CN103614734A - Environment-friendly type metal cleaning agent with anti-corrosion function - Google Patents
Environment-friendly type metal cleaning agent with anti-corrosion function Download PDFInfo
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- CN103614734A CN103614734A CN201310507809.9A CN201310507809A CN103614734A CN 103614734 A CN103614734 A CN 103614734A CN 201310507809 A CN201310507809 A CN 201310507809A CN 103614734 A CN103614734 A CN 103614734A
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- analogue
- alcohol
- imidazoles
- oxide
- metal cleaner
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 27
- 239000002184 metal Substances 0.000 title claims abstract description 27
- 238000005260 corrosion Methods 0.000 title abstract description 8
- 239000012459 cleaning agent Substances 0.000 title abstract description 7
- -1 benzimidazole-2-yl Chemical group 0.000 claims abstract description 55
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- IICOXEGVCNSPNG-UHFFFAOYSA-N 1-(1-hexadecylimidazol-2-yl)ethanol Chemical class OC(C)C1=NC=CN1CCCCCCCCCCCCCCCC IICOXEGVCNSPNG-UHFFFAOYSA-N 0.000 claims abstract description 17
- 150000001335 aliphatic alkanes Chemical class 0.000 claims abstract description 15
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 15
- 239000008367 deionised water Substances 0.000 claims abstract description 9
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 9
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 36
- 239000000047 product Substances 0.000 claims description 25
- 238000006243 chemical reaction Methods 0.000 claims description 20
- 238000005660 chlorination reaction Methods 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 18
- 238000002360 preparation method Methods 0.000 claims description 16
- ORIZJEOWAFVTGA-UHFFFAOYSA-N 1-hexadecylimidazole Chemical class CCCCCCCCCCCCCCCCN1C=CN=C1 ORIZJEOWAFVTGA-UHFFFAOYSA-N 0.000 claims description 15
- 238000004140 cleaning Methods 0.000 claims description 13
- SZIFAVKTNFCBPC-UHFFFAOYSA-N 2-chloroethanol Chemical compound OCCCl SZIFAVKTNFCBPC-UHFFFAOYSA-N 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 12
- 241000282326 Felis catus Species 0.000 claims description 11
- 239000013530 defoamer Substances 0.000 claims description 11
- 235000019353 potassium silicate Nutrition 0.000 claims description 10
- 239000001488 sodium phosphate Substances 0.000 claims description 10
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 10
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 10
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 10
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 9
- 150000001298 alcohols Chemical class 0.000 claims description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 238000013019 agitation Methods 0.000 claims description 8
- 150000002460 imidazoles Chemical class 0.000 claims description 8
- 239000000376 reactant Substances 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 8
- 229910001220 stainless steel Inorganic materials 0.000 claims description 8
- 239000010935 stainless steel Substances 0.000 claims description 8
- 238000001291 vacuum drying Methods 0.000 claims description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 7
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 claims description 7
- 239000010703 silicon Substances 0.000 claims description 7
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- 239000004094 surface-active agent Substances 0.000 claims description 7
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims description 7
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 229920000847 nonoxynol Polymers 0.000 claims description 6
- 229920000233 poly(alkylene oxides) Polymers 0.000 claims description 6
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 claims description 4
- HNTGIJLWHDPAFN-UHFFFAOYSA-N 1-bromohexadecane Chemical compound CCCCCCCCCCCCCCCCBr HNTGIJLWHDPAFN-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 239000012043 crude product Substances 0.000 claims description 4
- 239000012153 distilled water Substances 0.000 claims description 4
- 239000000706 filtrate Substances 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 238000010907 mechanical stirring Methods 0.000 claims description 4
- 239000004570 mortar (masonry) Substances 0.000 claims description 4
- 238000006396 nitration reaction Methods 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 238000001953 recrystallisation Methods 0.000 claims description 4
- 238000010992 reflux Methods 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 238000000967 suction filtration Methods 0.000 claims description 4
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 3
- JLBXCKSMESLGTJ-UHFFFAOYSA-N 1-ethoxypropan-1-ol Chemical compound CCOC(O)CC JLBXCKSMESLGTJ-UHFFFAOYSA-N 0.000 claims description 3
- IEORSVTYLWZQJQ-UHFFFAOYSA-N 2-(2-nonylphenoxy)ethanol Chemical compound CCCCCCCCCC1=CC=CC=C1OCCO IEORSVTYLWZQJQ-UHFFFAOYSA-N 0.000 claims description 3
- HFGIZDGKSNWKSD-UHFFFAOYSA-N CCC(O)OCC.CCC(O)OCC.O Chemical compound CCC(O)OCC.CCC(O)OCC.O HFGIZDGKSNWKSD-UHFFFAOYSA-N 0.000 claims description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 3
