CN106479759A - A kind of color changing cleansing composition - Google Patents
A kind of color changing cleansing composition Download PDFInfo
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- CN106479759A CN106479759A CN201510540796.4A CN201510540796A CN106479759A CN 106479759 A CN106479759 A CN 106479759A CN 201510540796 A CN201510540796 A CN 201510540796A CN 106479759 A CN106479759 A CN 106479759A
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- Prior art keywords
- color
- cleaning system
- changing composition
- acid
- composition cleaning
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Abstract
The invention discloses a kind of color-changing composition cleaning system, contain by weight percentage：The pH perception strain agent of 0.0001%-0.01%；The acid of 1%-20%；The solvent of 0.1%-10%；The viscosity of 0%-5% optimizes agent；The clarity regulator of 0%-1%；And the water of surplus.
Description
Technical field
The present invention relates to domestic chemicals field is and in particular to a kind of change that can be applicable to hard-surface cleaning
Colour cell compound.
Background technology
The main application of civilian hard surface cleaner has kitchen, toilet, door and window, furniture, floor etc.,
Material includes glass, pottery, plastics, paint, metal etc..Civilian cleaning agent requires simple to operate, to making
User is friendly, can not damage by cleaning object during decontamination.
Mostly civilian hard surface cleaner is liquid form, and mostly is for the cleaning agent of different dirt compositions
Specially thing is special.
Hard surface cleaner for kitchen use can be divided into dish washing detergent and kitchen grease cleaning agent.Wherein, kitchen
Grease cleaning agent is mainly in order to clean oil-based polymer, carbon distribution, dust.Oil-based polymer is mainly in culinary art
During evaporation edible oil in olein and linoleic acid fat unsaturated double-bond oxygen at high temperature
Change the network polymerss being cross-linked to form, and carbon distribution is then the result of further oxidative dehydrogenation carbonization.
Use in toilet hard surface cleaner, not only needs the ability removing grease, soap scum, calcium are dirty, and part is produced
Product also need to have functions that anti-antibacterial.Cleaning agent is generally acid system, it is possible to use acid have hydrochloric acid,
Pyrovinic acid, sulfamic acid, citric acid etc., the acid of high-load can remove rapidly spot.But except avoiding
Topple over or course of reaction in damage to human body, medicated clothing, it is also contemplated that acid can cause pottery after life-time service
Corrosion.It is that such product needs to accomplish to ensure to improve the safety of product while decontamination effect in use.
Bathroom detergent mainly clean ceramic tile, pottery, minute surface, plastics, rustless steel coating surface calcium dirt,
Soap scum.Bathroom detergent is usually acidic cleaner, and the acid of employing has pyrovinic acid, sulfamic acid, Fructus Citri Limoniae
Acid, lactic acid etc..Bathroom require cleaning after, light, do not stay washmarking.
Glass cleaner mainly cleans the light soil such as water spots on glass surface, fingerprint and dust, using low
Content surfactant solution can remove.In addition to meeting decontamination demand, after glass cleaner also requires cleaning
Residue is few, does not form streak marks, keeps the high grade of transparency of glass surface.
Furniture, floor cleaning agent, because furniture, floor surface have on coating, paint, metal, decorative panel
Have polychloroethylene film, polypropylene screen, amino resins etc., such cleaning agent is to avoid material is damaged,
With neutral or faintly acid system.
By the adjustment to existing hard surface cleaner, or the surface work adding appropriate specific function in system
Property agent, it is possible to obtain additional function, effectively improves the combination property of product.As added alkyl polyglucoside, alcohol ether
Carboxylate can reduce the zest to skin for the cleaning agent；The pH value of reasonable adjusting formula, reduce solvent
Usage amount can improve the safety of product；Add Shuangzi ester based quaternary ammonium salt, end capped polyether, isomery alcohol ether etc.
The performance of product can be improved.These special surfactants are more excellent than conventional surfactant performance,
Can meet using safety, ecological protection and carry efficient composite request.
Though there being various types of hard surface cleaners in prior art, and it is directed to how to improve hard table cleaning agent
Use safety, ecological protection and improve efficiency aspect constantly improve upgrading, but find no and be specifically designed for
While ensureing using safety, ecological protection and improve efficiency, the cleaning to crust can be taken into account just again
The considering of profit.The invention reside in seeking how to enable the convenience to hard-surface cleaning.
