CN109439460A - The minimizing technology of wax removing agent and preparation method thereof and wax - Google Patents
The minimizing technology of wax removing agent and preparation method thereof and wax Download PDFInfo
- Publication number
- CN109439460A CN109439460A CN201811450671.2A CN201811450671A CN109439460A CN 109439460 A CN109439460 A CN 109439460A CN 201811450671 A CN201811450671 A CN 201811450671A CN 109439460 A CN109439460 A CN 109439460A
- Authority
- CN
- China
- Prior art keywords
- cleaning solution
- washed
- oil
- fatty alcohol
- wax
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 26
- 238000005516 engineering process Methods 0.000 title claims abstract description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 139
- 238000004140 cleaning Methods 0.000 claims abstract description 92
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 74
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 54
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 51
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 39
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 38
- 229960000935 dehydrated alcohol Drugs 0.000 claims abstract description 36
- 239000002480 mineral oil Substances 0.000 claims abstract description 32
- 235000010446 mineral oil Nutrition 0.000 claims abstract description 32
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 32
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 32
- 239000003502 gasoline Substances 0.000 claims abstract description 31
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 28
- 229920001451 polypropylene glycol Polymers 0.000 claims abstract description 28
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 24
- 239000000194 fatty acid Substances 0.000 claims abstract description 24
- 229930195729 fatty acid Natural products 0.000 claims abstract description 24
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 23
- 244000060011 Cocos nucifera Species 0.000 claims abstract description 20
- 235000013162 Cocos nucifera Nutrition 0.000 claims abstract description 20
- 239000008367 deionised water Substances 0.000 claims abstract description 20
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 20
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 17
- 239000007788 liquid Substances 0.000 claims abstract description 17
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 17
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 17
- 239000003350 kerosene Substances 0.000 claims abstract description 16
- 239000003208 petroleum Substances 0.000 claims abstract description 15
- 235000015112 vegetable and seed oil Nutrition 0.000 claims abstract description 15
- 239000008158 vegetable oil Substances 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 239000000243 solution Substances 0.000 claims description 81
- 238000003756 stirring Methods 0.000 claims description 33
- 239000007864 aqueous solution Substances 0.000 claims description 25
- -1 polypropylene glycol - At Polymers 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 7
- 238000005406 washing Methods 0.000 claims description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- 235000019483 Peanut oil Nutrition 0.000 claims description 5
- 235000019484 Rapeseed oil Nutrition 0.000 claims description 5
- 239000000312 peanut oil Substances 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- 239000003549 soybean oil Substances 0.000 claims description 5
- 235000012424 soybean oil Nutrition 0.000 claims description 5
- 239000003240 coconut oil Substances 0.000 claims description 4
- 235000019864 coconut oil Nutrition 0.000 claims description 4
- 239000006210 lotion Substances 0.000 claims description 4
- 239000003921 oil Substances 0.000 claims description 4
- 235000019198 oils Nutrition 0.000 claims description 4
- 239000004006 olive oil Substances 0.000 claims description 3
- 235000008390 olive oil Nutrition 0.000 claims description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims 4
- YFDKVXNMRLLVSL-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid;sodium Chemical compound [Na].CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O YFDKVXNMRLLVSL-UHFFFAOYSA-N 0.000 claims 1
- 244000020551 Helianthus annuus Species 0.000 claims 1
- 235000003222 Helianthus annuus Nutrition 0.000 claims 1
- 125000002252 acyl group Chemical group 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 150000008107 benzenesulfonic acids Chemical class 0.000 claims 1
- 239000001993 wax Substances 0.000 abstract description 60
- 239000002699 waste material Substances 0.000 abstract description 12
- 239000012188 paraffin wax Substances 0.000 abstract description 9
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 8
- 238000002474 experimental method Methods 0.000 abstract description 5
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 235000019486 Sunflower oil Nutrition 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000002600 sunflower oil Substances 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- MGEVERFRGPRYII-UHFFFAOYSA-L disodium oxirane sulfate Chemical compound S(=O)(=O)([O-])[O-].[Na+].C1CO1.[Na+] MGEVERFRGPRYII-UHFFFAOYSA-L 0.000 description 3
- 238000005554 pickling Methods 0.000 description 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
- 125000005233 alkylalcohol group Chemical group 0.000 description 2
- CMMUKUYEPRGBFB-UHFFFAOYSA-L dichromic acid Chemical compound O[Cr](=O)(=O)O[Cr](O)(=O)=O CMMUKUYEPRGBFB-UHFFFAOYSA-L 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 238000004506 ultrasonic cleaning Methods 0.000 description 2
- 241000549173 Celastrus scandens Species 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical group [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 229960004756 ethanol Drugs 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 150000002194 fatty esters Chemical class 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Cleaning By Liquid Or Steam (AREA)
Abstract
The present invention relates to the minimizing technologies of a kind of wax removing agent and preparation method thereof and wax.The wax removing agent includes preceding cleaning solution and rear cleaning solution, according to mass percentage meter, the raw material for preparing the preceding cleaning solution includes: petroleum ether 18%~25%, kerosene 20%~30%, gasoline 15%~30%, vegetable oil 8%~16%, dehydrated alcohol 5%~10%, isopropanol %~10% and polypropylene glycol 2%~8%；The raw material for preparing the rear cleaning solution includes: neopelex 8%~12%, sodium sulfate of polyethenoxy ether of fatty alcohol 6%~10%, fatty alcohol polyoxyethylene ether 5%~10%, cocoanut fatty acid diethanolamide 1%~3%, dehydrated alcohol 5%~10%, White Mineral Oil 1%~5%, sodium hydroxide 1%~5% and deionized water surplus.It is tested through experiment, the paraffin removal ability of above-mentioned wax removing agent is strong, heavy metal in waste liquid content is low.
