예를 통해 본 발명에 첨가되는 각 조성물의 성분들이 전체적으로 혼할될 때의 변화를 통해 본 발명의 바람직한 조성범위를 확인할 수 있었다.On the other hand, through the various examples including the above embodiment was able to confirm the preferred composition range of the present invention through the change when the components of each composition added to the present invention as a whole mixed.
우선, 불화암모늄(NH4HF2)의 경우 전체 조성물 중량100%를 기준으로 중량1% 투입시 금속 표면에 변화가 없었으며, 중량2% 투입시에도 금속 표면의 오염때가 분리되는 것을 육안으로 판별하기 어려웠다. 그러나 중량3% 투입시에는 금속 표면의 오염때가 분리되는 미동의 변화를 확인할 수 있었다.First, in the case of ammonium fluoride (NH 4 HF 2 ), when the amount of 1% by weight based on 100% of the total composition did not change the metal surface, even when 2% by weight of the metal surface contamination was determined visually It was hard to do. However, when the weight of 3% was added, the change in the fineness of the contamination of the metal surface was confirmed.
계속해서 중량4% 투입 시부터 금속 표면의 오염때가 확실히 분리되는 것을 확인할 수 있었으며, 중량5% 투입시점에서 금속 표면의 오염때가 완전하게 분리되는 것을 확인할 수 있었고, 중량6% 이상 투입시에는 금속 표면에 미세한 손상(Damage)이 발생되는 것을 발견할 수 있었다. 이는 결과적으로 본 발명의 금속 세정제에 있어서 불화암모늄은 중량3% 이상 중량5% 이하의 범위 내에서 투입할 때 가장 원하는 세척효과가 제공될 수 있음을 알 수 있다.It was confirmed that the contamination of the metal surface was reliably separated from 4% by weight, and the contamination of the metal surface was completely separated at the time of 5% by weight. It was found that the fine damage (Damage) occurs in. As a result, it can be seen that in the metal cleaner of the present invention, when the ammonium fluoride is added in the range of 3% by weight to 5% by weight, the most desired washing effect can be provided.
그리고 구연산(acid)의 경우를 보면, 전체 조성물 중량100%를 기준으로 중량1% 투입시 금속 표면에 변화가 없었으며, 중량2% 투입 시부터 금속 표면의 오염때가 분리되는 미동의 변화를 확인할 수 있었다.And in the case of citric acid (acid), based on 100% by weight of the total composition did not change the metal surface when added 1% by weight, when the weight of 2% can be confirmed that the change in the microscopic separation of contamination of the metal surface from the input there was.
계속해서 중량4% 투입시점에서 금속 표면의 오염때가 완전하게 분리되는 것을 확인할 수 있었으나, 중량5% 이상 투입부터는 별다른 변화가 없어 결과적으로 가인 구연산에 대한 비용만 상승되었다. 이는 결과적으로 본 발명의 금속 세정제에 있어서 구연산은 중량2% 이상 중량4% 이하의 범위 내에서 투입할 때 가장 원하는 세척효과가 제공된다고 본다.It was confirmed that the contamination of the metal surface was completely separated at the time of 4% by weight, but since the input of more than 5% by weight, there was no change, resulting in an increase in the cost of Cain citric acid. As a result, in the metal cleaner of the present invention, citric acid is considered to provide the most desired washing effect when added within the range of 2% by weight to 4% by weight.
또한 부틸세로솔브(C4H9OCH2CH2OH)의 경우에는 전체 조성물 중량100%를 기준으로 중량1% 투입시부터 금속 표면의 오염때가 분리되는 미동의 변화를 확인할 수 있었으며, 중량3% 투입시점에서 금속 표면의 오염때가 완전하게 분리되는 것을 확인할 수 있었으나, 그 이상 투입부터는 별다른 변화가 없어 결과적으로 고가인 부틸세로솔브에 대한 비용만 상승되었다. 이는 결과적으로 본 발명의 금속 세정제에 있어서 부틸세로솔브는 중량1% 이상 중량3% 이하의 범위 내에서 투입할 때 가장 원하는 금속의 세척효과가 제공되는 것으로 확인되었다.In addition, in the case of butyl vertical solver (C 4 H 9 OCH 2 CH 2 OH) based on 100% of the total composition weight 1% by weight based on the change of microscopic separation of the contamination of the metal surface was confirmed, 3% by weight It was confirmed that the contamination of the metal surface was completely separated at the time of input, but there was no change from the input afterwards, and as a result, the cost for the expensive butyl vertical solver was increased. As a result, the butyl vertical solver in the metal cleaner of the present invention was found to provide the most desired cleaning effect of the metal when added in the range of 1% to 3% by weight.