For hard-surface cleaning, generally require and cleaning class product is coated with advance or is sprayed at its surface, allow clear
Clean class product is scrubbed after resident effect certain time on crust again, can be only achieved good clean effect.
Wherein resident time length can directly affect the effect of cleaning, and often during actual cleaning, stays
The length staying the time can be different and have larger difference based on the use habit that varies with each individual, thus for when brushing
Wash, time point does not have ocular and clear judge reference.The convenience to hard-surface cleaning sought by the present invention
Consider and be namely based on how to judge residence time to realize.Therefore, the present invention provides one kind first
Compositionss, the problem that said composition energy effectively solving hard-surface cleaning brushing time point cannot judge.
Content of the invention
It is an object of the invention to provide a kind of color-changing composition for hard-surface cleaning, this combination
Thing meets water variable color in use, and thereby indicates that cleaning process suitable action time.The present invention
Compositionss can also give consumer certain decontamination perception.
Therefore, in one aspect of the invention, there is provided a kind of color-changing composition cleaning system, described change
Colour cell compound cleaning system contains by weight percentage：
Remaining is water.
In the present invention, pH perception strain agent refers to can assume the examination of different colours at various ph values
Agent.In general, existing technology application is substantially all in analytical chemistry field, also it is not applied to hard
The application of the pH perception strain agent of surface cleaning.In one preferred embodiment, pH perception should
Become agent to be selected from：One of thymol blue, methyl yellow and methyl orange or two kinds.At one most preferably
In embodiment, pH perception strain agent is thymol blue.
In an embodiment of the invention, with the gross weight meter of color-changing composition cleaning system, institute
State the pH perception strain agent that cleaning system comprises 0.0001-0.01%.In one preferred embodiment,
With the gross weight meter of color-changing composition cleaning system, described cleaning system comprises the pH of 0.0005-0.01%
Perception strain agent.In one preferred embodiment, with the gross weight of color-changing composition cleaning system
Meter, described cleaning system comprises the pH perception strain agent of 0.005-0.01%.
Solvent is used for dissolving pH perception strain agent.In general, solvent can be in alcohol ethers solvent.?
In preferred embodiment, solvent is selected from：One kind of propylene glycol, glycerol and butyl or many
Kind.
In an embodiment of the invention, with the gross weight meter of color-changing composition cleaning system, institute
State the solvent that cleaning system comprises 0.1-10%.In one preferred embodiment, with color-changing composition
The gross weight meter of cleaning system, described cleaning system comprises the solvent of 1-10%.Preferably real at one
Apply in mode, with the gross weight meter of color-changing composition cleaning system, described cleaning system comprises 5-10%
Solvent.
Adopt acid in the present invention as cleaning agent.In a preferred embodiment, the acid of employing is selected from：
One or more of hydrochloric acid, phosphoric acid, citric acid, oxalic acid, formic acid, sulfamic acid and pyrovinic acid.
In an embodiment of the invention, with the gross weight meter of color-changing composition cleaning system, institute
State the acid that cleaning system comprises 1-20%.In one preferred embodiment, clear with color-changing composition
The gross weight meter of clean system, described cleaning system comprises the acid of 1-10%.In a preferred embodiment party
In formula, with the gross weight meter of color-changing composition cleaning system, described cleaning system comprises the acid of 3-10%.
In one preferred embodiment of the invention, described pH perception strain agent with sour weight ratio is
1:(2×105) to 1:100.
Viscosity optimizes the reagent that agent refers to make system viscosity increase.In a preferred embodiment, glue
Degree optimizes agent and is selected from：Ethoxylized fatty alcohol and one or more of ethoxylated fatty amine.At one
Most preferably in embodiment, it is to be purchased from bar with trade name ARLYPON VPC that described viscosity optimizes agent
The ethoxylized fatty alcohol of Si Fu company and the mixture of ethoxylated fatty amine.
In an embodiment of the invention, with the gross weight meter of color-changing composition cleaning system, institute
State the viscosity optimization agent that cleaning system comprises 0-5%.In one preferred embodiment, to become colour cell
The gross weight meter of compound cleaning system, the viscosity that described cleaning system comprises 1-5% optimizes agent.At one
In preferred embodiment, with the gross weight meter of color-changing composition cleaning system, described cleaning system bag
Viscosity containing 2-5% optimizes agent.
