CN102912365A - Special cleaning agent for cold rolled silicon steel plate - Google Patents
Special cleaning agent for cold rolled silicon steel plate Download PDFInfo
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- CN102912365A CN102912365A CN2012103946586A CN201210394658A CN102912365A CN 102912365 A CN102912365 A CN 102912365A CN 2012103946586 A CN2012103946586 A CN 2012103946586A CN 201210394658 A CN201210394658 A CN 201210394658A CN 102912365 A CN102912365 A CN 102912365A
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- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
The invention discloses a special cleaning agent for a cold rolled silicon steel plate for cleaning a cold rolled silicon steel plate. The special cleaning agent mainly comprises the following components in parts by weight: 17-31 parts of sodium hydroxide, 46-62 parts of sodium silicate, 12-23 parts of sodium tripolyphosphate, 1-8 parts of soap polyoxyethylene ether, 0.1-0.3 part of efficient organosilicone foam inhibitor and 0.1-0.3 part of general organosilicone defoaming powder. The special cleaning agent for a cold rolled silicon steel plate for cleaning a cold rolled silicon steel plate disclosed by the invention can overcome the shortcomings of the prior art that the cleaning effect is bad, the energy consumption is high, the operation fault is easily caused and the like so as to realize the advantages that the cleaning effect is good, the energy consumption is low and the operation fault is not easily caused.
Description
Technical field
The present invention relates to metallic substance cleaning technique field, particularly, relate to a kind of cold-rolled silicon iron scavenger specially.
Background technology
Because silicon steel sheet will use ROLLING OIL in cold-rolled process, so that the cold-rolled silicon iron surface is stained with one deck greasy dirt, this layer greasy dirt must clean up before annealing, to avoid silicon steel sheet greasy dirt carbonization in annealing process, the silicon steel sheet surface is polluted, affect the subsequent handling coating quality.
Usually, cold-rolled silicon iron surface and oil contaminant alkaline cleaner commonly used cleans.But these clean-out systems are bad to the cleaning performance of cold-rolled silicon iron, and one deck greasy dirt is usually also adhered on the cold-rolled silicon iron surface after the cleaning, cause the cold-rolled silicon iron surface after the annealing to form the carbonaceous stain, seriously affect the quality of surface of steel plate.And the working temperature of these clean-out systems is higher, and energy consumption is large during cleaning, and easily causes the e-quipment and pipe fouling and blocking pipe, and impact is normally produced.In addition, all do not contain defoamer in these clean-out systems, can produce a large amount of foams in to the cleaning process of cold-rolled silicon iron, these foams gently then pollute operating environment, and are heavy then production can not normally be carried out.
In realizing process of the present invention, the contriver finds to exist at least in the prior art that cleaning performance is poor, energy consumption greatly, easily causes the defectives such as operation fault.
Summary of the invention
The object of the invention is to, for the problems referred to above, propose a kind of cold-rolled silicon iron scavenger specially, to realize that cleaning performance is good, energy consumption is little and to be difficult for causing the advantage of operation fault.
For achieving the above object, the technical solution used in the present invention is: a kind of cold-rolled silicon iron scavenger specially, mainly comprise following component, and be expressed as with parts by weight:
Sodium hydroxide: 17 ~ 31 parts;
Water glass: 46-62 part;
Tripoly phosphate sodium STPP: 12-23 part;
Soxylat A 25-7: 1 ~ 8 part;
Efficient organosilicon suds suppressor: 0.1 ~ 0.3;
General organosilicon defoaming powder: 0.1 ~ 0.3 part.
Further, described Soxylat A 25-7 specifically comprises the Soxylat A 25-7 of the EO/PO block of Fatty Alcohol(C12-C14 and C12-C18).
Further, described efficient organosilicon suds suppressor specifically comprises any one among efficient organosilicon suds suppressor TSA-7133, TSA-672, TSA-10A, D-30X, TSA-630 and the TSA-5701.
Further, described general organosilicon defoaming powder specifically comprises general organosilicon defoaming powder T-20GB.
