CN103013687A - Foam cleaning disinfectant and preparation method thereof - Google Patents
Foam cleaning disinfectant and preparation method thereof Download PDFInfo
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- CN103013687A CN103013687A CN2012105726561A CN201210572656A CN103013687A CN 103013687 A CN103013687 A CN 103013687A CN 2012105726561 A CN2012105726561 A CN 2012105726561A CN 201210572656 A CN201210572656 A CN 201210572656A CN 103013687 A CN103013687 A CN 103013687A
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Abstract
The invention relates to foam cleaning disinfectant and a preparation method thereof, and belongs to the technical field of daily-use chemicals. The foam cleaning disinfectant comprises a propane and butane gas and a base material the mass ratio of which is (1 to 5): 10, wherein the base material comprises 0.1 to 10% of surface active agent, 0.1 to 1% of guanidine compound, 0.1 to 1% of quarternary ammonium compound, 2 to 30% of solvent, 0.01 to 2% of chelating agent, 0.01 to 1% of corrosion inhibitor, 0 to 0.2% of edible essence, and the balance of water. The preparation method comprises the following steps in sequence: adding the chelating agent to water with the temperature of 30 to 70 DEG C to dissolve; adding the surface active agent and the solvent; dispersing until dissolving; adding the guanidine compound, quarternary ammonium compound, corrosion inhibitor and edible essence; dispersing until dissolving; precipitating to obtain the base material; and then mixing the base material with the propane and butane gas to obtain the foam cleaning disinfectant. The disinfectant integrates the functions of cleaning, disinfecting, inhibiting bacteria, eradicating odor and preventing rust, is green and environmentally friendly, quick and efficient in acting, mild and stable in performance, safe and convenient in use, and specially applicable to cooling fins of an air conditioner.
Description
Technical field
The present invention relates to a kind of foam cleaning and sterilizing agent and preparation method thereof, belong to the household chemicals technical field.
Background technology
Along with the raising of people's living standard, the application of air-conditioning is increasingly extensive, when bringing a home from home to people, the health of human body has been produced huge negative impact.Air-conditioning in use for some time, gather a large amount of dusts and dirt on its filtering net and the radiator element, add that air conditioner condensate water is full of therebetween, grown thus a large amount of bacteriums, mould, harmful microorganism and the viruses such as acarid, these harmful microorganisms and virus along with cold and hot air in indoor circulation, cause the pollution of room air, strange taste appears, the long-term people that under this environment, live, produce easily dizzy, weak, feel sick, " air conditioning disease " symptoms such as vomiting and immunity degradation, increase the chance that various diseases infects, seriously influenced consumers in general's physical and mental health.In addition, the dirt that fin surface is adhered to forms larger heat transmission resistance, causes refrigeration to descend, increase the problems such as energy consumption, air output decline and air-conditioning shortening in work-ing life.
At present, the sterilizing agent that is used for the heat sink of air conditioner cleaning is of a great variety, but mostly be the spraying cleaning way, and existing sterilizing agent is shorter in the surperficial residence time of heat sink of air conditioner, be generally several seconds, therefore can't play good cleaning and sterilization effect, need repeatedly to use just can reach sterilization effect, but repeatedly use the large quantity of fluid that produces to drop onto easily the air-condition circuits part, cause the short circuit of air-conditioning.
The multi-functional air conditioner cleaning and sterilizing product that therefore, provide protection is arranged again in the urgent need to a kind of existing cleaning action.
Summary of the invention
The problems such as, clean-out system consumption poor at present commercially available air conditioner cleaning agent cleaning performance is many, one of purpose of the present invention provides the agent of a kind of foam cleaning and sterilizing, described sterilizing agent adopts the foam cleaning way, integrates cleaning, sterilizes, eliminates the unusual smell and antirust, has several functions; Described sterilizing agent mainly is applicable to cleaning and the sterilization of air-conditioning, is particularly useful for cleaning and the sterilization of heat sink of air conditioner.
Two of purpose of the present invention provides the preparation method of a kind of foam cleaning and sterilizing agent.
The objective of the invention is to be achieved through the following technical solutions.
