CN104342710A - Anti-corrosion metal surface cleaning agent and preparation method of anti-corrosion metal surface cleaning agent - Google Patents
Anti-corrosion metal surface cleaning agent and preparation method of anti-corrosion metal surface cleaning agent Download PDFInfo
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- CN104342710A CN104342710A CN201410622048.6A CN201410622048A CN104342710A CN 104342710 A CN104342710 A CN 104342710A CN 201410622048 A CN201410622048 A CN 201410622048A CN 104342710 A CN104342710 A CN 104342710A
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
Abstract
The invention discloses an anti-corrosion metal surface cleaning agent, which is characterized by being prepared from the following ingredients in parts by weight: 4 to 6 parts of kaolin, 1 to 2 parts of anhydrous sodium sulphate, 3 to 5 parts of triethanolamine, 3 to 5 parts of lauryl sodium sulfate, 1 to 2 parts of polyoxyethylene octylphenol ether, 0.3 to 0.5 part of triethanolamine borate, 0.1 to 0.2 part of disodium salt of 1-hydroxy ethylidene-1,1-diphosphonic acid, 0.1 to 0.2 part of polymaleic anhydride, 1 to 2 parts of polyvinylpyrrolidone, 3 to 5 parts of hydroxyethyl cellulose, 0.2 to 0.4 part of tributyl phosphate, 3 to 5 parts of auxiliary agents and 40 to 50 parts of water. The anti-corrosion metal surface cleaning agent has the advantages that the cleaning performance is better, meanwhile, a corrosion inhibition effect is achieved on metals, the metal corrosion is prevented, and the effective acting time of cleaning is prolonged.
Description
Technical field
The present invention relates to metal treatment field, be specifically related to a kind of corrosion-resistant metal surface cleaning agent and preparation method thereof.
Background technology
Metal and goods thereof often at the various dirt of surface contamination and impurity, as do not removed in time, can will affect the processing effect of next process, and then have influence on the overall performance of product in the course of processing.The Main Function of metal surface cleaning agent is exactly clean metal material surface oil, wax, rust, glue, paint, powder, carbon distribution, impression of the hand, sweat stain, cutting fluid and other dirt.Traditional metal surface cleaning agent is often solvent-borne type, and cost is high, toxicity is large, security is low and environmental pollution is large.Develop and apply environmental protection, safety, efficiently aqueous based surfactant shaped metal surface cleaning agent, becoming trend of the times.
Summary of the invention
The object of this invention is to provide a kind of corrosion-resistant metal surface cleaning agent.
The present invention is achieved by the following technical solutions:
A kind of corrosion-resistant metal surface cleaning agent, it is characterized in that, it is obtained by the raw material of following weight parts:
Kaolin 4-6, Sodium sulfate anhydrous.min(99) 1-2, trolamine 3-5, sodium lauryl sulphate 3-5, polyoxyethylene octylphenol ether 1-2, triethanolamine borate 0.3-0.5,1-Hydroxy Ethylidene-1,1-Diphosphonic Acid disodium 0.1-0.2, polymaleic anhydride 0.1-0.2, polyvinylpyrrolidone 1-2, Natvosol 3-5, tributyl phosphate 0.2-0.4, auxiliary agent 3-5, water 40-50
Wherein auxiliary agent is made up of the raw material of following weight part:
Grape skin 15-20, oxalic acid 2-4, citric acid 2-4, tripoly phosphate sodium STPP 1-2, propylene glycol 3-5, polyoxyethylene nonylphenol ether 1-2, silica powder 1-2, water 20-30;
The preparation method of auxiliary agent is:
Stir after grape skin is mixed with the water that 1/3-1/2 measures, supersound process 0.5-1h, add oxalic acid, citric acid, tripoly phosphate sodium STPP and propylene glycol 200-400r/min, 60-80 DEG C of process 12-24h again, after filtration, filter residue is mixed with the water of surplus, add polyoxyethylene nonylphenol ether and silica powder 1000-1200r/min, 60-80 DEG C of process 6-8h, again filter and the filtrate that twice is obtained merging, pH is adjusted to neutrality, obtains final product.
