CN103981038A - Long-acting antibacterial detergent for air conditioners and preparation method thereof - Google Patents
Long-acting antibacterial detergent for air conditioners and preparation method thereof Download PDFInfo
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- CN103981038A CN103981038A CN201410238210.4A CN201410238210A CN103981038A CN 103981038 A CN103981038 A CN 103981038A CN 201410238210 A CN201410238210 A CN 201410238210A CN 103981038 A CN103981038 A CN 103981038A
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Abstract
The invention relates to a long-acting antibacterial detergent for air conditioners and a preparation method thereof. The common air conditioner detergent has a single function, and can corrode the aluminum fins of the air conditioner due to strong acidity or alkality. The long-acting antibacterial detergent for air conditioners is prepared by mixing fatty alcohol polyethenoxy ether, fatty alcohol polyethenoxy ether sodium sulfate, organic alkali, organic acid, antibacterial agent, organic solvent, essence and water. The detergent can thoroughly remove various stubborn stains, bacteria, bacterium excrement and mold stains on the air conditioner aluminum fins, and can form an antibacterial film which has a long-acting inhibiting action on Escherichia coli and Staphylococcus aureus, thereby permanently protecting the health of the family. The detergent has the functions of cleaning, maintenance, bacteria resistance, peculiar smell removal, air refreshing and power saving, enhances the service efficiency of the air conditioner, and prolongs the service life of the air conditioner.
Description
Technical field
the present invention relates to a kind of liquid ceanser of domestic air conditioning, be specifically related to a kind of air-conditioning long-acting bacteriostatic clean-out system and preparation method thereof.
Background technology
Along with the raising of China's income level of resident and the improvement of housing condition, air conditioning machinery is universal with very fast speed in recent years.Along with popularizing of air conditioning machinery, " air conditioning disease " caused people's extensive attention.In fact, the basic reason that causes air conditioning disease is indoor apparatus of air conditioner " heart "---heat exchanger causes multiplying of microorganism because of dirt and the dust of long-term accumulation.The major cause that causes air conditioning disease is exactly in air conditioning room, to ventilate not freely, and the environment of constant temperature has manufactured hotbed to the breeding of various bacteriums and mould-growth.And human body treats for a long time in isoperibol, can make resistibility decline, the indoor and outdoor that the cold and hot gap of frequently coming in and going out is larger can make immunity degradation, and germ will be availed oneself of the opportunity to get in.The topmost symptom of air conditioning disease has headache, dizziness, dim eyesight, malaise, nausea and vomiting, poor appetite, poor sleep etc.
Room air is because heat exchange turns cold, and airborne moisture is tied aluminium sheet surface
Reveal.Although attaching has the strainer of removing dirt in air in domestic air conditioning, but the dirts such as the oil smoke swimming when trickle dust, the cigarette of cigarette, the cooking can not be removed, the strainer of domestic air conditioning and aluminium sheet are therefore contaminated, are attached on wetting aluminium sheet and form dirt.And these dirts can make bacterial reproduction as nutrition source, distinctive objectionable odor while generating domestic air conditioning running, and room air is worsened, and threaten to human health, also make domestic air conditioning decrease in efficiency simultaneously.2 air-conditionings are after using 2 years, if its dirt thickness reaches 0.2 millimeter, by saving 42% the electricity charge after cleaning, if use 8 hours in one day, the electricity charge are 0.7 yuan/degree, within 1 year, use 5 months, and the electricity charge of saving for a year are 706 yuan.Visible, user has only spent a small amount of cleaning charge, has but saved every year the electricity charge of 700 yuan of left and right.
Common air conditioner cleaning agent, generally synthetic by acidic components or basic component and surfactant compound, although it has desirable de-sludging performance, but function singleness, do not possess bacteriostasis property, and life-time service will certainly cause corrosion to aluminium fin, simultaneously, in use can cause certain injury to user's skin, and can not effectively remove peculiar smell.
Summary of the invention
The object of this invention is to provide a kind of air-conditioning long-acting bacteriostatic clean-out system and preparation method thereof, have simultaneously clean, antibacterial, eliminate the unusual smell, the multiple action of maintenance and fresh air.