The agent of a kind of foam cleaning and sterilizing, described sterilizing agent is comprised of the third butane gas (LPG) and base-material, wherein LPG: the mass ratio of base-material is 1～5:10; Take the oeverall quality of described base-material as 100%, wherein each component and mass percent thereof are as follows:
Tensio-active agent 0.1%～10%,
Guanidine compound 0.1%～1%,
Quaternary ammonium compound 0.1%～1%,
Solvent 2%～30%,
Sequestrant 0.01%～2%,
Inhibiter 0.01%～1%,
Food flavour 0%～0.2%,
Surplus is water;
Wherein, described tensio-active agent is nonionogenic tenside, is preferably one or more the mixture in APG (APG), N-methyl glucamine (AGA) or the aliphatic acid polyethenoxy methyl ether (FMEE);
Guanidine compound is preferably one or more the mixture in polyhexamethylene guanidine, poly hexamethylene biguanide, poly-hexamethylene guanidine, poly-[2-(2-oxyethyl group)-oxyethyl group second fat] guanidine, Guanidinium carbonate or the phosphoguanidine;
Quaternary ammonium compound is preferably one or more the mixture in benzalkonium chloride, Morpan BB, n-alkyl dimethyl benzyl ammonium chloride, dimethyl double hexadecyl ammonium chloride, the two n-alkyl dimethyl benzyl ammonium chloride;
Solvent is aliphatic alcohols, is preferably one or more the mixture in ethanol, Virahol, isopropylcarbinol, hexylene glycol, propylene glycol or the glycerol;
Sequestrant is one or more the mixture in disodium ethylene diamine tetraacetate, tetrasodium ethylenediamine tetraacetate, amino trimethylene methyl acid phosphate five sodium or the ethylenediamine tetraacetic acid (EDTA);
Inhibiter is water glass, three Unigly GO 102Ss, N, the mixture of one or more in N-dimethylethanolamine, poly-phosphate, Citrate trianion or the benzotriazole;
Water is the water of purity 〉=deionized water purity.
The preparation method of a kind of foam cleaning and sterilizing of the present invention agent, described method steps is as follows:
(1) water is joined in the reaction vessel, in reaction vessel, add sequestrant while stirring, be warming up to simultaneously 30 ℃～70 ℃, until sequestrant dissolves fully;
(2) then add while stirring tensio-active agent and solvent in the reaction vessel, be dispersed to tensio-active agent and solvent dissolves fully; Preferred 10min～the 30min that disperses;
(3) guanidine compound, quaternary ammonium compound, inhibiter and food flavour are joined in the reaction vessel again, be dispersed to guanidine compound, quaternary ammonium compound, inhibiter and food flavour and dissolve fully, base-material is made in sedimentation; Preferred 10min～the 30min that disperses;
(4) base-material and LPG are mixed with obtain the agent of a kind of foam cleaning and sterilizing.
Base-material and LPG can be filled to a kind of foam cleaning and sterilizing agent for preparing can in the aerosol sealed can according to the conventional packaging process of foam cleaning and sterilizing agent.Specifically can adopt following method:
(1) base-material is packed in the aerosol sealed can, filling ratio is 0～85% of aerosol sealed can volume;
(2) with sealing machine valve and aerosol sealed can are sealed;
(3) fill LPG with inflator to the aerosol sealed can, load onto supporting head, make the foam cleaning and sterilizing agent of can.
Beneficial effect
1. the invention provides the agent of a kind of foam cleaning and sterilizing, the effect of described sterilizing agent is quick, efficient: use to get final product on a small quantity interior dust and the greasy dirt of removing on air-conditioning filter net and the radiator element of short period of time, kill vegetative forms of bacteria and mould are eliminated peculiar smell simultaneously;
2. the invention provides the agent of a kind of foam cleaning and sterilizing, the performance of described sterilizing agent is gentle: have no irritating odor, to fabric and metal non-corrosiveness, can form layer protecting film in clean surface especially, can not only prevent the corrosion of filtering net and radiator element, and can effectively stop growing of bacterium, mould, reach long-time antibacterial effect;
3. the invention provides the agent of a kind of foam cleaning and sterilizing, described sterilizing agent environmental protection: the composition in the prescription is selected the environmental protection starting material, select that the low toxicity high effect disinfectants of present international popular---guanidine compound and quaternary ammonium compound carry out composite, the preferred high N-methyl glucamine of the feature of environmental protection, APG, the aliphatic acid polyethenoxy methyl ether is tensio-active agent, add inhibiter and sequestrant, do not contain and consume the ozone material, phosphoric acid salt, branched dodecylbenzene sulfonic acid sodium, the materials such as alkylphenol polyoxyethylene, fully biodegradable, prescription does not produce toxic byproduct in process of production, do not pollute the environment, meet among the HJ458-2009 " environmental labelling product technical requirements household detergent " the every specified requirement about fabric detergent and hard surface cleaner;
4. the invention provides the agent of a kind of foam cleaning and sterilizing, described sterilizing agent is easy to use, and is safe and reliable: fill a prescription nontoxic, residual less, to mucocutaneous non-stimulated and to human body toxicological harmless and toxic side effect;
5. the invention provides the agent of a kind of foam cleaning and sterilizing, described sterilizing agent stable and reliable for performance: not moldy metamorphism, precipitated and separated not, be convenient to standing storage.
