CN104946048A - Nanoscale water-resisting oil-stain-resisting leather surface treatment agent and preparing method thereof - Google Patents
Nanoscale water-resisting oil-stain-resisting leather surface treatment agent and preparing method thereof Download PDFInfo
- Publication number
- CN104946048A CN104946048A CN201510388491.6A CN201510388491A CN104946048A CN 104946048 A CN104946048 A CN 104946048A CN 201510388491 A CN201510388491 A CN 201510388491A CN 104946048 A CN104946048 A CN 104946048A
- Authority
- CN
- China
- Prior art keywords
- surface treatment
- treatment agent
- water
- oil
- leather surface
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Abstract
The invention discloses a nanoscale water-resisting oil-stain-resisting leather surface treatment agent and a preparing method thereof. The surface treatment agent comprises 2.0-4.0 parts of surface active agents, 28.0-50.0 parts of hydrogenated kerosene, 1.0-5.0 parts of synthetic wax, 5.0-8.0 parts of fluorine alkyl acrylate resin, 1.0-6.0 parts of active silicon oil, 0.1-0.5 part of essence, 4.0-12.0 parts of auxiliaries, 0.1-0.3 part of corrosion remover and 16.4-56.6 parts of water, wherein the surface active agents are water-in-oil type emulsifier. The preparing method includes the following steps that the surface active agents, the hydrogenated kerosene, the active silicon oil, the synthetic wax and the fluorine alkyl acrylate resin serve as the oil phase and are added into an emulsifying pot to be heated according to the ratio; water and glycerinum are added into a water phase pot to be heated, water phase drops are added into the emulsifying pot while stirring is conducted, and the mixture is evenly stirred and cooled; the corrosion remover and the essence are added to the mixture and evenly stirred. Water-in-oil type emulsifier transparent microemulsion is made through a special formula and process, the water-resisting performance and oil-stain-resisting performance are better, leather drape and tiny cracks can be effectively filled, and the mirror surface result of leather is kept.
Description
Technical field
The present invention relates to a kind of leather surface treatment agent and preparation method thereof, particularly relate to a kind of water resistant oil rub resistance leather surface treatment agent and preparation method thereof.
Background technology
The use of leather in our daily life widely, leather shoes can be made, fur clothing, the multiple leatherware such as suitcase, the irreplaceable advantage with its uniqueness of leather fabric, but after leatherware uses for some time, its surface is owing to making moist, be infected with dust, the reasons such as greasy dirt, leather surface is caused to be easy to seem intense darkness without light, seriously have impact on the aesthetics of its appearance, result of use and work-ing life, natural leather has superior moisture absorption, ventilative characteristic, for keeping this natural characteristic, during Finishing Process, generally covering with paint amount is lower or do not cover with paint, lacquer, colour wash, etc., because the wetting ability of leather is better, so its water resistant resistance to oily stain is generally poor, leathercraft has been stained with water, it can be made to harden, distortion, as stain various machine oil, salad oil, culinary art wet goods greasy dirt, human consumer is difficult to process, only deliver to leather nursing shop to clean, waste time and energy, the leather nursing product corium maintenance oil that present majority uses, although there is certain water-repellancy, but water resistant resistance to oily stain is bad, and present most leather surface treatment agent great majority are water aqua type or oil-in-water-type, water resistant resistance to oily stain own is not strong.
Summary of the invention
Technical problem to be solved by this invention is leather surface treatment agent that will provide a kind of high performance nano level water resistant oil rub resistance and preparation method thereof, special formulation and technique is adopted to make the translucent microemulsion of water-in-oil, not only water resistant oil rub resistance performance is better, and effectively can fill up leather fold and tiny slight crack, keep the mirror effect of leather.
For solving the problems of the technologies described above, technical scheme of the present invention is as follows:
A leather surface treatment agent for nano level water resistant oil rub resistance, the weight part of each component is as follows:
Wherein tensio-active agent is water-in-oil type emulsifier.
Described tensio-active agent is alkylpolyoxyethylene-9 polydimethylsiloxane.
Described synthetic wax is Microcrystalline Wax or S wax.