- 239000004258 Ethoxyquin Substances 0.000 claims description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 3
- 229930006000 Sucrose Natural products 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 3
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims description 3
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 claims description 3
- 150000004703 alkoxides Chemical class 0.000 claims description 3
- 125000005599 alkyl carboxylate group Chemical group 0.000 claims description 3
- 150000005215 alkyl ethers Chemical class 0.000 claims description 3
- 150000008052 alkyl sulfonates Chemical class 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 229920001400 block copolymer Polymers 0.000 claims description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 3
- 150000001733 carboxylic acid esters Chemical class 0.000 claims description 3
- 229960001927 cetylpyridinium chloride Drugs 0.000 claims description 3
- YMKDRGPMQRFJGP-UHFFFAOYSA-M cetylpyridinium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+]1=CC=CC=C1 YMKDRGPMQRFJGP-UHFFFAOYSA-M 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 3
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- DECIPOUIJURFOJ-UHFFFAOYSA-N ethoxyquin Chemical compound N1C(C)(C)C=C(C)C2=CC(OCC)=CC=C21 DECIPOUIJURFOJ-UHFFFAOYSA-N 0.000 claims description 3
- 229940093500 ethoxyquin Drugs 0.000 claims description 3
- 235000019285 ethoxyquin Nutrition 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 150000002191 fatty alcohols Chemical class 0.000 claims description 3
- 150000002193 fatty amides Chemical class 0.000 claims description 3
- 229930182478 glucoside Natural products 0.000 claims description 3
- 125000005908 glyceryl ester group Chemical group 0.000 claims description 3
- 150000008040 ionic compounds Chemical class 0.000 claims description 3
- 150000002632 lipids Chemical class 0.000 claims description 3
- 239000002480 mineral oil Substances 0.000 claims description 3
- 235000010446 mineral oil Nutrition 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 3
- 229920000151 polyglycol Polymers 0.000 claims description 3
- 239000010695 polyglycol Substances 0.000 claims description 3
- IKNCGYCHMGNBCP-UHFFFAOYSA-N propan-1-olate Chemical compound CCC[O-] IKNCGYCHMGNBCP-UHFFFAOYSA-N 0.000 claims description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 239000000600 sorbitol Substances 0.000 claims description 3
- 239000005720 sucrose Substances 0.000 claims description 3
- 230000019635 sulfation Effects 0.000 claims description 3
- 238000005670 sulfation reaction Methods 0.000 claims description 3
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 3
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 claims description 3
- 230000007797 corrosion Effects 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 4
- 239000003513 alkali Substances 0.000 abstract description 3
- 230000008901 benefit Effects 0.000 abstract description 2
- 239000003112 inhibitor Substances 0.000 abstract 2
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 239000003093 cationic surfactant Substances 0.000 abstract 1
- 239000006260 foam Substances 0.000 abstract 1
- 239000002736 nonionic surfactant Substances 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 7
- 238000003756 stirring Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- BQJGBCJGVCFQIN-UHFFFAOYSA-N sodium;methylbenzene Chemical compound [Na+].CC1=CC=CC=[C-]1 BQJGBCJGVCFQIN-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 239000002283 diesel fuel Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- YLZOPXRUQYQQID-UHFFFAOYSA-N 3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-1-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]propan-1-one Chemical compound N1N=NC=2CN(CCC=21)CCC(=O)N1CCN(CC1)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F YLZOPXRUQYQQID-UHFFFAOYSA-N 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 206010044565 Tremor Diseases 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 159000000013 aluminium salts Chemical class 0.000 description 1
- 229910000329 aluminium sulfate Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 238000007634 remodeling Methods 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
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- Detergent Compositions (AREA)
Abstract
The invention provides an environment-friendly type metal cleaning agent with anti-corrosion function. The cleaning agent comprises 0.3%-5% of a defoaming agent, 1%-15% of a cationic surfactant, 1%-10% of an anionic surfactant, 3%-15% of a non-ionic surfactant, 20%-40% of a main cleaning agent, 2%-5% of a corrosion inhibitor and the balance of deionized water. The corrosion inhibitor comprises chlorinated 1-hydroxyethyl-3-cetyl imidazole and omega,omega'-bis (benzimidazole-2-yl) alkane. The metal cleaning agent provided by the invention has the advantages of low alkali, low foam and environment-friendliness, very strong oil removal effect at a lower temperature and low corrosion.
