CN103668256A - Preparation method of metal surface treating agent - Google Patents
Preparation method of metal surface treating agent Download PDFInfo
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- CN103668256A CN103668256A CN201310663282.9A CN201310663282A CN103668256A CN 103668256 A CN103668256 A CN 103668256A CN 201310663282 A CN201310663282 A CN 201310663282A CN 103668256 A CN103668256 A CN 103668256A
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- titanium dioxide
- metal conditioner
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Abstract
The invention relates to a preparation method of a metal surface treating agent, specifically relates to a preparation method of an environment-friendly nonferrous metal surface treating agent, and belongs to the technical field of metal surface cleaning and surface antirust processing. The environment-friendly nonferrous metal surface treating agent comprises a corrosion inhibitor, a surfactant, chitosan, an anti-oxidant, titanium dioxide, silicon dioxide and water. When the environment-friendly nonferrous metal surface treating agent is used, a protection film layer is formed from nanoscale titanium dioxide and nanoscale silicon dioxide on metal surfaces; under sunniness, nanosacle F-doped titanium dioxide and nanoscale silicon dioxide are capable of decomposing bacteria on metal surfaces, possess relatively high hydrophilcity, are capable of protecting metal surfaces from corrosion caused by bacteria and rain; so that metal surfaces are cleaned with efficiency, the protection film is formed on metal surfaces, and glossiness of metal surfaces is protected.
Description
Technical field
The present invention relates to a kind of preparation method of metal conditioner, have and say the preparation method who relates to a kind of environment-friendly type non-ferrous metal surface treatment agent, it belongs to cleaning metal surface and surperficial antirust processing technology field.
Background technology
Traditional industry is all that each unlike material needs different clean-out system, cleaning equipment, and the protective treatment after cleaning also needs different treatment agents to carry out, and has increased the time that purchase cost, inter process clean and protect.In while scale removal process, due to complex procedures, the continuity of production is poor, increases disposal of pollutants load; And for some time after it cleans, workpiece need to clean again, and the time of its maintenance is short.
Summary of the invention
In view of the defect that prior art exists, the present invention is to provide a kind of preparation method of metal conditioner, to reach when can clean simultaneously, in metallic surface, scribbles layer protecting film, keeps the former glossiness object of metal.
For achieving the above object, technical scheme that the present invention adopts is a kind of preparation method of metal conditioner, its component is: inhibiter, tensio-active agent, chitosan, antioxidant, titanium dioxide, silicon-dioxide and water, and each substances in percentage by weight content has as follows: inhibiter 0.5-8.0, tensio-active agent 2.0-9.0, chitosan 2.0-8.5, antioxidant 0.1-1.0, titanium dioxide 1.5-9.0, silica 1 .5-9.0, water surplus, it is characterized in that: the inhibiter of 0.5-8.0% is stirred with the tensio-active agent of 2.0-9.0%, add again 20% deionized water fully to mix post-heating to 60 ℃-70 ℃, fully stir 30-40 minute, the chitosan that adds again 2.0-8.5%, speed dispersed with stirring with 1500 revs/min in reactor obtains stable solution, the antioxidant that adds again 0.1-1.0%, the titanium dioxide that adds 1.5-9.0%, the deionized water of the silicon-dioxide surplus of 1.5-9.0%, fully stir, and add acid-base modifier that pH value is adjusted to 8.0-9.0, stir and obtain stable solution, make metal conditioner.
Described inhibiter comprises: ethamine, diethylamine, triethylamine, diamylamine, β-naphthylamines, nonox, thanomin, diethanolamine, trolamine, benzo three nitrogen files ,-hydroxy benzo triazole, hexamethylenetetramine and sodium alginate.
Described tensio-active agent is nonionogenic tenside, comprises fatty alcohol-polyoxyethylene ether, polyoxyethylene nonylphenol ether and tween 80.
Described chitosan is N-deacetylation at 55%～100% chitosan.
Described antioxidant is Trisodium Citrate, potassium sulfite, S-WAT.
The massfraction of described titanium dioxide and silicon-dioxide is than being 1:1; Described titanium dioxide is nano level titanium dioxide, and described silicon-dioxide is nano level silicon-dioxide.
Described water is deionized water.