Description
Technical field
The present invention relates to cleaning solution fields, more particularly to the minimizing technology of a kind of wax removing agent and preparation method thereof and wax.
Background technique
In wax work production or scientific experiment work, it is commonly encountered various slop wax adherency on the wall, this is to production
Or scientific research brings inconvenience.
There are also common removing slop wax methods for workshop or R&D units at present, but in solvent for use often
Contain the ingredients such as the concentrated sulfuric acid, concentrated hydrochloric acid, potassium bichromate, chloroform, carbon tetrachloride.Use these conventional clean liquid, on the one hand,
Coating of wax film layer is also remained after drying, and has slop wax residual；On the other hand, since the presence of strong acid may corrode container, and
Waste liquid is also possible to the heavy metal component containing many pollution environment in washing.
Summary of the invention
Based on this, it is necessary to provide the wax removing agent that a kind of paraffin removal ability is strong, heavy metal in waste liquid content is low.
In addition, also providing a kind of preparation method of above-mentioned wax removing agent and the minimizing technology of wax.
A kind of wax removing agent, including preceding cleaning solution and rear cleaning solution, wherein according to mass percentage meter, prepare it is described before
The raw material of cleaning solution includes:
Prepare it is described after the raw material of cleaning solution include:
In one of the embodiments, the gasoline in 90# gasoline, 92# gasoline, 95# gasoline and 98# gasoline extremely
Few one kind；And/or the vegetable oil is selected from least one of rapeseed oil, peanut oil, soybean oil, olive oil and sunflower oil；
And/or the polypropylene glycol is selected from least one of polypropylene glycol -200, polypropylene glycol -400 and polypropylene glycol -600；And/
Or, the fatty alcohol polyoxyethylene ether is selected from fatty alcohol polyoxyethylene ether -7, fatty alcohol polyoxyethylene ether -9 and fatty alcohol polyoxy
At least one of vinethene -10；And/or the White Mineral Oil is selected from 15# cosmetics-stage White Mineral Oil, 26# cosmetics-stage White Mineral Oil
And at least one of 68# cosmetics-stage White Mineral Oil.
A kind of preparation method of wax removing agent, includes the following steps:
According to mass percentage meter, by described 18%~25% petroleum ether, described 20%~30% kerosene, described
15%~30% gasoline, described 8%~16% vegetable oil, described 5%~10% dehydrated alcohol, described 5%~10%
Isopropanol and described 2%~8% polypropylene glycol mixing, obtain preceding cleaning solution；By described 8%~12% detergent alkylate
Sodium sulfonate, described 6%~10% sodium sulfate of polyethenoxy ether of fatty alcohol, described 5%~10% fatty alcohol polyoxyethylene ether,
Described 1%~3% cocoanut fatty acid diethanolamide, described 5%~10% dehydrated alcohol, described 1%~5% it is white
Dormant oil and described 1%~5% sodium hydroxide mixing, obtain rear cleaning solution.
The specific steps for preparing the preceding cleaning solution in one of the embodiments, include: that at room temperature, control speed is
100r/min~120r/min stirring, makes the petroleum ether, the kerosene, the gasoline, the vegetable oil, the anhydrous second
Alcohol, the isopropanol and the polypropylene glycol are uniformly mixed, and obtain preceding cleaning solution.
Prepare in one of the embodiments, it is described after the specific steps of cleaning solution include:
The sodium hydroxide described in the deionized water dissolving obtains the aqueous solution of sodium hydroxide；
By the neopelex, the sodium sulfate of polyethenoxy ether of fatty alcohol, the aliphatic alcohol polyethenoxy
Ether and the cocoanut fatty acid diethanolamide are mixed with the aqueous solution of the sodium hydroxide, obtain the first mixed liquor；
The dehydrated alcohol and the White Mineral Oil is added into first mixed liquor, stands to after clarifying, it is clear after obtaining
Washing lotion.
The specific steps packet sodium hydroxide being dissolved into the deionized water in one of the embodiments,
It includes: at room temperature, with the stirring of the speed of the 100r/min~120r/min deionized water, described in stirring while is added
1%~5% sodium hydroxide is into the deionized water.
It is described by the neopelex, the fatty alcohol polyoxyethylene ether sulphur in one of the embodiments,
Sour sodium, the fatty alcohol polyoxyethylene ether and the cocoanut fatty acid diethanolamide are dissolved into the water-soluble of the sodium hydroxide
Specific steps in liquid include: to heat the aqueous solution of the sodium hydroxide to 40 DEG C~50 DEG C；Then with 300r/min~
Under conditions of the speed stirring of 500r/min, the detergent alkylate is added in the aqueous solution of the sodium hydroxide after the heating
Sodium sulfonate, the sodium sulfate of polyethenoxy ether of fatty alcohol, the fatty alcohol polyoxyethylene ether and the coco-nut oil fatty acid diethyl
Alkylolamides.
