CN106635484A - Air conditioner bactericidal cleaning agent and manufacturing method thereof - Google Patents

Air conditioner bactericidal cleaning agent and manufacturing method thereof Download PDF

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Publication number
CN106635484A
CN106635484A CN201611198165.XA CN201611198165A CN106635484A CN 106635484 A CN106635484 A CN 106635484A CN 201611198165 A CN201611198165 A CN 201611198165A CN 106635484 A CN106635484 A CN 106635484A
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China
Prior art keywords
cleaning agent
air conditioner
sterilizing cleaning
water
agent according
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Pending
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CN201611198165.XA
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Chinese (zh)
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叶宗耀
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Individual
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Individual
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Priority to CN201611198165.XA priority Critical patent/CN106635484A/en
Publication of CN106635484A publication Critical patent/CN106635484A/en
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/222Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/225Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/30Amines; Substituted amines ; Quaternized amines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/33Amino carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008Polymeric surface-active agents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29Sulfates of polyoxyalkylene ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • C11D1/721End blocked ethers

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention belongs to the technical field of daily chemicals, and specifically relates to an air conditioner bactericidal cleaning agent and a manufacturing method thereof. The cleaning agent comprises the following components in percentage by weight: 14 to 20% of nonionic surfactant, 7.5 to 12% of anionic surfactant, 4 to 6% of bactericide, 1.5 to 5% of thickening agent, 1 to 3% of chelating agent, and 54 to 72% of water. The cleaning agent has the advantages that after washing, the cleaning agent does not need to be washed off by water; and the cleaning agent can quickly kill bacteria and molds on the filter screens and cooling fins of an air conditioner and is capable of forming a bactericidal film on the cleaned parts to effectively prevent the growth and propagation of bacteria and molds.

