CN1248616A - Sterilizing detergent for cleaning air conditioner - Google Patents
Sterilizing detergent for cleaning air conditioner Download PDFInfo
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- CN1248616A CN1248616A CN 99116918 CN99116918A CN1248616A CN 1248616 A CN1248616 A CN 1248616A CN 99116918 CN99116918 CN 99116918 CN 99116918 A CN99116918 A CN 99116918A CN 1248616 A CN1248616 A CN 1248616A
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Abstract
The present invention provides a germicidal cleaning agent for air conditioner. Said cleaning agent adopts the surfactant which has no toxic side-effect, is easy to biologically degrade and does not result in any pollution to environment, solvent and germicide as raw materials, and possesses two effects of cleaning and germicide, and after the region of air conditioner is cleaned, a layer of germicidal film can be formed, and after the air conditioner is cleaned, it has no need of washing with water, and the said cleaning agent can meet the requirements for cleaning air conditioner.
Description
The invention belongs to the household chemicals technical field, relate to a kind of washing composition, relate in particular to a kind of washing composition that conditioner is carried out sterilization and cleaning.
In recent years, along with the sustainable growth of economy, people's standard of living is improved rapidly.Conditioner is moved into streets and lanes rapidly as a kind of brand-new durable consumer goods, has entered common people house.No matter be hot summer or piercingly cold severe winter, people can both be in the indoor comfort that it's like spring all the year round that indulges in luxuriousness to one's heart's desire.Yet, when air-conditioning of a specified duration and no has just been opened, can produce peculiar smell in the room; It is slow-witted of a specified duration that the somebody is reflected in air-conditioned room, feels to feel dizzy, even feel sick, vomit.The medical expert is called " air conditioning disease ".Trace it to its cause, conditioner in use for some time, filtering net, radiator element etc. locate to have gathered a large amount of dusts, add that air conditioner condensate water is full of therebetween bacterium that grows thus and mould, along with cold and hot air in indoor circulation, both reduce the working efficiency of conditioner, increased energy consumption, more polluted room air, spread disease, cause serious threat to human health.
Conditioner this " healthy killer " has caused the great attention of the hygiene department of many countries and regions, and with the important indicator of conditioner pollution as city environmental pollution.Therefore, how conditioner is carried out in time and effectively cleaning and sterilization, become an important problem.
At present, the washing composition that is used for crust and metal is of a great variety, and still, its function is all more single, and because the special construction that conditioner itself is had makes cleaning more difficult.
One emerging industry-conditioner specialty cleaning company arises at the historic moment, yet its high expense makes the general population be difficult to accept.
In sum, must develop the also spendable new sterilizing detergent for cleaning air conditioner of a kind of non-specialised staff as early as possible, to satisfy the needs of the daily cleaning conditioner of people.
The object of the present invention is to provide a kind of easy to usely, have concurrently and clean and two kinds of effects of sterilization, and form one deck sterilizing membrane cleaning the position, cleaning finishes need not the washing composition that water washes.
Design of the present invention is such:
(1) conditioner is often gathering a large amount of dusts and dirt in use for some time on filtering net and the radiator element.The environment difference that these dirts use owing to conditioner, its moiety are also slightly different.Smokeless place, as household bedroom, reading room, movie theater etc., the dirt of filtering net and radiator element is mainly formed by being suspended in koniology, and the conditioner dirt in places such as family parlor, restaurant, cafe, except above-mentioned suspension, also have a large amount of unctuousness dirts, these dirts can quicken the absorption of dust.Dirt, dust gather in a large number conditioner inside, can reduce the working efficiency of air-conditioning greatly, increase energy consumption.
