CN109852486A - A kind of scale removal mild detergent and preparation method thereof - Google Patents
A kind of scale removal mild detergent and preparation method thereof Download PDFInfo
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- CN109852486A CN109852486A CN201811592585.5A CN201811592585A CN109852486A CN 109852486 A CN109852486 A CN 109852486A CN 201811592585 A CN201811592585 A CN 201811592585A CN 109852486 A CN109852486 A CN 109852486A
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Abstract
The invention belongs to filed of daily-use chemical industry, and in particular to a kind of scale removal mild detergent and preparation method thereof.Scale removal mild detergent of the invention is made by composition and preservative, antioxidant, pH adjusting agent, fragrance, pigment.The composition is composed of the following components by mass parts: 11-19 parts of sodium carbonate, 4-7 parts of dispersing agent, 5-10 parts of nonionic surfactant, 0.1-0.5 parts of defoaming agent, 1-2 parts of dispersibility nano silica, 2-4 parts of softening agent, 50-65 parts of distilled water.Scale removal mild detergent provided by the invention without chlorine, without quaternary ammonium, anacidity, anaerobic agent, algicide fungicide, it is nontoxic, contained dispersibility nano silica ingredient can also make the long-term injury for cleaning region confrontation ultraviolet light, rust deposite and greasy dirt can rapidly and efficiently be removed, suitable for large-scale industrial production, process of producing product is environment-protecting and non-poisonous, non-pollutant discharge, and finished product is easy to filling.
Description
Technical field
The invention belongs to filed of daily-use chemical industry, and in particular to a kind of scale removal mild detergent and preparation method thereof.
Background technique
With the improvement of living standards, it was recognized that cleaning is not only to clean floor, dust and dirt on metope
It is turbid, and to establish on the basis of human health is unaffected and room air fresh and comfortable.Therefore it often to use to clear
Clean dose, disinfectant, the several functions product such as air freshener, many existing detergents are not only time-consuming and laborious, and are not easy
Reach ideal effect, some can also make, and floor is faded, metope falls paint and corrosion metal material, itself also with irritant and
Toxicity not only polluted room air, but also bring harm to human health.
Application No. is a kind of detergents of 201610952282.4 patent disclosure, by following mass fraction formula components group
At: 15-25 parts of acetic acid, 7-9 parts of acetone, 11-13 parts of sodium bicarbonate, 6-8 parts of polyquaternium, 10-20 parts of oxalic acid, stearic acid 10-
15 parts, 15-25 parts of diatomite, 15-25 parts of light-coloured vinegar, 50-60 parts of water.
Application No. is a kind of chemical cleaner of 201710243981.6 patent disclosure, the detergent include acetic acid,
Zwitterionic surfactant, oxalic acid, nonionic surfactant, sodium bicarbonate, defoaming agent and water；Wherein, relative to 1 weight
The acetic acid of part, the content of the zwitterionic surfactant are 0.5-2.0 parts by weight, and the dosage of the oxalic acid is 0.8-
2.5 parts by weight, the dosage of the nonionic surfactant are 0.3-1.5 parts by weight, and the dosage of the sodium bicarbonate is 0.5-
1.5 parts by weight, the dosage of the defoaming agent are 0.5-1.0 parts by weight, and the dosage of water is 20-50 parts by weight.
Application No. is a kind of Bactericidal cleaners of 201110371127.0 patent disclosure, by following raw materials according according to following
Weight proportion is made: 2-8 parts of benzene sulfonic acid sodium salt, 1-4 parts of trifluoroethanol, 1-2 parts of sodium hydroxide, 1-10 parts of sodium chloride, ethyl alcohol 5-15
Part, 10-20 parts of mixture of 5-10 parts of kuh-seng, 8-10 parts of camphor, 4-10 parts of 1,2 dichloroethylene, trichloro ethylene and tetrachloro-ethylene
It is mixed with 10-20 parts of alcohol ether.
It is built a nationally advanced clean city at present largely using strong acid and strong base class cleaning reagent, such as oxalic acid, caustic soda, to the material cleaned
Largely damage and environmental disruption are caused in material surface, bring a large amount of security risks to operating personnel and periphery pedestrian,And to some gold The rust of category and the cleaning speed of greasy dirt are slower,The dirt of some equipment and metal surface cannot be removed faster.Therefore it opens
Send out small toxicity a kind of, it is environmentally friendly, have compared with high definition except metal surface dirt ability and clear to the neutrality of cleaning personnel safety
Clean dose necessary.
