CN104404538A - Metal surface cleaning agent capable of strongly removing scales and preparation method thereof - Google Patents

Metal surface cleaning agent capable of strongly removing scales and preparation method thereof Download PDF

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Publication number
CN104404538A
CN104404538A CN201410622207.2A CN201410622207A CN104404538A CN 104404538 A CN104404538 A CN 104404538A CN 201410622207 A CN201410622207 A CN 201410622207A CN 104404538 A CN104404538 A CN 104404538A
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China
Prior art keywords
parts
water
sodium
powder
metal surface
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CN201410622207.2A
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Chinese (zh)
Inventor
姚侃
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HEFEI DAAN PRINTING Co Ltd
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HEFEI DAAN PRINTING Co Ltd
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Priority to CN201410622207.2A priority Critical patent/CN104404538A/en
Publication of CN104404538A publication Critical patent/CN104404538A/en
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a metal surface cleaning agent capable of strongly removing scales. The cleaning agent is characterized by being composed of the following raw materials in parts by weight: 3 to 5 parts of sodium dodecyl sulfate, 2 to 4 parts of N-acyl monosodium glutamate, 4 to 6 parts of illite powder, 1 to 2 parts of zeolite powder, 2 to 4 parts of calcite powder, 0.5 to 1 part of aluminum hydroxide, 3 to 5 parts of triethanolamine, 0.1 to 0.2 part of sodium laurate, 2 to 4 parts of sodium citrate, 1 to 2 parts of calcium citrate, 0.3 to 0.5 part of inositol hexaphosphate, 0.1 to 0.2 part of phosphatidylcholine, 0.1 to 0.2 part of calcium gluconate, 3 to 5 parts of auxiliary agent, and 40 to 50 parts of water. The invention has the function of strongly removing scales, and can effectively remove the water scales and high-temperature oxide scales on the metal surface so as to polish the metal surface. The washing time is short, the washing temperature is low, and the cleaning agent is suitable for scale removing treatment on surfaces of different metal materials and metal workpiece.