According to above-mentioned analysis, the dirt on known filter screen of air conditioner and the radiator element is mainly dust and unctuousness dirt, sticks to filtering net and fin surface securely.Want dusting out and unctuousness dirt simultaneously, optimal method is to adopt surfactant soln and solvent complex.Tensio-active agent exists hydrophilic group and hydrophobic group simultaneously, and this makes it have the effect that forms micelle in the adsorption on the interface with in solution, and the effect of this two aspect is the basic reason that tensio-active agent has washing and soil-removing action.In addition, that tensio-active agent has is wetting, emulsification and solublization are also played booster action to decontamination.For the unctuousness dirt, tensio-active agent causes interfacial tension lowering in the adsorption of water-oil interface, makes scavenging solution selective wetting solid surface, and greasy dirt is crispaturaed, and also helps greasy dirt simultaneously and disperses, and forms more stable emulsion, is suspended in the scavenging solution.For this class solid dirt of dust, when tensio-active agent during in its surface adsorption, generally with oleophilic group near solid surface, polar group is in water.Along with the carrying out of absorption, polar surfaces originally gradually becomes hydrophilic surface, and the solid dirt is dispersed in the water easily.The absorption of tensio-active agent also has anti-inhibition for dirt colloidal sol, in other words micelle is shielded, and has therefore strengthened dirt micelle dispersive stability, helps cleaning.The micelleization of surfactant soln has improved the solvability of water-fast liquids in tensio-active agent, has improved cleaning efficiency.Surfactant soln can effectively remove dust, and water-soluble dirt also can be removed part unctuousness dirt.But the unctuousness that clears all dirt, only the abutment surface promoting agent not enough, the best approach of removing the unctuousness dirt is with solvent it to be dissolved.
In addition, because spacing is very narrow between the aluminium flake of air conditioner radiation fin, and vertically the degree of depth is very dark, aluminium flake is very thin simultaneously, and intensity is very little, as cleaning with brush, can only clean the dirt of air conditioner radiation fin outside, radiator element depth position clean less than, just cause distortion easily with external force slightly and scratch influence heat (cold) exchange efficiency.So, the present invention adopts the aerosol-type with powerful injection dynamics, this formulation can make sterilization and clean composition and be deep into conditioner inside, act on each position of radiator element effectively, and can not produce hard friction, can not damage the surface of radiator element, simultaneously in the surface of radiator element, the pressure that produces by the spraying dirt on the radiator element that also can loosen makes more easy-clear of dirt.The dirt that washes down can be discharged by the air conditioner condensate water water outlet.
The tensio-active agent that the present invention selects for use comprises anion surfactant and nonionogenic tenside, and nonionogenic tenside is then better.Anion surfactant can adopt as Sodium dodecylbenzene sulfonate, AES (fatty alcohol-ether sodium sulfate) and other and contain SO
3 -, SO
4 -, COO
-The metal-salt of the tensio-active agent of group and with neutral salt such as organic bases such as trolamine, diethanolamine, monoethanolamine etc., and fatty alcohol-polyoxyethylene ether series, polyoxyethylene nonylphenol ether series, fatty acid alkyl amide etc.;
The solvent of selecting for use comprises ethanol, Virahol, isopropylcarbinol, diethylene glycol dimethyl ether, ethylene glycol ethyl ether, glycol isopropyl ether, butyl glycol ether, diethylene glycol dimethyl ether, Diethylene Glycol butyl ether, ethylene glycol benzyl ether, dipropylene glycol methyl ether, zellon etc.;
(2) after conditioner uses for some time, a large amount of dusts and dirt have often been gathered on filtering net and the radiator element.These dirts are mainly derived from the room inner suspension in airborne dust, also comprise some unctuousness dirts.The water of condensation that produces on the radiator element during operation of air conditioner and accumulate in the dirt of conditioner inlet mouth year in year out becomes the hotbed of bacterium and mould-growth breeding.Common pathogenic microorganism has Hemolytic streptococcus, tubercule bacillus, diphtheria corynebacterium, streptococcus aureus, intestinal bacteria, also has some respiratory pathogens, mould, yeast spore etc. in addition.Want thoroughly to remove bacterial propagule and mould on filter screen of air conditioner and the radiator element, the selection of sterilant is very crucial, must satisfy:
(1) efficient and requirement rapidly; This is because spray cleaning agent is shorter in the clean surface residence time, requires sterilant can reach the degerming purpose in short several minutes;
(2) sterilant harmless and corrosion to conditioner; Form because radiator element is fine and closely woven metal aluminium flake, filtering net is the nylon surface of second order, and the sterilant of selecting for use is cleaned the position to conditioner and can not be corrosive, otherwise can damage air-conditioning;
(3) sterilant is answered no color or smell, safety non-toxic; This is that the material that remains in fin surface may be with air in indoor circulation because preparation of the present invention need not the water flushing after cleaning;
(4) pH value of sterilant is neutral, and has excellent compatibility;
(5) sterilant should be easy to the body surface formation antibacterial film after cleaning, to reach the purpose of prevention house dust breed bacteria on radiator element.
