CN102899193B - Novel environmentally friendly efficient oil stain cleaning agent and preparation method thereof - Google Patents
Novel environmentally friendly efficient oil stain cleaning agent and preparation method thereof Download PDFInfo
- Publication number
- CN102899193B CN102899193B CN201210426449.5A CN201210426449A CN102899193B CN 102899193 B CN102899193 B CN 102899193B CN 201210426449 A CN201210426449 A CN 201210426449A CN 102899193 B CN102899193 B CN 102899193B
- Authority
- CN
- China
- Prior art keywords
- cleaning agent
- parts
- sodium
- white residue
- oil stain
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Abstract
The invention provides a novel environmentally friendly efficient oil stain cleaning agent and a preparation method thereof. The cleaning agent comprises the following components in parts by weight: 20-65 parts of waste silicon slag, 1-50 parts of surfactant and 0-76 parts of water. Solid waste slag-waste silicon slag generated in the production process of inorganic silica gel is mainly used as a main raw material and is compounded with a detergent builder such as a surface active agent to form the oil stain cleaning agent. The novel environmentally friendly efficient oil stain cleaning agent provided by the invention has the main characteristics that (1) the main component is inorganic silica, and the cleaning agent has no smell and is non-toxic and pollution-free, no organic solvents are volatile, and the cost is low; (2) the removal speed of stubborn stain oil and colloidal stain oil is fast; (3) the range of use is wide; and (4) the oil stain can be cleaned thoroughly, and the object is as clean as new after the surface of the object is treated with the oil stain cleaning agent. For silica gel enterprises, the cleaning agent is prepared from the waste silicon slag, thereby realizing the purposes of turning waste into treasure, developing circular economy and reducing waste emissions; and the cleaning agent has good economic and social benefits.
Description
Technical field
The invention belongs to grease dirt cleaning agent field, particularly relate to a kind of novel environment friendly high-efficiency grease dirt cleaning agent and preparation method thereof.
Background technology
Many obstinate greasy dirts are often run in daily life with in producing, as places such as kitchen, workshop wagon, engineering shop, shop equipment maintenances, these obstinate greasy dirts use conventional cleaning product, as common washing powder, scrubbing powder etc. are difficult to reach desirable wipe oil effect.And if use the organic solvent type sanitising agent of stronger soil removability, the treatment time is long, and can leave over organic solvent after processing, and works the mischief, be therefore badly in need of a kind of sanitising agent for these obstinate greasy dirts to the healthy of people and environment.
Summary of the invention
Be difficult to for the existing typical cleaning agent of use the present situation removing obstinate greasy dirt, the object of this invention is to provide a kind of novel environment friendly high-efficiency grease dirt cleaning agent and preparation method thereof.The present invention mainly adopts the inorganic materials of non-solvent, weakly alkaline chemical scavenging and physical adsorption, mechanical friction is adopted to clear up the processing mode combined, be mainly used in the clean of the surperficial obstinate greasy dirts such as pottery, glass, hardware, have that clean-up capability is strong, degreasing speed fast and the advantage such as free from extraneous odour, and healthy and environment can not work the mischief to the staff at scene.
For achieving the above object, the present invention adopts following technical proposals to be achieved:
A kind of novel environment friendly high-efficiency grease dirt cleaning agent, described sanitising agent comprises following component, with parts by weight: useless white residue 20-65 part, tensio-active agent 1-50 part, water 0-76 part, described useless white residue is the solid slag that solid-state sodium silicate liquid turns to liquid sodium silicate and produces in pressure-filtering process, and described useless white residue contains silicon-dioxide 45%-70%, sodium 8%-10%, calcium 2%-4%, iron 2%-4%, magnesium 0.5%-1%, surplus is inevitable impurity.
Further improvement to technique scheme: described tensio-active agent is one or more in Sodium dodecylbenzene sulfonate, fatty alcohol-polyoxyethylene ether, sodium lauryl sulphate, OP-10, Morpan BB, alkyl glycoside, Brij 35 sodium sulfate, cocoanut fatty acid diethanolamide, polyoxyethylene nonylphenol ether or EDTA.