Summary of the invention
In view of this, one of the objects of the present invention is to provide a kind of composition of scale removal mild detergent, the composition
A kind of scale removal mild detergent of high-efficiency environment friendly can be used to prepare.
To achieve the above object, the technical solution of the present invention is as follows:
A kind of composition of scale removal mild detergent, it is composed of the following components by mass parts: 11-19 parts of sodium carbonate, dispersion
4-7 parts of agent, 5-10 parts of nonionic surfactant, 0.1-0.5 parts of defoaming agent, 1-2 parts of dispersibility nano silica, softening
2-4 parts of agent, 50-65 parts of distilled water.
Preferably, the composition is composed of the following components by mass parts: 15 parts of sodium carbonate, 5 parts of dispersing agent, nonionic table
8 parts of face activator, 0.3 part of defoaming agent, 2 parts of dispersibility nano silica, 3 parts of softening agent, 53 parts of distilled water.
Sodium carbonate can be used for the cleaning of grease, have good degreasing performance.
Dispersibility nanometer silicon dioxide material have cleaning, antibacterial, anti-ultraviolet property, and it is nontoxic, to environment without
Adverse effect.
Further, the dispersing agent is calgon, sodium pyrophosphate, polyacrylic acid sodium salt, and polyethylene, carboxymethyl are fine
Tie up one of element or a variety of.
Dispersing agent (Dispersant) is one kind in the molecule while having lipophilic and two kinds of opposite natures of hydrophily
Interfacial agent.It uniform can disperse those to be poorly soluble in the inorganic of liquid, the solid and liquid particles of organic pigment, while
The sedimentation and cohesion of particle can be prevented, amphipathic reagent needed for forming stable suspension.The effect of dispersing agent is mainly reflected in
It promotes gloss, floating, raising tinting strength, tinting power is prevented to notice that tinting strength, tinting power is not that the higher the better, it is viscous to reduce in automatic color regulating system
Degree reduces flocculation, increases storage-stable, increases color developing, increases color saturation, increases transparency.
Carboxymethyl cellulose (No. 1 cellulose CMC (C6H7O2OH2OCH2COOH) n) is a kind of water solubility that application is wider
Cellulose.The carboxymethyl cellulose controlled with reed as raw material is used for nickel sulfide ore flotation, as calcic, magnesium mineral inhibitor.
Made from raw material is done with straw, magnetic iron ore, bloodstone, calcite and by quartz that CA2+, Fe3+ have been activated, brightness of receiving can inhibit
The silicates mineral such as stone
Further, the nonionic surfactant is octyl phenol polyoxyethylene ether, nonylphenol polyoxyethylene ether, carbon rouge
One of fat alcohol polyoxyethylene ether is a variety of.
Nonionic surfactant refers to unionization in aqueous solution, and hydrophilic group with a certain number of mainly by containing
Oxygen groups (generally ether and hydroxyl) are constituted.Exactly this point determines that nonionic surfactant compares ion in some aspects
Surfactant is more superior；Because not being in the solution ionic condition, stability is high, not vulnerable to strong electrolyte inorganic salts
Existing influence is good with other types surfactant compatibility also not vulnerable to the influence of pH value.Nonionic surfactant has
Good resistance to hard water ability, has the characteristics of low foaming characteristic, therefore be suitable for special detergent, have dispersion, emulsification, foam, wetting,
Solubilized multiple performance.
Further, the defoaming agent is one or both of silicone emulsion, dimethyl silicone polymer.
Defoaming agent is the chemical assistant that be used to eliminate unwanted bubbles, can also enhance the function and effect of dispersing agent.
Further, the dispersing agent is carboxymethyl cellulose and polyacrylic acid sodium salt, the carboxymethyl cellulose and poly-
The mass ratio of acrylic acid sodium salt is 2:1.
Further, the nonionic surfactant is nonylphenol polyoxyethylene ether.
The second object of the present invention is to provide a kind of scale removal mild detergent of composition preparation.
To achieve the above object, the present invention uses following scheme:
A kind of scale removal mild detergent of composition preparation, further include preservative, antioxidant, pH adjusting agent,
Fragrance, pigment.
The third object of the present invention is to provide a kind of application in preparation scale removal mild detergent of composition.
The fourth object of the present invention is in providing a kind of preparation method of scale removal mild detergent.
