CN106434025A - Sleeve sterilization agent and preparation method thereof - Google Patents
Sleeve sterilization agent and preparation method thereof Download PDFInfo
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- CN106434025A CN106434025A CN201610821674.7A CN201610821674A CN106434025A CN 106434025 A CN106434025 A CN 106434025A CN 201610821674 A CN201610821674 A CN 201610821674A CN 106434025 A CN106434025 A CN 106434025A
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-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/042—Acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2096—Heterocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a sleeve sterilization agent and a preparation method thereof. The sleeve sterilization agent is prepared from water, sodium dodecyl sulfate, ethyl acetate, propyl acetate, propylene epoxide, aluminum hydroxide, fatty acyl amide, sterilization agent and thickening agent, wherein relative to 20 parts by weight of sodium dodecyl sulfate, the consumption of water is 100-140 parts by weight, the consumption of ethyl acetate is 4.8-9.8 parts by weight, the consumption of propyl acetate is 3.2-7.8 parts by weight, the consumption of propylene epoxide is 1-5 parts by weight, the consumption of aluminum hydroxide is 2-7 parts by weight, the consumption of fatty acyl amide is 5-15 parts by weight, the consumption of the sterilization agent is 1.2-4.2 parts by weight and the consumption of the thickening agent is 3.1-6.1 parts by weight. The disclosed sleeve sterilization agent is efficient in decontamination ability, good in sterilizing effect and easy to flush away.
Description
Technical field
The present invention relates to biocide is and in particular to sleeve pipe biocide and preparation method thereof.
Background technology
Biocide typically refers to the material that can clean dirt under general wash conditions.Commercially available biocide often contains
Surfactant, there is affinity interaction with dirt in surfactant, opened by the surface activity changing water, the surface reducing water
Power, makes dirt spin off.According to the difference of hydrophilic group, biocide can be divided into:Ion-type biocide and nonionic sterilizing
Agent, its ionic biocide can be divided into anionic biocide and cationic biocide again.
A large amount of dusts and antibacterial are easily assembled in surface to sleeve pipe in use, or even can produce abnormal flavour it is therefore desirable to special
Abluent or cleaning combination be cleaned.And most abluent complicated process of preparation at present, high cost, soil release performance are poor
And remain abnormal flavour after using.
Content of the invention
An object of the present invention is to provide to have high-effective cleansing ability, strong bactericidal effect and the easy sleeve pipe sterilizing rinsed
Agent.
It is a further object of the present invention to provide the preparation method of mild condition, sleeve pipe biocide simple to operate.
The sleeve pipe biocide that the present invention provides is made up of following raw material:Water, sodium lauryl sulfate, ethyl acetate, acetic acid third
Ester, expoxy propane, aluminium hydroxide, fatty acid amide, antibacterial and thickening agent;Wherein, in parts by weight, with respect to 20 parts of lauryl alcohols
Sodium sulfate, the consumption of water is 100-140 part, and the consumption of ethyl acetate is 4.8-9.8 part, and the consumption of propyl acetate is 3.2-7.8
Part, the consumption of expoxy propane is 1-5 part, and the consumption of aluminium hydroxide is 2-7 part, and the consumption of fatty acid amide is 5-15 part, antibacterial
Consumption be 1.2-4.2 part, the consumption of thickening agent is 3.1-6.1 part.
In above-mentioned sleeve pipe biocide, the concentration of aluminium hydroxide can select in wide scope, but for improving this set
The dirt-removing power of pipe biocide is it is preferable that the concentration of aluminium hydroxide is 0.05mol/L-0.1mol/L.
In above-mentioned sleeve pipe biocide, the concrete species of antibacterial can select in wide scope, but should for improving
The clean result of sleeve pipe biocide is it is preferable that antibacterial is phosphomolybdic acid or trichloro hydroxyl diphenyl ether.
In above-mentioned sleeve pipe biocide, the concrete species of thickening agent can select in wide scope, examines from practicality
Consider it is preferable that thickening agent be selected from one of methylcellulose, sodium carboxymethyl cellulose, polyacrylamide and polyvinyl alcohol or
Multiple.