Further improvement to technique scheme: described sanitising agent also comprises oxyhydroxide.
Further improvement to technique scheme: useless white residue 20-45 part, oxyhydroxide 2-20 part, tensio-active agent 1-30 part, water 5-70 part.
Further improvement to technique scheme: useless white residue 42 parts, 4 parts, sodium hydroxide, Sodium dodecylbenzene sulfonate 1 part, OP-10 are 1 part, fatty alcohol-polyoxyethylene ether 1 part, 58 parts, water.
Further improvement to technique scheme: the pH value of described grease dirt cleaning agent is 8-13.
Present invention also offers the preparation method of described novel environment friendly high-efficiency grease dirt cleaning agent: after the useless white residue of described consumption and water being fed intake, open stirring to pulp, flotation ash disposal; Then by filtrate with 20-50 object strainer filtering, according to the pH value of filter cake, add the oxyhydroxide of described consumption, regulate the pH value of filter cake to 8-13; Finally add the tensio-active agent of described consumption, add water and after being uniformly dispersed or carrying out drying treatment, obtain liquid state, paste or powder detergent.
Compared with prior art, grease dirt cleaning agent of the present invention is main raw material primarily of the solid slag produced in inorganic silica gel production process-" useless white residue " (major ingredient is water glass, sodium sulfate and silicon dioxide microparticle), then forms so that the washing auxiliary detergents such as tensio-active agent are composite.The principal feature of described grease dirt cleaning agent is: (1) main component is inorganic silicon dioxide, and free from extraneous odour does not have organic solvent to volatilize, nontoxic, pollution-free, with low cost; (2) fast to the removal speed of obstinate greasy dirt, gluey greasy dirt; (3) of many uses; (4) thoroughly clean, sparkling clean behind handled object surface.
Embodiment
Below in conjunction with embodiment, technical scheme of the present invention is described in further detail.
The formula of grease dirt cleaning agent described in the present invention is, by weight: dry state is given up white residue 20-65 part, tensio-active agent 1-50 part, described tensio-active agent can be Sodium dodecylbenzene sulfonate, fatty alcohol-polyoxyethylene ether, sodium lauryl sulphate, OP-10, Morpan BB, alkyl glycoside, Brij 35 sodium sulfate, cocoanut fatty acid diethanolamide, one or more in polyoxyethylene nonylphenol ether or EDTA, water 0-76 part, on the basis of said components, described sanitising agent can also comprise hydroxide powder 5-20 part, for the adjustment of acid-basicity.
Described useless white residue is the solid slag that solid-state sodium silicate liquid turns to liquid sodium silicate and produces in pressure-filtering process, it mainly becomes silicon dioxide microparticle, water glass, sodium sulfate and other accumulative solid impurities, concrete content is silicon-dioxide 45%-70%, sodium 8%-10%, calcium 2%-4%, iron 2%-4%, magnesium 0.5%-1%, surplus is other impurity.
Main production flow process is: after described useless white residue 20-65 part and water 0-76 part being fed intake, open stirring to pulp, flotation ash disposal, then by filtrate with 20-50 object strainer filtering, according to the pH value of filter cake, add sodium hydroxide or potassium hydroxide, regulate the pH value of filter cake to 8-13; Finally add tensio-active agent 1-50 part.As required can by adding appropriate water and being uniformly dispersed or carrying out drying treatment, obtained liquid state, paste or powder detergent.
The further optimization of C/C composites of described grease dirt cleaning agent is, by weight: dry state is given up white residue 20-45 part, sodium hydroxide 2-20 part, tensio-active agent 1-30 part, water 5-70 part.
The optimum formula of described grease dirt cleaning agent is, by weight: give up white residue 42 parts, 4 parts, sodium hydroxide, Sodium dodecylbenzene sulfonate 1 part, OP-10 of dry state is 1 part, fatty alcohol-polyoxyethylene ether 1 part, 58 parts, water.
