CN104531914B - A kind of bating agent - Google Patents
A kind of bating agent Download PDFInfo
- Publication number
- CN104531914B CN104531914B CN201410776354.5A CN201410776354A CN104531914B CN 104531914 B CN104531914 B CN 104531914B CN 201410776354 A CN201410776354 A CN 201410776354A CN 104531914 B CN104531914 B CN 104531914B
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- China
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- parts
- leather
- peregal
- ethanol
- water
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C1/00—Chemical treatment prior to tanning
- C14C1/08—Deliming; Bating; Pickling; Degreasing
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C9/00—Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes
Abstract
The invention discloses a kind of bating agent, is by the raw material of following parts by weight：Polyether-modified 15 ~ 35 parts of hydrophilic silicon oil, 10 ~ 22 parts of phosphoglyceride, 8 ~ 25 parts of dodecyl sodium sulfate, 40 ~ 60 parts of ethanol, 5 ~ 15 parts of peregal, 30 ~ 50 parts of water, 0 ~ 3 part of lemon are prepared.Active component in the bating agent of the present invention can preferably enter inside leather forms Hydrogenbond with the hydrophilic radical on leather internal fiber, by interleaved or hardening fiber separation or re-form ordered arrangement, space between increase fiber causes leather to recover elastic force again, is aided with the good permeability of leather；Active component therein forms firm be connected with grease by the effect leather internal fiber of " bridge joint " inside leather and make it that leather internal grease is not volatile, extends the life-span of leather；Leather after bating agent processing of the present invention has good gas permeability, flexibility, resilience and smooth feel.
Description
Technical field
The present invention relates to a kind of leather treatment, specifically a kind of bating agent, belong to technical field of fine.
Background technology
Leather and fur products has used among people live extensively at present.But with use of the leather among daily life,
Due to environmental change, such as moisture, temperature can cause grease inside leather or oil film to be destroyed, grease volatilization so that skin
Will mutually it be bonded together between leather internal fiber, so that corium is hardened, become fragile.
This kind of product such as leather cleaning agent, leather care products, bating agent are filled oily often by again to leather
Fat reaches the purpose of softening leather.CN 103669002A disclose a kind of the following raw material including according to mass fraction meter：Hydroxyl
Base silicone oil 20-25 parts, acrylic acid 0.5-1 parts, Tissuemat E 0.2-0.3 parts, myristamide propyl group hydroxypropyl sulfobetaines
2-5 parts, ethanol 30-40 parts, water 40-45 parts, wherein, hydroxy silicon oil is made of the linear polydimethylsiloxane that end group is hydroxyl
Leather softening agent.CN1253980 discloses a kind of soft dose of leather, wherein include wax emulsion and methyl-silicone oil mixture, and
With high polymer material with 1:1:1 volume ratio is thoroughly mixed into milky white liquid at room temperature, its high polymer material be from
The synthetic chemical being extract in fish oil, vegetable oil and mineral oil.It is by each that CN104032049A, which discloses a kind of leather fat,
Material is prepared by following composition by weight：Lard 0-400 parts, olive oil macrogol ester 10-400 parts, sodium alkyl sulfonate 50-100
Part, polyoxyethylene alkyl phosphate 0-100 parts, 52# chlorinated paraffin 60-80 parts, softening agent 1-5 parts.
With the requirement to environmental protection, the selection of existing leather softening agent is often intended to select water-based leather soft
Agent, or oil-containing but the leather softening agent that can hydrolyze.Water-based product, its persistence are not grown, poor with the affinity of leather,
When from the grease of long-chain macromolecule composition, grease is not easily penetrated into inside leather the product of oiliness, can not be to leather inside
Hardening carry out maintenance.
The content of the invention
It is an object of the invention to provide a kind of bating agent, and it is by the raw material of following parts by weight：Polyether-modified
15 ~ 35 parts of hydrophilic silicon oil, 10 ~ 22 parts of phosphoglyceride, 8 ~ 25 parts of dodecyl sodium sulfate, 40 ~ 60 parts of ethanol, peregal 5 ~
15 parts, 30 ~ 50 parts of water, 0 ~ 3 part of lemon, prepared using following steps：
（1）Polyether-modified hydrophilic silicon oil, phosphoglyceride are mixed with 1200 ~ 1600r/min rotating speed and divided
10 ~ 15min is dissipated, 1/5th water, 1/3rd peregal, 1/3rd ethanol is added, continues 3 ~ 5min of stirring；
（2）Dodecyl sodium sulfate, remaining ethanol, remaining water are placed in other disperser and are mixed evenly,
Remaining peregal and lemon are added, continues 5 ~ 10min of stirring, then adds step（1）Obtained mixed emulsion, stirring
Scattered 5min, you can.