Description
Technical field
The present invention relates to clean-out system technical field, relate in particular to a kind of Environment-Protect Metal Cleaning Agents with corrosion proof function.
Background technology
When the maintenance and repair of machining and mechanical means, automobile etc., mostly adopt diesel oil, coal Water Oil Or Gas to carry out cleaning components as scavenging solution.This not only wastes energy, and exists potential unsafe factor, careless slightly, may lead to fire.In recent years, a kind of novel metal cleaner is widely used gradually, it well diesel oil substitute, kerosene and gasoline carry out cleaning components, and low price, is used safety, is well suited for mechanized cleaning operation.It can be for metal washs, and do not have rust staining.
At present, metal cleaner on the market contains the harmful chemical components such as strong acid, highly basic, phosphoric acid salt and aluminium salt mostly, and these chemical compositions not only can be brought certain infringement to metallic surface, and can cause certain harm to environment, due to complex process, cost is higher simultaneously.
Summary of the invention
Object of the present invention is exactly for the problems referred to above, and a kind of low alkali, low bubble, environmental protection are provided, and has at a lower temperature the effect of deoiling very by force, and the low-down efficient metal scavenger of corrodibility.
The invention provides a kind of metal cleaner, it comprises: defoamer 0.3%～5%, cats product 1%～15%, anion surfactant 1%～10%, nonionogenic tenside 3%～15%, cleaning host 20%～40%, inhibiter 2%～5% and surplus deionized water.
Wherein, described cleaning host consists of sodium phosphate and water glass, and the weight ratio between sodium phosphate and water glass is 2～4:1.
Wherein, described cats product can be one or more mixing in Varisoft TA 100, Trimethyllaurylammonium chloride, methyl-sulfuric acid alkyl trimethyl ammonium, chlorination cocoyl trimethyl ammonium and cetylpyridinium chloride.
Wherein, described anion surfactant can be alkyl carboxylate's (carboxylate salt) and poly-alkoxyl group carboxylate salt, alcohol b-oxide carboxylate salt, nonylphenol ethoxylate carboxylate salt, and analogue; Sulfonate, for example alkylsulfonate, alkylbenzene sulfonate, alkylaryl sulphonate, sulfonated fatty acid ester, and analogue; Vitriol, for example sulfated alcohols, sulfated alcohols b-oxide, sulfation alkylphenol, alkyl-sulphate, sulfosuccinate, sulfated alkyl ether, and analogue; And phosphoric acid ester, for example alkyl phosphate, and analogue.The anion surfactant exemplifying comprises sodium alkylarysulfonate, alpha-alefinically sulfonate and aliphatic alcohol sulfate.
Wherein, described nonionogenic tenside can for for example chloro-, benzyl-, methyl-, ethyl-, propyl group-butyl-and the polyglycol ether of other similar alkyl-blocked fatty alcohol; Do not contain the nonionogenic tenside of polyalkylene oxides, for example alkyl poly glucoside; Anhydro sorbitol and sucrose ester, and b-oxide; Amine oxide, for example alkoxide quadrol; Alcohol alkoxide, alcohol ethoxy propoxide for example, alcohol propoxide, alcohol the third oxygen ethoxy propoxide, alcohol ethoxy fourth oxide compound, and analogue; Nonylphenol ethoxylate, polyoxyethylene glycol ether and analogue; Carboxylicesters, glyceryl ester for example, polyoxyethylene ester, the ethoxyquin of lipid acid and binary alcohol esters, and analogue; Carboxylic acid amide, for example diethanolamine condenses, monoalkanolamine condenses, polyoxyethylene fatty amide, and analogue; And polyalkylene oxide block copolymer, comprising ethylene oxide/propylene oxide segmented copolymer, for example, with trade(brand)name
those that are purchased (BASF-Wyandotte), and analogue; With other similar non-ionic compound.Also can use organic silicon surfactant, for example
Described inhibiter is by chlorination 1-hydroxyethyl-3-hexadecyl imidazoles and ω, and ω '-bis-(benzimidazolyl-2 radicals-yl) alkane forms.
