CN108677199A - Low bubble antibacterial metal cleaning agent of one kind and preparation method thereof - Google Patents
Low bubble antibacterial metal cleaning agent of one kind and preparation method thereof Download PDFInfo
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- CN108677199A CN108677199A CN201810313920.7A CN201810313920A CN108677199A CN 108677199 A CN108677199 A CN 108677199A CN 201810313920 A CN201810313920 A CN 201810313920A CN 108677199 A CN108677199 A CN 108677199A
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- cleaning agent
- antibacterial metal
- low bubble
- metal cleaning
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/14—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
Abstract
The present invention provides a kind of low bubble antibacterial metal cleaning agents and preparation method thereof, including following parts by weight of component to be prepared：25 37 parts of alkyl polyglycoside, 26 35 parts of sodium secondary alkyl sulfonate, 1.3 4.7 parts of antiseptic, 14 parts of poly- tricarboxylic acid ester, 26 parts of antifoaming agent, 17 parts of builder, 0.8 3.7 parts of stabilizer, 50 68 parts of deionized water.The cleaning agent that the present invention is prepared has many advantages, such as that dirt-removing power is strong, and bacteriostasis property is good and defoams rapid.
Description
Technical field
The present invention relates to metal cleaner field, more particularly to a kind of low bubble antibacterial metal cleaning agent and preparation method thereof.
Background technology
After metal works processing, surface can carry various dirts, such as can influence converted products quality without processing, and
Performance service life of various mechanical equipments etc..Therefore, metal cleaning process has become indispensable in modern industrial production
Few important link.When being cleaned to mechanical devices, the dirt-removing power for considering cleaning agent is first had to, it is desirable that cleaning agent can have
The spot on the removal devices surface of effect, greasy dirt etc., and be easy to rinse, to reduce cleaning step, save water resource.Additionally
It is considered as the safety and environmental protection performance of cleaning agent, reduces the pollution to environment, and the harm to operating personnel as far as possible.China
Cleaning agent rapidly developed in recent years, type, the quality of cleaning agent all increase, but cleaning efficiency, disappear
Bubble performance and anti-microbial property tend not to meet the market demand simultaneously, develop that dirt-removing power is strong, and bacteriostasis property is good and disappears
Steep the hot spot that rapid cleaning agent is research.
Invention content
Technical problems to be solved：
The more difficult flushing of cleaning agent in the market, and anti-microbial property is poor, and the object of the present invention is to provide a kind of low bubble antibacterial metals
Cleaning agent and preparation method thereof, the cleaning agent have many advantages, such as that dirt-removing power is strong, and bacteriostasis property is good and defoams rapid.
Technical solution：
The present invention provides a kind of low bubble antibacterial metal cleaning agents, including following parts by weight of component to be prepared：
25-37 parts of alkyl polyglycoside,
26-35 parts of sodium secondary alkyl sulfonate,
1.3-4.7 parts of antiseptic,
1-4 parts of poly- tricarboxylic acid ester,
2-6 parts of antifoaming agent,
1-7 parts of builder,
0.8-3.7 parts of stabilizer,
50-68 parts of deionized water.
Preferably, the low bubble antibacterial metal cleaning agent of described one kind, the antiseptic prepared by following preparation methods and
At：
By Verbena officinalis in thermostatic drying chamber 60 DEG C of dry 5h, then mechanical crushing to 400 mesh, weigh the Verbena officinalis after 5g is crushed
40mL 65wt% methanol solutions are added in powder, stir 5min, and then ultrasonic extraction is to get to antiseptic.
It is further preferred that the preparation method of the antiseptic, temperature when ultrasonic extraction is 25 DEG C, and extraction time is
20min, ultrasonic power 400W.
Preferably, the low bubble antibacterial metal cleaning agent of described one kind, the antifoaming agent are mineral oil, methyl acetate, greatly
Fabaceous Lecithin and water are by weight 22:1:1.2:18 mix.
Preferably, the low bubble antibacterial metal cleaning agent of one kind, the builder are sodium gluconate.
Preferably, the low bubble antibacterial metal cleaning agent of one kind, the stabilizer are n-methyl-2-pyrrolidone.