In above-mentioned technical proposal, the parts by weight of the preferable constitutive material of bating agent can be：Polyether-modified parent
Water-based 18 ~ 30 parts of silicone oil, 15 ~ 20 parts of phosphoglyceride, 10 ~ 22 parts of dodecyl sodium sulfate, 40 ~ 50 parts of ethanol, peregal 5 ~
13 parts, 33 ~ 48 parts of water, 0 ~ 3 part of lemon.
The parts by weight of bating agent constitutive material can be：Polyether-modified 18 ~ 30 parts of hydrophilic silicon oil, phosphoric acid are sweet
15 ~ 20 parts of grease, 10 ~ 22 parts of dodecyl sodium sulfate, 40 ~ 50 parts of ethanol, 5 ~ 13 parts of peregal, 33 ~ 48 parts of water, lemon
0 ~ 3 part.
The parts by weight of the bating agent constitutive material further optimized are：Polyether-modified 22 parts of hydrophilic silicon oil,
18 parts of phosphoglyceride, 11 parts of dodecyl sodium sulfate, 52 parts of ethanol, 8 parts of peregal, 29 parts of water, 1 part of lemon.
Having the beneficial effect that relative to prior art of the invention：Leather is a kind of modified production of natural protein fibre
Thing, wherein house has substantial amounts of hydrophilic radical, the active component in bating agent of the invention is wrapped in water-in-oil type
In micro-fine capsule, when micro-fine capsule contacts with leather surface, similar polarity causes micro-fine capsule to be easier to enter inside leather,
So as to discharge active component hydrophilic in micro-fine capsule, Hydrogenbond is formed with the hydrophilic radical on leather internal fiber, will
Interleaved or hardening fiber separation re-forms ordered arrangement, and the space increased between fiber causes leather to recover again
Elastic force, while also it is aided with the good permeability of leather；Active component phosphoglyceride therein had not only had hydrophilic radical but also contained
There is hydrophobic grouping, after being released, its hydrophilic radical is combined with fiber, hydrophobic grouping is combined with the grease in leather, passes through " bridge
Connect " effect so that leather internal fiber and grease form it is firm be connected and so that leather internal grease is not volatile, prolong
The life-span of leather is grown；Polyether-modified hydrophilic silicon oil, soluble in water, compatibility is good, can assign the leather under coating covering
Good gas permeability, flexibility, resilience and smooth feel.
Embodiment
The present invention is described in further details below by embodiment, these embodiments are only used for illustrating the present invention, and
Do not limit the scope of the invention.
Embodiment 1 uses the raw material of following parts by weight：Polyether-modified 22 parts of hydrophilic silicon oil, phosphoglyceride 18
Part, 11 parts of dodecyl sodium sulfate, 52 parts of ethanol, 8 parts of peregal, 29 parts of water, 1 part of lemon, as follows：
（1）Polyether-modified hydrophilic silicon oil, phosphoglyceride are mixed with 1400r/min rotating speed and disperseed
12min, 1/5th water, 1/3rd peregal, 1/3rd ethanol are added, continue to stir 3min；
（2）Dodecyl sodium sulfate, remaining ethanol, remaining water are placed in other disperser and are mixed evenly,
Remaining peregal and lemon are added, continues to stir 5min, then adds step（1）Obtained mixed emulsion, stirring point
5min is dissipated, bating agent is made.
Embodiment 2 uses the raw material of following parts by weight：Polyether-modified 28 parts of hydrophilic silicon oil, phosphoglyceride 15
Part, 10.5 parts of dodecyl sodium sulfate, 55 parts of ethanol, 10.5 parts of peregal, 30 ~ 50 parts of water, 3 parts of lemon, by following step
Suddenly：
（1）Polyether-modified hydrophilic silicon oil, phosphoglyceride are mixed with 1200r/min rotating speed and disperseed
15min, 1/5th water, 1/3rd peregal, 1/3rd ethanol are added, continue to stir 5min；
（2）Dodecyl sodium sulfate, remaining ethanol, remaining water are placed in other disperser and are mixed evenly,
Remaining peregal and lemon are added, continues to stir 6min, then adds step（1）Obtained mixed emulsion, stirring point
5min is dissipated, bating agent is made.
Embodiment 3 uses the raw material of following parts by weight：By 33 parts polyether-modified of hydrophilic silicon oil, phosphoglyceride 22
Part, 20 parts of dodecyl sodium sulfate, 60 parts of ethanol, 15 parts of peregal, 50 parts of water, 2 parts of lemon, as follows：
（1）Polyether-modified hydrophilic silicon oil, phosphoglyceride are mixed with 1600r/min rotating speed and disperseed
10min, 1/5th water, 1/3rd peregal, 1/3rd ethanol are added, continue to stir 5min；
（2）Dodecyl sodium sulfate, remaining ethanol, remaining water are placed in other disperser and are mixed evenly,
Remaining peregal and lemon are added, continues to stir 8min, then adds step（1）Obtained mixed emulsion, stirring point
5min is dissipated, bating agent is made.