Embodiment
In order to prove absolutely characteristic of the present invention and implement mode of the present invention that the below provides embodiment.
Embodiment 1
(1) deionized water is added in the reactor, under 800 rev/mins rotating speeds stir, adds disodium ethylene diamine tetraacetate, the temperature with reactor is controlled to be 40 ℃ simultaneously, until fully dissolving;
(2) under 1000 rev/mins rotating speed stirring, APG1214 and Virahol are joined in the reactor, disperse 15min to fully dissolving;
(3) drop into poly-hexamethylene guanidine, dodecyl benzyl dimethyl ammonium chloride, water glass and lemon flavour in reactor, disperse 30min to fully dissolving, standing sedimentation 2h makes base-material;
(4) get the 400g base-material and pack in the 600ml aerosol sealed can, with sealing machine valve and aerosol sealed can are sealed, be filled with the LPG of 80g with inflator to the aerosol sealed can, load onto supporting head, obtain the foam cleaning and sterilizing agent of can.
Take the oeverall quality of described base-material as 100%, wherein each component and mass percent thereof are as shown in table 1:
Table 1
| Component | Quality (kg) | Mass percent (%) |
| APG1214 | 5 | 5% |
| Poly-hexamethylene guanidine | 1 | 1% |
| Dodecyl benzyl dimethyl ammonium chloride | 0.5 | 0.5% |
| Virahol | 5 | 5% |
| Disodium ethylene diamine tetraacetate | 0.1 | 0.1% |
| Water glass | 0.5 | 0.5% |
| Lemon flavour | 0.2 | 0.2% |
| Deionized water | 87.7 | 87.7% |
| Amount to | 100 | 100% |
Embodiment 2
(1) deionized water is added in the reactor, under 1000 rev/mins rotating speeds stir, adds disodium ethylene diamine tetraacetate, the temperature with reactor is controlled to be 60 ℃ simultaneously, until fully dissolving;
(2) under 1200 rev/mins rotating speed stirring, AGA and ethanol are joined in the reactor, disperse 20min to fully dissolving;
(3) drop into Polyhaxemethylenguanidine Hydrochloride, Morpan BB and Trisodium Citrate, disperse 30min to fully dissolving, standing sedimentation 1.5h makes base-material;
(4) get the 300g base-material and pack in the 500ml aerosol sealed can, with sealing machine valve and aerosol sealed can are sealed, be filled with the LPG of 30g with inflator to the aerosol sealed can, load onto supporting head, obtain the foam cleaning and sterilizing agent of can.
Take the oeverall quality of described base-material as 100%, wherein each component and mass percent thereof are as shown in table 2:
Table 2
| Component | Quality (kg) | Mass percent (%) |
| AGA | 8 | 8% |
| Polyhaxemethylenguanidine Hydrochloride | 1 | 1% |
| Morpan BB | 0.5 | 0.5% |
| Ethanol | 5 | 5% |
| Disodium ethylene diamine tetraacetate | 0.5 | 0.5% |
| Trisodium Citrate | 1 | 1% |
| Deionized water | 84 | 84% |
| Amount to | 100 | 100% |
Embodiment 3
(1) deionized water is added in the reactor, under 800 rev/mins rotating speeds stir, adds ethylenediamine tetraacetic acid (EDTA), the temperature with reactor is controlled to be 30 ℃ simultaneously, until fully dissolving;
(2) under 1500 rev/mins rotating speed stirring, APG1214 and ethanol are joined in the reactor, be dispersed to fully dissolving;
(3) drop into Guanidinium carbonate, poly hexamethylene biguanide, two decyl dimethyl benzyl ammonium chloride and sodium polyphosphate, disperse 30min to fully dissolving, standing sedimentation is made base-material;
(4) get the 450g base-material and pack in the 700ml aerosol sealed can, with sealing machine valve and aerosol sealed can are sealed, be filled with the LPG of 45g with inflator to the aerosol sealed can, load onto supporting head, obtain the foam cleaning and sterilizing agent of can.