Sterilant comprises aldehydes, alcohols, chlorine-containing compound and two guanidine classes etc.
Aldehyde disinfectant comprises formaldehyde and derivative thereof, as Paraformaldehyde 96, melamino-formaldehyde, urea formaldehyde etc., also comprises some saturated dialdehydes, as oxalic dialdehyde, glutaraldehyde etc.;
Alcohol disinfectant comprises ethanol, Virahol, phenylcarbinol, Dichlorbenzyl Alcohol etc., preferably ethanol and Virahol;
Chlorine-containing compound is meant the sterilizing agent person that can produce hypochlorous acid soluble in water, its sterilization mechanism comprises hypochlorous oxygenizement, newborn oxygen effect and chlorization, preferred chlorine-containing disinfectant comprises liquid chlorine and derivative thereof, as chlorinated lime, hypochlorite, dioxide peroxide, chloramines series, two chloramines series, chlorinated isocyanurates class, trichlorine melamine, trichlorine dihydroxy diphenyl ether etc., more preferably trichlorine melamine, trichlorine dihydroxy diphenyl ether, most preferably trichlorine dihydroxy diphenyl ether;
Sterilant also comprises two guanidine classes, as Tubulicid etc.
Sterilant can use separately, and form that also can compound exists, and not only can bring into play synergy, also can reduce the using dosage of each composition.
The various advantages of nontoxic raw materials side effects that the present invention adopts, readily biodegradable can not cause any pollution to environment.
The said washing composition of the present invention is a composition, and its component and content are:
Tensio-active agent 0.01%--15%
Sterilant 0.025%--90%
Solvent 5%--90%
Essence 0%--5%
Water surplus
Below all be weight percentage.
Aerosol LPG (third butane gas) 10%～70% is a benchmark with the weight of feed liquid.
The preferred ratio of each component is:
Tensio-active agent 0.02%--10%
Sterilant 0.025%--80%
Solvent 10%--80%
Essence 0.01%--3%
Water surplus
Below all be weight percentage.
Aerosol LPG (third butane gas) 15%～60% is a benchmark with the weight of feed liquid.
The more preferred ratio of each component is:
Tensio-active agent 0.05--1.0%
Sterilant 0.5%--2%
Solvent 40--70%
Essence 0.1%--3%
Water surplus
Below all be weight percentage.
Aerosol LPG (third butane gas) 20%～50% is a benchmark with the weight of feed liquid.
Said tensio-active agent comprises anion surfactant and nonionogenic tenside;
Said anion surfactant comprises that Sodium dodecylbenzene sulfonate, AES (fatty alcohol-ether sodium sulfate) and other contain SO
3 -, SO
4 -, COO
-The metal-salt of the tensio-active agent of group and with neutral salt such as organic bases such as trolamine, diethanolamine, monoethanolamines;
Said ionic surfactant pack is drawn together fatty alcohol-polyoxyethylene ether series, polyoxyethylene nonylphenol ether series, fatty acid alkyl amide etc.;
Preferred surfactants is that the fatty alcohol-polyoxyethylene ether (9) of Sodium dodecylbenzene sulfonate, poly-9 Sauerstoffatoms (is called for short AEO
9) or the polyoxyethylene nonylphenol ether (10) (being called for short TX-10) of poly-10 Sauerstoffatoms;
Said solvent comprises one or more in ethanol, Virahol, isopropylcarbinol, diethylene glycol dimethyl ether, ethylene glycol ethyl ether, glycol isopropyl ether, butyl glycol ether, diethylene glycol dimethyl ether, Diethylene Glycol butyl ether, ethylene glycol benzyl ether, dipropylene glycol methyl ether, the zellon etc.;
Preferred solvent is one or more in Virahol, Diethylene Glycol butyl ether or the ethylene glycol monomethyl ether;
Said sterilant comprises one or more in aldehydes, alcohols, chlorine-containing compound or the two guanidine classes etc.