The addition dehydrated alcohol and the White Mineral Oil are into first mixed liquor in one of the embodiments,
Specific steps include: under conditions of with the stirring of the speed of 300r/min~500r/min, in first mixed liquor plus
Enter the dehydrated alcohol and the White Mineral Oil, stand to after clarifying, obtains the rear cleaning solution.
A kind of minimizing technology of wax, includes the following steps:
It is first washed with preceding cleaning solution and wipes container to be washed, wherein according to mass percentage meter, the preceding cleaning solution includes petroleum
Ether 18%~25%, kerosene 20%~30%, gasoline 15%~30%, vegetable oil 8%~16%, dehydrated alcohol 5%~10%,
Isopropanol 5%~10% and polypropylene glycol 2%~8%；
Then it is washed with rear cleaning solution and wipes the container to be washed, wherein according to mass percentage meter, the rear cleaning solution packet
Include neopelex 8%~12%, sodium sulfate of polyethenoxy ether of fatty alcohol 6%~10%, fatty alcohol polyoxyethylene ether
5%~10%, cocoanut fatty acid diethanolamide 1%~3%, dehydrated alcohol 5%~10%, White Mineral Oil 1%~5% and hydrogen
Sodium oxide molybdena 1%~5%；
The container to be washed is cleaned with 80 DEG C~100 DEG C of water again.
In one of the embodiments, it is described wash the step of wiping container to be washed with preceding cleaning solution before, further include with 80
DEG C~100 DEG C of water the step of impregnating the container 5min~10min to be washed；And/or it is cleaned with 80 DEG C~100 DEG C of water
After the step of container to be washed, further include the steps that container to be washed described in the water ultrasonic cleaning with 50 DEG C~70 DEG C.
Prove through experiment test: the paraffin removal ability of above-mentioned wax removing agent is strong, heavy metal in waste liquid content is low.
Detailed description of the invention
Fig. 1 is the minimizing technology flow chart of the wax of a way of example.
Specific embodiment
To facilitate the understanding of the present invention, a more comprehensive description of the invention is given in the following sections with reference to the relevant attached drawings.In attached drawing
Give preferred embodiment of the invention.But the invention can be realized in many different forms, however it is not limited to herein
Described embodiment.On the contrary, purpose of providing these embodiments is keeps the understanding to the disclosure more saturating
It is thorough comprehensive.
Unless otherwise defined, all technical and scientific terms used herein and belong to technical field of the invention
The normally understood meaning of technical staff is identical.Term as used herein in the specification of the present invention is intended merely to description tool
The purpose of the embodiment of body, it is not intended that in the limitation present invention.
Herein, unless there are particularly illustrating, the content of all raw materials is all mass percentage；Room temperature refers to 20 DEG C
~30 DEG C.
A kind of wax removing agent of embodiment, including preceding cleaning solution and rear cleaning solution, wherein according to mass percentage meter,
The raw material of cleaning solution includes: before preparing
The raw material of cleaning solution includes: after preparation
It should be noted that above-mentioned dodecyl sodium sulfate can be by neopelex or Disodium sulfosuccinate
Substitution；Above-mentioned cocoanut fatty acid diethanolamide can be substituted by coconut oil fatty acid monoethanolamide.
Prove through experiment test: the paraffin removal ability of above-mentioned wax removing agent is strong, heavy metal in waste liquid content is low.
In one of the embodiments, gasoline in 90# gasoline, 92# gasoline, 95# gasoline and 98# gasoline at least one
Kind；And/or vegetable oil is selected from least one of rapeseed oil, peanut oil, soybean oil, olive oil and sunflower oil；And/or it is poly-
Propylene glycol is selected from least one of polypropylene glycol -200, polypropylene glycol -400 and polypropylene glycol -600；And/or fatty alcohol
Polyoxyethylene ether is in fatty alcohol polyoxyethylene ether -7, fatty alcohol polyoxyethylene ether -9 and fatty alcohol polyoxyethylene ether -10
It is at least one and/or, White Mineral Oil is selected from 15# cosmetics-stage White Mineral Oil, 26# cosmetics-stage White Mineral Oil and the white mine of 68# cosmetics-stage
At least one of oil.
The preparation method of the wax removing agent of one embodiment, includes the following steps:
Step S100: according to mass percentage meter, by 18%~25% petroleum ether, 20%~30% kerosene,
15%~30% gasoline, 8%~16% vegetable oil, 5%~10% dehydrated alcohol, 5%~10% isopropanol and 2%
~8% polypropylene glycol mixing, obtains preceding cleaning solution；
Step S200: by 8%~12% neopelex, 6%~10% fatty alcohol polyoxyethylene ether sulphur
Sour sodium, 5%~10% fatty alcohol polyoxyethylene ether, 1%~3% cocoanut fatty acid diethanolamide, 5%~10%
Dehydrated alcohol, 1%~5% White Mineral Oil and the mixing of 1%~5% sodium hydroxide, obtain rear cleaning solution.