Described ω, ω '-bis-(benzimidazolyl-2 radicals-yl) alkane as shown in Equation 1, wherein, n=8.
Described chlorination 1-hydroxyethyl-3-hexadecyl imidazoles and ω, the mass ratio of ω '-bis-(benzimidazolyl-2 radicals-yl) alkane is 1:1～1:2.
The preparation method of described chlorination 1-hydroxyethyl-3-hexadecyl imidazoles is specially:
The first step, the preparation of 1-hexadecyl imidazoles mixes the bromohexadecane of 1.79 imidazoles and 3.8mL in the ethyl acetate of 35mL, and magnetic agitation mixes for 10 minutes.Mixture is poured in the polytetrafluoroethyllining lining that capacity is 60mL, polytetrafluoroethyllining lining is encapsulated in stainless steel cauldron, and put into digital baking oven, from room temperature is heated to 120 ℃ of isothermal reaction 16h, naturally cool to room temperature.Then mixture filtration is taken out to filtrate, with distilled water wash, for several times to remove the imidazoles of not participating in reaction, with Rotary Evaporators, solvent ethyl acetate is steamed, products therefrom 1-hexadecyl imidazoles is dried 12 hours to constant weight in 70 ℃ of vacuum drying ovens.Obtain weak yellow liquid, weigh product;
Second step, the ethylene chlorhydrin of the 1-hexadecyl imidazoles of 2.9g and 1ml is mixed in the ethyl acetate of 35ml, and magnetic agitation mixes for 10 minutes, wherein, reactant ethylene chlorhydrin is excessive, 1-hexadecyl imidazoles is fully reacted, mixture is poured in the polytetrafluoroethyllining lining that capacity is 60mL, polytetrafluoroethyllining lining is encapsulated in stainless steel cauldron, and put into digital baking oven, from room temperature, be heated to 120 ℃, isothermal reaction 6h, naturally cools to room temperature.With Rotary Evaporators, solvent and excessive reactant ethylene chlorhydrin are steamed, within dry 12 hours in 70 ℃ of vacuum drying ovens, to constant weight, the chlorination 1-hydroxyethyl-3-hexadecyl imidazoles obtaining is white solid to products therefrom.
Described ω, the preparation method of ω '-bis-(benzimidazolyl-2 radicals-yl) alkane is specially:
Take respectively 0.11mol O-Phenylene Diamine and 0.05mol fat diacid, in mortar, fully grind it is mixed, be transferred in three-necked flask.Add nitration mixture, logical nitrogen, heating reflux reaction under mechanical stirring.TLC tracking monitor finishes to reaction, and about 10h, pours in 250mL beaker, standing cooling, with strong aqua, regulates pH=7.Standing over night at 4 ℃, suction filtration is dry, and gained crude product methanol/water recrystallization, obtains sterling.
Wherein, described defoamer is selected from one or more in octanol, mineral oil, tributyl phosphate.
Beneficial effect of the present invention:
Metal cleaner provided by the invention has the advantage of low alkali, low bubble, environmental protection, have at a lower temperature the effect of deoiling very by force, and corrodibility is very low.
Embodiment
The invention provides a kind of metal cleaner, it comprises: defoamer 0.3%～5%, cats product 1%～15%, anion surfactant 1%～10%, nonionogenic tenside 3%～15%, cleaning host 20%～40%, inhibiter 2%～5% and surplus deionized water.
Described cleaning host consists of sodium phosphate and water glass, and the weight ratio between sodium phosphate and water glass is 2～4:1.
Described cats product can be one or more mixing in Varisoft TA 100, Trimethyllaurylammonium chloride, methyl-sulfuric acid alkyl trimethyl ammonium, chlorination cocoyl trimethyl ammonium and cetylpyridinium chloride.