Claims (3)
- A kind of 1. bating agent, it is characterised in that：By 22 parts polyether-modified of hydrophilic silicon oil, 18 parts of phosphoglyceride, ten 11 parts of dialkyl sulfonates, 52 parts of ethanol, 8 parts of peregal, 29 parts of water, 1 part of lemon, are prepared using following steps：（1）Polyether-modified hydrophilic silicon oil, phosphoglyceride are mixed into scattered 12min with 1400r/min rotating speed, added Enter 1/5th water, 1/3rd peregal, 1/3rd ethanol, continue to stir 3min；（2）Dodecyl sodium sulfate, remaining ethanol, remaining water are placed in other disperser and is mixed evenly, is added Remaining peregal and lemon, continue to stir 5min, then add step（1）Obtained mixed emulsion, is dispersed with stirring 5min, you can.
- A kind of 2. bating agent, it is characterised in that：By 28 parts polyether-modified of hydrophilic silicon oil, 15 parts of phosphoglyceride, ten 10.5 parts of dialkyl sulfonates, 55 parts of ethanol, 10.5 parts of peregal, 30 ~ 50 parts of water, 3 parts of lemon, using following steps system It is standby：（1）Polyether-modified hydrophilic silicon oil, phosphoglyceride are mixed into scattered 15min with 1200r/min rotating speed, added Enter 1/5th water, 1/3rd peregal, 1/3rd ethanol, continue to stir 5min；（2）Dodecyl sodium sulfate, remaining ethanol, remaining water are placed in other disperser and is mixed evenly, is added Remaining peregal and lemon, continue to stir 6min, then add step（1）Obtained mixed emulsion, is dispersed with stirring 5min, you can.
- A kind of 3. bating agent, it is characterised in that：By 33 parts polyether-modified of hydrophilic silicon oil, 22 parts of phosphoglyceride, ten 20 parts of dialkyl sulfonates, 60 parts of ethanol, 15 parts of peregal, 50 parts of water, 2 parts of lemon, are prepared using following steps：（1）Polyether-modified hydrophilic silicon oil, phosphoglyceride are mixed into scattered 10min with 1600r/min rotating speed, added Enter 1/5th water, 1/3rd peregal, 1/3rd ethanol, continue to stir 5min；（2）Dodecyl sodium sulfate, remaining ethanol, remaining water are placed in other disperser and is mixed evenly, is added Remaining peregal and lemon, continue to stir 8min, then add step（1）Obtained mixed emulsion, is dispersed with stirring 5min, you can.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410776354.5A CN104531914B (en) | 2014-12-17 | 2014-12-17 | A kind of bating agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410776354.5A CN104531914B (en) | 2014-12-17 | 2014-12-17 | A kind of bating agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104531914A CN104531914A (en) | 2015-04-22 |
| CN104531914B true CN104531914B (en) | 2018-01-16 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN201410776354.5A Active CN104531914B (en) | 2014-12-17 | 2014-12-17 | A kind of bating agent |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104928409A (en) * | 2015-06-19 | 2015-09-23 | 周彩球 | Leather softener |
| CN105200766A (en) * | 2015-11-13 | 2015-12-30 | 付淑珍 | Novel softening agent for leather and preparation method of softening agent |
| CN107460262A (en) * | 2017-09-21 | 2017-12-12 | 安徽鞋匠世家新型鞋材科技有限公司 | A kind of leather environment-friendly type softening agent |
| CN116162747A (en) * | 2023-04-18 | 2023-05-26 | 广州市鸿峥实业有限公司 | Perfuming type sheepskin handfeel agent |
| CN116574854A (en) * | 2023-06-12 | 2023-08-11 | 浙江红蜻蜓鞋业股份有限公司 | Leather softener and preparation process thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004062201A1 (en) * | 2004-12-23 | 2006-07-13 | Basf Ag | A urethane compound incorporating a polyether group-containing silicone derivative and a nitrogen heterocycle |
| CN103666881A (en) * | 2013-12-17 | 2014-03-26 | 常熟虞贵人家居用品有限公司 | Leather detergent |
| CN103966031A (en) * | 2014-05-30 | 2014-08-06 | 于文 | Environment-friendly leather cleaning care agent and preparation method thereof |
-
2014
- 2014-12-17 CN CN201410776354.5A patent/CN104531914B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004062201A1 (en) * | 2004-12-23 | 2006-07-13 | Basf Ag | A urethane compound incorporating a polyether group-containing silicone derivative and a nitrogen heterocycle |
| CN103666881A (en) * | 2013-12-17 | 2014-03-26 | 常熟虞贵人家居用品有限公司 | Leather detergent |
| CN103966031A (en) * | 2014-05-30 | 2014-08-06 | 于文 | Environment-friendly leather cleaning care agent and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 皮革用聚醚硅油的研究;张建雨等;《皮革与化工》;20111031;第28卷(第5期);第1-6和39页 * |
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| CN104531914A (en) | 2015-04-22 |
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