The preparation method of the above-mentioned sleeve pipe biocide that the present invention provides, the method includes:First by described sodium lauryl sulfate,
Ethyl acetate, propyl acetate, expoxy propane, fatty acid amide and antibacterial are mixed and heated, and are subsequently added into aluminium hydroxide and adjust pH
Prepared compositionss, are eventually adding the viscosity of thickening agent regulation composition, and stirring is mixed to prepare sleeve pipe biocide.Wherein, with weight
Part meter, with respect to 20 parts of described sodium lauryl sulfates, the consumption of described water is 100-140 part, and the consumption of described ethyl acetate is
4.8-9.8 part, the consumption of described propyl acetate is 3.2-7.8 part, and the consumption of described expoxy propane is 1-5 part, described hydroxide
The consumption of aluminum is 2-7 part, and the consumption of described fatty acid amide is 5-15 part, and the consumption of described antibacterial is 1.2-4.2 part, described increasing
Thick dose of consumption is 3.1-6.1 part.
In above-mentioned preparation method, the actual conditions of heating can select in wide scope, but in order to carry further
It is preferable that the temperature of heating is 40-50 DEG C, the time of heating is 20-30min to the clean effect of this sleeve pipe biocide high.
In above-mentioned preparation method, the numerical value of pH can select, from clean effect and the peace of biocide in wide scope
Consider in full property it is preferable that the numerical value of pH is 5.5-6.5.
In above-mentioned preparation method, the concrete time of stirring mixing and rotating speed can select in wide scope, but are
Improve the preparation efficiency of this sleeve pipe biocide further it is preferable that the rotating speed of stirring mixing is 500-600rpm, the time is
10-20min.
By technique scheme, the present invention is main cleaning action by selecting sodium lauryl sulfate, ethyl acetate
Material, and hydrous water, propyl acetate, expoxy propane, fatty acid amide and antibacterial to be increasing dispersibility, the wettability of mixture,
Increased clean dirt effect;The aluminium hydroxide adding in order to regulation composition pH it is ensured that the active function of active substance,
The viscosity adding thickening agent regulation composition afterwards is obtained sleeve pipe biocide.The method is a kind of with low cost, mild condition, green
Environmental protection and method simple to operate, prepared sleeve pipe biocide has high-effective cleansing ability.
Other features and advantages of the present invention will be described in detail in subsequent specific embodiment part.
Specific embodiment
Hereinafter the specific embodiment of the present invention is described in detail.It should be appreciated that it is described herein concrete
Embodiment is merely to illustrate and explains the present invention, is not limited to the present invention.
Embodiment 1
In parts by weight, first by 100 parts of water, 20 parts of sodium lauryl sulfates, 5 parts of ethyl acetate, 3.5 parts of propyl acetates, 1 part
Expoxy propane, 5 parts of fatty acid amides and 1.5 parts of phosphomolybdic acid mixing, and heat 20min at a temperature of 42 DEG C;It is subsequently added into 2 parts of concentration
It is 5.5 prepared compositionss that aluminium hydroxide for 0.05mol/L adjusts pH;It is eventually adding 3.5 parts of methylcellulose regulation compositions
Viscosity be 7000mpas, and with the rotating speed of 500rpm stirring mixing 10min so that sleeve pipe biocide A1 is obtained.
Embodiment 2
In parts by weight, first by 140 parts of water, 20 parts of sodium lauryl sulfates, 9.5 parts of ethyl acetate, 7.5 parts of propyl acetates, 5
Part expoxy propane, 15 parts of fatty acid amides and 4 parts of trichloro hydroxyl diphenyl ether mixing, and heat 0min at a temperature of 48 DEG C;Then plus
Enter the aluminium hydroxide that 7 parts of concentration are 0.1mol/L to adjust pH is 6.5 prepared compositionss;It is eventually adding 5.5 parts of carboxymethyl celluloses
The viscosity of sodium regulation composition is 9000mpas, and with the rotating speed stirring mixing 20min of 600rpm so that sleeve pipe biocide A2 is obtained.