The present invention also provides a kind of preparation methods of low bubble antibacterial metal cleaning agent, including following preparation process：
（1）Deionized water is added in stirred tank for 50-68 parts, 60 DEG C of water temperature is warming up to, is added with stirring alkyl polyglycoside 25-
37 parts, 26-35 parts of sodium secondary alkyl sulfonate continue to stir 10min to being completely dissolved；
（2）Sequentially add 1-4 parts of poly- tricarboxylic acid ester, 1.3-4.7 parts of antistatic agent, 2-6 parts of antifoaming agent, builder 1-7
Part, 0.8-3.7 parts of stabilizer are stirred 60min, are cooled to room temperature to obtain the final product.
Advantageous effect：
The present invention is compounded with two kinds of small surfactants of biological degradability height, effect on environment, and is added to and body
It is the good auxiliary agent of compatibility, the surface that the antistatic metal cleaner of low bubble being prepared is suitable for a variety of component of machine is clear
It washes, has dirt-removing power strong, the good advantage of bacteriostasis property, and pollute less, it is environmental-friendly.Defoaming is rapid, is easy to rinse, and saves
The energy has good economic benefit and social benefit.
Specific implementation mode
The following examples can make those skilled in the art that the present invention be more fully understood, but not limit this in any way
Invention.
The preparation method of antiseptic is in embodiment 1-5 and comparative example 1-2：Verbena officinalis is done for 60 DEG C in thermostatic drying chamber
Dry 5h, then mechanical crushing to 400 mesh, weighs the European Verbena Herb after 5g is crushed, and 40mL 65wt% methanol solutions, stirring is added
5min, then ultrasonic extraction is to get to antiseptic, and temperature when ultrasonic extraction is 25 DEG C, extraction time 20min, ultrasonic work(
Rate is 400W.
Embodiment 1
（1）68 parts of deionized water is added in stirred tanks, 60 DEG C of water temperature is warming up to, is added with stirring 25 parts of alkyl polyglycoside, secondary
35 parts of sodium alkyl sulfonate continues to stir 10min to being completely dissolved；
（2）Sequentially add 1 part of poly- tricarboxylic acid ester, 4.7 parts of antistatic agent, 2 parts of antifoaming agent, 7 parts of sodium gluconate, N- first
0.8 part of base -2-Pyrrolidone is stirred 60min, is cooled to room temperature to obtain the final product.
Antifoaming agent is mineral oil, methyl acetate, soybean lecithin and water by weight 22:1:1.2:18 mix.
Embodiment 2
（1）50 parts of deionized water is added in stirred tanks, 60 DEG C of water temperature is warming up to, is added with stirring 37 parts of alkyl polyglycoside, secondary
26 parts of sodium alkyl sulfonate continues to stir 10min to being completely dissolved；
（2）Sequentially add 4 parts of poly- tricarboxylic acid ester, 1.3 parts of antistatic agent, 6 parts of antifoaming agent, 1 part of sodium gluconate, N- first
3.7 parts of base -2-Pyrrolidone is stirred 60min, is cooled to room temperature to obtain the final product.
Antifoaming agent is mineral oil, methyl acetate, soybean lecithin and water by weight 22:1:1.2:18 mix.
Embodiment 3
（1）62 parts of deionized water is added in stirred tanks, 60 DEG C of water temperature is warming up to, is added with stirring 29 parts of alkyl polyglycoside, secondary
33 parts of sodium alkyl sulfonate continues to stir 10min to being completely dissolved；
（2）Sequentially add 1.5 parts of poly- tricarboxylic acid ester, 3.7 parts of antistatic agent, 3 parts of antifoaming agent, 6 parts of sodium gluconate, N-
1.8 parts of N-methyl-2-2-pyrrolidone N is stirred 60min, is cooled to room temperature to obtain the final product.
Antifoaming agent is mineral oil, methyl acetate, soybean lecithin and water by weight 22:1:1.2:18 mix.