이와 같은 실시예의 방법으로 조성되는 본 발명의 금속 세정제는 도 1a 내지 도 1d에서와 같이, 스테인리스나 니켈과 같은 금속 제품의 오염부위에 대략 25-30㎝ 의 거리를 두고 본 발명의 세정제를 분사시키면 세정제의 거품이 금속 제품의 표면으로 균등하게 도포되며, 계속해서 마른 헝겊이나 스폰지로 깨끗이 닦은 다음 다시 젖은 걸레로 깨끗이 닦으면 도 1d에서 보는 것처럼 금속 표면의 이물질을 확실하게 완전 제거시킬 수 있다. 특히 금속 표면에 대한 걸레질은 부드러운 스폰지나 천으로 결방향을 따라 실시하며 이물질을 제거한 다음에는 반드시 젖은 걸레로 깨끗하게 린스작업을 실시함이 바람직하다.The metal cleaning agent of the present invention prepared by the method of this embodiment is sprayed with the cleaning agent of the present invention at a distance of approximately 25-30 cm to a contaminated part of a metal product such as stainless steel or nickel, as shown in FIGS. 1A to 1D. The foam of the cleaning agent is evenly applied to the surface of the metal product, and then continuously cleaned with a dry cloth or sponge and then again with a wet mop to completely remove the foreign matter from the metal surface as shown in FIG. 1D. In particular, mop the metal surface with a soft sponge or cloth along the grain direction, and after removing the foreign matter, it is preferable to rinse with a wet mop.
이는 본 발명의 금속 세정제가 기존의 세정제와는 달리 적은 양으로도 금속 제품의 오염부위에 도포되어 충분한 거품을 발생시켜 금속 표면에 오염되어 달라붙어 있는 이물질(때)을 쉽게 제거할 수 있으며, 특히 본 발명의 조성이 물분해도가 좋아 자연 친화적인 세척제로 인체에는 해가 없어 누구나 쉽고 안전하게 세척 작업할 수 있다.This is because the metal cleaner of the present invention, unlike conventional cleaners, is applied to the contaminated parts of the metal product in a small amount to generate sufficient bubbles, so that foreign substances (contamination) contaminated on the metal surface can be easily removed. The composition of the present invention has a good degree of water decomposition, there is no harm to the human body as a natural friendly cleaner, anyone can easily and safely wash.
이상에서 설명한 바와 같이, 본 발명의 금속 세정제는 스테인리스나 신주 등과 같은 금속 제품의 표면에 대해 신속히 침투해서 작은 양으로도 충분한 거품을 발생시켜 오염된 녹물이나 찌든 때 등을 쉽게 제거하여 금속 본래의 품위와 광택을 되살려 줄 수 있으며, 특히 물분해도가 좋아 자연 친화적인 세척제로 인체에는 해가 없어 누구나 쉽고 안전하게 세척 작업할 수 있는 효과가 제공될 수 있는바, 스테인리스, 수도꼭지, 싱크대, 가스렌지, 공구류, 자동차 보조범퍼, 오토바이, 엘리베이터, 계단난간, 에스컬레이터, 호텔 로비 회전문, 스텐 냄비 등과 같은 금속 제품에 폭넓게 적용될 수 있다.As described above, the metal cleaner of the present invention quickly penetrates into the surface of a metal product such as stainless steel or new liquor, and generates sufficient bubbles even in a small amount, thereby easily removing contaminated rust or streaks, thereby intrinsic quality of the metal. It can restore the shine and luster. Especially, it is water-friendly, and it is a nature-friendly cleaner, which can harm the human body easily and safely. Therefore, stainless steel, faucet, sink, stove, tools, It can be widely applied to metal products such as automobile auxiliary bumpers, motorcycles, elevators, stair railings, escalators, hotel lobby revolving doors, stainless steel pots, etc.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011063353A3 (en) * | 2009-11-23 | 2011-11-24 | Metcon, Llc | Electrolyte solution and electropolishing methods |
| WO2012071030A1 (en) * | 2010-11-22 | 2012-05-31 | Metcon, Llc | Electrolyte solution and electrochemical surface modification methods |
| US9499919B2 (en) | 2010-11-22 | 2016-11-22 | MetCon LLC | Electrolyte solution and electrochemical surface modification methods |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011063353A3 (en) * | 2009-11-23 | 2011-11-24 | Metcon, Llc | Electrolyte solution and electropolishing methods |
| CN102686786A (en) * | 2009-11-23 | 2012-09-19 | 梅特康有限责任公司 | Electrolyte solution and electropolishing methods |
| US8357287B2 (en) | 2009-11-23 | 2013-01-22 | MetCon LLC | Electrolyte solution and electropolishing methods |
| EA021898B1 (en) * | 2009-11-23 | 2015-09-30 | МЕТКОН, ЭлЭлСи | Use of an aqueous electrolyte solution for electrochemical machining a surface of anode metal workpiece, and corresponding methods |
| WO2012071030A1 (en) * | 2010-11-22 | 2012-05-31 | Metcon, Llc | Electrolyte solution and electrochemical surface modification methods |
| EA024812B1 (en) * | 2010-11-22 | 2016-10-31 | МЕТКОН, ЭлЭлСи | Electrolyte solution and electrochemical surface modification methods |
| US9499919B2 (en) | 2010-11-22 | 2016-11-22 | MetCon LLC | Electrolyte solution and electrochemical surface modification methods |
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