Described anion surfactant can be alkyl carboxylate's (carboxylate salt) and poly-alkoxyl group carboxylate salt, alcohol b-oxide carboxylate salt, nonylphenol ethoxylate carboxylate salt, and analogue; Sulfonate, for example alkylsulfonate, alkylbenzene sulfonate, alkylaryl sulphonate, sulfonated fatty acid ester, and analogue; Vitriol, for example sulfated alcohols, sulfated alcohols b-oxide, sulfation alkylphenol, alkyl-sulphate, sulfosuccinate, sulfated alkyl ether, and analogue; And phosphoric acid ester, for example alkyl phosphate, and analogue.The anion surfactant exemplifying comprises sodium alkylarysulfonate, alpha-alefinically sulfonate and aliphatic alcohol sulfate.
Described nonionogenic tenside can for for example chloro-, benzyl-, methyl-, ethyl-, propyl group-butyl-and the polyglycol ether of other similar alkyl-blocked fatty alcohol; Do not contain the nonionogenic tenside of polyalkylene oxides, for example alkyl poly glucoside; Anhydro sorbitol and sucrose ester, and b-oxide; Amine oxide, for example alkoxide quadrol; Alcohol alkoxide, alcohol ethoxy propoxide for example, alcohol propoxide, alcohol the third oxygen ethoxy propoxide, alcohol ethoxy fourth oxide compound, and analogue; Nonylphenol ethoxylate, polyoxyethylene glycol ether and analogue; Carboxylicesters, glyceryl ester for example, polyoxyethylene ester, the ethoxyquin of lipid acid and binary alcohol esters, and analogue; Carboxylic acid amide, for example diethanolamine condenses, monoalkanolamine condenses, polyoxyethylene fatty amide, and analogue; And polyalkylene oxide block copolymer, comprising ethylene oxide/propylene oxide segmented copolymer, for example, with trade(brand)name
those that are purchased (BASF-Wyandotte), and analogue; With other similar non-ionic compound.Also can use organic silicon surfactant, for example
Described inhibiter is by chlorination 1-hydroxyethyl-3-hexadecyl imidazoles and ω, and ω '-bis-(benzimidazolyl-2 radicals-yl) alkane forms.
Described ω, ω '-bis-(benzimidazolyl-2 radicals-yl) alkane as shown in Equation 1, wherein, n=8.
Described chlorination 1-hydroxyethyl-3-hexadecyl imidazoles and ω, the mass ratio of ω '-bis-(benzimidazolyl-2 radicals-yl) alkane is 1:1～1:2.
The preparation method of described chlorination 1-hydroxyethyl-3-hexadecyl imidazoles is specially:
The first step, the preparation of 1-hexadecyl imidazoles mixes the bromohexadecane of 1.79 imidazoles and 3.8mL in the ethyl acetate of 35mL, and magnetic agitation mixes for 10 minutes.Mixture is poured in the polytetrafluoroethyllining lining that capacity is 60mL, polytetrafluoroethyllining lining is encapsulated in stainless steel cauldron, and put into digital baking oven, from room temperature is heated to 120 ℃ of isothermal reaction 16h, naturally cool to room temperature.Then mixture filtration is taken out to filtrate, with distilled water wash, for several times to remove the imidazoles of not participating in reaction, with Rotary Evaporators, solvent ethyl acetate is steamed, products therefrom 1-hexadecyl imidazoles is dried 12 hours to constant weight in 70 ℃ of vacuum drying ovens.Obtain weak yellow liquid, weigh product;
Second step, the ethylene chlorhydrin of the 1-hexadecyl imidazoles of 2.9g and 1ml is mixed in the ethyl acetate of 35ml, and magnetic agitation mixes for 10 minutes, wherein, reactant ethylene chlorhydrin is excessive, 1-hexadecyl imidazoles is fully reacted, mixture is poured in the polytetrafluoroethyllining lining that capacity is 60mL, polytetrafluoroethyllining lining is encapsulated in stainless steel cauldron, and put into digital baking oven, from room temperature, be heated to 120 ℃, isothermal reaction 6h, naturally cools to room temperature.With Rotary Evaporators, solvent and excessive reactant ethylene chlorhydrin are steamed, within dry 12 hours in 70 ℃ of vacuum drying ovens, to constant weight, the chlorination 1-hydroxyethyl-3-hexadecyl imidazoles obtaining is white solid to products therefrom.