Embodiment 4
（1）55 parts of deionized water is added in stirred tanks, 60 DEG C of water temperature is warming up to, is added with stirring 34 parts of alkyl polyglycoside, secondary
27 parts of sodium alkyl sulfonate continues to stir 10min to being completely dissolved；
（2）Sequentially add 3.4 parts of poly- tricarboxylic acid ester, 2.1 parts of antistatic agent, 5 parts of antifoaming agent, 2 parts of sodium gluconate, N-
2.7 parts of N-methyl-2-2-pyrrolidone N is stirred 60min, is cooled to room temperature to obtain the final product.
Antifoaming agent is mineral oil, methyl acetate, soybean lecithin and water by weight 22:1:1.2:18 mix.
Embodiment 5
（1）59 parts of deionized water is added in stirred tanks, 60 DEG C of water temperature is warming up to, is added with stirring 31 parts of alkyl polyglycoside, secondary
29 parts of sodium alkyl sulfonate continues to stir 10min to being completely dissolved；
（2）Sequentially add 2 parts of poly- tricarboxylic acid ester, 2.8 parts of antistatic agent, 4 parts of antifoaming agent, 5 parts of sodium gluconate, N- first
2 parts of base -2-Pyrrolidone is stirred 60min, is cooled to room temperature to obtain the final product.
Antifoaming agent is mineral oil, methyl acetate, soybean lecithin and water by weight 22:1:1.2:18 mix.
Comparative example 1
Difference lies in replace alkyl polyglycoside with sodium secondary alkyl sulfonate with embodiment 1 for this comparative example.Specifically：
（1）Deionized water is added in stirred tank for 68 parts, 60 DEG C of water temperature is warming up to, is added with stirring 60 parts of sodium secondary alkyl sulfonate,
Continue to stir 10min to being completely dissolved；
（2）Sequentially add 1 part of poly- tricarboxylic acid ester, 4.7 parts of antistatic agent, 2 parts of antifoaming agent, 7 parts of sodium gluconate, N- first
0.8 part of base -2-Pyrrolidone is stirred 60min, is cooled to room temperature to obtain the final product.
Antifoaming agent is mineral oil, methyl acetate, soybean lecithin and water by weight 22:1:1.2:18 mix.
Comparative example 2
That difference lies in antifoaming agent is different for this comparative example and embodiment 1.Specifically：
（1）68 parts of deionized water is added in stirred tanks, 60 DEG C of water temperature is warming up to, is added with stirring 25 parts of alkyl polyglycoside, secondary
35 parts of sodium alkyl sulfonate continues to stir 10min to being completely dissolved；
（2）Sequentially add 1 part of poly- tricarboxylic acid ester, 4.7 parts of antistatic agent, 2 parts of antifoaming agent, 7 parts of sodium gluconate, N- first
0.8 part of base -2-Pyrrolidone is stirred 60min, is cooled to room temperature to obtain the final product.
Antifoaming agent is mineral oil, soybean lecithin and water by weight 22:1.2:18 mix.
Comparative example 3
Difference lies in the preparation method of antiseptic is different from embodiment 1 for this comparative example.Specifically：
（1）68 parts of deionized water is added in stirred tanks, 60 DEG C of water temperature is warming up to, is added with stirring 25 parts of alkyl polyglycoside, secondary
35 parts of sodium alkyl sulfonate continues to stir 10min to being completely dissolved；
（2）Sequentially add 1 part of poly- tricarboxylic acid ester, 4.7 parts of antistatic agent, 2 parts of antifoaming agent, 7 parts of sodium gluconate, N- first
0.8 part of base -2-Pyrrolidone is stirred 60min, is cooled to room temperature to obtain the final product.
Antifoaming agent is mineral oil, methyl acetate, soybean lecithin and water by weight 22:1:1.2:18 mix.
The preparation method of antiseptic is：By Verbena officinalis in thermostatic drying chamber 60 DEG C of dry 5h, then mechanical crushing to 400
Mesh, weigh 5g crush after European Verbena Herb, be added 60mL 65wt% methanol solutions, stir 5min, then ultrasonic extraction to get
To antiseptic, temperature when ultrasonic extraction is 20 DEG C, extraction time 30min, ultrasonic power 400W.