The specific steps (i.e. step S100) for preparing above-mentioned preceding cleaning solution in one of the embodiments, include:
At room temperature, control speed is that 100r/min~120r/min is stirred, and makes above-mentioned petroleum ether, above-mentioned kerosene, above-mentioned
Gasoline, above-mentioned vegetable oil, above-mentioned dehydrated alcohol, above-mentioned isopropanol and above-mentioned polypropylene glycol are uniformly mixed, and obtain preceding cleaning solution.
Prepare in one of the embodiments, it is above-mentioned after the specific steps (i.e. step S200) of cleaning solution include:
Step S220: the sodium hydroxide described in deionized water dissolving obtains the aqueous solution of sodium hydroxide；
Step S240: by the neopelex, the sodium sulfate of polyethenoxy ether of fatty alcohol, the fatty alcohol
Polyoxyethylene ether and the cocoanut fatty acid diethanolamide are mixed with the aqueous solution of the sodium hydroxide, obtain the first mixing
Liquid；
Step S260: being added the dehydrated alcohol and the White Mineral Oil into first mixed liquor, stands to after clarifying,
Obtain rear cleaning solution.
The above-mentioned specific steps being dissolved into the sodium hydroxide in above-mentioned ionized water in one of the embodiments,
(i.e. step S220) includes: at room temperature, with the agitating deionized water of the speed of 100r/min~120r/min, while stirring
Described 1%~5% sodium hydroxide is added into the deionized water.
In one of the embodiments, by neopelex, sodium sulfate of polyethenoxy ether of fatty alcohol, poly alkyl alcohol
Ethylene oxide ether and cocoanut fatty acid diethanolamide are dissolved into specific steps (the i.e. step in the aqueous solution of sodium hydroxide
It S240) include: to heat the aqueous solution of above-mentioned sodium hydroxide to 40 DEG C~50 DEG C；Then with the speed of 300r/min~500r/min
Under conditions of degree stirring, neopelex, fatty alcohol polyoxy second are added in the aqueous solution of sodium hydroxide after the heating
Alkene ether sodium sulfate, fatty alcohol polyoxyethylene ether and cocoanut fatty acid diethanolamide.
Dehydrated alcohol is added in one of the embodiments, and White Mineral Oil (is walked to the specific steps in the first mixed liquor
Rapid S260) it include: that anhydrous second is added in the first mixed liquor under conditions of the speed stirring with 300r/min~500r/min
Pure and mild White Mineral Oil stands to after clarifying, obtains rear cleaning solution.
As shown in Figure 1, the minimizing technology of the wax of an embodiment, includes the following steps:
Step S320: it is first washed with preceding cleaning solution and wipes container to be washed, wherein according to mass percentage meter, preceding cleaning solution packet
Include petroleum ether 18%~25%, kerosene 20%~30%, gasoline 15%~30%, vegetable oil 8%~16%, dehydrated alcohol 5%
~10%, isopropanol 5%~10% and polypropylene glycol 2%~8%；
It should be noted that being mainly used for the slop wax cleaned on container wall to be washed using above-mentioned preceding cleaning solution, wherein stone
Oily ether, kerosene and gasoline mainly provide aliphatic hydrocarbon and cycloalkane, and vegetable oil mainly provides higher fatty acids and high-grade fatty ester,
The two achievees the purpose that remove slop wax for dissolving each other with the component in slop wax；Dehydrated alcohol and isopropanol are for removing in slop wax
Polar compound；Polypropylene glycol primarily serves lubrication, increase-volume and the effect of defoaming.
Step S330: and then washed with rear cleaning solution and wipe above-mentioned container to be washed, wherein it is rear clear according to mass percentage meter
Washing lotion includes neopelex 8%~12%, sodium sulfate of polyethenoxy ether of fatty alcohol 6%~10%, fatty alcohol polyoxy
Vinethene 5%~10%, cocoanut fatty acid diethanolamide 1%~3%, dehydrated alcohol 5%~10%, White Mineral Oil 1%~
5% and sodium hydroxide 1%~5%；
It should be noted that being mainly used for cleaning on wall remaining cere and remaining preceding clear using cleaning solution after above-mentioned
Washing lotion, wherein dodecyl sodium sulfate, sodium sulfate of polyethenoxy ether of fatty alcohol, fatty alcohol polyoxyethylene ether and coconut oil fat
Sour diglycollic amide has the function of decontamination, emulsification, foaming as surfactant, and four synergy can be preferably clear
Wash remaining cere and preceding cleaning solution.
Step S340: above-mentioned container to be washed is cleaned with 80 DEG C~100 DEG C of water again.
In one of the embodiments, it is above-mentioned with preceding cleaning solution wash the step of wiping container to be washed (i.e. step S320) it
Before, include the steps that impregnating above-mentioned container 5min~10min S310 to be washed with 80 DEG C~100 DEG C of water；And/or with 80
DEG C~100 DEG C of water the step of cleaning above-mentioned container to be washed (i.e. step S340) after, further include being surpassed with 50 DEG C~70 DEG C of water
Sound wave cleans the step S350 of the container to be washed.