Described ω, the preparation method of ω '-bis-(benzimidazolyl-2 radicals-yl) alkane is specially:
Take respectively 0.11mol O-Phenylene Diamine and 0.05mol fat diacid, in mortar, fully grind it is mixed, be transferred in three-necked flask.Add nitration mixture, logical nitrogen, heating reflux reaction under mechanical stirring.TLC tracking monitor finishes to reaction, and about 10h, pours in 250mL beaker, standing cooling, with strong aqua, regulates pH=7.Standing over night at 4 ℃, suction filtration is dry, and gained crude product methanol/water recrystallization, obtains sterling.
Described defoamer is selected from one or more in octanol, mineral oil, tributyl phosphate.
The present invention also provides the preparation method of above-mentioned metal cleaner, in deionized water, add in proportion defoamer, cats product, anion surfactant, nonionogenic tenside, cleaning host and inhibiter, stir about 30 minutes, obtain.
Below adopt embodiment to describe embodiments of the present invention in detail, to the present invention, how utilisation technology means solve technical problem whereby, and the implementation procedure of reaching technique effect can fully understand and implement according to this.
The preparation of embodiment 1 chlorination 1-hydroxyethyl-3-hexadecyl imidazoles
The bromohexadecane of 1.79 imidazoles and 3.8mL (amount of substance is than being 2:1) is mixed in the ethyl acetate of 35mL, and magnetic agitation mixes for 10 minutes.Mixture is poured in the polytetrafluoroethyllining lining that capacity is 60mL, polytetrafluoroethyllining lining is encapsulated in stainless steel cauldron, and put into digital baking oven, from room temperature is heated to 120 ℃ of isothermal reaction 16h, naturally cool to room temperature.Then mixture filtration is taken out to filtrate, with distilled water wash, for several times to remove the imidazoles of not participating in reaction, with Rotary Evaporators, solvent ethyl acetate is steamed, products therefrom 1-hexadecyl imidazoles is dried 12 hours to constant weight in 70 ℃ of vacuum drying ovens.Obtain weak yellow liquid, weigh product, the ethylene chlorhydrin of the 1-hexadecyl imidazoles of 2.9g and 1ml (amount of substance is than being 1:1.2) is mixed in the ethyl acetate of 35ml, magnetic agitation mixes for 10 minutes, wherein, reactant ethylene chlorhydrin is excessive, 1-hexadecyl imidazoles is fully reacted, mixture is poured in the polytetrafluoroethyllining lining that capacity is 60mL, polytetrafluoroethyllining lining is encapsulated in stainless steel cauldron, and puts into digital baking oven, from room temperature, be heated to 120 ℃, isothermal reaction 6h, naturally cools to room temperature.With Rotary Evaporators, solvent and excessive reactant ethylene chlorhydrin are steamed, within dry 12 hours in 70 ℃ of vacuum drying ovens, to constant weight, the chlorination 1-hydroxyethyl-3-hexadecyl imidazoles obtaining is white solid to products therefrom.
Embodiment 2 ω, the preparation of ω '-bis-(benzimidazolyl-2 radicals-yl) alkane
Take respectively 0.11mol O-Phenylene Diamine and 0.05mol fat diacid, in mortar, fully grind it is mixed, be transferred in three-necked flask.Add nitration mixture, logical nitrogen, heating reflux reaction under mechanical stirring.TLC tracking monitor finishes to reaction, and about 10h, pours in 250mL beaker, standing cooling, with strong aqua, regulates pH=7.Standing over night at 4 ℃, suction filtration is dry, and gained crude product methanol/water recrystallization, obtains sterling.
Embodiment 3: metal cleaner 1
Using defoamer tributyl phosphate 2g, cats product Varisoft TA 100 8g, anion surfactant tolyl sodium sulfonate 6g, by name as nonionogenic tenside commodity
silicon surfactant 12g, sodium phosphate 20g and chlorination 1-hydroxyethyl-3-hexadecyl imidazoles 2g of water glass 10g, embodiment 1 preparation, the ω of embodiment 2 preparations, ω '-bis-(benzimidazolyl-2 radicals-yl) alkane 2g is dissolved in deionized water, stirs about 30 minutes, obtains.