Said aldehydes sterilant comprises formaldehyde and derivative thereof, as Paraformaldehyde 96, melamino-formaldehyde, urea formaldehyde etc., also comprises some saturated dialdehydes, as oxalic dialdehyde, glutaraldehyde etc.;
Said pure series bactericidal agent comprises ethanol, Virahol, phenylcarbinol, Dichlorbenzyl Alcohol etc., preferably ethanol and Virahol;
Said chlorine-containing compound is meant that sterilant energy soluble in water produces hypochlorous compound, preferred chlorine-containing disinfectant comprises liquid chlorine and derivative thereof, as chlorinated lime, hypochlorite, dioxide peroxide, chloramines series, two chloramines series, chlorinated isocyanurates class, trichlorine melamine, trichlorine dihydroxy diphenyl ether etc., more preferably trichlorine melamine, trichlorine dihydroxy diphenyl ether, most preferably trichlorine dihydroxy diphenyl ether;
Said two guanidine series bactericidal agents such as Tubulicid etc.
Said washing composition also is performed such preparation:
Tensio-active agent is added in the entry, stir under the room temperature, make it to be dissolved in the water, add one or more solvent again, stirring and dissolving under the room temperature, one or more sterilant is added, add an amount of essence, and mix, charge into aerosol LPG (third butane gas) according to the above ratio, under the normal temperature, its pressure is 0.3MPa～0.4MPa, can obtain said washing composition.
Quantitative sterilization effect test method:
Adopt the carrier spray method to carry out.Test organisms is streptococcus aureus (ATCC 6538), Candida albicans (ATCC 10231) and aspergillus niger.It is respectively the representative bacterial classification of bacterial propagule, yeast and mould.Carrier is selected metallic aluminium for use, makes the circular metal plate that diameter is 2.4cm.Carry out the neutralizing agent qualification test at different sterilization systems in advance, select suitable neutralizing agent.The metal aluminium flake is dyed respectively with the different strain suspension, and it is 10 that bacterium sheet viable bacteria content is reached
5-10
6Cfu/ml after the seasoning, is sprayed to bacterium sheet surface (contrast is phosphate buffer soln) with above-mentioned prescription, acts on to the scheduled time, the bacterium sheet is moved into fill in the test tube of 5ml neutralizing agent, and neutralizing effect 10min washes the bacterium on the bacterium sheet, carries out live bacterial count.Calculate killing rate as follows.