It should be noted that above-mentioned steps S310 and step S350 are additional step, and not necessarily the step of, clearly
Hot-water soak (i.e. step S310) before washing is provided to guarantee with the ultrasonic cleaning (i.e. step S350) after water cleaning
It is more time saving more efficient to clean slop wax.
It is proved through experiment test: removing the slop wax on container to be washed using above-mentioned wax removing agent according to above-mentioned steps, cleaning is more
Clean thorough, the heavy metal in waste liquid content after cleaning is low.
The following are specific embodiment parts:
Embodiment 1
The preparation step of the wax removing agent of the present embodiment is as follows:
(1) preparation step of cleaning solution before:
At room temperature, control speed is 100r/min stirring, makes 18.7% petroleum ether, 28.9% kerosene, 19.4%
92# gasoline, 15.6% rapeseed oil, 9.5% dehydrated alcohol, 5.6% isopropanol and 2.3% polypropylene glycol -200 it is mixed
It closes, obtains preceding cleaning solution.
(2) preparation step of cleaning solution afterwards:
1) at room temperature, with the deionized water of the stirring 61.2% of the speed of 100r/min, stirring while, is added 1.6%
Sodium hydroxide into above-mentioned deionized water, obtain the aqueous solution of sodium hydroxide.
2) aqueous solution of above-mentioned sodium hydroxide is heated to 40 DEG C；Then in the condition of the speed stirring with 300r/min
Under, 11.7% neopelex, 6.4% fatty alcohol polyoxy are added in the aqueous solution of sodium hydroxide after the heating
Ethylene ether sodium sulfate, 9.8% fatty alcohol polyoxyethylene ether -9 and 2.8% cocoanut fatty acid diethanolamide obtain
One mixed liquor.
3) under conditions of with the stirring of the speed of 300r/min, be added in the first mixed liquor 5.2% dehydrated alcohol and
1.3% 26# cosmetics-stage White Mineral Oil stands to after clarifying, obtains rear cleaning solution.
The slop wax on container to be washed is removed using the wax removing agent that embodiment 1 is prepared:
1) the container 5min to be washed for being stained with slop wax is impregnated with 80 DEG C of water；
2) it is washed and is wiped container 3 times to be washed with preceding cleaning solution；
3) it is washed with rear cleaning solution and wipes above-mentioned container to be washed 3 times；
4) above-mentioned container to be washed is cleaned 3 times with 80 DEG C of water；
5) setting water temperature is 50 DEG C, cleans above-mentioned container 5min to be washed with supersonic wave cleaning machine, dries.
Embodiment 2
The preparation step of the wax removing agent of the present embodiment is as follows:
(1) preparation step of cleaning solution before:
At room temperature, control speed is 110r/min stirring, makes 24.3% petroleum ether, 20.6% kerosene, 29.7%
95# gasoline, 8.7% peanut oil, 5.7% dehydrated alcohol, 5.8% isopropanol and 5.2% polypropylene glycol -400 it is mixed
It closes, obtains preceding cleaning solution.
(2) preparation step of cleaning solution afterwards:
1) at room temperature, with the deionized water of the stirring 59.7% of the speed of 110r/min, stirring while, is added 4.6%
Sodium hydroxide into above-mentioned deionized water, obtain the aqueous solution of sodium hydroxide.
2) aqueous solution of above-mentioned sodium hydroxide is heated to 45 DEG C；Then in the condition of the speed stirring with 400r/min
Under, 8.2% neopelex, 9.9% fatty alcohol polyoxy are added in the aqueous solution of sodium hydroxide after the heating
Ethylene ether sodium sulfate, 5.4% fatty alcohol polyoxyethylene ether -7 and 1.2% cocoanut fatty acid diethanolamide obtain
One mixed liquor.
3) under conditions of with the stirring of the speed of 400r/min, be added in the first mixed liquor 6.2% dehydrated alcohol and
4.8% 15# cosmetics-stage White Mineral Oil stands to after clarifying, obtains rear cleaning solution.
The slop wax on container to be washed is removed using the wax removing agent that embodiment 2 is prepared:
1) the container 5min to be washed for being stained with slop wax is impregnated with 90 DEG C of water；
2) it is washed and is wiped container 2 times to be washed with preceding cleaning solution；
3) it is washed with rear cleaning solution and wipes above-mentioned container to be washed 2 times；
4) above-mentioned container to be washed is cleaned 2 times with 90 DEG C of water；
5) setting water temperature is 60 DEG C, cleans above-mentioned container 4min to be washed with supersonic wave cleaning machine, dries.
Embodiment 3
The preparation step of the wax removing agent of the present embodiment is as follows:
(1) preparation step of cleaning solution before:
At room temperature, control speed is 110r/min stirring, makes 22.6% petroleum ether, 24.3% kerosene, 15.2%
98# gasoline, 13.6% soybean oil, 7.2% dehydrated alcohol, 9.5% isopropanol and 7.6% polypropylene glycol -600 it is mixed
It closes, obtains preceding cleaning solution.
(2) preparation step of cleaning solution afterwards:
1) at room temperature, with the deionized water of the stirring 54.9% of the speed of 110r/min, stirring while, is added 2.8%
Sodium hydroxide into above-mentioned deionized water, obtain the aqueous solution of sodium hydroxide.