Clarity regulator can make system become emulsion form, increases identification.In a preferred embodiment,
Clarity regulator is styrene-acrylic emulsion.In a most preferred embodiment, described clarity is adjusted
Agent is the styrene-acrylic emulsion being purchased from the Dow Chemical Company with trade name Acusol OP305.
In an embodiment of the invention, with the gross weight meter of color-changing composition cleaning system, institute
State the clarity regulator that cleaning system comprises 0-1%.In one preferred embodiment, with variable color
The gross weight meter of compositionss cleaning system, described cleaning system comprises the clarity regulator of 0.5-1%.
The preparation technology of color-changing composition cleaning system of the present invention includes：Dissolving acid in water, adds viscous
Degree optimizes agent stirring and dissolving, adds clarity regulator and stirs.PH perception strain agent solvent
Dissolving (for example, being made into 0.1% solution), is then proportionally added into, stirs.
In the present invention, water is preferably deionized water.
Color-changing composition cleaning system of the present invention can be used for hard-surface cleaning, preferably bathroom hard-surface cleaning,
The toilet cleaner of more preferably detergent of closet.Basic using method includes will be hard in the bathroom having water for product extrusion
Surface, meets liquid slowly variable color after water, and that is, prompting dirt is disintegrated and finished, and then scrubs.
Therefore, in another aspect of this invention, there is provided a kind of method of cleaning of hard surfaces, described side
Method includes：
A) will by weight percentage, the color-changing composition cleaning system containing following component has been applied to
The crust of water：
Remaining is water,
B) scrubbed after color-changing composition cleaning system variable color.
The color-changing composition cleaning system of the present invention can be prepared into the toilet cleaner for detergent of closet, packaging
As common toilet cleaner, basic using method is to squeeze mouth upwards, gently extrudes a circle along toilet inwall, makes
Toilet cleaner uniform fold is in water closet pan undercut and inwall surrounding.The slowly variable color of liquid in water seal, that is, point out
Dirt is disintegrated and is finished, and then scrubs.
Therefore, a kind of another aspect of the present invention, there is provided cleaning toilet liquid product for detergent of closet,
Described cleaning toilet liquid product includes the color-changing composition cleaning system of the present invention and accommodates described color shift combinations
The packaging of thing cleaning system.
Brief description
Fig. 1 shows the variable color of the color-changing composition cleaning system cleaning closestool of the present invention using embodiment 11
Figure.
Specific embodiment
Compared with cleaning system existing with this area, the color-changing composition cleaning system of the present invention can lead to
Cross product colour change, allow consumer can perceive the process of cleaning action.Meanwhile, using the present invention's
Color-changing composition cleaning system, user can easily judge the time point scrubbed, thus producing specially
Industry sense and the association of technology sense.Therefore, the color-changing composition cleaning system of the present invention will be answered in business
With middle acquisition immense success.
The present invention is expanded on further with reference to specific embodiment.It should be appreciated, however, that these are real
Apply example to be merely to illustrate the present invention and be not meant to limit the scope of the invention.Do not note in the following example
The test method of bright actual conditions, generally according to normal condition, or according to the bar proposed by manufacturer
Part.Unless otherwise stated, all of percentage ratio and number be by weight.
Embodiment 1-9：The preparation of pH perception strain agent solution
According to shown in table 1, weighing a certain amount of pH perception strain agent, it is made into the dissolving of alcohol ethers solvent
0.1% solution, standby.
Table 1
Embodiment 10-20：The preparation of color-changing composition cleaning system of the present invention
According to shown in table 2-3, prepare the color-changing composition of embodiment 10-20.It is specifically included in molten in water
Solution acid, adds viscosity to optimize agent stirring and dissolving, adds clarity regulator and stir.PH perceives
Strain agent is dissolved with solvent as described in embodiment 1-9, is made into 0.1% solution.Then, according to table 2-3
Shown be proportionally added into, stir, standby.
Table 2
aRepresent ethoxylized fatty alcohol and the ethoxylated fat being purchased from BASF AG with trade name ARLYPON VPC
The mixture of amine.
bRepresent the styrene-acrylic emulsion being purchased from the Dow Chemical Company with trade name Acusol OP305.
Table 3
aRepresent ethoxylized fatty alcohol and the ethoxylated fat being purchased from BASF AG with trade name ARLYPON VPC
The mixture of amine.
bRepresent the styrene-acrylic emulsion being purchased from the Dow Chemical Company with trade name Acusol OP305.