The cleaning agent being prepared in embodiment 1-5 and comparative example 1-3 is referred to《JB/T4323.1-1999 water-base metals
Cleaning agent》It is tested for the property, antibiotic property test is carried out with reference to QB/T 2850-2007.
1 anti-microbial property test of table
| Excrement colibacillus group | Total plate count/(cfu/g) | |
| Embodiment 1 | It is not detected | 146 |
| Embodiment 2 | It is not detected | 130 |
| Embodiment 3 | It is not detected | 125 |
| Embodiment 4 | It is not detected | 127 |
| Embodiment 5 | It is not detected | 110 |
| Comparative example 1 | It is not detected | 152 |
| Comparative example 2 | It is not detected | 147 |
| Comparative example 3 | 10cfu/g | 189 |
2 all-round property testing of table
| Cleaning efficiency/% | Appearance | PH value | Residual foam height/mm after 10min | |
| Embodiment 1 | 94.3 | Uniform not stratified no precipitation | 8.7 | 1.6 |
| Embodiment 2 | 95.4 | Uniform not stratified no precipitation | 8.9 | 1.4 |
| Embodiment 3 | 97.3 | Uniform not stratified no precipitation | 8.8 | 1.3 |
| Embodiment 4 | 96.5 | Uniform not stratified no precipitation | 9.2 | 0.8 |
| Embodiment 5 | 98.7 | Uniform not stratified no precipitation | 9.1 | 0.5 |
| Comparative example 1 | 90.4 | Uniform not stratified no precipitation | 9.1 | 1.5 |
| Comparative example 2 | 94.6 | Uniform not stratified no precipitation | 8.8 | 2.3 |
| Comparative example 3 | 93.7 | Uniform not stratified no precipitation | 8.6 | 1.6 |
From test result：The low antistatic metal cleaner of bubble provided by the invention, performance are stablized, and cleaning efficiency is high, and has
There are excellent anti-microbial property, cleaning rate to be up to 98.7%, far above 90% as defined in standard.It is reachable to the bacteriostasis rate of coliform
100%, it can quickly defoam, residual foam height is below 5mm after cleaning 10min, has preferable inhibition to foam caused by greasy dirt
Effect.The cleaning efficiency of cleaning agent is less than embodiment 1 in comparative example 1, illustrates 2 kinds of surfactant alkyl polyglycoside and secondary alkyl
Synergistic function is generated between sodium sulfonate, to contribute to the raising of cleaning performance.The antifoaming constituent that comparative example 2 is added
In, lack methyl acetate, the cleaning agent antifoam performance being prepared declines, and methyl acetate can improve antifoaming agent in cleaning agent
Dispersibility in system, contributes to suds, can also reduce cost.Antiseptic extraction preparation method is different in comparative example 3, can shadow
The content of effective antimicrobial component is rung, therefore is unable to reach best antibacterial effect.
Claims (7)
1. a kind of low bubble antibacterial metal cleaning agent, which is characterized in that be prepared including following parts by weight of component：
25-37 parts of alkyl polyglycoside,
26-35 parts of sodium secondary alkyl sulfonate,
1.3-4.7 parts of antiseptic,
1-4 parts of poly- tricarboxylic acid ester,
2-6 parts of antifoaming agent,
1-7 parts of builder,
0.8-3.7 parts of stabilizer,
50-68 parts of deionized water.
2. the low bubble antibacterial metal cleaning agent of one kind according to claim 1, which is characterized in that the antiseptic is by following
Preparation method is prepared：
By Verbena officinalis in thermostatic drying chamber 60 DEG C of dry 5h, then mechanical crushing to 400 mesh, weigh the Verbena officinalis after 5g is crushed
40mL 65wt% methanol solutions are added in powder, stir 5min, and then ultrasonic extraction is to get to antiseptic.
3. the preparation method of antiseptic according to claim 2, which is characterized in that temperature when ultrasonic extraction is 25 DEG C,
Extraction time is 20min, ultrasonic power 400W.
4. the low bubble antibacterial metal cleaning agent of one kind according to claim 1, which is characterized in that the antifoaming agent is mineral
Oil, methyl acetate, soybean lecithin and water are by weight 22:1:1.2:18 mix.