Description

A kind of powerful de-sludging metal surface cleaning agent and preparation method thereof
Technical field
The present invention relates to metal treatment field, be specifically related to a kind of powerful de-sludging metal surface cleaning agent and preparation method thereof.
Background technology
Metal and goods thereof often at the various dirt of surface contamination and impurity, as do not removed in time, can will affect the processing effect of next process, and then have influence on the overall performance of product in the course of processing.The Main Function of metal surface cleaning agent is exactly clean metal material surface oil, wax, rust, glue, paint, powder, carbon distribution, impression of the hand, sweat stain, cutting fluid and other dirt.Traditional metal surface cleaning agent is often solvent-borne type, and cost is high, toxicity is large, security is low and environmental pollution is large.Develop and apply environmental protection, safety, efficiently aqueous based surfactant shaped metal surface cleaning agent, becoming trend of the times.
Summary of the invention
The object of this invention is to provide a kind of powerful de-sludging metal surface cleaning agent.
The present invention is achieved by the following technical solutions:
A kind of powerful de-sludging metal surface cleaning agent, it is characterized in that, it is obtained by the raw material of following weight parts:
Sodium lauryl sulphate 3-5, N-acyl glutamic acid sodium 2-4, Erie stone flour 4-6; zeolite powder 1-2, calcite in powder 2-4, aluminium hydroxide 0.5-1; trolamine 3-5, sodium laurate 0.1-0.2, Trisodium Citrate 2-4; citrate of lime 1-2; myo-Inositol hexaphosphate 0.3-0.5, Yelkin TTS 0.1-0.2, calglucon 0.1-0.2; auxiliary agent 3-5, water 40-50
Wherein auxiliary agent is made up of the raw material of following weight part:
Grape skin 15-20, oxalic acid 2-4, citric acid 2-4, tripoly phosphate sodium STPP 1-2, propylene glycol 3-5, polyoxyethylene nonylphenol ether 1-2, silica powder 1-2, water 20-30;
The preparation method of auxiliary agent is:
Stir after grape skin is mixed with the water that 1/3-1/2 measures, supersound process 0.5-1h, add oxalic acid, citric acid, tripoly phosphate sodium STPP and propylene glycol 200-400r/min, 60-80 DEG C of process 12-24h again, after filtration, filter residue is mixed with the water of surplus, add polyoxyethylene nonylphenol ether and silica powder 1000-1200r/min, 60-80 DEG C of process 6-8h, again filter and the filtrate that twice is obtained merging, pH is adjusted to neutrality, obtains final product.
A preparation method for powerful de-sludging metal surface cleaning agent, is characterized in that, comprise the following steps:
(1) 1-2h is ground after Erie's stone flour, zeolite powder, calcite in powder and aluminium hydroxide being mixed with trolamine, add the water of N-acyl glutamic acid sodium and 1/4-1/3 amount again, first ultrasonic disperse 10-15min, then 8000-10000r/min high-speed homogenization 15-30min, obtain component A;
(2) sodium lauryl sulphate and sodium laurate are added 800-1000r/min in the water of surplus and stir 5-10min, then stir 20-30min under adding Yelkin TTS and myo-Inositol hexaphosphate 60-80 DEG C, equally rotating speed, obtain B component;
(3) 800-1000r/min after the mixing of component A, B component and all the other raw materials is stirred 15-30min, after packing and get final product.
Advantage of the present invention is:
By the improvement of recipe optimization, make product have effect of powerful de-sludging, effectively can remove incrustation scale and the high temperature scale of metallic surface, make metallic surface light; Scavenging period is short, and cleaning temperature is low, is applicable to the de-sludging process of different metal material surface and metal works.
Embodiment
Non-limiting examples of the present invention is as follows:
A kind of powerful de-sludging metal surface cleaning agent, is prepared from by the component raw material of following weight (kg):
Sodium lauryl sulphate 4, N-acyl glutamic acid sodium 3, Erie's stone flour 5, zeolite powder 1.5, calcite in powder 3, aluminium hydroxide 0.8, trolamine 4, sodium laurate 0.15, Trisodium Citrate 3, citrate of lime 1.5, myo-Inositol hexaphosphate 0.4, Yelkin TTS 0.15, calglucon 0.15, auxiliary agent 4, water 45;
Wherein, auxiliary agent is made up of the raw material of following weight (kg):
Grape skin 18, oxalic acid 3, citric acid 3, tripoly phosphate sodium STPP 1.5, propylene glycol 4, polyoxyethylene nonylphenol ether 1.5, silica powder 1.5, water 25;
The preparation method of auxiliary agent:
Stir after grape skin is mixed with the water of 1/2 amount, supersound process 0.5h, add oxalic acid, citric acid, tripoly phosphate sodium STPP and propylene glycol 400r/min, 80 DEG C of process 24h again, after filtration, filter residue is mixed with the water of surplus, add polyoxyethylene nonylphenol ether and silica powder 1200r/min, 60 DEG C of process 8h, again filter and the filtrate that twice is obtained merging, pH is adjusted to neutrality, obtains final product.
The preparation method of powerful de-sludging metal surface cleaning agent comprises the following steps:
(1) grind 2h after Erie's stone flour, zeolite powder, calcite in powder and aluminium hydroxide being mixed with trolamine, then add the water of N-acyl glutamic acid sodium and 1/4 amount, first ultrasonic disperse 10min, then 8000r/min high-speed homogenization 30min, obtain component A;
(2) sodium lauryl sulphate and sodium laurate are added 1000r/min in the water of surplus and stir 5min, then stir 20min under adding Yelkin TTS and myo-Inositol hexaphosphate 80 DEG C, equally rotating speed, obtain B component;
(3) 1000r/min after the mixing of component A, B component and all the other raw materials is stirred 15min, after packing and get final product.
Through inspection, clean-out system Fouling Cleaning rate >=98% of the present embodiment.

Claims (2)

1. a powerful de-sludging metal surface cleaning agent, is characterized in that, it is obtained by the raw material of following weight parts:
Sodium lauryl sulphate 3-5, N-acyl glutamic acid sodium 2-4, Erie stone flour 4-6, zeolite powder 1-2, calcite in powder 2-4, aluminium hydroxide 0.5-1, trolamine 3-5, sodium laurate 0.1-0.2, Trisodium Citrate 2-4, citrate of lime 1-2, myo-Inositol hexaphosphate 0.3-0.5, Yelkin TTS 0.1-0.2, calglucon 0.1-0.2, auxiliary agent 3-5, water 40-50;
Described auxiliary agent is made up of the raw material of following weight part:
Grape skin 15-20, oxalic acid 2-4, citric acid 2-4, tripoly phosphate sodium STPP 1-2, propylene glycol 3-5, polyoxyethylene nonylphenol ether 1-2, silica powder 1-2, water 20-30;
The preparation method of described auxiliary agent is:
Stir after grape skin is mixed with the water that 1/3-1/2 measures, supersound process 0.5-1h, add oxalic acid, citric acid, tripoly phosphate sodium STPP and propylene glycol 200-400r/min, 60-80 DEG C of process 12-24h again, after filtration, filter residue is mixed with the water of surplus, add polyoxyethylene nonylphenol ether and silica powder 1000-1200r/min, 60-80 DEG C of process 6-8h, again filter and the filtrate that twice is obtained merging, pH is adjusted to neutrality, obtains final product.
2. the preparation method of a kind of powerful de-sludging metal surface cleaning agent according to claim 1, is characterized in that, comprise the following steps:
(1) 1-2h is ground after Erie's stone flour, zeolite powder, calcite in powder and aluminium hydroxide being mixed with trolamine, add the water of N-acyl glutamic acid sodium and 1/4-1/3 amount again, first ultrasonic disperse 10-15min, then 8000-10000r/min high-speed homogenization 15-30min, obtain component A;
(2) sodium lauryl sulphate and sodium laurate are added 800-1000r/min in the water of surplus and stir 5-10min, then stir 20-30min under adding Yelkin TTS and myo-Inositol hexaphosphate 60-80 DEG C, equally rotating speed, obtain B component;
(3) 800-1000r/min after the mixing of component A, B component and all the other raw materials is stirred 15-30min, after packing and get final product.
CN201410622207.2A 2014-11-07 2014-11-07 Metal surface cleaning agent capable of strongly removing scales and preparation method thereof Pending CN104404538A (en)