Take the oeverall quality of described base-material as 100%, wherein each component and mass percent thereof are as shown in table 3:
Table 3
| Component | Quality (kg) | Mass percent (%) |
| APG1214 | 0.1 | 0.1% |
| Guanidinium carbonate | 0.05 | 0.05% |
| Poly hexamethylene biguanide | 0.05 | 0.05% |
| Two decyl dimethyl benzyl ammonium chlorides | 0.1 | 0.1% |
| Ethanol | 2 | 2% |
| Ethylenediamine tetraacetic acid (EDTA) | 0.01 | 0.01% |
| Sodium polyphosphate | 0.01 | 0.01% |
| Deionized water | 97.68 | 97.68% |
| Amount to | 100 | 100% |
Embodiment 4
(1) deionized water is added in the reactor, under 1000 rev/mins rotating speeds stir, adds amino trimethylene methyl acid phosphate five sodium, the temperature with reactor is controlled to be 50 ℃ simultaneously, until fully dissolving;
(2) under 1500 rev/mins rotating speed stirring, FMEE and propylene glycol are joined in the reactor, disperse 30min to fully dissolving;
(3) drop into poly-[2-(2-oxyethyl group)-oxyethyl group second fat] guanidine, dimethyl double hexadecyl ammonium chloride, benzotriazole and green tea essence, disperse 30min to fully dissolving, standing sedimentation 2h makes base-material;
(4) get the 450g base-material and pack in the 700ml aerosol sealed can, with sealing machine valve and aerosol sealed can are sealed, be filled with the LPG of 60g with inflator to the aerosol sealed can, load onto supporting head, obtain the foam cleaning and sterilizing agent of can.
Take the oeverall quality of described base-material as 100%, wherein each component and mass percent thereof are as shown in table 4:
Table 4
| Component | Quality (kg) | Mass percent (%) |
| FMEE | 10 | 10% |
| Poly-[the 2-(2-oxyethyl group)-oxyethyl group second fat] guanidine | 0.2 | 0.2% |
| Dimethyl double hexadecyl ammonium chloride | 1 | 1% |
| Propylene glycol | 15 | 15% |
| Amino trimethylene methyl acid phosphate five sodium | 1 | 1% |
| Benzotriazole | 1 | 1% |
| Green tea essence | 0.2 | 0.2% |
| Deionized water | 71.6 | 71.6% |
| Amount to | 100 | 100% |
Embodiment 5
The foam cleaning and sterilizing agent that embodiment 1～4 is prepared detects according to concerned countries standard, industry standard and company standard, and the correlation detection result is as shown in table 5:
Table 5
Embodiment 6
Quantitative sterilization is carried out in the foam cleaning and sterilizing agent that embodiment 1～4 is prepared, the fungistatic effect test is as follows:
Test organisms is chosen respectively streptococcus aureus (ATCC6538), Candida albicans (ATCC10231) and black-koji mould (ATCC16404) as the representative bacterial classification of bacterial propagule, fungi and mould;
(1) quantitative disinfecting test
Adopt the carrier spray method to carry out quantitative disinfecting test, according to " disinfection technology standard " aluminium being made diameter is that the circular aluminium flake of 24mm is as carrier; Aluminium flake dyed respectively with different tests bacterium bacteria suspension obtain the bacterium sheet, the viable bacteria content on the bacterium sheet is 10
5～10
7Cfu/ml, seasoning.
Test group: the foam cleaning and sterilizing agent that embodiment 1～4 is prepared is sprayed to respectively dry bacterium sheet surface, act on to the time described in the table 6, the bacterium sheet is moved into fill in the test tube of 5ml neutralizing agent, in and 10min, wash the bacterial classification on the bacterium sheet, carry out live bacterial count.
Control group: deionized water is sprayed to dry bacterium sheet surface, acts on to the time described in the table 6, the bacterium sheet is moved into fill in the test tube of 5ml neutralizing agent, in and 10min, wash the bacterial classification on the bacterium sheet, carry out live bacterial count.
Described neutralizing agent is that the Sulfothiorine of 10g/L, the Yelkin TTS of 10g/L and the tween 80 mixing of 20mg/L make.