Comparative example 1 metal cleaner 2
Using defoamer tributyl phosphate 2g, cats product Varisoft TA 100 8g, anion surfactant tolyl sodium sulfonate 6g, by name as nonionogenic tenside commodity
silicon surfactant 12g, sodium phosphate 20g and chlorination 1-hydroxyethyl-3-hexadecyl imidazoles 4g of water glass 10g, embodiment 1 preparation be dissolved in deionized water, stir about 30 minutes, obtain.
Comparative example 2 metal cleaners 3
Using defoamer tributyl phosphate 2g, cats product Varisoft TA 100 8g, anion surfactant tolyl sodium sulfonate 6g, by name as nonionogenic tenside commodity
silicon surfactant 12g, sodium phosphate 20g and the ω of water glass 10g, embodiment 2 preparations, ω '-bis-(benzimidazolyl-2 radicals-yl) alkane 4g is dissolved in deionized water, stirs about 30 minutes, obtains.
Comparative example 3 metal cleaners 4
Using defoamer tributyl phosphate 2g, cats product Varisoft TA 100 8g, anion surfactant tolyl sodium sulfonate 6g, by name as nonionogenic tenside commodity
silicon surfactant 12g, sodium phosphate 20g and water glass 10g be dissolved in deionized water, stir about 30 minutes, obtain.
The metal cleaner of embodiment 1 and comparative example 1-3 acquisition is carried out to metallic aluminium clean surface greasy dirt and clean, the results are shown in Table 1.
Cleaning rate: the greasy dirt weight/greasy dirt original weight of cleaning rate=wash;
Non-corrosibility: grading standard: 0 grade of surface is rustless, without considerable change.
1 grade of surface is rustless, light discolouration or loss of gloss.
2 grades of light rust in surface or inhomogeneous variable color.
3 grades of surperficial big area corrosions.
Stability: mixed composition was placed after 4 hours, observed its layering situation, stabilizes to not stratified not muddyly, and shakiness is decided to be layering or muddiness.
Table 1
| Group | Non-corrosibility | Cleaning rate | Stability |
| Embodiment 3 | 0 grade | 95.3 | Stable |
| Comparative example 1 | 2 grades | 92.7 | Stable |
| Comparative example 2 | 2 grades | 91.6 | Stable |
| Comparative example 3 | 3 grades | 90.3 | Stable |
All above-mentioned these intellecture properties of primary enforcement, do not set restriction this product innovation of other forms of enforcement and/or novel method.Those skilled in the art will utilize this important information, and foregoing is revised, to realize similar implementation status.But all modifications or transformation belong to the right of reservation based on product innovation of the present invention.
The above, be only preferred embodiment of the present invention, is not the present invention to be done to the restriction of other form, and any those skilled in the art may utilize the technology contents of above-mentioned announcement to be changed or be modified as the equivalent embodiment of equivalent variations.But every technical solution of the present invention content that do not depart from, any simple modification, equivalent variations and the remodeling above embodiment done according to technical spirit of the present invention, still belong to the protection domain of technical solution of the present invention.
Claims (9)
1. a metal cleaner, it is characterized in that, comprise: defoamer 0.3%～5%, cats product 1%～15%, anion surfactant 1%～10%, nonionogenic tenside 3%～15%, cleaning host 20%～40%, inhibiter 2%～5% and surplus deionized water, described inhibiter is by chlorination 1-hydroxyethyl-3-hexadecyl imidazoles and ω, and ω '-bis-(benzimidazolyl-2 radicals-yl) alkane forms.
2. metal cleaner as claimed in claim 1, is characterized in that: described cleaning host consists of sodium phosphate and water glass, and the weight ratio between sodium phosphate and water glass is 2～4:1.
3. metal cleaner as claimed in claim 1 or 2, is characterized in that: described cats product can be one or more mixing in Varisoft TA 100, Trimethyllaurylammonium chloride, methyl-sulfuric acid alkyl trimethyl ammonium, chlorination cocoyl trimethyl ammonium and cetylpyridinium chloride.