To achieve the above object, the present invention uses following scheme:
A kind of preparation of the scale removal mild detergent, comprising the following steps:
1) sodium carbonate, dispersing agent, dispersibility nano silica, softening agent are added in distilled water by mass parts,
In 90-95 DEG C of sufficiently dissolution, when being cooled to 35-40 DEG C, it is 7 that pH adjusting agent, which is added, and adjusts pH value；
2) heating water bath is slowly added to nonionic surfactant, defoaming agent is stirred continuously dissolution, room temperature to 75-85 DEG C
It is cooling, preservative, antioxidant, fragrance and pigment are added to get the scale removal mild detergent.
The beneficial effects of the present invention are: 1) scale removal mild detergent provided by the invention without chlorine, without quaternary ammonium, anacidity, nothing
Oxidant, algicide fungicide, nontoxic, contained dispersibility nano silica ingredient can also make to clean regionTo anti-ultraviolet long-term injury；2) cleaning range is relatively broad, can be applicable in most of public domain, be particularly suitable for gold
The cleaning for belonging to material surface, can rapidly and efficiently goExcept rust deposite and greasy dirt；3) preparation method is simple and can take a tonne stirred tank
It is produced, is applicable inIn large-scale industrial production, process of producing product is environment-protecting and non-poisonous, non-pollutant discharge, finished product is easy to filling.
Specific embodiment
Illustrated embodiment is in order to which preferably the present invention will be described, but is not that the contents of the present invention are limited only to institute
For embodiment.So those skilled in the art according to foregoing invention content to embodiment carry out it is nonessential improvement and
Adjustment, still falls within protection scope of the present invention.
Embodiment 1
A kind of composition of scale removal mild detergent, the composition are composed of the following components by mass parts: sodium carbonate 11
Part, 4 parts of dispersing agent, 5 parts of nonionic surfactant, 0.1 part of defoaming agent, 1 part of dispersibility nano silica, softening agent 2
Part, 50 parts of distilled water.The dispersing agent is calgon, and the nonionic surfactant is nonylphenol polyoxyethylene ether,
The defoaming agent is silicone emulsion.
Embodiment 2
A kind of composition of scale removal mild detergent, the composition are composed of the following components by mass parts: sodium carbonate 19
Part, 7 parts of dispersing agent, 10 parts of nonionic surfactant, 0.5 part of defoaming agent, 2 parts of dispersibility nano silica, softening agent 4
Part, 65 parts of distilled water.The dispersing agent is sodium pyrophosphate, and the nonionic surfactant is nonylphenol polyoxyethylene ether, institute
Stating defoaming agent is dimethyl silicone polymer.
Embodiment 3
A kind of composition of scale removal mild detergent, the composition are composed of the following components by mass parts:: sodium carbonate 15
Part, 5 parts of dispersing agent, 8 parts of nonionic surfactant, 0.3 part of defoaming agent, 2 parts of dispersibility nano silica, softening agent 3
Part, 53 parts of distilled water.The dispersing agent is carboxymethyl cellulose and polyacrylic acid sodium salt, the carboxymethyl cellulose and polypropylene
The mass ratio of acid sodium-salt is 2:1, and the nonionic surfactant is nonylphenol polyoxyethylene ether, and the defoaming agent is poly- diformazan
Radical siloxane.
Embodiment 4
A kind of composition of scale removal mild detergent, the composition are composed of the following components by mass parts: sodium carbonate 16
Part, 6 parts of dispersing agent, 6 parts of nonionic surfactant, 0.2 part of infusion, 1.5 parts of dispersibility nano silica, softening agent
3.5 parts, 60 parts of distilled water.The dispersing agent is polyethylene, and the nonionic surfactant is nonylphenol polyoxyethylene ether, institute
Stating defoaming agent is silicone emulsion.
Comparative example 1
A kind of composition of scale removal mild detergent, the composition are composed of the following components by mass parts: sodium carbonate 11
Part, 4 parts of dispersing agent, 5 parts of nonionic surfactant, 0.1 part of defoaming agent, 2 parts of softening agent, 50 parts of distilled water.The dispersing agent
For calgon, the nonionic surfactant is nonylphenol polyoxyethylene ether, and the defoaming agent is silicone emulsion.
Comparative example 2
A kind of composition of scale removal mild detergent, the composition are composed of the following components by mass parts: dispersing agent 7
Part, 10 parts of nonionic surfactant, 0.5 part of defoaming agent, 2 parts of dispersibility nano silica, 4 parts of softening agent, distilled water
65 parts.The dispersing agent is sodium pyrophosphate, and the nonionic surfactant is nonylphenol polyoxyethylene ether, and the defoaming agent is
Dimethyl silicone polymer.