Comparative example 21-26：The preparation of the cleaning system of pH perception strain agent without embodiment 1-9
According to shown in table 4, dissolving acid in water, add viscosity to optimize agent stirring and dissolving, add clear
Clear degree regulator stirs, standby.
Table 4
aRepresent ethoxylized fatty alcohol and the ethoxylated fat being purchased from BASF AG with trade name ARLYPON VPC
The mixture of amine.
bRepresent the styrene-acrylic emulsion being purchased from the Dow Chemical Company with trade name Acusol OP305.
Test example：Coloring Time and the investigation of cleaning efficiency
Toilet from different pollution levels amounts to 17, by the color shift combinations of embodiment 10-20 preparation
Thing cleaning system and the cleaning system perceiving strain agent without pH of comparative example 21-26 preparation, edge respectively
Toilet inwall is gently coated with a circle, and controls the amount used by each coating suitable, makes cleaning system uniform
It is covered in water closet pan undercut and inwall surrounding.Then, constantly observe and be coated with different embodiments and comparative example
Whether there is variable color to occur inside toilet after cleaning system, and record the time that corresponding variable color occurs,
After there is variable color, the comparative example of corresponding embodiment and same recipe (in addition to pH perceives strain agent) starts
With the closet bowl brush of equivalent specifications size, after scrubbing 2 circles in the direction of the clock along inside toilet, observe horse
The cleaning effect of bucket inner surface.Result is as shown in table 5.
Table 5
Remarks：
0 point～5 points of toilet pollution level
0 point：Pollution-free, toilet water closet pan surface-brightening is as newly
1 point：Pollution is the lightest, and toilet water closet pan surface there is no dirt
2 points：Pollution is relatively light, and there is a small amount of dirt on toilet water closet pan surface
3 points：Pollution is general, and there is a certain amount of dirt on toilet water closet pan surface
4 points：Heavy contamination, there is substantial amounts of dirt on toilet water closet pan surface
5 points：Pollution is the heaviest, and toilet water closet pan surface is almost covered by dirt
0 point～5 points of cleaning effect
0 point：No cleaning effect, compared with before cleaning, dirt does not remove
1 point：Cleaning effect is worst, and compared with before cleaning, dirt does not almost remove
2 points：Cleaning effect is poor, and compared with before cleaning, dirt removes small part
3 points：Cleaning effect is general, and compared with before cleaning, dirt removes part
4 points：Preferably, compared with before cleaning, dirt removes cleaning effect substantially
5 points：Preferably, compared with before cleaning, dirt thoroughly removes cleaning effect
The interpretation of result of embodiment 11, embodiment 14 and embodiment 15 and comparative example 21
Formula identical (except pH perceives strain agent), from identical pollution level toilet as test object,
Scrub, on the time point that variable color occurs, the cleaning effect that all can reach 5 points.
Embodiment 16 and comparative example 22
Formula identical (except pH perceives strain agent), from identical pollution level toilet as test object,
Scrub, on the time point that variable color occurs, the cleaning effect that all can reach 5 points.
Embodiment 17 and comparative example 23
Formula identical (except pH perceives strain agent), from identical pollution level toilet as test object,
Scrub, on the time point that variable color occurs, the cleaning effect that all can reach 5 points.
Embodiment 18 and comparative example 24
Formula identical (except pH perceives strain agent), from identical pollution level toilet as test object,
Scrub, on the time point that variable color occurs, the cleaning effect that all can reach 5 points.
Embodiment 19 and comparative example 25
Formula identical (except pH perceives strain agent), from identical pollution level toilet as test object,
Scrub, on the time point that variable color occurs, the cleaning effect that all can reach 5 points.
Embodiment 20 and comparative example 26
Formula identical (except pH perceives strain agent), from identical pollution level toilet as test object,
Scrub, on the time point that variable color occurs, the cleaning effect that all can reach 5 points.
From result, the color-changing composition cleaning system of the present invention can indicate that cleaning process is suitable
Action time, realize preferable clean effect.
Claims (10)
1. a kind of color-changing composition cleaning system for hard-surface cleaning is it is characterised in that described change
Colour cell compound cleaning system contains by weight percentage：
2. color-changing composition cleaning system as claimed in claim 1 is it is characterised in that described pH
Perception strain agent and sour weight ratio is for 1：(2×105) to 1:100.