Embodiment 1
The formula of described grease dirt cleaning agent is as follows, by weight: dry state is given up white residue 40 parts, and 60 parts, water, benzalkonium bromide (bromogeramine) 20 parts, 8 parts, sodium hydroxide, stir obtained clean-out system.
Embodiment 2
The formula of described grease dirt cleaning agent is as follows, by weight: dry state is given up white residue 45 parts, and 55 parts, water, fatty alcohol-polyoxyethylene ether 15 parts, 8 parts, potassium hydroxide, stir obtained clean-out system.
Embodiment 3
The formula of described grease dirt cleaning agent is as follows, by weight: dry state is given up white residue 42 parts, and 58 parts, water, 4 parts, sodium hydroxide, Sodium dodecylbenzene sulfonate 2 parts, 2 parts of OP-10, stir obtained clean-out system.
Embodiment 4
The formula of described grease dirt cleaning agent is as follows, by weight: dry state is given up white residue 24 parts, and 76 parts, water, 10 parts, sodium hydroxide, Sodium dodecylbenzene sulfonate 5 parts, fatty alcohol-polyoxyethylene ether 5 parts, stir obtained clean-out system.
Embodiment 5
The formula of described grease dirt cleaning agent is as follows, by weight: dry state is given up white residue 42 parts, and 58 parts, water, 4 parts, sodium hydroxide, Sodium dodecylbenzene sulfonate 1 part, OP-10 are 1 part, fatty alcohol-polyoxyethylene ether 1 part.
Cleaning performance experiment is: be evenly coated in by 3g lubricating oil on round plastic plate that diameter is 30cm, and get after a certain amount of clean-out system is coated in greasy surfaces and clean with rag, then rinse with water, at room temp 28 DEG C, cleaning performance experimental data table is as shown in table 1 below.
Table 1: cleaning performance experimental result (28 DEG C)
| Embodiment | Greasy dirt coated weight/g | Clean up clean-out system consumption/g |
| 1 | 3 | 3.0 |
| 2 | 3 | 3.0 |
| 3 | 3 | 2.5 |
| 4 | 3 | 2.4 |
| 5 | 3 | 1.5 |
| Certain brand washing powder | 3 | 3.0 |
| Certain brand liquid detergent | 3 | 2.5 |
As can be seen from Table 1, when clean same greasy dirt, the clean-out system cleaning performance that the single tensio-active agent of the present invention obtains is close with washing powder; The sanitising agent cleaning performance of two kinds of composite systems is better than washing powder, close with liquid detergent; The obtained sanitising agent cleaning performance of three kinds of surfactant compounds is better than liquid detergent.
The index of the sanitising agent of product of the present invention is: grey or light gray solid powder or paste, or emulsion liquid.Described sanitising agent includes has adsorb organic compound and heavy metal ion, and containing having the silicon dioxide microparticle of physical friction cleanup action, this product is nontoxic, free from extraneous odour, do not fire, not quick-fried.
The clean-out system obtained through the above-mentioned technique of the present invention has good cleaning efficacy, especially for material surfaces such as clean pottery, glass, metals, between the component of such as smoke exhaust ventilator, servicing installation and instrument, vehicle, maintenance work, the cleaning of place's stain such as kitchen range, toilet.
Above embodiment only in order to technical scheme of the present invention to be described, but not is limited; Although with reference to previous embodiment to invention has been detailed description; for the person of ordinary skill of the art; still can the technical scheme described in previous embodiment be modified; or equivalent replacement is carried out to wherein portion of techniques feature; and these amendments or replacement, do not make the essence of appropriate technical solution depart from the spirit and scope of the present invention's technical scheme required for protection.