Description

A kind of air conditioner sterilizing cleaning agent and its manufacture method
Technical field
The invention belongs to household chemicals technical field, and in particular to a kind of air conditioner sterilizing cleaning agent and its manufacture method.
Background technology
Recently as economic sustainable growth, the living standard of people is gradually stepped up, and air-conditioner is used as a kind of brand-new Durable consumer goods move into rapidly streets and lanes, into common people family, but when long and no air-conditioning is just opened, room In can produce peculiar smell, somebody is reflected in air-conditioned room and has stayed to feel to feel dizzy even n and V long, and medical expert is referred to as Air conditioner disease, traces it to its cause, and in use for some time, screen pack, fin etc. have gathered a large amount of dusts, plus overhead to air-conditioner Condensed water is adjusted to be full of therebetween, resulting bacterium and mould are circulated indoors with air, have both reduced the work of air-conditioning Make efficiency, increase energy consumption, more pollute air, spread disease.
Chinese patent CN102138566B discloses a kind of nontoxic mite killing sterilizing centralized air ventilation system cleaning agent, this Ming and Qing lotion includes d-limonen, d-phenothrin, dtetramethrin and polyhexamethylene guanide and emulsifying agent, the cleaning Although agent is with excellent bactericidal action, sterilization is not had, except mould, anlistatig effect, its decontamination dust effect It is bad.
Chinese patent CN101475878B discloses a kind of air conditioner cleaning agent and cleaning method, by citric acid, phosphoric acid Or in boric acid, inorganic acid at least two, nonionic surfactant or nonionic surfactant and anionic surface are lived Property agent compounding, oxo solvent and acid inhibitor composition, although the cleaning agent can effectively remove the dirt on air-conditioning surface, It does not have sterilization, except mould, anlistatig effect.
Therefore, problems of the prior art are solved, is developed a kind of with excellent sterilization, except mould and dirt-removing power Household air-conditioner cleaning agent is the difficult problem in current air conditioner cleaning agent field.
The content of the invention
To solve problems of the prior art, the present invention provides a kind of air conditioner sterilizing cleaning agent and its manufacture method.
A kind of air conditioner sterilizing cleaning agent, including following components and its mass percent:
Nonionic surfactant 14~20%, anion surfactant 7.5~12%, bactericide 4~6%, thickening Agent 1.5~5%, chelating agent 1~3% and water 54~72%.
Preferably, described air conditioner sterilizing cleaning agent, is made up of following components and its mass percent:
Nonionic surfactant 18%, anion surfactant 9.5%, bactericide 5%, thickener 3.5%, chelating Agent 2% and water 62%.
Preferably, described nonionic surfactant is OPEO.
Preferably, described anion surfactant is alkylpolyoxyethylene sodium sulphate.
Preferably, described bactericide is by dodecyl benzyl dimethyl ammonium chloride and daconil M in mass ratio 3: 5 compositions.
Preferably, described thickener is sodium cellulose glycolate.
Further preferably, described chelating agent is disodium ethylene diamine tetraacetate.
In addition, present invention also offers a kind of manufacture method of air conditioner sterilizing cleaning agent, comprises the following steps:
S1, add in tank is pre-dissolved nonionic surfactant and anion surfactant;
S2,30% water is added to stir to being completely dissolved;
S3, the lower addition bactericide of stirring, thickener and chelating agent are until be completely dissolved;
S4, the water for persistently stirring lower addition surplus, obtain final product.
OPEO CAS:9036-19-5;Alkylpolyoxyethylene sodium sulphate CAS:68585- 34-2;Dodecyl benzyl dimethyl ammonium chloride CAS:139-07-1;Daconil M CAS:1897-45-6;Hydroxyl first Base sodium cellulosate CAS:9004-32-4;Disodium ethylene diamine tetraacetate CAS:139-33-3.
Nonionic surfactant OPEO does not produce in aqueous ion in the present invention, in its molecule Lipophilic group it is roughly the same with the lipophilic group of ionic surfactant, its hydrophilic radical be mainly by with certain amount Oxygen-containing group constitute.
Anion surfactant alkylpolyoxyethylene sodium sulphate ionize in water after its surface-active action Part is negatively charged;The presence of non-/ anion surfactant makes cleaning agent have dirt-removing power.
Dodecyl benzyl dimethyl ammonium chloride has wide spectrum, efficient sterilization algae removal ability, can efficiently control in water Bacterium algae is bred and foundry loam growth, and with good sludge stripping effect and certain dispersion, osmosis, while having certain Deoil, deodorant and corrosion inhibition, surface tension can be reduced, make fat emulsification, therefore have cleaning decontamination effect, bacterium born of the same parents can be changed The permeability of serous coat, makes some important substance extravasations in thalline, hinders its metabolism and is in bactericidal effect, acts on strong and fast, toxicity It is low;Daconil M is high-effective broad-spectrum fungicide, thermally-stabilised to weak acid, weak base and light with protective effect, corrosion-free work With.
Sodium cellulose glycolate is thickener, with the several functions such as thickening, suspension, emulsification, stable.
Disodium ethylene diamine tetraacetate is the chelating agent of function admirable, has good chelate effect to metal.
Compatibility of the present invention is reasonable, science, and each component cooperates, acts synergistically, and collaboration strengthens its detergency and sterilized work( Energy.
Compared with prior art, it is of the invention it is a technical advantage that:It is rapid to kill sky without the need for being rinsed with water after the completion of washing Adjust the bacterium and mould on device screen pack and fin, at cleaning position one layer of sterilizing membrane formed, can effectively pre- bacteriological protection with The growth and breeding of mould.
Specific embodiment
The present invention is described in further details below by specific embodiment, these embodiments are only used for the mesh of illustration , it is in no way intended to limit protection scope of the present invention.
Embodiment 1-3, comparative example 1-2
Table 1 lists the component and its mass percent of embodiment 1-3 and comparative example 1-2 air conditioner sterilizing cleaning agent.
Comparative example 1 is with the difference of embodiment 2:Without dodecyl benzyl dimethyl ammonium chloride, increase tetrachloro isophthalic The content of dintrile.
Comparative example 2 is with the difference of embodiment 2:Bactericide is by dodecyl benzyl dimethyl ammonium chloride and tetrachloro isophthalic Dintrile in mass ratio 1:1 composition.
The manufacture method of the air conditioner sterilizing cleaning agent of embodiment 2:
S1, add in tank is pre-dissolved nonionic surfactant and anion surfactant;
S2,30% water is added to stir to being completely dissolved;
S3, the lower addition bactericide of stirring, thickener and chelating agent are until be completely dissolved;
S4, the water for persistently stirring lower addition surplus, obtain final product.
The manufacture method of embodiment 1, embodiment 3 and comparative example 1-2 air conditioner sterilizing cleaning agent is similar to Example 2.
Properties of product evaluation test
Fungus and mildew resistance performance test is carried out to embodiment of the present invention 1-3 and comparative example 1-2 gained air conditioner sterilizing cleaning agent, is adopted Carried out with carrier spray-on process, test organisms is staphylococcus aureus and aspergillus niger, respectively the representative bacterial classification of bacterium, mould, is carried Body selects metallic aluminium, makes the circular metal plate of a diameter of 2.4cm, is neutralized agent identification examination for different sterilization systems in advance Test, select suitable nertralizer.Metal aluminium flake is contaminated respectively with different strain suspension, bacterium piece viable bacteria content is made up to 105-106cfu/ ML, after natural drying, by above-mentioned formula bacterium piece surface (control is PBS) is sprayed to, and is acted on to the scheduled time, During bacterium piece to be moved into the test tube for filling 5mL nertralizers, neutralization 10min, the bacterium washed on lower bacterium piece carries out count plate, presses Formula calculates sterilization rate:Sterilization rate (%)=(control group viable bacteria concentration mean value-test group viable bacteria concentration mean value)/control group Viable bacteria concentration mean value, as a result as shown in table 2.
The fungus and mildew resistance performance test data of the embodiment of table 2 and comparative example air conditioner sterilizing cleaning agent
As can be seen from Table 2 embodiment of the present invention 1-3 is higher than contrast to the sterilization rate of staphylococcus aureus and aspergillus niger Example 1-2, illustrates bactericide of the present invention by dodecyl benzyl dimethyl ammonium chloride and daconil M in mass ratio 3:5 compositions There is more preferable bactericidal effect to staphylococcus aureus and aspergillus niger.
The above is only the preferred embodiment of the present invention, it is noted that it is right that above-mentioned preferred embodiment is not construed as The restriction of the present invention, protection scope of the present invention should be defined by claim limited range.For the art For those of ordinary skill, without departing from the spirit and scope of the present invention, some improvements and modifications can also be made, these change Enter and retouch also to should be regarded as protection scope of the present invention.