Embodiment 3
In parts by weight, first by 120 parts of water, 20 parts of sodium lauryl sulfates, 7 parts of ethyl acetate, 5 parts of propyl acetates, 3 parts of rings
Ethylene Oxide, 10 parts of fatty acid amides and 3 parts of phosphomolybdic acid mixing, and heat 25min at a temperature of 45 DEG C;Being subsequently added into 4 parts of concentration is
It is 6 prepared compositionss that the aluminium hydroxide of 0.075mol/L adjusts pH;It is eventually adding the viscous of 4.5 parts of polyacrylamide regulation compositions
Spend for 8000mpas, and with the rotating speed stirring mixing 15min of 550rpm so that sleeve pipe biocide A3 is obtained.
Comparative example 1
Method according to embodiment 1 carries out biocide B1 is obtained, except that, do not add sodium lauryl sulfate.
Comparative example 2
Method according to embodiment 1 carries out biocide B2 is obtained, except that, do not add ethyl acetate.
Comparative example 3
Method according to embodiment 1 carries out biocide B3 is obtained, except that, do not add propyl acetate.
Comparative example 4
Method according to embodiment 1 carries out biocide B4 is obtained, except that, do not add aluminium hydroxide.
Comparative example 5
Method according to embodiment 1 carries out biocide B5 is obtained, except that, do not add phosphomolybdic acid.
Comparative example 6
Method according to embodiment 1 carries out biocide B6 is obtained, except that, do not add methylcellulose.
Detection example 1
Will be respectively through A1-A3, the washed sleeve pipe of B1-B6 carries out SC total amount and the detection of abnormal flavour, concrete outcome
It is shown in Table 1.
Table 1
Learn from the above, the sleeve pipe biocide that the present invention provides has good cleaning effect, have very well simultaneously
Sterilization, fungistatic effect, and there is the effect of purify air;And do not add sodium lauryl sulfate, ethyl acetate, acetic acid third
The biocide effect that ester, aluminium hydroxide, antibacterial, the comparative example of thickening agent are obtained is bad.This shows that this sleeve pipe biocide is each
The coefficient result of material.Additionally, can be seen that the sleeve pipe sterilizing of present invention offer from preparation method provided by the present invention
The preparation method mild condition of agent, environmental protection, preparation is simple.
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited in above-mentioned embodiment
Detail, in the range of the technology design of the present invention, multiple simple variant can be carried out to technical scheme, this
A little simple variant belong to protection scope of the present invention.
It is further to note that each particular technique feature described in above-mentioned specific embodiment, in not lance
In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to various can
The compound mode of energy no longer separately illustrates.
Additionally, combination in any can also be carried out between the various different embodiment of the present invention, as long as it is without prejudice to this
The thought of invention, it equally should be considered as content disclosed in this invention.
Claims (9)
1. a kind of sleeve pipe biocide is it is characterised in that described sleeve pipe biocide is made up of following raw material:Water, sodium lauryl sulfate,
Ethyl acetate, propyl acetate, expoxy propane, aluminium hydroxide, fatty acid amide, antibacterial and thickening agent;
Wherein, in parts by weight, with respect to 20 parts of described sodium lauryl sulfates, the consumption of described water is 100-140 part, described second
The consumption of acetoacetic ester is 4.8-9.8 part, and the consumption of described propyl acetate is 3.2-7.8 part, and the consumption of described expoxy propane is 1-5
Part, the consumption of described aluminium hydroxide is 2-7 part, and the consumption of described fatty acid amide is 5-15 part, and the consumption of described antibacterial is
1.2-4.2 part, the consumption of described thickening agent is 3.1-6.1 part.
2. sleeve pipe biocide according to claim 1, wherein, the concentration of described aluminium hydroxide is 0.05mol/L-
0.1mol/L.