The invention has the advantages that: in use, nano level titanium dioxide and nano level silicon-dioxide form layer protecting film in metallic surface, the titanium dioxide of nano level doped F and nano level silicon-dioxide its can decomposing metal surface under the irradiation of sunlight bacterium, and there is very high wetting ability, protect more fully metallic surface not by bacterium and rain erosion; Thereby not only well clear up metallic surface, in metallic surface, form protective membrane simultaneously, can protect the glossiness of metallic surface.
Embodiment
A kind of preparation method of metal conditioner, its component is: inhibiter, tensio-active agent, chitosan, antioxidant, titanium dioxide, silicon-dioxide and water, and each substances in percentage by weight content has as follows: inhibiter 0.5-8.0, tensio-active agent 2.0-9.0, chitosan 2.0-8.5, antioxidant 0.1-1.0, titanium dioxide 1.5-9.0, silica 1 .5-9.0, water surplus, it is characterized in that: the inhibiter of 0.5-8.0% is stirred with the tensio-active agent of 2.0-9.0%, add again 20% deionized water fully to mix post-heating to 60 ℃-70 ℃, fully stir 30-40 minute, the chitosan that adds again 2.0-8.5%, speed dispersed with stirring with 1500 revs/min in reactor obtains stable solution, the antioxidant that adds again 0.1-1.0%, the titanium dioxide that adds 1.5-9.0%, the deionized water of the silicon-dioxide surplus of 1.5-9.0%, fully stir, and add soda acid additive that pH value is adjusted to 8.0-9.0, stir and obtain stable solution, make metal conditioner.
Claims (7)
1. the preparation method of a metal conditioner, its component is: inhibiter, tensio-active agent, chitosan, antioxidant, titanium dioxide, silicon-dioxide and water, and each substances in percentage by weight content has as follows: inhibiter 0.5-8.0, tensio-active agent 2.0-9.0, chitosan 2.0-8.5, antioxidant 0.1-1.0, titanium dioxide 1.5-9.0, silica 1 .5-9.0, water surplus, it is characterized in that: the inhibiter of 0.5-8.0% is stirred with the tensio-active agent of 2.0-9.0%, add again 20% deionized water fully to mix post-heating to 60 ℃-70 ℃, fully stir 30-40 minute, the chitosan that adds again 2.0-8.5%, speed dispersed with stirring with 1500 revs/min in reactor obtains stable solution, the antioxidant that adds again 0.1-1.0%, the titanium dioxide that adds 1.5-9.0%, the deionized water of the silicon-dioxide surplus of 1.5-9.0%, fully stir, and add acid-base modifier that pH value is adjusted to 8.0-9.0, stir and obtain stable solution, make metal conditioner.
2. the preparation method of a kind of metal conditioner according to claim 1, is characterized in that: described inhibiter comprises: ethamine, diethylamine, triethylamine, diamylamine, β-naphthylamines, nonox, thanomin, diethanolamine, trolamine, benzo three nitrogen files ,-hydroxy benzo triazole, hexamethylenetetramine and sodium alginate.
3. the preparation method of a kind of metal conditioner according to claim 1, is characterized in that: described tensio-active agent is nonionogenic tenside, comprises fatty alcohol-polyoxyethylene ether, polyoxyethylene nonylphenol ether and tween 80.
4. the preparation method of a kind of metal conditioner according to claim 1, is characterized in that: described chitosan is N-deacetylation at 55%～100% chitosan.
5. the preparation method of a kind of metal conditioner according to claim 1, is characterized in that: described antioxidant is Trisodium Citrate, potassium sulfite, S-WAT.
6. the preparation method of a kind of metal conditioner according to claim 1, is characterized in that: the massfraction of described titanium dioxide and silicon-dioxide is than being 1:1; Described titanium dioxide is nano level titanium dioxide, and described silicon-dioxide is nano level silicon-dioxide.