Below will the invention will be further elaborated by embodiment, but embodiment does not limit protection scope of the present invention.Embodiment 1
1 kilogram of polyoxyethylene nonylphenol ether is added in the entry, stir under the room temperature, make it to be dissolved in 38.2 kg of water, add 60 kilograms of Virahols again, stirring and dissolving under the room temperature, add 0.5 kilogram of trichlorine dihydroxy diphenyl ether and 0.3 kilogram of essence then and mix, ratio (weight) inflation with 8 parts of feed liquids and 2 parts of LPG promptly obtains the said washing composition of the present invention.Embodiment 2～6
Adopt the preparation method identical with embodiment 1, the component and the quantity that are added are as shown in table 1:
Table 1
| Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | |
| Polyoxyethylene nonylphenol ether | ??- | ???- | ??0.6 | ??- | ???- |
| Coconut oil diethanol amide | ??- | ???- | ??- | ??0.8 | ???0.4 |
| Sodium dodecylbenzene sulfonate | ??0.8 | ???- | ??0.2 | ??- | ???- |
| Fatty alcohol-ether sodium sulfate | ??- | ???0.5 | ??- | ??- | ???0.3 |
| Virahol | ??- | ???50 | ??60 | ??30 | ???20 |
| Ethylene glycol monomethyl ether | ??- | ???10 | ??6 | ??- | ???5 |
| Ethylene glycol | ??70 | ???- | ??- | ??30 | ???30 |
| The trichlorine dihydroxy diphenyl ether | ??- | ???0.2 | ??- | ??- | ???0.25 |
| Glutaraldehyde | ??2 | ???- | ??1 | ??- | ???- |
| Tubulicid | ??- | ???0.1 | ??- | ??0.5 | ???- |
| Essence | ??0.3 | ???0.3 | ??0.3 | ??0.3 | ???0.3 |
| Water | ??26.9 | ???38.9 | ??31.9 | ??38.4 | ???43.75 |
Washing composition to embodiment 1～6 carries out the clean effect simultaneous test, effect is very good, test method is as follows: each sample and contrast washing composition are sprayed to the air conditioner radiation fin surface respectively or smeared, spray area is 5cm * 5cm, score by the different cleaning degree, judgment criteria is as follows:
+ cleaning performance is poor
++ cleaning performance is general
+++cleaning performance is better
++ ++ cleaning performance is fine
The result is as follows:
The score of embodiment cleaning performance
1??????????????????+++
2??????????????????+++
3??????????????????+++
4??????????????????++++
5??????????????????++
6??????????????????++
The contrast washing composition+
Said contrast washing composition is the agent for cleaning air conditioner that Japanese Kobayashi Pharmaceutical Co., Ltd produces.
Adopt above-mentioned quantitative sterilization effect test method that the washing composition of embodiment 1～6 is carried out bactericidal effect, the results are shown in Table 2:
Table 2
| Action time (min) | Killing rate (%) to test organisms | |||||
| Example 1 | Example 2 | Example 3 | Example 4 | Example 5 | Example 6 | |
| Streptococcus aureus (ATCC 6538) | ||||||
| ????2 | ??100 | ??100 | ??100 | ??100 | ??100 | ??100 |
| ????4 | ??100 | ??100 | ??100 | ??100 | ??100 | ??100 |
| Candida albicans (ATCC 10231) | ||||||
| ????2 | ??99.99 | ??100 | ??98.3 | ??100 | ??100 | ??98.15 |
| ????4 | ??99.99 | ??100 | ??99.01 | ??100 | ??100 | ??98.23 |
| Aspergillus niger | ||||||
| ????2 ????4 | ??98.7 ??99.57 | ??100 ??100 | ??85.47 ??88.6 | ??99.54 ??99.87 | ??90.23 ??91.11 | ??88.33 ??89.12 |
Test temperature is 25 ℃, and the average bacterium of control group is counted streptococcus aureus (ATCC6538) and is 565000cfu/ml, and Candida albicans (ATCC 10231) is 275000cfu/ml, and aspergillus niger is 320000cfu/ml.The result is five test mean values.
The in-site modeling bactericidal effect:
Sampled in the air conditioner radiation fin surface earlier and detect its original natural bacteria sum, sampling area is 5cm * 5cm, smears sampling around circumference with aseptic cotton carrier, will adopt to such an extent that sample is made live bacterial count, with this as positive control.Each prescription is sprayed to fin surface respectively, the spraying number of times is identical with dynamics again.Act on to the scheduled time, sampling once more, the sampling cotton swab moves into the neutralizing agent test tube, in and 10min, detects residual natural bacteria sum, the calculating killing rate.The results are shown in Table 3.