The technical solution adopted in the present invention is:
A kind of air-conditioning long-acting bacteriostatic clean-out system, is characterized in that:
Component by following mass percent is made:
Fatty alcohol-polyoxyethylene ether 0.1-10%;
Polyoxyethylenated alcohol sodium sulfate 0.1-5%;
Organic bases 0.1-5%;
Organic acid 0.01-1%;
Fungistat 0.1-0.5%;
Organic solvent 0.1-10%;
Essence 0.1-0.5%;
Water surplus
.
Described fatty alcohol-polyoxyethylene ether is selected from the ethoxylate of straight or branched fatty alcohol, and carbon chain lengths is C12-C15, and the average adduct number of EO is 5-10.
It is polyoxyethylenated alcohol sodium sulfate, fatty alcohol-polyoxyethylene ether potassium sulfate, the AESA that C10-C18, ethoxymer distribution are 2-4 that described fatty alcohol polyoxyethylene ether sulfate is selected from fatty alcohol carbochain.
Described organic bases is selected from Monoethanolamine MEA BASF, diethanolamine, trolamine.
Described organic acid is selected from acetic acid, ethylenediamine tetraacetic acid (EDTA), citric acid, oxyacetic acid.
Described sterilant is selected from triclosan, triclocarban, parachlormetaxylenol, orthoxenol.
Described solvent is selected from ethanol, Virahol, propylene glycol.
Described water is deionized water or softening water.
A preparation method for air-conditioning long-acting bacteriostatic clean-out system, is characterized in that:
Realized by following steps:
Step 1: following mass percent is got the raw materials ready to raw material:
Fatty alcohol-polyoxyethylene ether 0.1-10%;
Polyoxyethylenated alcohol sodium sulfate 0.1-5%;
Organic bases 0.1-5%;
Organic acid 0.01-1%;
Fungistat 0.1-0.5%;
Organic solvent 0.1-10%;
Essence 0.1-0.5%;
Water surplus
.
Step 2: in pre-molten tank, add fungistat and organic solvent, and stir 20-30 minute, stand-by.
Step 3: add 20% water, fatty alcohol-polyoxyethylene ether and polyoxyethylenated alcohol sodium sulfate in batch tank, and stir, be stirred to completely and dissolve;
Step 4: in the situation that stirring, add pre-solvent fungistat, until dissolve completely;
Step 5: in the situation that continuing to stir, add successively organic bases, organic acid and essence, be stirred to completely and dissolve;
Step 6: in the situation that continuing to stir, add the water of residual content.
Step 7: work in-process carry out ripening;
Step 8: sampling Detection, finished product packing.
Described fatty alcohol-polyoxyethylene ether is selected from the ethoxylate of straight or branched fatty alcohol, and carbon chain lengths is C12-C15, and the average adduct number of EO is 5-10;
It is polyoxyethylenated alcohol sodium sulfate, fatty alcohol-polyoxyethylene ether potassium sulfate, the AESA that C10-C18, ethoxymer distribution are 2-4 that described fatty alcohol polyoxyethylene ether sulfate is selected from fatty alcohol carbochain;
Described organic bases is selected from Monoethanolamine MEA BASF, diethanolamine, trolamine;
Described organic acid is selected from acetic acid, ethylenediamine tetraacetic acid (EDTA), citric acid, oxyacetic acid;
Described sterilant is selected from triclosan, triclocarban, parachlormetaxylenol, orthoxenol;
Described solvent is selected from ethanol, Virahol, propylene glycol;
Described water is deionized water or softening water.
The present invention has the following advantages:
The present invention is a kind of liquid ceanser containing compositions such as tensio-active agent and fungistats, can not only thoroughly remove all kinds of stains, bacterium and bacterium movement and mildew on air-conditioning aluminium fin, i.e. spray is clean, need not clean by water, dirt flows out naturally, makes air-conditioning sparkling clean; And with the antibacterial film of rear formation, intestinal bacteria and streptococcus aureus are had to long-acting restraining effect, protect lastingly household's health; Can eliminate air-conditioning peculiar smell simultaneously; Neutral formula, non-corrosiveness and do not hinder skin; Improve air conditioner heat exchange efficiency, improve refrigerating duty, saves energy, extends air-conditioning work-ing life.
2, antibacterial clean-out system of the present invention is colourless or flaxen transparent liquid, in formula, do not contain branched dodecylbenzene sulfonic acid sodium,, alkylphenol polyoxyethylene, nitrilotriacetic acid and salt thereof, without white dyes, meet household detergent environmental labelling product technical requirements (HJ 458-2009), there is technique simple, easy to prepare, be easy to batch production, the features such as shelf-life is long, product cost ideal, can be widely used in the cleaning and disinfection of Domestic hanging or split-type air conditioner.
Brief description of the drawings
Fig. 1 is the analogue residue testing program of fungistat in air-conditioning long-acting bacteriostatic clean-out system.
Embodiment
Below in conjunction with embodiment, the present invention will be described in detail.
The preparation method of a kind of air-conditioning long-acting bacteriostatic clean-out system the present invention relates to, is realized by following steps:
Step 1: following mass percent is got the raw materials ready to raw material:
Fatty alcohol-polyoxyethylene ether 0.1-10%;
Polyoxyethylenated alcohol sodium sulfate 0.1-5%;
Organic bases 0.1-5%;
Organic acid 0.01-1%;
Fungistat 0.1-0.5%;
Organic solvent 0.1-10%;
Essence 0.1-0.5%;
Water surplus
.
Step 2: in pre-molten tank, add fungistat and organic solvent, and stir 20-30 minute, stand-by.
Step 3: add 20% water, fatty alcohol-polyoxyethylene ether and polyoxyethylenated alcohol sodium sulfate in batch tank, and stir, be stirred to completely and dissolve;
Step 4: in the situation that stirring, add pre-solvent fungistat, until dissolve completely;
Step 5: in the situation that continuing to stir, add successively organic bases, organic acid and essence, be stirred to completely and dissolve;
Step 6: in the situation that continuing to stir, add the water of residual content.
Step 7: work in-process carry out ripening;
Step 8: sampling Detection, finished product packing.
Wherein:
Described fatty alcohol-polyoxyethylene ether is selected from the ethoxylate of straight or branched fatty alcohol, and carbon chain lengths is C12-C15, and the average adduct number of EO is 5-10;
It is polyoxyethylenated alcohol sodium sulfate, fatty alcohol-polyoxyethylene ether potassium sulfate, the AESA that C10-C18, ethoxymer distribution are 2-4 that described fatty alcohol polyoxyethylene ether sulfate is selected from fatty alcohol carbochain;
Described organic bases is selected from Monoethanolamine MEA BASF, diethanolamine, trolamine;
Described organic acid is selected from acetic acid, ethylenediamine tetraacetic acid (EDTA), citric acid, oxyacetic acid;
Described sterilant is selected from triclosan, triclocarban, parachlormetaxylenol, orthoxenol;
Described solvent is selected from ethanol, Virahol, propylene glycol;
Described water is deionized water or softening water.
Embodiment 1:
Step 1: following mass percent is got the raw materials ready to raw material:
Fatty alcohol-polyoxyethylene ether 0.1%;
Polyoxyethylenated alcohol sodium sulfate 0.1%;
Organic bases 0.1%;
Organic acid 0.01%;
Fungistat 0.1%;
Organic solvent 0.1%;
Essence 0.1%;
Water surplus
.
Step 2: in pre-molten tank, add fungistat and organic solvent, and stir 20 minutes, stand-by.
Step 3: add 20% water, fatty alcohol-polyoxyethylene ether and polyoxyethylenated alcohol sodium sulfate in batch tank, and stir, be stirred to completely and dissolve;
Step 4: in the situation that stirring, add pre-solvent fungistat, until dissolve completely;
Step 5: in the situation that continuing to stir, add successively organic bases, organic acid and essence, be stirred to completely and dissolve;
Step 6: in the situation that continuing to stir, add the water of residual content.
Step 7: work in-process carry out ripening;
Step 8: sampling Detection, finished product packing.
Wherein:
Described fatty alcohol-polyoxyethylene ether is selected from the ethoxylate of straight or branched fatty alcohol, and carbon chain lengths is C12-C15, and the average adduct number of EO is 5-10;
It is the polyoxyethylenated alcohol sodium sulfate that C10-C18, ethoxymer distribution are 2-4 that described fatty alcohol polyoxyethylene ether sulfate is selected from fatty alcohol carbochain;
Described organic bases is chosen Monoethanolamine MEA BASF;
Described organic acid is chosen acetic acid;
Described sterilant is chosen triclosan;
Described solvent is chosen ethanol;
Described water is deionized water.
Embodiment 2:
Step 1: following mass percent is got the raw materials ready to raw material:
Fatty alcohol-polyoxyethylene ether 5%;
Polyoxyethylenated alcohol sodium sulfate 2.5%;
Organic bases 2.5%;
Organic acid 0.5%;
Fungistat 0.25%;
Organic solvent 5%;
Essence 0.25%;
Water surplus
.
Step 2: in pre-molten tank, add fungistat and organic solvent, and stir 25 minutes, stand-by.
Step 3: add 20% water, fatty alcohol-polyoxyethylene ether and polyoxyethylenated alcohol sodium sulfate in batch tank, and stir, be stirred to completely and dissolve;
Step 4: in the situation that stirring, add pre-solvent fungistat, until dissolve completely;
Step 5: in the situation that continuing to stir, add successively organic bases, organic acid and essence, be stirred to completely and dissolve;
Step 6: in the situation that continuing to stir, add the water of residual content.
Step 7: work in-process carry out ripening;
Step 8: sampling Detection, finished product packing.
Wherein:
Described fatty alcohol-polyoxyethylene ether is selected from the ethoxylate of straight or branched fatty alcohol, and carbon chain lengths is C12-C15, and the average adduct number of EO is 5-10;
It is the fatty alcohol-polyoxyethylene ether potassium sulfate that C10-C18, ethoxymer distribution are 2-4 that described fatty alcohol polyoxyethylene ether sulfate is selected from fatty alcohol carbochain;
Described organic bases is chosen diethanolamine;
Described organic acid is chosen ethylenediamine tetraacetic acid (EDTA);
Described sterilant is chosen triclocarban;
Described solvent is chosen Virahol;
Described water is deionized water.
Embodiment 3:
Step 1: following mass percent is got the raw materials ready to raw material:
Fatty alcohol-polyoxyethylene ether 10%;
Polyoxyethylenated alcohol sodium sulfate 5%;
Organic bases 5%;
Organic acid 1%;
Fungistat 0.5%;
Organic solvent 10%;
Essence 0.5%;
Water surplus
.
Step 2: in pre-molten tank, add fungistat and organic solvent, and stir 30 minutes, stand-by.
Step 3: add 20% water, fatty alcohol-polyoxyethylene ether and polyoxyethylenated alcohol sodium sulfate in batch tank, and stir, be stirred to completely and dissolve;
Step 4: in the situation that stirring, add pre-solvent fungistat, until dissolve completely;
Step 5: in the situation that continuing to stir, add successively organic bases, organic acid and essence, be stirred to completely and dissolve;
Step 6: in the situation that continuing to stir, add the water of residual content.
Step 7: work in-process carry out ripening;
Step 8: sampling Detection, finished product packing.
Wherein:
Described fatty alcohol-polyoxyethylene ether is selected from the ethoxylate of straight or branched fatty alcohol, and carbon chain lengths is C12-C15, and the average adduct number of EO is 5-10;
It is the AESA that C10-C18, ethoxymer distribution are 2-4 that described fatty alcohol polyoxyethylene ether sulfate is selected from fatty alcohol carbochain;
Described organic bases is chosen trolamine;
Described organic acid is chosen citric acid or oxyacetic acid;
Described sterilant is chosen parachlormetaxylenol or orthoxenol;
Described solvent is chosen propylene glycol;
Described water is softening water.
In the present invention, fatty alcohol-polyoxyethylene ether is a kind of low bubble nonionogenic tenside, has good clearing power, good to the detersive power of oily dirt.The electrolytical ability of stability in hard water and resisting high-concentration is all more intense.The advantage of polyoxyethylene nonionogenic tenside maximum is the adjustability of hydrophobic group and hydrophilic group part.By selecting different EO numbers to adapt to various kinds of substrates, reach best clearing power, there is in addition good cold washing.In the present invention, by adopting straight or branched, carbon number is C12-C15, and the nonionogenic tenside that EO mean number is 5-10 is adjusted the rheological characteristics of formula, the especially flowability problem under cold condition, thus ensure that product has good application performance.
In the present invention, selected fungistat is phenols sterilizing agent, its to gram-positive microorganism and Gram-negative bacteria, fungi, yeast and virus have extensively, its sterilization mechanism is that it is first adsorbed on bacteria cell wall, then penetration cell wall, lipid, proteins react with bacterial cytoplasm, make it irreversible sex change, finally cause low-molecular-weight entocyte to flow out and make bacterium death, thereby reach the object of quick-acting sterilizations.It is safe and be easy to compatibility, and fungicidal spectrum is wide, rapid, lasting etc., has desirable shelf-life simultaneously.
The analogue residue of fungistat test in air-conditioning long-acting bacteriostatic clean-out system of the present invention:
Object: by measuring fungistatic effect and the action time that in air-conditioning long-acting bacteriostatic clean-out system, fungistat carrys out quantitative evaluation product in the residual quantity of aluminium flake.
Principle: having or not antibacterial effect is to decide by antibacterial technical ability number of residual quantity on alum gate.Allocate and transport change border by analog space, detect the residual quantity of different time sections on the air conditioning evaporator alum gate of fungistat after clean-out system sprays, draw the relation curve of itself and time, quantize the fungistatic effect of this product.
Scheme is referring to Fig. 1.
Experimental procedure:
1, aluminium flake is made to 5 5cm specifications, clean by washed with methanol respectively, dry in the shade for subsequent use;
2, the aluminium flake of handling well is fully immersed in the antibacterial clean-out system of domestic air conditioning to be measured, after 15 minutes, takes out, dry in the shade for subsequent use;
3, take out two aluminium flakes as Duplicate Samples, use respectively methyl alcohol ultrasonic extraction 3 times, concentrated being dissolved in 25 milliliters of volumetric flasks.
4, use the content of 0 day fungistat of high performance liquid chromatograph quantitative analysis.
5, will remain aluminium flake and fully soak with 250 ml sterile waters respectively, sealing room temperature preservation 7 days.
6 and then take out two aluminium flakes as Duplicate Samples, dry in the shade for subsequent use.Residue aluminium flake fully soaks with 250 ml sterile waters again, sealing room temperature preservation 7 days.
7, by the aluminium flake experimental procedure method for subsequent use same 3 of drying in the shade in 6.
8, with 7 days antiseptic-germicide content of high performance liquid chromatograph quantitative analysis.
9, with the content of identical 14 days antiseptic-germicides of method quantitative analysis.
Test required instrument and condition:
TSP company of HPLC Thermo Electron Corp.;
Spectra system SCM1000 P4000 SN4000 UV60000LP λ=210nm; 4.6150mmKR100C18 post, methyl alcohol: water=80:20, flow velocity: 1.0ml/min.
Experimental result:
Conclusion:
Even fungistat triclosan on aluminium flake, soak within 14 days, also can ensure certain residual, thereby can ensure effectively antibacterial to air-conditioning aluminium fin.
It is cited that content of the present invention is not limited to embodiment, and the conversion of any equivalence that those of ordinary skill in the art take technical solution of the present invention by reading specification sheets of the present invention, is claim of the present invention and contains.
Claims (10)
1. an air-conditioning long-acting bacteriostatic clean-out system, is characterized in that:
Component by following mass percent is made:
Fatty alcohol-polyoxyethylene ether 0.1-10%;
Polyoxyethylenated alcohol sodium sulfate 0.1-5%;
Organic bases 0.1-5%;
Organic acid 0.01-1%;
Fungistat 0.1-0.5%;
Organic solvent 0.1-10%;
Essence 0.1-0.5%;
Water surplus
.
2. a kind of air-conditioning long-acting bacteriostatic clean-out system according to claim 1, is characterized in that:
Described fatty alcohol-polyoxyethylene ether is selected from the ethoxylate of straight or branched fatty alcohol, and carbon chain lengths is C12-C15, and the average adduct number of EO is 5-10.
3. a kind of air-conditioning long-acting bacteriostatic clean-out system according to claim 2, is characterized in that:
It is polyoxyethylenated alcohol sodium sulfate, fatty alcohol-polyoxyethylene ether potassium sulfate, the AESA that C10-C18, ethoxymer distribution are 2-4 that described fatty alcohol polyoxyethylene ether sulfate is selected from fatty alcohol carbochain.
4. a kind of air-conditioning long-acting bacteriostatic clean-out system according to claim 3, is characterized in that:
Described organic bases is selected from Monoethanolamine MEA BASF, diethanolamine, trolamine.
5. a kind of air-conditioning long-acting bacteriostatic clean-out system according to claim 4, is characterized in that:
Described organic acid is selected from acetic acid, ethylenediamine tetraacetic acid (EDTA), citric acid, oxyacetic acid.
6. a kind of air-conditioning long-acting bacteriostatic clean-out system according to claim 5, is characterized in that:
Described sterilant is selected from triclosan, triclocarban, parachlormetaxylenol, orthoxenol.
7. a kind of air-conditioning long-acting bacteriostatic clean-out system according to claim 6, is characterized in that:
Described solvent is selected from ethanol, Virahol, propylene glycol.
8. a kind of air-conditioning long-acting bacteriostatic clean-out system according to claim 7, is characterized in that:
Described water is deionized water or softening water.
9. a preparation method for air-conditioning long-acting bacteriostatic clean-out system, is characterized in that:
Realized by following steps:
Step 1: following mass percent is got the raw materials ready to raw material:
Fatty alcohol-polyoxyethylene ether 0.1-10%;
Polyoxyethylenated alcohol sodium sulfate 0.1-5%;
Organic bases 0.1-5%;
Organic acid 0.01-1%;
Fungistat 0.1-0.5%;
Organic solvent 0.1-10%;
Essence 0.1-0.5%;
Water surplus
;
Step 2: in pre-molten tank, add fungistat and organic solvent, and stir 20-30 minute, stand-by;
Step 3: add 20% water, fatty alcohol-polyoxyethylene ether and polyoxyethylenated alcohol sodium sulfate in batch tank, and stir, be stirred to completely and dissolve;
Step 4: in the situation that stirring, add pre-solvent fungistat, until dissolve completely;
Step 5: in the situation that continuing to stir, add successively organic bases, organic acid and essence, be stirred to completely and dissolve;
Step 6: in the situation that continuing to stir, add the water of residual content;
Step 7: work in-process carry out ripening;
Step 8: sampling Detection, finished product packing.
10. the preparation method of a kind of air-conditioning long-acting bacteriostatic clean-out system according to claim 9, is characterized in that:
Described fatty alcohol-polyoxyethylene ether is selected from the ethoxylate of straight or branched fatty alcohol, and carbon chain lengths is C12-C15, and the average adduct number of EO is 5-10;
It is polyoxyethylenated alcohol sodium sulfate, fatty alcohol-polyoxyethylene ether potassium sulfate, the AESA that C10-C18, ethoxymer distribution are 2-4 that described fatty alcohol polyoxyethylene ether sulfate is selected from fatty alcohol carbochain;
Described organic bases is selected from Monoethanolamine MEA BASF, diethanolamine, trolamine;
Described organic acid is selected from acetic acid, ethylenediamine tetraacetic acid (EDTA), citric acid, oxyacetic acid;
Described sterilant is selected from triclosan, triclocarban, parachlormetaxylenol, orthoxenol;
Described solvent is selected from ethanol, Virahol, propylene glycol;
Described water is deionized water or softening water.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410238210.4A CN103981038A (en) | 2014-05-30 | 2014-05-30 | Long-acting antibacterial detergent for air conditioners and preparation method thereof |
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| CN201410238210.4A CN103981038A (en) | 2014-05-30 | 2014-05-30 | Long-acting antibacterial detergent for air conditioners and preparation method thereof |
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| CN104593792A (en) * | 2014-12-25 | 2015-05-06 | 宁波市川宁环保科技有限公司 | Efficient environment-friendly type aluminum fin cleaning agent and preparation method thereof |
| CN105542994A (en) * | 2015-12-16 | 2016-05-04 | 天津兰黛采妆环保科技开发有限公司 | Environmentally friendly air cleaner |
| CN105647679A (en) * | 2016-01-25 | 2016-06-08 | 龙笑琼 | Air conditioner pipe cleaning agent and production process thereof |
| CN106366938A (en) * | 2016-08-27 | 2017-02-01 | 安徽天瞳智能科技有限公司 | Antibacterial composite material with high cleaning performance |
| CN106479372A (en) * | 2016-08-27 | 2017-03-08 | 安徽天瞳智能科技有限公司 | A kind of Clean- composite of lasting light |
| CN106635484A (en) * | 2016-12-22 | 2017-05-10 | 叶宗耀 | Air conditioner bactericidal cleaning agent and manufacturing method thereof |
| CN106701335A (en) * | 2015-11-14 | 2017-05-24 | 中山市大田汽车护理用品有限公司 | Air conditioning detergent and preparing method thereof |
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| CN104388201A (en) * | 2014-12-19 | 2015-03-04 | 北京绿伞化学股份有限公司 | Anticorrosive air-conditioner disinfection detergent and preparation method thereof |
| CN104388201B (en) * | 2014-12-19 | 2017-10-31 | 北京绿伞化学股份有限公司 | A kind of anti-corrosion type Air conditioner sterilizing cleaning agent and preparation method thereof |
| CN104593792B (en) * | 2014-12-25 | 2018-11-09 | 宁波市川宁环保科技有限公司 | Efficient and environment-friendly type aluminum fin-stock cleaning agent and preparation method thereof |
| CN104593792A (en) * | 2014-12-25 | 2015-05-06 | 宁波市川宁环保科技有限公司 | Efficient environment-friendly type aluminum fin cleaning agent and preparation method thereof |
| CN106701335A (en) * | 2015-11-14 | 2017-05-24 | 中山市大田汽车护理用品有限公司 | Air conditioning detergent and preparing method thereof |
| CN105542994A (en) * | 2015-12-16 | 2016-05-04 | 天津兰黛采妆环保科技开发有限公司 | Environmentally friendly air cleaner |
| CN105647679A (en) * | 2016-01-25 | 2016-06-08 | 龙笑琼 | Air conditioner pipe cleaning agent and production process thereof |
| CN106366938A (en) * | 2016-08-27 | 2017-02-01 | 安徽天瞳智能科技有限公司 | Antibacterial composite material with high cleaning performance |
| CN106479372A (en) * | 2016-08-27 | 2017-03-08 | 安徽天瞳智能科技有限公司 | A kind of Clean- composite of lasting light |
| CN106635484A (en) * | 2016-12-22 | 2017-05-10 | 叶宗耀 | Air conditioner bactericidal cleaning agent and manufacturing method thereof |
| CN107674771A (en) * | 2017-08-09 | 2018-02-09 | 深圳沃海森科技有限公司 | Neutral air conditioning for automobiles cleaning agent and preparation method thereof |
| CN109777647A (en) * | 2019-03-04 | 2019-05-21 | 广东欧蝶兰高新科技日用品有限公司 | A kind of clothing removes peculiar smell composition |
| CN112355861A (en) * | 2020-10-08 | 2021-02-12 | 中山市光大光学仪器有限公司 | Special material polishing process |
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Application publication date: 20140813 |