Comparative example 3
A kind of composition of scale removal mild detergent, the composition are composed of the following components by mass parts:: sodium carbonate 15
Part, 8 parts of nonionic surfactant, 0.3 part of defoaming agent, 2 parts of dispersibility nano silica, 3 parts of softening agent, distilled water 53
Part.The defoaming agent is dimethyl silicone polymer.
Comparative example 4
A kind of composition of scale removal mild detergent, the composition are composed of the following components by mass parts: sodium carbonate 16
Part, 6 parts of dispersing agent, 0.2 part of infusion, 1.5 parts of dispersibility nano silica, 3.5 parts of softening agent, 60 parts of distilled water.It is described
Dispersing agent is polyethylene, and the defoaming agent is silicone emulsion.
Embodiment 5
A kind of scale removal mild detergent, the cleaning of the scale removal neutrality as described in embodiment 1-4 and comparative example 1-4 any example
The composition of agent is made, and the scale removal mild detergent further includes preservative, antioxidant, pH adjusting agent, fragrance, pigment.
Embodiment 6
Detergent is prepared according to the proportion of embodiment 1-4 and comparative example 1-4, specifically includes the following steps:
1) by sodium carbonate (comparative example 2 lacks this component), dispersing agent (comparative example 3 lacks this component), can divide
Scattered property nano silica (comparative example 1 lacks this component), softening agent are added in distilled water by mass parts, in 90-95
DEG C sufficiently dissolution, when being cooled to 35-40 DEG C, be added pH adjusting agent adjust pH value be 7；
2) heating water bath is to 75-85 DEG C, be slowly added to nonionic surfactant (comparative example 4 lacks this component),
Defoaming agent is stirred continuously dissolution, and room temperature is cooling, and it is neutral to get the scale removal to add preservative, antioxidant, fragrance and pigment
Detergent.
7 washing tests of embodiment and effect assessment
(1) pollution such as each public arena wall face mushroom, mosses trace is removed
Mild detergent of the invention is sprayed on by the exterior wall surface for having mildew, algae, fungal contamination trace with spraying
Surface；
The spot natural decomposition of mould, bacterium and algae, killing after 5-10 minutes, not only metope is gradually recovered primary colors, and there are also light
Pool.Product application method of the invention is simple, through can simply remove spot by spraying, and it is harmless to metope.
(2) metal equipment dirt removal
Experiment metallic aluminum material, using 10 parts of unit quantities as benchmark dirt formula are as follows: 2 parts of mineral oil, 2.5 parts of black-lead paints with
2 clays, 2 calcium silicates, 1.5 polyvinyl alcohol；Experiment is with 8 parts of iron material (getting rusty, band rust deposite).
Dirt applies program: being uniformly applied to clean practice ground plate brick respectively by mixing the substance in above-mentioned formula
On, cladding thickness is 1~2mm.
Cleaning supplies: the detergent of embodiment 1-4 and comparative example 1-4 preparation, commercial product A are commercially available every
Its mild detergent used.
Cleaning procedure:
It is cleaned respectively to tested with metallic aluminum material and iron material with different cleaning articles: by different cleaning articles
Uniformly it is applied on test metallic aluminum material and iron material after 1~3 minute, 1) it is rinsed 2 minutes with the flowing water of identical dynamics, estimate
Calculate clearance rate；2) experiment is cleaned with identical dynamics with sponge through machine with metallic aluminum material and iron material, calculates cleaning
The clean time used.
2. experimental result:
1 cleaning result of table
As a result, it has been found that using inventive formulation mild detergent to degrease and the elimination effect of rust deposite much higher than its
His detergent, the experimental results showed that mild detergent clean effect of the invention is very good.
The physical property and stability test of the mild detergent of the invention of embodiment 9
Further analyze the physical property and stability of the detergent of embodiment 1-4 and comparative example 1-4 preparation.
Different cleaning agent is placed in 50 DEG C of baking ovens, balances it 2 hours in 50 DEG C of baking ovens.After 2 hours,
Sample is taken out from baking oven and records visual inspection result.
Evaluation criterion: the uniform outer appearance of no separation, muddy discoloration is recorded as passing through evaluation.For any muddy outer
It sees and/or separation is recorded as unsuccessful evaluation, as a result see the table below.
The physical property and estimation of stability of the detergent of the present invention of table 2
Finally, it is stated that the above examples are only used to illustrate the technical scheme of the present invention and are not limiting, although referring to compared with
Good embodiment describes the invention in detail, those skilled in the art should understand that, it can be to skill of the invention
Art scheme is modified or replaced equivalently, and without departing from the objective and range of technical solution of the present invention, should all be covered at this
In the scope of the claims of invention.