Calculate as follows killing rate:
(2) fungistatic effect test
Test group: get respectively aseptic and dry filter paper, then the every foam cleaning and sterilizing agent 20 μ l that drip embodiment 1～4 lie against filter paper in the aseptic plate of cleaning, and uncapping places 37 ℃ of incubators to dry, and obtains the fungistat print.
Control group: get respectively aseptic and dry filter paper, every drips sterile distilled water 20 μ l, obtains the negative control print after the drying, for subsequent use.
Dipping concentration with the sterile cotton swab is 5 * 10
5Cfu/ml～5 * 10
6Cfu/ml test organisms suspension is evenly smeared 3 times at the nutrient agar planar surface; Wherein, whenever smear 1 time, 60 ° of dull and stereotyped rotations are smeared a week with cotton swab around plate edge at last; Build plate, put drying at room temperature 5min, obtain the microbiological contamination flat board.
Print is placed with: each test is placed with 1 microbiological contamination flat board, and each microbiological contamination flat board is placed with 4 fungistat prints, 1 negative control print, totally 5; Getting described print with aseptic nipper is placed with in the microbiological contamination planar surface; Between each described print center at a distance of more than the 25mm, with the periphery of microbiological contamination flat board at a distance of more than the 15mm; After being placed with, with the described print of the light pressure of aseptic nipper, make it be close to the microbiological contamination planar surface; Build plate, put 37 ℃ of incubators, cultivate 16h～18h observations.Diameter (comprising paster) and record with the antibacterial ring of vernier caliper measurement.
Estimate regulation:
Inhibition zone diameter has been judged to bacteriostatic action greater than 7mm person.
Inhibition zone diameter is less than or equal to 7mm person, is judged to without bacteriostatic action.
Test-results is as shown in table 6:
Table 6
Embodiment 7
It is as follows that the foam cleaning and sterilizing agent that embodiment 1～4 is prepared is carried out stability test as sample:
According to " disinfection technology standard ", foam cleaning and sterilizing agent sealing is positioned in 54 ℃ of constant temperature ovens 14 days, measure and place front and back sterilization component---the change in concentration of quaternary ammonium compound and guanidine compound, if change in concentration illustrates that less than 10% the preservation period of described foam cleaning and sterilizing agent was greater than 1 year before and after placing.
The mensuration of quaternary ammonium compound concentration: accurately take by weighing the 3.7g sample, be accurate to 0.001g, place the 250ml iodine flask that is added with in advance 50.0ml distilled water, the 0.05% tetrabromophenol sulfonphthalein reagent, 10.0ml chloroform and the 1mol/L sodium hydroxide 1.0ml that add again 0.5ml, in the stable stirring of magnetic stirring apparatus, being titrated to the sodium tetraphenylborate reference liquid that chloroform becomes when colourless by blueness is terminal point, the total amount of the sodium tetraphenylborate reference liquid that record spends.
In the formula:
N---the concentration of sodium tetraphenylborate standardized solution, mol/L;
V---the consumption of sample titration sodium tetraphenylborate standardized solution, ml;
W---take by weighing the quality of sample, g.
The mensuration of guanidine compound concentration: the sample that pipettes 20ml with transfer pipet is poured in the volumetric flask of 25ml, adds 1ml sodium acetate soln and 2.5ml eosin W or W S indicator, with distilled water diluting to scale and mix; Place 5min, obtain solution to be measured, measure the absorbancy of solution to be measured with ultraviolet spectrophotometer at wavelength 545nm place.
In the formula:
The light absorption ratio of D---measurement;
The volume of Y---sample, ml;
ρ---liquid density to be measured, ρ=1.0g/cm
3
Test-results is as shown in table 7:
Table 7
Through overtesting as can be known, the rate of loss of quaternary ammonium compound and guanidine compound illustrates that all less than 10% the preservation period of described foam cleaning and sterilizing agent was greater than 1 year in the foam cleaning and sterilizing agent that embodiment 1～4 prepares.
The present invention is further elaborated by above embodiment, but does not limit the scope of the invention.
Claims (10)
1. foam cleaning and sterilizing agent is characterized in that: described sterilizing agent is comprised of the third butane gas and base-material, wherein the third butane gas: the mass ratio of base-material is 1～5:10; Take the oeverall quality of described base-material as 100%, wherein each component and mass percent thereof are as follows:
Tensio-active agent 0.1%～10%,
Guanidine compound 0.1%～1%,
Quaternary ammonium compound 0.1%～1%,
Solvent 2%～30%,
Sequestrant 0.01%～2%,
Inhibiter 0.01%～1%,
Food flavour 0%～0.2%,
Surplus is water;
Wherein, described tensio-active agent is nonionogenic tenside;
Solvent is aliphatic alcohols;
Sequestrant is one or more in disodium ethylene diamine tetraacetate, tetrasodium ethylenediamine tetraacetate, amino trimethylene methyl acid phosphate five sodium or the ethylenediamine tetraacetic acid (EDTA);
Inhibiter is water glass, three Unigly GO 102Ss, N, one or more in N-dimethylethanolamine, poly-phosphate, Citrate trianion or the benzotriazole;
Water is the water of purity 〉=deionized water purity.
2. a kind of foam cleaning and sterilizing according to claim 1 agent is characterized in that: tensio-active agent is one or more in APG, N-methyl glucamine or the aliphatic acid polyethenoxy methyl ether.
3. a kind of foam cleaning and sterilizing according to claim 1 agent is characterized in that: guanidine compound is one or more in polyhexamethylene guanidine, poly hexamethylene biguanide, poly-hexamethylene guanidine, poly-[2-(2-oxyethyl group)-oxyethyl group second fat] guanidine, Guanidinium carbonate or the phosphoguanidine.
4. a kind of foam cleaning and sterilizing according to claim 1 agent is characterized in that: quaternary ammonium compound is one or more in benzalkonium chloride, Morpan BB, n-alkyl dimethyl benzyl ammonium chloride, dimethyl double hexadecyl ammonium chloride, the two n-alkyl dimethyl benzyl ammonium chloride.
5. a kind of foam cleaning and sterilizing according to claim 1 agent is characterized in that: solvent is one or more in ethanol, Virahol, isopropylcarbinol, hexylene glycol, propylene glycol or the glycerol.
6. preparation method such as each described foam cleaning and sterilizing agent of claim 1～5, it is characterized in that: described method steps is as follows:
(1) water is joined in the reaction vessel, add while stirring sequestrant, be warming up to simultaneously 30 ℃～70 ℃, to fully dissolving;
(2) then add while stirring tensio-active agent and solvent, be dispersed to fully dissolving;
(3) add guanidine compound, quaternary ammonium compound, inhibiter and food flavour again, be dispersed to fully dissolving, base-material is made in sedimentation;
(4) base-material and the third butane gas are mixed with obtain the agent of a kind of foam cleaning and sterilizing.
7. the preparation method of a kind of foam cleaning and sterilizing according to claim 6 agent is characterized in that: disperse 10min～30min in the step (2).
8. the preparation method of a kind of foam cleaning and sterilizing according to claim 6 agent is characterized in that: disperse 10min～30min in the step (3).
9. the preparation method of a kind of foam cleaning and sterilizing according to claim 6 agent is characterized in that: base-material and the third butane gas are filled to a kind of foam cleaning and sterilizing agent for preparing can in the aerosol sealed can.
10. the preparation method of a kind of foam cleaning and sterilizing according to claim 9 agent, it is characterized in that: method is as follows:
(1) base-material is packed in the aerosol sealed can, filling ratio is 0～85% of aerosol sealed can volume;
(2) with sealing machine valve and aerosol sealed can are sealed;
(3) fill the third butane gas with inflator to the aerosol sealed can, load onto supporting head, make a kind of foam cleaning and sterilizing agent of can.
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| CN111718804A (en) * | 2020-07-24 | 2020-09-29 | 上海绿瑞生物科技有限公司 | Foam type cleaning agent composition and application thereof |
| CN114181781A (en) * | 2021-12-24 | 2022-03-15 | 山东富斯特油脂科技有限公司 | Washing bactericide, preparation method and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1248616A (en) * | 1999-09-27 | 2000-03-29 | 上海家化联合股份有限公司 | Sterilizing detergent for cleaning air conditioner |
| CN101086065A (en) * | 2007-06-13 | 2007-12-12 | 长沙市永峰水质处理服务有限公司 | Descaling agent for cleaning central air conditioner main machine |
-
2012
- 2012-12-24 CN CN2012105726561A patent/CN103013687A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1248616A (en) * | 1999-09-27 | 2000-03-29 | 上海家化联合股份有限公司 | Sterilizing detergent for cleaning air conditioner |
| CN101086065A (en) * | 2007-06-13 | 2007-12-12 | 长沙市永峰水质处理服务有限公司 | Descaling agent for cleaning central air conditioner main machine |
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