Owing in the greasy dirt on the cold-rolled silicon iron, containing a small amount of vegetable and animals oils (or synthetic fat) and a large amount of mineral oil.Adopt the cold-rolled silicon iron scavenger specially of various embodiments of the present invention, can overcome the defective that cleaning performance is poor in the prior art, energy consumption greatly, easily causes the operation fault, to realize that cleaning performance is good, energy consumption is little and to be difficult for causing the advantage of operation fault; For example:
⑴ can utilize on sodium hydroxide and the cold-rolled silicon iron a small amount of that saponification reaction occurs vegetable and animals oils (or synthetic fat), generate Soxylat A 25-7 and glycerine, Soxylat A 25-7 and glycerine can be dissolved in the scavenging solution well, thereby the vegetable and animals oils on the cold-rolled silicon iron is removed;
⑵ can utilize the emulsifying effect of water glass, effectively removes mineral oil a large amount of on the cold-rolled silicon iron;
⑶ utilize calcium ion and the magnesium ion generation complexing action in tripoly phosphate sodium STPP and the hard water, and complexing is dissolved in other metal ion in the scavenging solution, washes simultaneously the silicon dioxide film on cold-rolled silicon iron surface off, to improve cleaning performance;
⑷ utilize Soxylat A 25-7 as tensio-active agent, can reduce the surface tension of scavenging solution, increases surfactivity and the cleaning performance of scavenging solution;
⑸ utilize efficient organosilicon suds suppressor and general organosilicon defoaming powder as defoamer, can effectively eliminate the foam that produces in the cleaning process, avoids polluting operating environment, also to normally ensureing to some extent of producing.
Other features and advantages of the present invention will be set forth in the following description, and, partly from specification sheets, become apparent, perhaps understand by implementing the present invention.
Below by embodiment, technical scheme of the present invention is described in further detail.
Embodiment
Describe below in conjunction with the preferred embodiments of the present invention, should be appreciated that preferred embodiment described herein only is used for description and interpretation the present invention, is not intended to limit the present invention.
Embodiment one
According to the embodiment of the invention, provide a kind of cold-rolled silicon iron scavenger specially.This cold-rolled silicon iron scavenger specially mainly comprises following component, is expressed as with parts by weight:
Sodium hydroxide: 17 parts;
Water glass: 62 parts;
Tripoly phosphate sodium STPP: 16.5 parts;
Soxylat A 25-7: 1 part;
Efficient organosilicon suds suppressor: 0.3 part;
General organosilicon defoaming powder: 0.1 part.
After the even mixing of above-mentioned raw materials, pack and namely can be made into qualified cold-rolled silicon iron scavenger specially.During use, only needing to plant solid-state cold-rolled silicon iron scavenger specially pours in the tap water, fully stir and make its dissolving, be configured to concentration and be 3%, the scavenging solution of liquid temperature between 62 ℃, send into silicon steel sheet factory by pipeline and get in the strip cleaning groove, cold-rolled silicon iron is sprayed cleaning, empirical tests, clean rate can reach more than 98%, and e-quipment and pipe does not all produce fouling after using.
Embodiment two
According to the embodiment of the invention, provide a kind of cold-rolled silicon iron scavenger specially.This cold-rolled silicon iron scavenger specially mainly comprises following component, is expressed as with parts by weight:
Sodium hydroxide: 31 parts;
Water glass: 46 parts;
Tripoly phosphate sodium STPP: 12 parts;
Soxylat A 25-7: 8 parts;
Efficient organosilicon suds suppressor: 0.1 part;
General organosilicon defoaming powder: 0.3 part.
After the even mixing of above-mentioned raw materials, pack and namely can be made into qualified cold-rolled silicon iron scavenger specially.During use, only needing to plant solid-state cold-rolled silicon iron scavenger specially pours in the tap water, fully stir and make its dissolving, be configured to concentration and be 4%, the scavenging solution of liquid temperature between 65 ℃, send into silicon steel sheet factory by pipeline and get in the strip cleaning groove, cold-rolled silicon iron is sprayed cleaning, empirical tests, clean rate can reach more than 99%, and e-quipment and pipe does not all produce fouling after using.
Embodiment three
According to the embodiment of the invention, provide a kind of cold-rolled silicon iron scavenger specially.This cold-rolled silicon iron scavenger specially mainly comprises following component, is expressed as with parts by weight:
Sodium hydroxide: 24 parts;
Water glass: 49 parts;
Tripoly phosphate sodium STPP: 23 parts;
Soxylat A 25-7: 4.5 parts;
Efficient organosilicon suds suppressor: 0.2 part;
General organosilicon defoaming powder: 0.2 part.
After the even mixing of above-mentioned raw materials, pack and namely can be made into qualified cold-rolled silicon iron scavenger specially.During use, only needing to plant solid-state cold-rolled silicon iron scavenger specially pours in the tap water, fully stir and make its dissolving, be configured to concentration and be 3.5%, the scavenging solution of liquid temperature between 60 ℃, send into silicon steel sheet factory by pipeline and get in the strip cleaning groove, cold-rolled silicon iron is sprayed cleaning, empirical tests, clean rate can reach more than 97%, and e-quipment and pipe does not all produce fouling after using.