Described auxiliary agent is propylene glycol or glycerine.
Weight part as its each component of one of specific embodiment is as follows:
Weight part as two its each components of specific embodiment is as follows:
Weight part as three its each components of specific embodiment is as follows:
Weight part as four its each components of specific embodiment is as follows:
Weight part as five its each components of specific embodiment is as follows:
Invention also provides a kind of preparation method of leather surface treatment agent of above-mentioned nano level water resistant oil rub resistance, step comprises:
A, by proportioning, by tensio-active agent, hydrogenated kerosene, active silicone oil, synthetic wax, perfluoroalkyl acrylic resin adds in emulsification pot as oil phase, is heated to 85-90 DEG C; Water and glycerine are added aqueous phase pot, is heated to 85-90 DEG C, under agitation, aqueous phase is added dropwise to emulsification pot, after adding, stirs, cooling;
B. be cooled to 40 degree, add sanitas, essence, stir.
The invention provides a kind of leather surface treatment agent of high performance nano level water resistant oil rub resistance, special formulation and technique is adopted to make the translucent microemulsion of water-in-oil, water-in-oil microemulsion and foreign minister are oil, inside water mutually, and traditional oil-in-water-type is just in time contrary, oil-in-water-type is met water and can be melted away, and water-in-oil-type chance water can not melt away, water in oil microemulsion realizes primarily of water-in-oil emulsifier, the hydrophobic chain of water-in-oil emulsifier points to oil phase, hydrophilic chain is fixed in aqueous phase, stablize to make phase interface, the most foreign minister of water-in-oil is oil, be coated on leather and will form one deck waterproof oil film, this is the feature that O/w emulsion does not have.There is water resistant oil rub resistance agent perfluoroalkyl acrylic resin simultaneously, water resistant oil rub resistance performance is better than oil-in-water-type and water aqua type emulsion all greatly, because being refine to the Nano grade of emulsion particle diameter 50 ~ 100nm by the formula wax of elite emulsification reagent of the present invention etc. and active silicone oil, effectively can fill up leather fold and tiny slight crack, keep the mirror effect of leather, easy to use, not only water resistant oil rub resistance is effective, and luminance brightness is excellent, feel is smooth.
Perfluoroalkyl acrylic resin, there is the water resistant oil-resistant characteristic that other hydro carbons are incomparable, and there is high perviousness, its mechanism of action infiltrates 2-3mm in leather surface, not film forming, do not block the pore of natural leather, the water vapor permeable rate of leather substance is unaffected, and keeps the original outward appearance of leather
During use, with after the even spreadable emulsion of dry soft cloth on leather, then wipe to thin layer even, naturally parch, through the upper leather surface crossing leather surface treatment agent prepared by the present invention, there is very strong water resistant oil rub resistance function, stick in the greasy dirt on leather, can easily remove, because emulsion itself is water-in-oil-type, existing water-repellancy, add perfluoroalkyl acrylic resin, water resistant oil rub resistance performance is more excellent, and luminance brightness is good, and feel is smooth.
Accompanying drawing explanation
In order to be illustrated more clearly in the embodiment of the present invention or technical scheme of the prior art, be briefly described to the accompanying drawing used required in embodiment or description of the prior art below.
Fig. 1 is preparation method's schematic flow sheet of the leather surface treatment agent of nano level water resistant oil rub resistance of the present invention.
Embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described.
A leather surface treatment agent for nano level water resistant oil rub resistance, the weight part of each component is as follows:
Wherein tensio-active agent is water-in-oil type emulsifier.
Described tensio-active agent is alkylpolyoxyethylene-9 polydimethylsiloxane.
Described synthetic wax is Microcrystalline Wax or S wax.
Described auxiliary agent is propylene glycol or glycerine.