2) aqueous solution of above-mentioned sodium hydroxide is heated to 45 DEG C；Then in the condition of the speed stirring with 400r/min
Under, 10.5% neopelex, 8.8% fatty alcohol polyoxy are added in the aqueous solution of sodium hydroxide after the heating
Ethylene ether sodium sulfate, 7.9% fatty alcohol polyoxyethylene ether -10 and 2.3% cocoanut fatty acid diethanolamide obtain
One mixed liquor.
3) under conditions of with the stirring of the speed of 400r/min, be added in the first mixed liquor 9.6% dehydrated alcohol and
3.2% 68# cosmetics-stage White Mineral Oil stands to after clarifying, obtains rear cleaning solution.
The slop wax on container to be washed is removed using the wax removing agent that embodiment 3 is prepared:
1) the container 5min to be washed for being stained with slop wax is impregnated with 100 DEG C of water；
2) it is washed and is wiped container 3 times to be washed with preceding cleaning solution；
3) it is washed with rear cleaning solution and wipes above-mentioned container to be washed 3 times；
4) above-mentioned container to be washed is cleaned 3 times with 100 DEG C of water；
5) setting water temperature is 70 DEG C, cleans above-mentioned container 3min to be washed with supersonic wave cleaning machine, dries.
Embodiment 4
The preparation step of the wax removing agent of the present embodiment is as follows:
(1) preparation step of cleaning solution before:
At room temperature, control speed is 120r/min stirring, makes 23.5% petroleum ether, 22.8% kerosene, 24.7%
92# gasoline, 11.4% sunflower oil, 6.3% dehydrated alcohol, 8.1% isopropanol and 3.2% polypropylene glycol -200
Mixing, obtains preceding cleaning solution.
(2) preparation step of cleaning solution afterwards:
1) at room temperature, with the deionized water of the stirring 55.3% of the speed of 120r/min, stirring while, is added 2.3%
Sodium hydroxide into above-mentioned deionized water, obtain the aqueous solution of sodium hydroxide.
2) aqueous solution of above-mentioned sodium hydroxide is heated to 50 DEG C；Then in the condition of the speed stirring with 500r/min
Under, 11.3% neopelex, 10.8% poly alkyl alcohol are added in the aqueous solution of sodium hydroxide after the heating
Ethylene oxide ether sodium sulfate, 8.6% fatty alcohol polyoxyethylene ether -9 and 2.6% cocoanut fatty acid diethanolamide, obtain
First mixed liquor.
3) under conditions of with the stirring of the speed of 500r/min, be added in the first mixed liquor 7.3% dehydrated alcohol and
1.8% 26# cosmetics-stage White Mineral Oil stands to after clarifying, obtains rear cleaning solution.
The slop wax on container to be washed is removed using the wax removing agent that embodiment 4 is prepared:
1) the container 5min to be washed for being stained with slop wax is impregnated with 100 DEG C of water；
2) it is washed and is wiped container 3 times to be washed with preceding cleaning solution；
3) it is washed with rear cleaning solution and wipes above-mentioned container to be washed 3 times；
4) above-mentioned container to be washed is cleaned 3 times with 100 DEG C of water；
5) setting water temperature is 50 DEG C, cleans above-mentioned container 5min to be washed with supersonic wave cleaning machine, dries.
The following table 1 is the mass percentage table of each raw material of the wax removing agent of 1~embodiment of embodiment 4.
The mass percentage table of each raw material in each embodiment of table 1
| The raw material of preceding cleaning solution | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Petroleum ether (%) | 18.7 | 24.3 | 22.6 | 23.5 |
| Kerosene (%) | 28.9 | 20.6 | 24.3 | 22.8 |
| 92# gasoline (%) | 19.4 | / | / | 24.7 |
| 95# gasoline (%) | / | 29.7 | / | / |
| 98# gasoline (%) | / | / | 15.2 | / |
| Rapeseed oil (%) | 15.6 | / | / | / |
| Peanut oil (%) | / | 8.7 | / | / |
| Soybean oil (%) | / | / | 13.6 | / |
| Sunflower oil (%) | / | / | / | 11.4 |
| Dehydrated alcohol (%) | 9.5 | 5.7 | 7.2 | 6.3 |
| Isopropanol (%) | 5.6 | 5.8 | 9.5 | 8.1 |
| Polypropylene glycol -200 (%) | 2.3 | / | / | 3.2 |
| Polypropylene glycol -400 (%) | / | 5.2 | / | / |
| Polypropylene glycol -600 (%) | / | / | 7.6 | / |
| The raw material of cleaning solution afterwards | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Neopelex (%) | 11.7 | 8.2 | 10.5 | 11.3 |
| Sodium sulfate of polyethenoxy ether of fatty alcohol (%) | 6.4 | 9.9 | 8.8 | 10.8 |
| Fatty alcohol polyoxyethylene ether -7 (%) | / | 5.4 | / | / |
| Fatty alcohol polyoxyethylene ether -9 (%) | 9.8 | / | / | 8.6 |
| Fatty alcohol polyoxyethylene ether -10 (%) | / | / | 7.9 | / |
| Cocoanut fatty acid diethanolamide (%) | 2.8 | 1.2 | 2.3 | 2.6 |
| Dehydrated alcohol (%) | 5.2 | 6.2 | 9.6 | 7.3 |
| 15# White Mineral Oil (%) | / | 4.8 | / | / |
| 26# White Mineral Oil (%) | 1.3 | / | / | 1.8 |
| 68# White Mineral Oil (%) | / | / | 3.2 | / |
| Sodium hydroxide (%) | 1.6 | 4.6 | 2.8 | 2.3 |
| Deionized water (%) | 61.2 | 59.7 | 54.9 | 55.3 |
Comparative example 1
The wax removing agent of comparative example 1 is potassium bichromate pickling solution commonly used in the trade, wherein preceding cleaning solution: mass percentage
Respectively 50% dehydrated alcohol and 50% methylene chloride；Cleaning solution afterwards: mass percentage is respectively 8% dichromic acid acid potassium pickling
Liquid, 24.5% concentrated sulfuric acid (concentration 98%) and 67.5% distilled water.