Priority Applications (1)

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CN201410622207.2A CN104404538A (en) 2014-11-07 2014-11-07 Metal surface cleaning agent capable of strongly removing scales and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201410622207.2A CN104404538A (en) 2014-11-07 2014-11-07 Metal surface cleaning agent capable of strongly removing scales and preparation method thereof

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105714315A (en) * 2016-03-23 2016-06-29 苏州市贝克生物科技有限公司 Aluminum alloy scale chemical cleaning agent and preparation method thereof
CN106222680A (en) * 2016-08-17 2016-12-14 安徽江淮车轮有限公司 A kind of steel ring wheel surface processes technique
CN106283093A (en) * 2016-08-17 2017-01-04 安徽江淮车轮有限公司 A kind of fork truck steel ring process of surface treatment
CN106635437A (en) * 2016-12-15 2017-05-10 佛山慧创正元新材料科技有限公司 Novel solid detergent for metal surface
CN106675854A (en) * 2016-12-15 2017-05-17 佛山慧创正元新材料科技有限公司 Improved commemorative coin solid detergent
CN106884172A (en) * 2017-01-19 2017-06-23 南京百丝胜新材料科技有限公司 A kind of environment-friendly type metal surface cleaning agent and activation method

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1076478A (en) * 1992-03-16 1993-09-22 铁道部第十九工程局科学技术协会 Dirt-removing polishing agent and preparation method thereof
CN1078258A (en) * 1992-03-20 1993-11-10 普罗格特-甘布尔公司 The neutral pH cleaning soap
CN1950336A (en) * 2004-07-28 2007-04-18 可泰克斯有限合伙公司 Polymers produced by using sulphur compounds in the form of transfer agents for controlled radical polymerisation of acrylic acid and the use thereof
CN102911799A (en) * 2012-10-25 2013-02-06 高碑店市中煤神海科技发展有限公司 Cleaning agent for electrohydraulic control system of fully-mechanized mining hydraulic support and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1076478A (en) * 1992-03-16 1993-09-22 铁道部第十九工程局科学技术协会 Dirt-removing polishing agent and preparation method thereof
CN1078258A (en) * 1992-03-20 1993-11-10 普罗格特-甘布尔公司 The neutral pH cleaning soap
CN1950336A (en) * 2004-07-28 2007-04-18 可泰克斯有限合伙公司 Polymers produced by using sulphur compounds in the form of transfer agents for controlled radical polymerisation of acrylic acid and the use thereof
CN102911799A (en) * 2012-10-25 2013-02-06 高碑店市中煤神海科技发展有限公司 Cleaning agent for electrohydraulic control system of fully-mechanized mining hydraulic support and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105714315A (en) * 2016-03-23 2016-06-29 苏州市贝克生物科技有限公司 Aluminum alloy scale chemical cleaning agent and preparation method thereof
CN106222680A (en) * 2016-08-17 2016-12-14 安徽江淮车轮有限公司 A kind of steel ring wheel surface processes technique
CN106283093A (en) * 2016-08-17 2017-01-04 安徽江淮车轮有限公司 A kind of fork truck steel ring process of surface treatment
CN106635437A (en) * 2016-12-15 2017-05-10 佛山慧创正元新材料科技有限公司 Novel solid detergent for metal surface
CN106675854A (en) * 2016-12-15 2017-05-17 佛山慧创正元新材料科技有限公司 Improved commemorative coin solid detergent
CN106884172A (en) * 2017-01-19 2017-06-23 南京百丝胜新材料科技有限公司 A kind of environment-friendly type metal surface cleaning agent and activation method

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Application publication date: 20150311

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