Following table is the component proportioning table of embodiment 1-5:
As shown in Figure 1, the preparation method of the leather surface treatment agent of the nano level water resistant oil rub resistance of above embodiment comprises the steps:
A, by proportioning, tensio-active agent, hydrogenated kerosene, active silicone oil, synthetic wax, perfluoroalkyl acrylic resin are added in emulsification pot as oil phase, be heated to 85-90 DEG C, water and glycerine are added aqueous phase pot, is heated to 85-90 DEG C, under agitation (120-150rpm), aqueous phase is added dropwise to emulsification pot, after adding, stir 20 minutes, cooling;
B, be cooled to 40 degree, add sanitas, essence, stir.
The above; be only the specific embodiment of the present invention, but protection scope of the present invention is not limited thereto, is anyly familiar with those skilled in the art in the technical scope that the present invention discloses; change can be expected easily or replace, all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should described be as the criterion with the protection domain of claim.
Claims (10)
1. a leather surface treatment agent for nano level water resistant oil rub resistance, is characterized in that the weight part of each component is as follows:
Wherein tensio-active agent is water-in-oil type emulsifier.
2. the leather surface treatment agent of nano level water resistant oil rub resistance according to claim 1, is characterized in that: described tensio-active agent is alkylpolyoxyethylene-9 polydimethylsiloxane.
3. the leather surface treatment agent of nano level water resistant oil rub resistance according to claim 1, is characterized in that: described synthetic wax is Microcrystalline Wax or S wax.
4. the leather surface treatment agent of nano level water resistant oil rub resistance according to claim 1, is characterized in that: described auxiliary agent is propylene glycol or glycerine.
5. the leather surface treatment agent of nano level water resistant oil rub resistance according to claim 1, is characterized in that the weight part of each component is as follows:
6. the leather surface treatment agent of nano level water resistant oil rub resistance according to claim 1, is characterized in that the weight part of each component is as follows:
7. the leather surface treatment agent of nano level water resistant oil rub resistance according to claim 1, is characterized in that the weight part of each component is as follows:
8. the leather surface treatment agent of nano level water resistant oil rub resistance according to claim 1, is characterized in that the weight part of each component is as follows:
9. the leather surface treatment agent of nano level water resistant oil rub resistance according to claim 1, is characterized in that the weight part of each component is as follows:
10. the preparation method of the leather surface treatment agent of a nano level water resistant oil rub resistance according to claim 1: it is characterized in that step comprises:
A, by proportioning, by tensio-active agent, hydrogenated kerosene, active silicone oil, synthetic wax, perfluoroalkyl acrylic resin adds in emulsification pot as oil phase, is heated to 85-90 DEG C; Water and glycerine are added aqueous phase pot, is heated to 85-90 DEG C, under agitation, aqueous phase is added dropwise to emulsification pot, after adding, stirs, cooling;
B. be cooled to 40 degree, add sanitas, essence, stir.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510388491.6A CN104946048A (en) | 2015-07-03 | 2015-07-03 | Nanoscale water-resisting oil-stain-resisting leather surface treatment agent and preparing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510388491.6A CN104946048A (en) | 2015-07-03 | 2015-07-03 | Nanoscale water-resisting oil-stain-resisting leather surface treatment agent and preparing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104946048A true CN104946048A (en) | 2015-09-30 |
Family
ID=54161130
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510388491.6A Pending CN104946048A (en) | 2015-07-03 | 2015-07-03 | Nanoscale water-resisting oil-stain-resisting leather surface treatment agent and preparing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104946048A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107099626A (en) * | 2017-05-26 | 2017-08-29 | 上海皇宇科技发展有限公司 | A kind of vamp filling glazing dressing agent and preparation method thereof |