A preparation method for corrosion-resistant metal surface cleaning agent, is characterized in that, comprises the following steps:
(1) grind 1-2h after being mixed with trolamine by kaolin, then add the water of polyoxyethylene octylphenol ether, polymaleic anhydride and 1/4-1/3 amount, first ultrasonic disperse 10-15min, then 8000-10000r/min high-speed homogenization 15-30min, obtain component A;
(2) sodium lauryl sulphate and polyvinylpyrrolidone are added 800-1000r/min in the water of surplus and stir 5-10min, then stir 20-30min under adding triethanolamine borate and tributyl phosphate 60-80 DEG C, equally rotating speed, obtain B component;
(3) 800-1000r/min after the mixing of component A, B component and all the other raw materials is stirred 15-30min, after packing and get final product.
Advantage of the present invention is:
1. by the improvement of recipe optimization, make product have higher cleaning performance, have corrosion inhibition to metal simultaneously, extend the effective acting time of cleaning;
2. being attached to the greasy dirt of metallic surface by adding medical stone powder energy active adsorption, both shortening scavenging period, and making again cleaning more thorough; And when metal detergent discharge of wastewater by mode separating most pollutents such as centrifugal, filtrations, be conducive to alleviating sewage disposal burden, more easily reach emission standard.。
Embodiment
Non-limiting examples of the present invention is as follows:
A kind of corrosion-resistant metal surface cleaning agent, is prepared from by the component raw material of following weight (kg):
Kaolin 5, Sodium sulfate anhydrous.min(99) 1.5, trolamine 4, sodium lauryl sulphate 4, polyoxyethylene octylphenol ether 1.5, triethanolamine borate 0.4,1-Hydroxy Ethylidene-1,1-Diphosphonic Acid disodium 0.15, polymaleic anhydride 0.15, polyvinylpyrrolidone 1.5, Natvosol 4, tributyl phosphate 0.3, auxiliary agent 4, water 45;
Wherein, auxiliary agent is made up of the raw material of following weight (kg):
Grape skin 18, oxalic acid 3, citric acid 3, tripoly phosphate sodium STPP 1.5, propylene glycol 4, polyoxyethylene nonylphenol ether 1.5, silica powder 1.5, water 25;
The preparation method of auxiliary agent:
Stir after grape skin is mixed with the water of 1/2 amount, supersound process 0.5h, add oxalic acid, citric acid, tripoly phosphate sodium STPP and propylene glycol 400r/min, 80 DEG C of process 24h again, after filtration, filter residue is mixed with the water of surplus, add polyoxyethylene nonylphenol ether and silica powder 1200r/min, 60 DEG C of process 8h, again filter and the filtrate that twice is obtained merging, pH is adjusted to neutrality, obtains final product.
The preparation method of corrosion-resistant metal surface cleaning agent comprises the following steps:
(1) grind 1h after being mixed with trolamine by kaolin, then add the water of polyoxyethylene octylphenol ether, polymaleic anhydride and 1/4 amount, first ultrasonic disperse 10min, then 8000r/min high-speed homogenization 15min, obtain component A;
(2) sodium lauryl sulphate and polyvinylpyrrolidone are added 1000r/min in the water of surplus and stir 5min, then stir 30min under adding triethanolamine borate and tributyl phosphate 80 DEG C, equally rotating speed, obtain B component;
(3) 1000r/min after the mixing of component A, B component and all the other raw materials is stirred 15min, after packing and get final product.
Through inspection, clean-out system cleaning rate >=95% of the present embodiment.
Claims (2)
1. a corrosion-resistant metal surface cleaning agent, is characterized in that, it is obtained by the raw material of following weight parts:
Kaolin 4-6, Sodium sulfate anhydrous.min(99) 1-2, trolamine 3-5, sodium lauryl sulphate 3-5, polyoxyethylene octylphenol ether 1-2, triethanolamine borate 0.3-0.5,1-Hydroxy Ethylidene-1,1-Diphosphonic Acid disodium 0.1-0.2, polymaleic anhydride 0.1-0.2, polyvinylpyrrolidone 1-2, Natvosol 3-5, tributyl phosphate 0.2-0.4, auxiliary agent 3-5, water 40-50;
Described auxiliary agent is made up of the raw material of following weight part:
Grape skin 15-20, oxalic acid 2-4, citric acid 2-4, tripoly phosphate sodium STPP 1-2, propylene glycol 3-5, polyoxyethylene nonylphenol ether 1-2, silica powder 1-2, water 20-30;
The preparation method of described auxiliary agent is:
Stir after grape skin is mixed with the water that 1/3-1/2 measures, supersound process 0.5-1h, add oxalic acid, citric acid, tripoly phosphate sodium STPP and propylene glycol 200-400r/min, 60-80 DEG C of process 12-24h again, after filtration, filter residue is mixed with the water of surplus, add polyoxyethylene nonylphenol ether and silica powder 1000-1200r/min, 60-80 DEG C of process 6-8h, again filter and the filtrate that twice is obtained merging, pH is adjusted to neutrality, obtains final product.