Claims (8)

1. a kind of air conditioner sterilizing cleaning agent, it is characterised in that including following components and its mass percent:
Nonionic surfactant 14~20%, anion surfactant 7.5~12%, bactericide 4~6%, thickener 1.5 ~5%, chelating agent 1~3% and water 54~72%.
2. air conditioner sterilizing cleaning agent according to claim 1, it is characterised in that by following components and its mass percent group Into:Nonionic surfactant 18%, anion surfactant 9.5%, bactericide 5%, thickener 3.5%, chelating agent 2% With water 62%.
3. air conditioner sterilizing cleaning agent according to claim 1 and 2, it is characterised in that described nonionic surfactant For OPEO.
4. air conditioner sterilizing cleaning agent according to claim 1 and 2, it is characterised in that described anion surfactant For alkylpolyoxyethylene sodium sulphate.
5. air conditioner sterilizing cleaning agent according to claim 1 and 2, it is characterised in that described bactericide is by dodecyl Dimethyl benzyl ammonium chloride and daconil M in mass ratio 3:5 compositions.
6. air conditioner sterilizing cleaning agent according to claim 1 and 2, it is characterised in that described thickener is that methylol is fine The plain sodium of dimension.
7. air conditioner sterilizing cleaning agent according to claim 1 and 2, it is characterised in that described chelating agent is ethylenediamine tetraacetic Acetic acid disodium.
8. the manufacture method of the air conditioner sterilizing cleaning agent according to any one of claim 1-7, it is characterised in that including following Step:
S1, add in tank is pre-dissolved nonionic surfactant and anion surfactant;
S2,30% water is added to stir to being completely dissolved;
S3, the lower addition bactericide of stirring, thickener and chelating agent are until be completely dissolved;
S4, the water for persistently stirring lower addition surplus, obtain final product.
CN201611198165.XA 2016-12-22 2016-12-22 Air conditioner bactericidal cleaning agent and manufacturing method thereof Pending CN106635484A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107674775A (en) * 2017-11-07 2018-02-09 邵莹 Bag type filtering machine filter core cleaning fluid
CN109819983A (en) * 2019-02-19 2019-05-31 无锡威士德气体净化科技有限公司 A kind of compound disinfectant and its preparation method and application for circulating water sterilizing

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103981038A (en) * 2014-05-30 2014-08-13 于文 Long-acting antibacterial detergent for air conditioners and preparation method thereof
CN106221959A (en) * 2016-08-03 2016-12-14 南安辰光日用化工品有限公司 A kind of detergent air-conditioner being sterilized and cleaning

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103981038A (en) * 2014-05-30 2014-08-13 于文 Long-acting antibacterial detergent for air conditioners and preparation method thereof
CN106221959A (en) * 2016-08-03 2016-12-14 南安辰光日用化工品有限公司 A kind of detergent air-conditioner being sterilized and cleaning

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107674775A (en) * 2017-11-07 2018-02-09 邵莹 Bag type filtering machine filter core cleaning fluid
CN109819983A (en) * 2019-02-19 2019-05-31 无锡威士德气体净化科技有限公司 A kind of compound disinfectant and its preparation method and application for circulating water sterilizing

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Application publication date: 20170510