3. color-changing composition cleaning system as claimed in claim 1 is it is characterised in that described acid is selected
From：One kind of hydrochloric acid, phosphoric acid, citric acid, oxalic acid, formic acid, sulfamic acid and pyrovinic acid or many
Kind.
4. color-changing composition cleaning system as claimed in claim 1 is it is characterised in that described pH
Perception strain agent is selected from：One of thymol blue, methyl yellow and methyl orange or two kinds.
5. color-changing composition cleaning system as claimed in claim 1 is it is characterised in that described solvent
It is selected from：One or more of propylene glycol, glycerol and butyl.
6. color-changing composition cleaning system as claimed in claim 1 is it is characterised in that described viscosity
Optimize agent to be selected from：Ethoxylized fatty alcohol and one or more of ethoxylated fatty amine.
7. color-changing composition cleaning system as claimed in claim 1 is it is characterised in that described clarification
Degree regulator is selected from：Styrene-acrylic emulsion.
8. the color-changing composition cleaning system as described in any one of claim 1-7 it is characterised in that
The Coloring Time of described color-changing composition cleaning system is 2-12 minute.
9. the color-changing composition cleaning system as described in any one of claim 1-7 it is characterised in that
Described crust is toilet crust, preferably toilet.
10. a kind of method of cleaning of hard surfaces, methods described is included such as any one of claim 1-7 institute
The color-changing composition cleaning system stated is applied to the crust of water, treats that color-changing composition cleaning system becomes
Scrubbed after color.
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| CN201510540796.4A CN106479759A (en) | 2015-08-28 | 2015-08-28 | A kind of color changing cleansing composition |
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| CN201510540796.4A CN106479759A (en) | 2015-08-28 | 2015-08-28 | A kind of color changing cleansing composition |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109576088A (en) * | 2018-12-21 | 2019-04-05 | 上海应用技术大学 | A kind of preparation method for the scale cleaning agent that changes colour |
| CN110804501A (en) * | 2019-11-15 | 2020-02-18 | 南京魄力倍清洁科技有限公司 | Efficient environment-friendly color tracing acidic cleaning agent |
| CN111699238A (en) * | 2018-02-05 | 2020-09-22 | 日本曹达株式会社 | Urinary calculus removing and preventing agent |
| CN111996082A (en) * | 2020-08-05 | 2020-11-27 | 名臣健康用品股份有限公司 | Color-changing toilet cleaner composition and preparation method thereof |
| CN112143568A (en) * | 2020-10-27 | 2020-12-29 | 北京同禧科技有限公司 | Cleaning agent capable of changing color when meeting dirt and preparation method thereof |
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| US20070142263A1 (en) * | 2005-12-15 | 2007-06-21 | Stahl Katherine D | Color changing cleansing composition |
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| EP2510082A4 (en) * | 2009-12-07 | 2014-07-09 | Dial Corp | Color-changing pre-treatment stain removers and methods for fabricating the same |
| CN104508108A (en) * | 2012-06-08 | 2015-04-08 | 约翰逊父子公司 | Self-adhesive detergent compositions with color-changing systems |
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| CN1042201A (en) * | 1988-10-18 | 1990-05-16 | 普罗格特-甘布尔公司 | The acidic liquid fabric softener of yellow color that changes to blue upon dilution |
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| CN101568631A (en) * | 2006-12-20 | 2009-10-28 | 荷兰联合利华有限公司 | Laundry detergent composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111699238A (en) * | 2018-02-05 | 2020-09-22 | 日本曹达株式会社 | Urinary calculus removing and preventing agent |
| CN109576088A (en) * | 2018-12-21 | 2019-04-05 | 上海应用技术大学 | A kind of preparation method for the scale cleaning agent that changes colour |
| CN110804501A (en) * | 2019-11-15 | 2020-02-18 | 南京魄力倍清洁科技有限公司 | Efficient environment-friendly color tracing acidic cleaning agent |
| CN111996082A (en) * | 2020-08-05 | 2020-11-27 | 名臣健康用品股份有限公司 | Color-changing toilet cleaner composition and preparation method thereof |
| CN112143568A (en) * | 2020-10-27 | 2020-12-29 | 北京同禧科技有限公司 | Cleaning agent capable of changing color when meeting dirt and preparation method thereof |
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Application publication date: 20170308 |