5. the low bubble antibacterial metal cleaning agent of one kind according to claim 1, which is characterized in that the builder is grape
Sodium saccharate.
6. the low bubble antibacterial metal cleaning agent of one kind according to claim 1, which is characterized in that the stabilizer is N- first
Base -2-Pyrrolidone.
7. a kind of preparation method of low bubble antibacterial metal cleaning agent, which is characterized in that including following preparation process：
（1）Deionized water is added in stirred tank for 50-68 parts, 60 DEG C of water temperature is warming up to, is added with stirring alkyl polyglycoside 25-
37 parts, 26-35 parts of sodium secondary alkyl sulfonate continue to stir 10min to being completely dissolved；
（2）Sequentially add 1-4 parts of poly- tricarboxylic acid ester, 1.3-4.7 parts of antistatic agent, 2-6 parts of antifoaming agent, builder 1-7
Part, 0.8-3.7 parts of stabilizer are stirred 60min, are cooled to room temperature to obtain the final product.
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| CN201810313920.7A CN108677199A (en) | 2018-04-10 | 2018-04-10 | Low bubble antibacterial metal cleaning agent of one kind and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810313920.7A CN108677199A (en) | 2018-04-10 | 2018-04-10 | Low bubble antibacterial metal cleaning agent of one kind and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109825838A (en) * | 2019-04-10 | 2019-05-31 | 上海福岛新材料科技有限公司 | A kind of high cleanliness metal cleaner and the method prolonged its service life |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103614734A (en) * | 2013-10-25 | 2014-03-05 | 青岛华仁技术孵化器有限公司 | Environment-friendly type metal cleaning agent with anti-corrosion function |
| CN103820800A (en) * | 2014-02-20 | 2014-05-28 | 苏州龙腾万里化工科技有限公司 | Low-temperature degreasing cleaning agent |
| CN105239084A (en) * | 2015-11-20 | 2016-01-13 | 广东梅雁吉祥实业投资股份有限公司 | Metal product rustproof cleaning agent |
| CN105239081A (en) * | 2015-11-18 | 2016-01-13 | 南京科润工业介质股份有限公司 | Phosphorus-free water base degreasing agent for phosphorus-free coating pretreatment process |
| CN105297038A (en) * | 2015-11-18 | 2016-02-03 | 南京科润工业介质股份有限公司 | Non-phosphorous water-based degreasing agent used in non-phosphorous coating pretreatment |
| CN106835231A (en) * | 2016-12-22 | 2017-06-13 | 当涂县宏宇金属炉料有限责任公司 | A kind of aluminium alloy surface treatment method |
-
2018
- 2018-04-10 CN CN201810313920.7A patent/CN108677199A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103614734A (en) * | 2013-10-25 | 2014-03-05 | 青岛华仁技术孵化器有限公司 | Environment-friendly type metal cleaning agent with anti-corrosion function |
| CN103820800A (en) * | 2014-02-20 | 2014-05-28 | 苏州龙腾万里化工科技有限公司 | Low-temperature degreasing cleaning agent |
| CN105239081A (en) * | 2015-11-18 | 2016-01-13 | 南京科润工业介质股份有限公司 | Phosphorus-free water base degreasing agent for phosphorus-free coating pretreatment process |
| CN105297038A (en) * | 2015-11-18 | 2016-02-03 | 南京科润工业介质股份有限公司 | Non-phosphorous water-based degreasing agent used in non-phosphorous coating pretreatment |
| CN105239084A (en) * | 2015-11-20 | 2016-01-13 | 广东梅雁吉祥实业投资股份有限公司 | Metal product rustproof cleaning agent |
| CN106835231A (en) * | 2016-12-22 | 2017-06-13 | 当涂县宏宇金属炉料有限责任公司 | A kind of aluminium alloy surface treatment method |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109825838A (en) * | 2019-04-10 | 2019-05-31 | 上海福岛新材料科技有限公司 | A kind of high cleanliness metal cleaner and the method prolonged its service life |
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Application publication date: 20181019 |