7. the preparation method of a kind of metal conditioner according to claim 1, is characterized in that: described water is deionized water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310663282.9A CN103668256A (en) | 2013-12-10 | 2013-12-10 | Preparation method of metal surface treating agent |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310663282.9A CN103668256A (en) | 2013-12-10 | 2013-12-10 | Preparation method of metal surface treating agent |
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| CN103668256A true CN103668256A (en) | 2014-03-26 |
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| CN201310663282.9A Pending CN103668256A (en) | 2013-12-10 | 2013-12-10 | Preparation method of metal surface treating agent |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104862682A (en) * | 2015-04-08 | 2015-08-26 | 安徽豪鼎金属制品有限公司 | Sericin wear-resisting metal surface treatment agent |
| CN104962966A (en) * | 2015-06-09 | 2015-10-07 | 宫中林 | Metal part surface electroplating pretreatment process |
| CN104962967A (en) * | 2015-06-09 | 2015-10-07 | 宫中林 | Surface cleaning fluid used for processing metal part |
| CN105002511A (en) * | 2015-06-09 | 2015-10-28 | 宫中林 | Metal surface treatment agent |
| CN106011817A (en) * | 2016-07-01 | 2016-10-12 | 施和琴 | Treatment agent for galvanized metal surfaces |
| CN106399988A (en) * | 2016-12-05 | 2017-02-15 | 郑州丽福爱生物技术有限公司 | Surface anti-oxidation treatment agent for aluminum alloy processing |
| CN107366000A (en) * | 2017-08-01 | 2017-11-21 | 合肥择浚电气设备有限公司 | A kind of preparation method of cleaning agent for surface of metal product |
| CN107747113A (en) * | 2017-10-25 | 2018-03-02 | 宝鸡市铭坤有色金属有限公司 | A kind of surface treatment method of non-ferrous metal workpiece |
| CN108118350A (en) * | 2017-12-21 | 2018-06-05 | 芜湖品度电子科技有限公司 | The electronic jacquard machine cleaning solution and preparation method thereof that deoils |
| CN109082666A (en) * | 2018-08-17 | 2018-12-25 | 南京世界村汽车动力有限公司 | A kind of engine surface antioxidant and preparation method thereof |
| CN109576754A (en) * | 2018-12-28 | 2019-04-05 | 浙江跃进有色金属制造有限公司 | The surface treatment method of non-ferrous metal workpiece |
| CN114075670A (en) * | 2021-11-17 | 2022-02-22 | 新昌中国计量大学企业创新研究院有限公司 | Corrosion inhibitor and application thereof |
-
2013
- 2013-12-10 CN CN201310663282.9A patent/CN103668256A/en active Pending
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104862682A (en) * | 2015-04-08 | 2015-08-26 | 安徽豪鼎金属制品有限公司 | Sericin wear-resisting metal surface treatment agent |
| CN104962966A (en) * | 2015-06-09 | 2015-10-07 | 宫中林 | Metal part surface electroplating pretreatment process |
| CN104962967A (en) * | 2015-06-09 | 2015-10-07 | 宫中林 | Surface cleaning fluid used for processing metal part |
| CN105002511A (en) * | 2015-06-09 | 2015-10-28 | 宫中林 | Metal surface treatment agent |
| CN106011817A (en) * | 2016-07-01 | 2016-10-12 | 施和琴 | Treatment agent for galvanized metal surfaces |
| CN106399988A (en) * | 2016-12-05 | 2017-02-15 | 郑州丽福爱生物技术有限公司 | Surface anti-oxidation treatment agent for aluminum alloy processing |
| CN107366000A (en) * | 2017-08-01 | 2017-11-21 | 合肥择浚电气设备有限公司 | A kind of preparation method of cleaning agent for surface of metal product |
| CN107747113A (en) * | 2017-10-25 | 2018-03-02 | 宝鸡市铭坤有色金属有限公司 | A kind of surface treatment method of non-ferrous metal workpiece |
| CN108118350A (en) * | 2017-12-21 | 2018-06-05 | 芜湖品度电子科技有限公司 | The electronic jacquard machine cleaning solution and preparation method thereof that deoils |
| CN109082666A (en) * | 2018-08-17 | 2018-12-25 | 南京世界村汽车动力有限公司 | A kind of engine surface antioxidant and preparation method thereof |
| CN109576754A (en) * | 2018-12-28 | 2019-04-05 | 浙江跃进有色金属制造有限公司 | The surface treatment method of non-ferrous metal workpiece |
| CN114075670A (en) * | 2021-11-17 | 2022-02-22 | 新昌中国计量大学企业创新研究院有限公司 | Corrosion inhibitor and application thereof |
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Application publication date: 20140326 |