2. the preparation method of a kind of corrosion-resistant metal surface cleaning agent according to claim 1, is characterized in that, comprise the following steps:
(1) grind 1-2h after being mixed with trolamine by kaolin, then add the water of polyoxyethylene octylphenol ether, polymaleic anhydride and 1/4-1/3 amount, first ultrasonic disperse 10-15min, then 8000-10000r/min high-speed homogenization 15-30min, obtain component A;
(2) sodium lauryl sulphate and polyvinylpyrrolidone are added 800-1000r/min in the water of surplus and stir 5-10min, then stir 20-30min under adding triethanolamine borate and tributyl phosphate 60-80 DEG C, equally rotating speed, obtain B component;
(3) 800-1000r/min after the mixing of component A, B component and all the other raw materials is stirred 15-30min, after packing and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410622048.6A CN104342710A (en) | 2014-11-07 | 2014-11-07 | Anti-corrosion metal surface cleaning agent and preparation method of anti-corrosion metal surface cleaning agent |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410622048.6A CN104342710A (en) | 2014-11-07 | 2014-11-07 | Anti-corrosion metal surface cleaning agent and preparation method of anti-corrosion metal surface cleaning agent |
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| CN104342710A true CN104342710A (en) | 2015-02-11 |
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| CN201410622048.6A Pending CN104342710A (en) | 2014-11-07 | 2014-11-07 | Anti-corrosion metal surface cleaning agent and preparation method of anti-corrosion metal surface cleaning agent |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105002516A (en) * | 2015-08-10 | 2015-10-28 | 苏州科淼新材料有限公司 | Mechanical equipment cleaning agent and preparation method thereof |
| CN105177599A (en) * | 2015-07-21 | 2015-12-23 | 安徽江威精密制造有限公司 | Non-phosphorus degreaser and preparing method thereof |
| CN105296205A (en) * | 2015-11-25 | 2016-02-03 | 济南昊泽环保科技有限公司 | Cleaning agent for mechanical equipment, and preparation method of cleaning agent |
| CN106277375A (en) * | 2016-10-13 | 2017-01-04 | 林少忠 | A kind of environment-friendly type anti-incrustation corrosion inhibitor and its preparation method and application |
| CN106591855A (en) * | 2016-11-25 | 2017-04-26 | 南宁市黑晶信息技术有限公司 | Metal surface cleaning agent and preparation method thereof |
| CN112048730A (en) * | 2020-09-17 | 2020-12-08 | 东莞市麦克莱恩新材料有限公司 | Foamless spray cleaning agent for hairbrush machine |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1194297A (en) * | 1996-06-11 | 1998-09-30 | 安小炳 | High efficiency health detergent |
| CN102146320A (en) * | 2011-02-16 | 2011-08-10 | 张震红 | Medical stone detergent and preparation method thereof |
-
2014
- 2014-11-07 CN CN201410622048.6A patent/CN104342710A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1194297A (en) * | 1996-06-11 | 1998-09-30 | 安小炳 | High efficiency health detergent |
| CN102146320A (en) * | 2011-02-16 | 2011-08-10 | 张震红 | Medical stone detergent and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105177599A (en) * | 2015-07-21 | 2015-12-23 | 安徽江威精密制造有限公司 | Non-phosphorus degreaser and preparing method thereof |
| CN105002516A (en) * | 2015-08-10 | 2015-10-28 | 苏州科淼新材料有限公司 | Mechanical equipment cleaning agent and preparation method thereof |
| CN105296205A (en) * | 2015-11-25 | 2016-02-03 | 济南昊泽环保科技有限公司 | Cleaning agent for mechanical equipment, and preparation method of cleaning agent |
| CN106277375A (en) * | 2016-10-13 | 2017-01-04 | 林少忠 | A kind of environment-friendly type anti-incrustation corrosion inhibitor and its preparation method and application |
| CN106591855A (en) * | 2016-11-25 | 2017-04-26 | 南宁市黑晶信息技术有限公司 | Metal surface cleaning agent and preparation method thereof |
| CN112048730A (en) * | 2020-09-17 | 2020-12-08 | 东莞市麦克莱恩新材料有限公司 | Foamless spray cleaning agent for hairbrush machine |
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Application publication date: 20150211 |