3. sleeve pipe biocide according to claim 1 and 2, wherein, described antibacterial is phosphomolybdic acid or trichlorine hydroxyl hexichol
Ether.
4. sleeve pipe biocide according to claim 3, wherein, described thickening agent is selected from methylcellulose, carboxymethyl cellulose
One or more of plain sodium, polyacrylamide and polyvinyl alcohol.
5. a kind of preparation method of the sleeve pipe biocide as described in any one in claim 1-4 is it is characterised in that described system
Preparation Method is:First by described water, sodium lauryl sulfate, ethyl acetate, propyl acetate, expoxy propane, fatty acid amide and antibacterial
It is mixed and heated, be subsequently added into aluminium hydroxide and adjust the prepared compositionss of pH, be eventually adding the viscosity of thickening agent regulation composition, and
Stirring is mixed to prepare sleeve pipe biocide.
6. preparation method according to claim 5, wherein, the temperature of described heating is 40-50 DEG C, and the time of heating is
20-30min.
7. the preparation method according to claim 5 or 6, wherein, the numerical value of described pH is 5.5-6.5.
8. preparation method according to claim 7, wherein, when 25 DEG C, described viscosity is 7000-9000mpas.
9. preparation method according to claim 8, wherein, the rotating speed of described stirring mixing is 500-600rpm, and the time is
10-20min.
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CN201610821674.7A CN106434025A (en) | 2016-09-14 | 2016-09-14 | Sleeve sterilization agent and preparation method thereof |
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CN201610821674.7A CN106434025A (en) | 2016-09-14 | 2016-09-14 | Sleeve sterilization agent and preparation method thereof |
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Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1170036A (en) * | 1996-06-28 | 1998-01-14 | 徐彩荣 | Waterless detergent for dry cleaning |
CN1248616A (en) * | 1999-09-27 | 2000-03-29 | 上海家化联合股份有限公司 | Sterilizing detergent for cleaning air conditioner |
CN1259162A (en) * | 1997-06-04 | 2000-07-05 | 东陶机器株式会社 | Method for surface pretreatment before formation of photocatalytic hydrophilic film, and detergent and undercoat composition for use in the same |
CN1612927A (en) * | 2002-01-09 | 2005-05-04 | 气体产品及化学制品公司 | Aqueous stripping and cleaning composition |
US20050164913A1 (en) * | 2002-06-28 | 2005-07-28 | Veckis Industries Ltd. | Disinfecting composition |
CN1683484A (en) * | 2004-04-16 | 2005-10-19 | 上海宏略实业有限公司 | Cleaning composition and its use |
CN103055465A (en) * | 2011-10-18 | 2013-04-24 | 上海格伦化学科技有限公司 | Formaldehyde scavenging agent with oil solubility and preparation method |
-
2016
- 2016-09-14 CN CN201610821674.7A patent/CN106434025A/en active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1170036A (en) * | 1996-06-28 | 1998-01-14 | 徐彩荣 | Waterless detergent for dry cleaning |
CN1259162A (en) * | 1997-06-04 | 2000-07-05 | 东陶机器株式会社 | Method for surface pretreatment before formation of photocatalytic hydrophilic film, and detergent and undercoat composition for use in the same |
CN1248616A (en) * | 1999-09-27 | 2000-03-29 | 上海家化联合股份有限公司 | Sterilizing detergent for cleaning air conditioner |
CN1612927A (en) * | 2002-01-09 | 2005-05-04 | 气体产品及化学制品公司 | Aqueous stripping and cleaning composition |
US20050164913A1 (en) * | 2002-06-28 | 2005-07-28 | Veckis Industries Ltd. | Disinfecting composition |
CN1683484A (en) * | 2004-04-16 | 2005-10-19 | 上海宏略实业有限公司 | Cleaning composition and its use |
CN103055465A (en) * | 2011-10-18 | 2013-04-24 | 上海格伦化学科技有限公司 | Formaldehyde scavenging agent with oil solubility and preparation method |
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Application publication date: 20170222 |