| CN107189684A (en) * | 2017-05-19 | 2017-09-22 | 上海皇宇科技发展有限公司 | A kind of leather surface treatment agent of anti-aging water resistant oil rub resistance and preparation method thereof |
| WO2018196023A1 (en) * | 2017-04-27 | 2018-11-01 | 陈秋华 | Liquid shoe polish and preparation method therefor |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1040051A (en) * | 1989-07-12 | 1990-02-28 | 金颖逵 | Multifunction detergent and preparation method thereof |
| CN1093389A (en) * | 1993-04-05 | 1994-10-12 | 肖石 | Changeable type (transition), multipurpose dirt removing optical brightener and preparation method thereof |
| CN101659906A (en) * | 2008-08-28 | 2010-03-03 | 北京玉佳明三态离子科学研究院有限公司 | Water-in-oil type multipurpose high-performance decontamination polishing agent |
| CN102464949A (en) * | 2010-11-09 | 2012-05-23 | 王礼胜 | Leather surface treating agent |
| CN103695578A (en) * | 2013-12-30 | 2014-04-02 | 青昊环保科技（上海）有限公司 | Leather water-proof curing agent and preparing method thereof |
-
2015
- 2015-07-03 CN CN201510388491.6A patent/CN104946048A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1040051A (en) * | 1989-07-12 | 1990-02-28 | 金颖逵 | Multifunction detergent and preparation method thereof |
| CN1093389A (en) * | 1993-04-05 | 1994-10-12 | 肖石 | Changeable type (transition), multipurpose dirt removing optical brightener and preparation method thereof |
| CN101659906A (en) * | 2008-08-28 | 2010-03-03 | 北京玉佳明三态离子科学研究院有限公司 | Water-in-oil type multipurpose high-performance decontamination polishing agent |
| CN102464949A (en) * | 2010-11-09 | 2012-05-23 | 王礼胜 | Leather surface treating agent |
| CN103695578A (en) * | 2013-12-30 | 2014-04-02 | 青昊环保科技（上海）有限公司 | Leather water-proof curing agent and preparing method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018196023A1 (en) * | 2017-04-27 | 2018-11-01 | 陈秋华 | Liquid shoe polish and preparation method therefor |
| CN107189684A (en) * | 2017-05-19 | 2017-09-22 | 上海皇宇科技发展有限公司 | A kind of leather surface treatment agent of anti-aging water resistant oil rub resistance and preparation method thereof |
| CN107099626A (en) * | 2017-05-26 | 2017-08-29 | 上海皇宇科技发展有限公司 | A kind of vamp filling glazing dressing agent and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104946048A (en) | Nanoscale water-resisting oil-stain-resisting leather surface treatment agent and preparing method thereof | |
| CN105754750B (en) | A kind of renovation dry cleaning agent of leather product and preparation method thereof | |
| CN101906717A (en) | Product turning liquid into printing and production method thereof | |
| CN105779670A (en) | Wax emulsion for leather finishing and preparing method of wax emulsion | |
| CN103146276A (en) | Leather dressing treatment composite material and preparation method thereof | |
| CN106753930A (en) | A kind of liquid detergent | |
| CN103642954A (en) | Care wet tissue for cleaning and polishing leather | |
| CN101892592A (en) | Dry-skid charred bright finishing agent for synthetic leather and preparation method thereof | |
| CN102168376A (en) | Ultra-black plush polish processing agent used for synthetic leather and preparation method thereof | |
| CN102168374A (en) | Tar-containing resin for synthetic leather and method for preparing same | |
| GB2579750A (en) | Superhydrophobic surfaces using non-fluorinated compositions with plant-based materials | |
| TW200833363A (en) | Cleansing composition | |
| CA2503769A1 (en) | Wipes impregnated with biliquid foam treating liquids | |
| CN105088800A (en) | Low-temperature water-based water-proofing agent and production process thereof | |
| US2213643A (en) | Coated fibrous sheet materials | |
| CN103669004A (en) | Fabric waterproof finishing agent | |
| CN107099626A (en) | A kind of vamp filling glazing dressing agent and preparation method thereof | |
| CN108403560A (en) | A kind of Efficient decontamination hand sanitizer and preparation method thereof containing friction particles object | |
| CN107353815A (en) | A kind of aqueous one-component blank paint emulsion and preparation method thereof | |
| CN109280172B (en) | A kind of preparation method and purposes of modified silicon oil | |
| CN204626150U (en) | PUA ultrafine fiber simulation skin | |
| CN106118928A (en) | A kind of Antibacterial laundry detergent | |
| CN102676006A (en) | External coating liquid for agricultural greenhouse film and production method thereof | |
| CN104358134A (en) | Wool fabric smoothing method | |
| CN109366301A (en) | A kind of process of surface treatment of button |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150930 |