Table 3
| Subjects | Interventions Requested | Time (min) | Average kill ratio (%) |
| Example 1 | The total plate count total number of molds | ????4 ????4 | ????99.99 ????95.56 |
| Example 2 | The total plate count total number of molds | ????4 ????4 | ????100.00 ????100.00 |
| Example 4 | The total plate count total number of molds | ????4 ????4 | ????99.99 ????99.75 |
Test temperature is 25 ℃, and the positive controls total plate count is 7252000cfu/ml, and total number of molds is 8000cfu/ml, and the result is five test mean values.
Said sterilizing detergent for cleaning air conditioner has very significant advantage, at first, cleans thoroughly, after washing is finished, need not the water flushing.Secondly, kill bacterium and mould on filter screen of air conditioner and the radiator element rapidly; The 3rd, cleaning position formation one deck sterilizing membrane, the growth and breeding of bacteriological protection and mould effectively in advance.The said preparation non-toxic, colorless, safety does not have corrosion, is conditioner ideal sterilizing detergent for cleaning.
Claims (17)
1. sterilizing detergent for cleaning air conditioner, it is characterized in that: main component and content comprise:
Tensio-active agent 0.01%～15%
Sterilant 0.025%～90%
Solvent 5%～90%
All be weight percentage more than the water surplus.Aerosol LPG (third butane gas) 10%～70% is a benchmark with the weight of feed liquid; Said tensio-active agent comprises Sodium dodecylbenzene sulfonate, AES (fatty alcohol-ether sodium sulfate), contains SO
3 -, SO
4 -, COO
-The metal-salt of the tensio-active agent of group or with in organic bases neutral salt, fatty alcohol-polyoxyethylene ether series, polyoxyethylene nonylphenol ether series or the fatty acid alkyl amide one or more; Said solvent comprises one or more in ethanol, Virahol, isopropylcarbinol, diethylene glycol dimethyl ether, ethylene glycol ethyl ether, glycol isopropyl ether, butyl glycol ether, diethylene glycol dimethyl ether, Diethylene Glycol butyl ether, ethylene glycol benzyl ether, dipropylene glycol methyl ether, the zellon; Said sterilant comprises one or more in aldehydes, alcohols, chlorine-containing compound or the two guanidine classes.
2. sterilizing detergent for cleaning as claimed in claim 1 is characterized in that: main component and content comprise:
Tensio-active agent 0.02%～10%
Sterilant 0.025%～80%
Solvent 10%～80%
All be weight percentage more than the water surplus.Aerosol LPG (third butane gas) 15%～60% is a benchmark with the weight of feed liquid.
3. sterilizing detergent for cleaning as claimed in claim 2 is characterized in that: main component and content comprise:
Tensio-active agent 0.05--1.0%
Sterilant 0.5--2%
Solvent 40--70%
All be weight percentage more than the water surplus.Aerosol LPG (third butane gas) 20%～50% is a benchmark with the weight of feed liquid.
4. as claim 1, or 2, or 3 described sterilizing detergent for cleaning, it is characterized in that: also comprise an amount of essence in the component.
5. sterilizing detergent for cleaning as claimed in claim 1 is characterized in that: said tensio-active agent is one or more in Sodium dodecylbenzene sulfonate, fatty alcohol-polyoxyethylene ether (9) or the polyoxyethylene nonylphenol ether (10).
6. sterilizing detergent for cleaning as claimed in claim 2 is characterized in that: said tensio-active agent is one or more in Sodium dodecylbenzene sulfonate, fatty alcohol-polyoxyethylene ether (9) or the polyoxyethylene nonylphenol ether (10).
7. sterilizing detergent for cleaning as claimed in claim 3 is characterized in that: said tensio-active agent is one or more in Sodium dodecylbenzene sulfonate, fatty alcohol-polyoxyethylene ether (9) or the polyoxyethylene nonylphenol ether (10).
8. sterilizing detergent for cleaning as claimed in claim 1 is characterized in that: solvent is one or more in Virahol, ethylene glycol monomethyl ether or the Diethylene Glycol butyl ether.
9. sterilizing detergent for cleaning as claimed in claim 2 is characterized in that: solvent is one or more in Virahol, ethylene glycol monomethyl ether or the Diethylene Glycol butyl ether.