Claims (4)
1. an environment-friendly high-efficiency grease dirt cleaning agent, is characterized in that: described sanitising agent comprises following component, with parts by weight: useless white residue 20-45 part, tensio-active agent 1-30 part, water 5-70 part, described sanitising agent also comprises oxyhydroxide 2-20 part, and described useless white residue is the solid slag that solid-state sodium silicate liquid turns to liquid sodium silicate and produces in pressure-filtering process, described useless white residue contains silicon-dioxide 45%-70%, sodium 8%-10%, calcium 2%-4%, iron 2%-4%, magnesium 0.5%-1%, surplus is inevitable impurity;
The preparation method of described High-efficiency oil cleanser, is characterized in that: after the useless white residue of described consumption and water being fed intake, and opens stirring to pulp, flotation ash disposal; Then by filtrate with 20-50 object strainer filtering, according to the pH value of filter cake, add the oxyhydroxide of described consumption, regulate the pH value of filter cake to 8-13; Finally add the tensio-active agent of described consumption, add water and after being uniformly dispersed or carrying out drying treatment, obtain liquid state, paste or powder detergent.
2. a kind of environment-friendly high-efficiency grease dirt cleaning agent according to claim 1, is characterized in that: described tensio-active agent is one or more in Sodium dodecylbenzene sulfonate, fatty alcohol-polyoxyethylene ether, sodium lauryl sulphate, OP-10, Morpan BB, alkyl glycoside, Brij 35 sodium sulfate, cocoanut fatty acid diethanolamide, polyoxyethylene nonylphenol ether or EDTA.
3. a kind of environment-friendly high-efficiency grease dirt cleaning agent according to claim 1, it is characterized in that: the optimum formula of described sanitising agent is: useless white residue 42 parts, 4 parts, sodium hydroxide, Sodium dodecylbenzene sulfonate 1 part, OP-10 are 1 part, fatty alcohol-polyoxyethylene ether 1 part, 58 parts, water.
4. a kind of environment-friendly high-efficiency grease dirt cleaning agent according to claim 1, is characterized in that: the pH value of described grease dirt cleaning agent is 8-13.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210426449.5A CN102899193B (en) | 2012-10-31 | 2012-10-31 | Novel environmentally friendly efficient oil stain cleaning agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210426449.5A CN102899193B (en) | 2012-10-31 | 2012-10-31 | Novel environmentally friendly efficient oil stain cleaning agent and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102899193A CN102899193A (en) | 2013-01-30 |
| CN102899193B true CN102899193B (en) | 2015-01-14 |
Family
ID=47571687
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210426449.5A Active CN102899193B (en) | 2012-10-31 | 2012-10-31 | Novel environmentally friendly efficient oil stain cleaning agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102899193B (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105623890B (en) * | 2014-11-04 | 2018-12-18 | 南京精锐化工科技有限公司 | High-efficiency environment friendly industry weight greasy dirt detergent |
| CN107696208A (en) * | 2017-09-25 | 2018-02-16 | 阜南县大自然工艺品有限公司 | A kind of spray cleaning agent conserved to cogongrass basket |
| CN111747550A (en) * | 2020-06-10 | 2020-10-09 | 苏州华烯环保科技有限公司 | Waste water membrane separation device |
| CN112011415A (en) * | 2020-08-31 | 2020-12-01 | 上海申仰实业有限公司 | Kitchen oil stain cleaning agent |
| CN113801741A (en) * | 2021-08-10 | 2021-12-17 | 广东莱雅新化工科技有限公司 | Cleaning agent for cleaning dirt on textured surface and preparation method thereof |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1052895A (en) * | 1989-12-22 | 1991-07-10 | 四平硅藻土过滤器材联合厂 | With diatomite is the scrubbing powder of raw material |
| CN1119673A (en) * | 1994-09-29 | 1996-04-03 | 周承宇 | Detergent |
| CN1173533A (en) * | 1997-08-06 | 1998-02-18 | 广州市荔湾区得洁洗涤剂厂 | Superconcentration paste state semi-solid detergent |