In the various embodiments described above, Soxylat A 25-7 specifically comprises the Soxylat A 25-7 of the EO/PO block of Fatty Alcohol(C12-C14 and C12-C18), efficient organosilicon suds suppressor specifically comprises any one among efficient organosilicon suds suppressor TSA-7133, TSA-672, TSA-10A, D-30X, TSA-630 and the TSA-5701, and general organosilicon defoaming powder specifically comprises general organosilicon defoaming powder T-20GB.
The cold-rolled silicon iron scavenger specially of the various embodiments described above of the present invention can be exclusively used in the cleaning cold-rolled silicon iron, adopts dipping degreasing or spray degreasing mode all can; This cold-rolled silicon iron scavenger specially also is applicable to the matting of other steel.
It should be noted that at last: the above only is the preferred embodiments of the present invention, be not limited to the present invention, although with reference to previous embodiment the present invention is had been described in detail, for a person skilled in the art, it still can be made amendment to the technical scheme that aforementioned each embodiment puts down in writing, and perhaps part technical characterictic wherein is equal to replacement.Within the spirit and principles in the present invention all, any modification of doing, be equal to replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (4)
1. a cold-rolled silicon iron scavenger specially is characterized in that, mainly comprises following component, is expressed as with parts by weight:
Sodium hydroxide: 17 ~ 31 parts;
Water glass: 46-62 part;
Tripoly phosphate sodium STPP: 12-23 part;
Soxylat A 25-7: 1 ~ 8 part;
Efficient organosilicon suds suppressor: 0.1 ~ 0.3;
General organosilicon defoaming powder: 0.1 ~ 0.3 part.
2. cold-rolled silicon iron scavenger specially according to claim 1 is characterized in that, described Soxylat A 25-7 specifically comprises the Soxylat A 25-7 of the EO/PO block of Fatty Alcohol(C12-C14 and C12-C18).
3. cold-rolled silicon iron scavenger specially according to claim 1, it is characterized in that, described efficient organosilicon suds suppressor specifically comprises any one among efficient organosilicon suds suppressor TSA-7133, TSA-672, TSA-10A, D-30X, TSA-630 and the TSA-5701.
4. cold-rolled silicon iron scavenger specially according to claim 1 is characterized in that, described general organosilicon defoaming powder specifically comprises general organosilicon defoaming powder T-20GB.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012103946586A CN102912365A (en) | 2012-10-17 | 2012-10-17 | Special cleaning agent for cold rolled silicon steel plate |
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| Application Number | Priority Date | Filing Date | Title |
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| CN2012103946586A CN102912365A (en) | 2012-10-17 | 2012-10-17 | Special cleaning agent for cold rolled silicon steel plate |
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| CN102912365A true CN102912365A (en) | 2013-02-06 |
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| CN2012103946586A Pending CN102912365A (en) | 2012-10-17 | 2012-10-17 | Special cleaning agent for cold rolled silicon steel plate |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103726063A (en) * | 2013-12-20 | 2014-04-16 | 柳州译海网络科技有限公司 | Cold rolled silicon steel plate cleaner |
| CN112553635A (en) * | 2020-11-23 | 2021-03-26 | 武汉迪赛新材料有限公司 | Environment-friendly foamless liquid degreasing agent for cleaning before cold rolling continuous annealing |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2440837A (en) * | 1943-07-28 | 1948-05-04 | J H Shoemaker | Metal cleaning composition |
| CN1098748A (en) * | 1993-08-12 | 1995-02-15 | 武汉钢铁(集团)公司 | Cleaning agent for cold-rolled silicon steel plate |
| CN101736353A (en) * | 2008-11-14 | 2010-06-16 | 沈阳晟豪化工有限公司 | Metal surface degreasing agent |
-
2012
- 2012-10-17 CN CN2012103946586A patent/CN102912365A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2440837A (en) * | 1943-07-28 | 1948-05-04 | J H Shoemaker | Metal cleaning composition |
| CN1098748A (en) * | 1993-08-12 | 1995-02-15 | 武汉钢铁(集团)公司 | Cleaning agent for cold-rolled silicon steel plate |
| CN101736353A (en) * | 2008-11-14 | 2010-06-16 | 沈阳晟豪化工有限公司 | Metal surface degreasing agent |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103726063A (en) * | 2013-12-20 | 2014-04-16 | 柳州译海网络科技有限公司 | Cold rolled silicon steel plate cleaner |
| CN112553635A (en) * | 2020-11-23 | 2021-03-26 | 武汉迪赛新材料有限公司 | Environment-friendly foamless liquid degreasing agent for cleaning before cold rolling continuous annealing |
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Application publication date: 20130206 |