The slop wax on container to be washed is removed using the wax removing agent that embodiment 4 is prepared:
(1) after taking suitable preceding cleaning solution to be stained with the container 30min to be washed of slop wax, container is wiped with hairbrush, is poured out anhydrous
Ethyl alcohol and methylene chloride mixed liquor；
(2) after taking appropriate rear cleaning solution to impregnate above-mentioned container 15min to be washed, container, recycling dichromic acid acid are wiped with hairbrush
Then potassium pickling solution is used clear water eluant container, is dried.
Paraffin removal effect and the test of waste liquid content of beary metal:
Paraffin removal effect and a waste liquid huge sum of money are carried out to the container that the above-mentioned wax removing agent with Examples 1 to 4 and comparative example 1 cleaned
Belong to content measuring.
Test method: whether the vessel surface that detects by an unaided eye has remaining grease stain and wax stain, and touching vessel surface with hand is
No smooth pieces.The detection reference of waste liquid content of beary metal: standard " HJBZ 8-1999 detergent ".
Test result: as the paraffin removal effect and waste liquid content of beary metal of the wax removing agent of Examples 1 to 44 and comparative example 1 compare
Shown in table (table 2).
The paraffin removal effect of the wax removing agent of 2 Examples 1 to 4 of table and comparative example 1 and useless drop content of beary metal contrast table
Have known to upper table: compared with comparative example 1, being removed on container to be washed using the wax removing agent that Examples 1 to 4 is prepared
Slop wax, washed on container without grease stain residual, wax stain residual, clean surface is smooth and heavy metal in waste liquid content is extremely low.Therefore
It is found that the paraffin removal ability of above-mentioned wax removing agent is strong, heavy metal in waste liquid content is low.
Each technical characteristic of embodiment described above can be combined arbitrarily, for simplicity of description, not to above-mentioned reality
It applies all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited
In contradiction, all should be considered as described in this specification.
The embodiments described above only express several embodiments of the present invention, and the description thereof is more specific and detailed, but simultaneously
It cannot therefore be construed as limiting the scope of the patent.It should be pointed out that coming for those of ordinary skill in the art
It says, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to protection of the invention
Range.Therefore, the scope of protection of the patent of the invention shall be subject to the appended claims.
Claims (10)
1. a kind of wax removing agent, which is characterized in that including preceding cleaning solution and rear cleaning solution, wherein according to mass percentage meter, system
Include: for the raw material of the preceding cleaning solution
Prepare it is described after the raw material of cleaning solution include:
2. wax removing agent according to claim 1, which is characterized in that the gasoline is selected from 90# gasoline, 92# gasoline, 95# vapour
At least one of oil and 98# gasoline；And/or the vegetable oil is selected from rapeseed oil, peanut oil, soybean oil, olive oil and sunflower
At least one of seed oil；And/or the polypropylene glycol is selected from polypropylene glycol -200, polypropylene glycol -400 and polypropylene glycol -
At least one of 600；And/or the fatty alcohol polyoxyethylene ether is selected from fatty alcohol polyoxyethylene ether -7, fatty alcohol polyoxy second
At least one of alkene ether -9 and fatty alcohol polyoxyethylene ether -10；And/or the White Mineral Oil is selected from the white mine of 15# cosmetics-stage
At least one of oil, 26# cosmetics-stage White Mineral Oil and 68# cosmetics-stage White Mineral Oil.
3. a kind of preparation method of wax removing agent, which comprises the steps of:
According to mass percentage meter, by described 18%~25% petroleum ether, described 20%~30% kerosene, described 15%
~30% gasoline, described 8%~16% vegetable oil, described 5%~10% dehydrated alcohol, described 5%~10% it is different
Propyl alcohol and described 2%~8% polypropylene glycol mixing, obtain preceding cleaning solution；
By described 8%~12% neopelex, described 6%~10% sodium sulfate of polyethenoxy ether of fatty alcohol,
Described 5%~10% fatty alcohol polyoxyethylene ether, described 1%~3% cocoanut fatty acid diethanolamide, described 5%
~10% dehydrated alcohol, described 1%~5% White Mineral Oil and the mixing of described 1%~5% sodium hydroxide, are cleaned after obtaining
Liquid.