| CN1242419A (en) * | 1998-07-03 | 2000-01-26 | 上海兴达工贸实业有限公司 | High efficiency phosphorus-free neutral detergent paste |
| CN1326821A (en) * | 2001-07-12 | 2001-12-19 | 柳云珍 | Process for treating silicon slag |
| CN101020867A (en) * | 2007-02-12 | 2007-08-22 | 陆丽玲 | Fast foaming air conditioner cleaning agent |
| CN101402901A (en) * | 2008-11-12 | 2009-04-08 | 江门市蓬江区海润化工有限公司 | Plaster shaped decontaminating agent of silicon dioxide with disinfection function and method of producing the same |
| CN101508942A (en) * | 2009-03-11 | 2009-08-19 | 李汉辉 | Alkaline liquor special for dish washing machine |
-
2012
- 2012-10-31 CN CN201210426449.5A patent/CN102899193B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1052895A (en) * | 1989-12-22 | 1991-07-10 | 四平硅藻土过滤器材联合厂 | With diatomite is the scrubbing powder of raw material |
| CN1119673A (en) * | 1994-09-29 | 1996-04-03 | 周承宇 | Detergent |
| CN1173533A (en) * | 1997-08-06 | 1998-02-18 | 广州市荔湾区得洁洗涤剂厂 | Superconcentration paste state semi-solid detergent |
| CN1242419A (en) * | 1998-07-03 | 2000-01-26 | 上海兴达工贸实业有限公司 | High efficiency phosphorus-free neutral detergent paste |
| CN1326821A (en) * | 2001-07-12 | 2001-12-19 | 柳云珍 | Process for treating silicon slag |
| CN101020867A (en) * | 2007-02-12 | 2007-08-22 | 陆丽玲 | Fast foaming air conditioner cleaning agent |
| CN101402901A (en) * | 2008-11-12 | 2009-04-08 | 江门市蓬江区海润化工有限公司 | Plaster shaped decontaminating agent of silicon dioxide with disinfection function and method of producing the same |
| CN101508942A (en) * | 2009-03-11 | 2009-08-19 | 李汉辉 | Alkaline liquor special for dish washing machine |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102899193A (en) | 2013-01-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102899193B (en) | Novel environmentally friendly efficient oil stain cleaning agent and preparation method thereof | |
| CN100575471C (en) | A kind of environmental protection multifunctional deoiling decontaminant | |
| CN104294297A (en) | Water-based metal cleaner and preparation method thereof | |
| CN102732389B (en) | Vehicle cleaning agent | |
| CN103774164A (en) | Water-based metal-degreasing cleaning agent | |
| CN103710720B (en) | A kind of long-life water base oil removing anti-rust cleaning agent | |
| CN1098748A (en) | Cleaning agent for cold-rolled silicon steel plate | |
| CN102978022A (en) | Phosphorus-free foam-free low-temperature steel plate surface cleaning agent and preparation method thereof | |
| CN103374726A (en) | Efficient multipurpose metal cleaning agent | |
| CN101368131A (en) | Mechanical equipment detergent | |
| CN105297042A (en) | Metal material cleaning agent and use method thereof | |
| CN102220592B (en) | Foamless floating-oil-type alkaline cleaning agent used for pre-treatment of pre-coated steel plate | |
| CN101994126A (en) | Environmentally friendly multifunctional metal cleaning agent | |
| CN101463481B (en) | Acid rust remover | |
| CN105002020A (en) | Ceramic cleaning agent | |
| CN106319536A (en) | Industrial metal cleaner and preparation method thereof | |
| CN104357251A (en) | Mechanical filter oil stain cleaning agent and preparation method thereof | |
| CN104313607A (en) | Metal cleaner and preparation method thereof | |
| CN102936539A (en) | Environment-friendly wax removing and oil removing cleaning agent | |
| CN101457366A (en) | Degreasing agent for cleaning steel plate | |
| CN110724607B (en) | Shower room cleaning cream and preparation method thereof | |
| CN107587145A (en) | A kind of without phosphorus deashing agent for strengthening cleaning performance | |
| CN111575123B (en) | Special cleaning agent for ceramic anilox roller and preparation method and application thereof | |
| CN105063636A (en) | Ultrasonic cleaning agent for aluminium alloy mobile phone shells and preparation method of ultrasonic cleaning agent | |
| CN105220166A (en) | A kind of painting dressing automobiles Environment-friendlydegreasant degreasant and using method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |