CN109370800A - A kind of automotive air-conditioning system sterilizing detergent for cleaning and preparation method thereof - Google Patents

A kind of automotive air-conditioning system sterilizing detergent for cleaning and preparation method thereof Download PDF

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Publication number
CN109370800A
CN109370800A CN201811406335.8A CN201811406335A CN109370800A CN 109370800 A CN109370800 A CN 109370800A CN 201811406335 A CN201811406335 A CN 201811406335A CN 109370800 A CN109370800 A CN 109370800A
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China
Prior art keywords
conditioning system
cleaning
automotive air
sterilizing detergent
parts
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CN201811406335.8A
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Chinese (zh)
Inventor
林壮
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Kaiping Bao Jie Jie Automotive Supplies Technology Co Ltd
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Kaiping Bao Jie Jie Automotive Supplies Technology Co Ltd
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Priority to CN201811406335.8A priority Critical patent/CN109370800A/en
Publication of CN109370800A publication Critical patent/CN109370800A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/046Salts
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2006Monohydric alcohols
    • C11D3/201Monohydric alcohols linear
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2068Ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50Perfumes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008Polymeric surface-active agents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Air-Conditioning For Vehicles (AREA)

Abstract

The invention discloses a kind of automotive air-conditioning system sterilizing detergent for cleaning and preparation method thereof, according to the mass fraction, including following components: 1-10 parts of ethylene glycol monobutyl ether, 0.5-5 parts of neopelex, 0.3-5 parts of isomerous tridecanol polyoxyethylene ether, 0-5 parts of essence, 0-5 parts of defoaming agent, 0.5-5 parts of fatty alcohol polyoxyethylene ether, 0.01-5 parts of silver ion disinfectant, 50-100 parts of water.Sterilizing detergent for cleaning of the present invention includes the surfactant factor of novel easily biological-degradable, with efficient emulsification, infiltration and release effect, it can be rapidly by the dust on air-conditioner evaporation tank surface, greasy dirt, worm stain and other dirt rapid cleanings, and give out pleasant fragrance, enable air-conditioning smell pure and fresh, and it can effectively restore the original performance of radiator, improve air-conditioning system refrigeration effect, reduce energy dissipation.The neutral environmental protection of this product, does not damage fin and tubing, does not influence radiator service life.

Description

A kind of automotive air-conditioning system sterilizing detergent for cleaning and preparation method thereof
Technical field
The invention belongs to sterilize cleaning technique field, and in particular to a kind of automotive air-conditioning system sterilizing detergent for cleaning and its preparation Method.
Background technique
With the development and progress of science and technology, people's lives level is gradually increased.Automobile has also spread to huge numbers of families, vapour The use scope and frequency of vehicle are also expanding always.And air conditioning for automobiles is as an important component for improving automobile riding comfort Approved by auto manufacturing and consumer.But after air conditioning for automobiles through a long time use, internal and air louver all can Assemble a large amount of dusts and bacterium, or even peculiar smell can be generated, it is therefore desirable to which dedicated cleaning agent or cleaning combination carry out it clearly It is clean.When unused air-conditioning is just opened for a long time, car can generate peculiar smell, or even can feel to feel dizzy, or even nausea, vomit It spits, this is because automotive air-conditioning system is in use for some time, the bacterium and mould that can be bred, in the car with hot and cold air Circulation, had both reduced the working efficiency of air-conditioning system, increased energy consumption, more polluted in-vehicle air, it spreads the disease, gives car owner's health It causes to seriously threaten.
Automotive air-conditioning system this " health threat ", has caused the great attention of automobile production and accessory manufacturer, because How this, effectively clean and sterilize in time to air-conditioning system, have become an important project, and at present mostly Several air conditioning for automobiles cleaning combination preparation processes are complicated, at high cost, soil release performance is poor and has musty after, and bactericidal effect is not shown It writes, greatly reduces the routine use comfort level and wholesomeness of automobile.
Summary of the invention
In view of the problems of the existing technology, the present invention provides a kind of automotive air-conditioning system sterilizing detergent for cleaning and its preparations Method.
The invention adopts the following technical scheme:
A kind of automotive air-conditioning system sterilizing detergent for cleaning, according to the mass fraction, including following components:
Further, the automotive air-conditioning system sterilizing detergent for cleaning, according to the mass fraction, including following components:
Further, the automotive air-conditioning system sterilizing detergent for cleaning, according to the mass fraction, including following components:
Further, the sterilizing detergent for cleaning can not include polyacrylate, preservative.
Further, the water is filter sterilization water.
Further, the fatty alcohol polyoxyethylene ether model AEO-9.
Further, the silver ion disinfectant, according to the mass fraction, including following components:
Further, the silver ion disinfectant, according to the mass fraction, including following components:
Further, the content of free silver ions is 500~2000ppm in the silver ion disinfectant.
Further, the content of free silver ions is 800~1500ppm in the silver ion disinfectant.
Further, the density of the silver ion disinfectant is 0.95~1.05g/mL, such as 1.0g/mL.
Further, the pH value of the silver ion disinfectant is 9~12.
A kind of preparation method of automotive air-conditioning system sterilizing detergent for cleaning, comprising the following steps: according to the ratio by water, isomery 13 Alcohol polyoxyethylene ether, neopelex, ethylene glycol monobutyl ether, defoaming agent, fatty alcohol polyoxyethylene ether, silver ion for sterilization Agent, essence stir evenly to get the automotive air-conditioning system sterilizing detergent for cleaning.
Further, water, isomerous tridecanol polyoxyethylene ether, neopelex are stirred evenly according to the ratio, pH Value is 7~10, and ethylene glycol monobutyl ether, defoaming agent, fatty alcohol polyoxyethylene ether, silver ion disinfectant, essence, stirring is then added Uniformly (such as stirring 15-30min under 80rpm revolving speed) is to get the automotive air-conditioning system sterilizing detergent for cleaning.
Automotive air-conditioning system sterilizing detergent for cleaning of the invention is added in water (2wt%), measures and Escherichia coli is killed Bacterium rate is 99.99%, and the sterilizing rate to staphylococcus aureus is 99.99%, and the sterilizing rate to Candida albicans is 99.99%.
Sterilizing detergent for cleaning of the present invention includes the surfactant factor of novel easily biological-degradable, has efficiently emulsification, seeps Saturating and release effect, can be rapidly by the dust on air-conditioner evaporation tank surface, greasy dirt, worm stain and other dirt rapid cleanings, and distribute Pleasant fragrance out enables air-conditioning smell pure and fresh, and can effectively restore the original performance of radiator, improves air-conditioning system refrigeration effect Fruit reduces energy dissipation.This product weak base environmental protection, does not damage fin and tubing, does not influence radiator service life.
Sterilizing detergent for cleaning of the present invention is colourless, clear liquid, is mildly had no irritating odor, and standard density (20 DEG C, g/ cm3): 0.95~1.05, such as 1.008;PH value is 6.5~11.8, preferably 7.5~11.0, such as 8.20, optional 8.5~ 10.5, such as 9.43.Test the influence to LY12 duralumin appearance using QB/T 2117-95 method: surface is without slight uniformly discoloration Or loss of gloss.Detergency, test result 99% are tested using QB/T 4348-2012 method.
Beneficial effects of the present invention:
(1) automotive air-conditioning system sterilizing detergent for cleaning of the invention can remove various dusts on air-conditioner evaporation tank, greasy dirt, Worm stain and other dirts improve refrigeration effect;
(2) preparation method of automotive air-conditioning system sterilizing detergent for cleaning of the invention is easy, at low cost, is suitble to large-scale industry Production application;
(3) automotive air-conditioning system sterilizing detergent for cleaning of the invention can remove mould in air-conditioner evaporation tank and pipeline, disease Bacterium etc. improves in-vehicle air environment, keeps motor space pure and fresh pleasant;
(4) automotive air-conditioning system sterilizing detergent for cleaning of the invention can improve smelly interior cigarette, fume and food distribute it is each Kind peculiar smell, improves riding space environment;
(5) automotive air-conditioning system sterilizing detergent for cleaning of the invention can restore the original performance of radiator, and extending evaporation tank makes Use the service life.
Specific embodiment
In order to preferably explain the present invention, it is described further now in conjunction with following specific embodiments, but the present invention is unlimited In specific embodiment.
Automotive air-conditioning system sterilizing detergent for cleaning is prepared according to table 1.
Table 1: the component (mass parts) of each embodiment.
The silver ion disinfectant of embodiment 1-3 includes silver-colored 0.1 part of ammonia, and 1 part of neopelex, 0.05 part of ethyl alcohol, 98.85 parts of water.The silver ion disinfectant of embodiment 4-6 includes silver-colored 0.15 part of ammonia, and 2 parts of neopelex, ethyl alcohol 0.1 Part, 97.75 parts of water.
Bactericidal effect test is carried out to automotive air-conditioning system sterilizing detergent for cleaning of the invention:
Test method: with reference to the bactericidal effect method of inspection (suspension of 7.2 antimicrobial form daily chemical products of QB/T 2738-2012 Sizing technique)
1) neutralizer qualification test:
A. test strain: staphylococcus aureus (ATCC 6538) is as a result listed in table 2.
Neutralization agent prescription :+0.5% peptone of+0.5% sodium thiosulfate+0.5%L- histidine of 3% Tween-80+ + 0.1% cysteine of+1.43% lecithin of 0.85% sodium chloride
Sample concentration: 100%;The sample effect time: 5min.
Table 2:
B. test strain: escherichia coli (ATCC 25922) is as a result listed in table 3.
Neutralize agent prescription :+0.5% peptone+2.5% of+1.0% sodium thiosulfate+0.5%L- histidine of 3% Tween-80 + 0.1% cysteine of+1.43% lecithin of sodium chloride
Sample concentration: 100%;The sample effect time: 2min.
Table 3:
C. test strain: Pseudomonas aeruginosa (ATCC 15442) is as a result listed in table 4.
Neutralize agent prescription :+0.5% peptone+2.5% of+1.0% sodium thiosulfate+0.5%L- histidine of 3% Tween-80 + 0.1% cysteine of+1.43% lecithin of sodium chloride
Sample concentration: 100%;The sample effect time: 2min.
Table 4:
2) table 5: sterilizing rate test result
The above strain is commercially available or routine obtains.Automotive air-conditioning system sterilizing detergent for cleaning of the invention is to Pseudomonas aeruginosa (ATCC 5442), the sterilizing rate of staphylococcus aureus (ATCC6538) and escherichia coli (ATCC 5922) is at least 99%, table Significant bactericidal effect is revealed.
Above is only a specific embodiment of the present invention, it is not intended to limit the scope of the invention, all utilizations The equivalent transformation that the present invention makees, is applied directly or indirectly in other relevant technical fields, similarly includes of the invention Among scope of patent protection.

Claims (10)

1. a kind of automotive air-conditioning system sterilizing detergent for cleaning, which is characterized in that according to the mass fraction, including following components:
2. automotive air-conditioning system sterilizing detergent for cleaning according to claim 1, which is characterized in that according to the mass fraction, including Following components:
3. automotive air-conditioning system sterilizing detergent for cleaning according to claim 1, which is characterized in that according to the mass fraction, including Following components:
4. automotive air-conditioning system sterilizing detergent for cleaning according to any one of claim 1-3, which is characterized in that the water is Filter sterilization water;The fatty alcohol polyoxyethylene ether model AEO-9.
5. automotive air-conditioning system sterilizing detergent for cleaning according to any one of claim 1-3, which is characterized in that it is described silver from Sub- fungicide, according to the mass fraction, including following components:
6. automotive air-conditioning system sterilizing detergent for cleaning according to any one of claim 1-3, which is characterized in that it is described silver from The content of free silver ions is 500~2000ppm in sub- fungicide.
7. automotive air-conditioning system sterilizing detergent for cleaning according to any one of claim 1-3, which is characterized in that it is described silver from The density of sub- fungicide is 0.95~1.05g/mL;The pH value of the silver ion disinfectant is 9~12.
8. automotive air-conditioning system sterilizing detergent for cleaning according to any one of claim 1-3, which is characterized in that the automobile The pH value of air-conditioning system sterilizing detergent for cleaning is 6.5~11.8.
9. a kind of preparation method of automotive air-conditioning system sterilizing detergent for cleaning according to claim 1 to 8, special Sign is, comprising the following steps: according to the ratio by water, isomerous tridecanol polyoxyethylene ether, neopelex, ethylene glycol list Butyl ether, defoaming agent, fatty alcohol polyoxyethylene ether, silver ion disinfectant, essence stir evenly to kill to get the automotive air-conditioning system Bacterium cleaning agent.
10. a kind of application of automotive air-conditioning system sterilizing detergent for cleaning according to claim 1 to 8, feature exist In being used to kill Pseudomonas aeruginosa, staphylococcus aureus, escherichia coli for the automotive air-conditioning system sterilizing detergent for cleaning.
CN201811406335.8A 2018-11-23 2018-11-23 A kind of automotive air-conditioning system sterilizing detergent for cleaning and preparation method thereof Pending CN109370800A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110408472A (en) * 2019-08-07 2019-11-05 深圳市车安达汽保设备有限公司 The formula and its manufacture craft of deodorization and sterilization purification cleaning solution
CN114027299A (en) * 2021-12-09 2022-02-11 江苏瑞安汽车实业有限公司 Atomizing and refreshing bactericide for internal circulation space of air conditioner and preparation method of bactericide
CN114891573A (en) * 2022-06-24 2022-08-12 沈阳中大环新制冷技术有限公司 Cleaning agent for automobile air conditioner refrigeration system and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1248616A (en) * 1999-09-27 2000-03-29 上海家化联合股份有限公司 Sterilizing detergent for cleaning air conditioner
CN1480516A (en) * 2003-07-14 2004-03-10 何俊虹 Dedicated wash and maintenance liquid containing silver ion for sterilization of underwear
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US20080171804A1 (en) * 2006-08-24 2008-07-17 Venkataram Krishnan Anionic latex as a carrier for bioactive ingredients and methods for making and using the same
CN101437400A (en) * 2006-03-14 2009-05-20 印可得株式会社 Antibacterial composition containing organic silver complexes, antibacterial treatment methods using the same and antibacterial formed article
CN106062161A (en) * 2014-01-29 2016-10-26 荷兰联合利华有限公司 Cleansing compositions containing stable silver
CN106434020A (en) * 2016-09-07 2017-02-22 芜湖德鑫汽车部件有限公司 Automobile air conditioner cleaning composition and preparation method thereof
CN106954638A (en) * 2016-06-19 2017-07-18 王金明 A kind of antimicrobial composition

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1248616A (en) * 1999-09-27 2000-03-29 上海家化联合股份有限公司 Sterilizing detergent for cleaning air conditioner
CN1480516A (en) * 2003-07-14 2004-03-10 何俊虹 Dedicated wash and maintenance liquid containing silver ion for sterilization of underwear
CN101163784A (en) * 2005-02-25 2008-04-16 生物医学解决方案有限责任公司 Aqueous disinfectants and sterilants
CN101437400A (en) * 2006-03-14 2009-05-20 印可得株式会社 Antibacterial composition containing organic silver complexes, antibacterial treatment methods using the same and antibacterial formed article
US20080171804A1 (en) * 2006-08-24 2008-07-17 Venkataram Krishnan Anionic latex as a carrier for bioactive ingredients and methods for making and using the same
CN106062161A (en) * 2014-01-29 2016-10-26 荷兰联合利华有限公司 Cleansing compositions containing stable silver
CN106954638A (en) * 2016-06-19 2017-07-18 王金明 A kind of antimicrobial composition
CN106434020A (en) * 2016-09-07 2017-02-22 芜湖德鑫汽车部件有限公司 Automobile air conditioner cleaning composition and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110408472A (en) * 2019-08-07 2019-11-05 深圳市车安达汽保设备有限公司 The formula and its manufacture craft of deodorization and sterilization purification cleaning solution
CN114027299A (en) * 2021-12-09 2022-02-11 江苏瑞安汽车实业有限公司 Atomizing and refreshing bactericide for internal circulation space of air conditioner and preparation method of bactericide
CN114027299B (en) * 2021-12-09 2023-02-28 江苏瑞安汽车实业有限公司 Atomizing and refreshing bactericide for internal circulation space of air conditioner and preparation method of bactericide
CN114891573A (en) * 2022-06-24 2022-08-12 沈阳中大环新制冷技术有限公司 Cleaning agent for automobile air conditioner refrigeration system and preparation method thereof

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Application publication date: 20190222