4. the preparation method of wax removing agent according to claim 3, which is characterized in that prepare the specific step of the preceding cleaning solution
It suddenly include: at room temperature, to control speed as 100r/min~120r/min stirring, make the petroleum ether, the kerosene, the vapour
Oily, the described vegetable oil, the dehydrated alcohol, the isopropanol and the polypropylene glycol are uniformly mixed, and obtain preceding cleaning solution.
5. the preparation method of wax removing agent according to claim 3, which is characterized in that prepare the specific step of the rear cleaning solution
Suddenly include:
The sodium hydroxide described in the deionized water dissolving obtains the aqueous solution of sodium hydroxide；
By the neopelex, the sodium sulfate of polyethenoxy ether of fatty alcohol, the fatty alcohol polyoxyethylene ether and
The cocoanut fatty acid diethanolamide is mixed with the aqueous solution of the sodium hydroxide, obtains the first mixed liquor；
The dehydrated alcohol and the White Mineral Oil is added into first mixed liquor, stands to after clarifying, obtains rear cleaning solution.
6. the preparation method of wax removing agent according to claim 5, which is characterized in that described to be dissolved into the sodium hydroxide
Specific steps in the deionized water include: at room temperature, to go described in the stirring of the speed of 100r/min~120r/min
Described 1%~5% sodium hydroxide is added into the deionized water in ionized water, stirring while.
7. the preparation method of wax removing agent according to claim 5, which is characterized in that described by the dodecyl benzene sulfonic acid
Sodium, the sodium sulfate of polyethenoxy ether of fatty alcohol, the fatty alcohol polyoxyethylene ether and the coco-nut oil fatty acid diethanol acyl
The specific steps that amine is dissolved into the aqueous solution of the sodium hydroxide include: heat the aqueous solution of the sodium hydroxide to 40 DEG C~
50℃；Then under conditions of the speed stirring with 300r/min~500r/min, the water of the sodium hydroxide after the heating
The neopelex, the sodium sulfate of polyethenoxy ether of fatty alcohol, the aliphatic alcohol polyethenoxy are added in solution
Ether and the cocoanut fatty acid diethanolamide.
8. the preparation method of wax removing agent according to claim 5, which is characterized in that described that the dehydrated alcohol and institute is added
State White Mineral Oil to the specific steps in first mixed liquor include: with the item of the speed of 300r/min~500r/min stirring
Under part, the dehydrated alcohol and the White Mineral Oil are added in first mixed liquor, stands to after clarifying, obtains described rear clear
Washing lotion.
9. a kind of minimizing technology of wax, which comprises the steps of:
It is first washed with preceding cleaning solution and wipes container to be washed, wherein according to mass percentage meter, the preceding cleaning solution includes petroleum ether
18%~25%, kerosene 20%~30%, gasoline 15%~30%, vegetable oil 8%~16%, dehydrated alcohol 5%~10%, different
Propyl alcohol 5%~10% and polypropylene glycol 2%~8%；
Then it is washed with rear cleaning solution and wipes the container to be washed, wherein according to mass percentage meter, the rear cleaning solution includes ten
Dialkyl benzene sulfonic acids sodium 8%~12%, sodium sulfate of polyethenoxy ether of fatty alcohol 6%~10%, fatty alcohol polyoxyethylene ether 5%~
10%, cocoanut fatty acid diethanolamide 1%~3%, dehydrated alcohol 5%~10%, White Mineral Oil 1%~5% and hydroxide
Sodium 1%~5%；
The container to be washed is cleaned with 80 DEG C~100 DEG C of water again.
10. the minimizing technology of wax according to claim 9, which is characterized in that wipe appearance to be washed in described washed with preceding cleaning solution
Before the step of device, further include the steps that impregnating the container 5min~10min to be washed with 80 DEG C~100 DEG C of water；And/or
It further include clear with 50 DEG C~70 DEG C of water ultrasonic wave after the step of cleaning the container to be washed with 80 DEG C~100 DEG C of water
The step of washing the container to be washed.
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| CN112808684A (en) * | 2020-12-30 | 2021-05-18 | 蓝思科技股份有限公司 | Method for dewaxing nickel-plated metal product |
| CN117625313A (en) * | 2023-12-05 | 2024-03-01 | 广州芙莉莱化妆品有限公司 | Cleaning agent for water-in-oil foundation cosmetics and preparation and cleaning methods thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110477441A (en) * | 2019-07-16 | 2019-11-22 | 河南中烟工业有限责任公司 | A kind of additive, paraffin removal solvent and minimizing technology removing tobacco leaf wax |
| CN112808684A (en) * | 2020-12-30 | 2021-05-18 | 蓝思科技股份有限公司 | Method for dewaxing nickel-plated metal product |
| CN112808684B (en) * | 2020-12-30 | 2022-05-03 | 蓝思科技股份有限公司 | Method for dewaxing nickel-plated metal product |
| CN117625313A (en) * | 2023-12-05 | 2024-03-01 | 广州芙莉莱化妆品有限公司 | Cleaning agent for water-in-oil foundation cosmetics and preparation and cleaning methods thereof |
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| CN109439460B (en) | 2020-09-08 |
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