Claims (10)
1. a kind of composition of scale removal mild detergent, which is characterized in that the composition is composed of the following components by mass parts:
11-19 parts of sodium carbonate, 4-7 parts of dispersing agent, 5-10 parts of nonionic surfactant, 0.1-0.5 parts of defoaming agent, dispersibility nanometer
- 2 parts of silica 1,2-4 parts of softening agent, 50-65 parts of distilled water.
2. composition according to claim 1, which is characterized in that the composition is composed of the following components by mass parts:
15 parts of sodium carbonate, 5 parts of dispersing agent, 8 parts of nonionic surfactant, 0.3 part of defoaming agent, 2 parts of dispersibility nano silica,
3 parts of softening agent, 53 parts of distilled water.
3. composition according to claim 1, which is characterized in that the dispersing agent is calgon, sodium pyrophosphate, gathers
Acrylic acid sodium salt, one of polyethylene, carboxymethyl cellulose or a variety of.
4. composition according to claim 1, which is characterized in that the nonionic surfactant is octyl phenol polyoxy second
One of alkene ether, nonylphenol polyoxyethylene ether, carbon fatty alcohol polyoxyethylene ether are a variety of.
5. composition according to claim 1, which is characterized in that the defoaming agent is silicone emulsion, polydimethylsiloxanes
One or both of alkane.
6. composition according to claim 3, which is characterized in that the dispersing agent is carboxymethyl cellulose and polyacrylic acid
The mass ratio of sodium salt, the carboxymethyl cellulose and polyacrylic acid sodium salt is 2:1.
7. composition according to claim 4, which is characterized in that the nonionic surfactant is polyoxyethylene nonyl phenyl second
Alkene ether.
8. the scale removal mild detergent of the preparation of composition described in claim 1-7, which is characterized in that the scale removal neutrality cleaning
Agent further includes preservative, antioxidant, pH adjusting agent, fragrance, pigment.
9. application of the composition described in claim 1-7 in preparation scale removal mild detergent.
10. the preparation method of scale removal mild detergent according to any one of claims 8, comprising the following steps:
1) sodium carbonate, dispersing agent, dispersibility nano silica, softening agent are added in distilled water by mass parts, in 90-
95 DEG C of sufficiently dissolutions, when being cooled to 35-40 DEG C, it is 7 that pH adjusting agent, which is added, and adjusts pH value；
2) heating water bath is to 75-85 DEG C, is slowly added to nonionic surfactant, defoaming agent is stirred continuously dissolution, and room temperature is cooling,
Preservative, antioxidant, fragrance and pigment are added to get the scale removal mild detergent.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811592585.5A CN109852486A (en) | 2018-12-25 | 2018-12-25 | A kind of scale removal mild detergent and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811592585.5A CN109852486A (en) | 2018-12-25 | 2018-12-25 | A kind of scale removal mild detergent and preparation method thereof |
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| CN109852486A true CN109852486A (en) | 2019-06-07 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112159732A (en) * | 2020-09-23 | 2021-01-01 | 杭州一享净环保科技有限公司 | Neutral environment-friendly strong stain cleaning agent and preparation method thereof |
| CN114891571A (en) * | 2022-04-29 | 2022-08-12 | 苏州炽蓝生物科技有限公司 | Foamless high-concentration hard surface cleaner |
| CN116554972A (en) * | 2023-05-12 | 2023-08-08 | 朱从政 | Cleaning agent and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108330009A (en) * | 2018-04-02 | 2018-07-27 | 重庆清徽节能环保科技有限公司 | A kind of nano environmental protection mild detergent and preparation method thereof |
-
2018
- 2018-12-25 CN CN201811592585.5A patent/CN109852486A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108330009A (en) * | 2018-04-02 | 2018-07-27 | 重庆清徽节能环保科技有限公司 | A kind of nano environmental protection mild detergent and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112159732A (en) * | 2020-09-23 | 2021-01-01 | 杭州一享净环保科技有限公司 | Neutral environment-friendly strong stain cleaning agent and preparation method thereof |
| CN114891571A (en) * | 2022-04-29 | 2022-08-12 | 苏州炽蓝生物科技有限公司 | Foamless high-concentration hard surface cleaner |
| CN114891571B (en) * | 2022-04-29 | 2023-08-08 | 苏州炽蓝生物科技有限公司 | Foamless high concentrated hard surface cleaner |
| CN116554972A (en) * | 2023-05-12 | 2023-08-08 | 朱从政 | Cleaning agent and preparation method thereof |
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Application publication date: 20190607 |