10. sterilizing detergent for cleaning as claimed in claim 3 is characterized in that: solvent is one or more in Virahol, ethylene glycol monomethyl ether or the Diethylene Glycol butyl ether.
11. sterilizing detergent for cleaning as claimed in claim 1 is characterized in that:
Said aldehydes sterilant comprises formaldehyde and derivative or saturated aldehyde; Said saturated aldehyde comprises oxalic dialdehyde or glutaraldehyde.
Said pure series bactericidal agent comprises one or more in ethanol, Virahol, phenylcarbinol, the Dichlorbenzyl Alcohol;
Said chlorine-containing compound comprises one or more in chlorinated lime, hypochlorite, dioxide peroxide, chloramines series, two chloramines series, chlorinated isocyanurates class, trichlorine melamine, trichlorine dihydroxy diphenyl ether, trichlorine melamine, trichlorine dihydroxy diphenyl ether or the trichlorine dihydroxy diphenyl ether;
Said two guanidine series bactericidal agents are Tubulicid.
12. sterilizing detergent for cleaning as claimed in claim 2 is characterized in that:
Said sterilant comprises one or more in formaldehyde and derivative or saturated aldehyde, ethanol, Virahol, phenylcarbinol, Dichlorbenzyl Alcohol, chlorinated lime, hypochlorite, dioxide peroxide, chloramines series, two chloramines series, chlorinated isocyanurates class, trichlorine melamine, trichlorine dihydroxy diphenyl ether, trichlorine melamine, trichlorine dihydroxy diphenyl ether, trichlorine dihydroxy diphenyl ether or the Tubulicid, and said saturated aldehyde comprises oxalic dialdehyde or glutaraldehyde.
13. sterilizing detergent for cleaning as claimed in claim 3 is characterized in that:
Said sterilant comprises one or more in formaldehyde and derivative or saturated aldehyde, ethanol, Virahol, phenylcarbinol, Dichlorbenzyl Alcohol, chlorinated lime, hypochlorite, dioxide peroxide, chloramines series, two chloramines series, chlorinated isocyanurates class, trichlorine melamine, trichlorine dihydroxy diphenyl ether, trichlorine melamine, trichlorine dihydroxy diphenyl ether, trichlorine dihydroxy diphenyl ether or the Tubulicid, and said saturated aldehyde comprises oxalic dialdehyde or glutaraldehyde.
14. sterilizing detergent for cleaning as claimed in claim 11 is characterized in that: said sterilant is ethanol, Virahol or trichlorine dihydroxy diphenyl ether and composition thereof.
15. sterilizing detergent for cleaning as claimed in claim 12 is characterized in that: said sterilant is ethanol, Virahol or trichlorine dihydroxy diphenyl ether and composition thereof.
16. sterilizing detergent for cleaning as claimed in claim 13 is characterized in that: said sterilant is ethanol, Virahol or trichlorine dihydroxy diphenyl ether and composition thereof.
17. sterilizing detergent for cleaning as claimed in claim 1 is characterized in that: said organic bases is a kind of in trolamine, diethanolamine or the monoethanolamine.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN99116918A CN1077914C (en) | 1999-09-27 | 1999-09-27 | Sterilizing detergent for cleaning air conditioner |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN99116918A CN1077914C (en) | 1999-09-27 | 1999-09-27 | Sterilizing detergent for cleaning air conditioner |
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| CN1248616A true CN1248616A (en) | 2000-03-29 |
| CN1077914C CN1077914C (en) | 2002-01-16 |
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Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1170036A (en) * | 1996-06-28 | 1998-01-14 | 徐彩荣 | Waterless detergent for dry cleaning |
| AU4981097A (en) * | 1996-10-11 | 1998-05-11 | Colgate-Palmolive Company, The | All purpose liquid cleaning compositions |
-
1999
- 1999-09-27 CN CN99116918A patent/CN1077914C/en not_active Expired - Lifetime
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