4. the metal cleaner as described in claims 1 to 3, it is characterized in that: described anion surfactant can be alkyl carboxylate's (carboxylate salt) and poly-alkoxyl group carboxylate salt, alcohol b-oxide carboxylate salt, nonylphenol ethoxylate carboxylate salt, and analogue; Sulfonate, for example alkylsulfonate, alkylbenzene sulfonate, alkylaryl sulphonate, sulfonated fatty acid ester, and analogue; Vitriol, for example sulfated alcohols, sulfated alcohols b-oxide, sulfation alkylphenol, alkyl-sulphate, sulfosuccinate, sulfated alkyl ether, and analogue; And phosphoric acid ester, for example alkyl phosphate, and analogue.The anion surfactant exemplifying comprises sodium alkylarysulfonate, alpha-alefinically sulfonate and aliphatic alcohol sulfate.
5. the metal cleaner as described in claim 1 to 4, is characterized in that: described nonionogenic tenside can for for example chloro-, benzyl-, methyl-, ethyl-, propyl group-butyl-and the polyglycol ether of other similar alkyl-blocked fatty alcohol; Do not contain the nonionogenic tenside of polyalkylene oxides, for example alkyl poly glucoside; Anhydro sorbitol and sucrose ester, and b-oxide; Amine oxide, for example alkoxide quadrol; Alcohol alkoxide, alcohol ethoxy propoxide for example, alcohol propoxide, alcohol the third oxygen ethoxy propoxide, alcohol ethoxy fourth oxide compound, and analogue; Nonylphenol ethoxylate, polyoxyethylene glycol ether and analogue; Carboxylicesters, glyceryl ester for example, polyoxyethylene ester, the ethoxyquin of lipid acid and binary alcohol esters, and analogue; Carboxylic acid amide, for example diethanolamine condenses, monoalkanolamine condenses, polyoxyethylene fatty amide, and analogue; And polyalkylene oxide block copolymer, comprising ethylene oxide/propylene oxide segmented copolymer, for example, with trade(brand)name
those that are purchased (BASF-Wyandotte), and analogue; With other similar non-ionic compound.Also can use organic silicon surfactant, for example
6. the metal cleaner as described in claim 1 to 5, is characterized in that: described chlorination 1-hydroxyethyl-3-hexadecyl imidazoles and ω, the mass ratio of ω '-bis-(benzimidazolyl-2 radicals-yl) alkane is 1:1～1:2.
7. the metal cleaner as described in claim 1 to 6, is characterized in that: the preparation method of described chlorination 1-hydroxyethyl-3-hexadecyl imidazoles is specially,
The first step, the preparation of 1-hexadecyl imidazoles mixes the bromohexadecane of 1.79 imidazoles and 3.8mL in the ethyl acetate of 35mL, and magnetic agitation mixes for 10 minutes.Mixture is poured in the polytetrafluoroethyllining lining that capacity is 60mL, polytetrafluoroethyllining lining is encapsulated in stainless steel cauldron, and put into digital baking oven, from room temperature is heated to 120 ℃ of isothermal reaction 16h, naturally cool to room temperature.Then mixture filtration is taken out to filtrate, with distilled water wash, for several times to remove the imidazoles of not participating in reaction, with Rotary Evaporators, solvent ethyl acetate is steamed, products therefrom 1-hexadecyl imidazoles is dried 12 hours to constant weight in 70 ℃ of vacuum drying ovens.Obtain weak yellow liquid, weigh product;
Second step, the ethylene chlorhydrin of the 1-hexadecyl imidazoles of 2.9g and 1ml is mixed in the ethyl acetate of 35ml, and magnetic agitation mixes for 10 minutes, wherein, reactant ethylene chlorhydrin is excessive, 1-hexadecyl imidazoles is fully reacted, mixture is poured in the polytetrafluoroethyllining lining that capacity is 60mL, polytetrafluoroethyllining lining is encapsulated in stainless steel cauldron, and put into digital baking oven, from room temperature, be heated to 120 ℃, isothermal reaction 6h, naturally cools to room temperature.With Rotary Evaporators, solvent and excessive reactant ethylene chlorhydrin are steamed, within dry 12 hours in 70 ℃ of vacuum drying ovens, to constant weight, the chlorination 1-hydroxyethyl-3-hexadecyl imidazoles obtaining is white solid to products therefrom.
8. the metal cleaner as described in claim 1 to 7, it is characterized in that: described ω, the preparation method of ω '-bis-(benzimidazolyl-2 radicals-yl) alkane is specially and takes respectively 0.11mol O-Phenylene Diamine and 0.05mol fat diacid, in mortar, fully grind it is mixed, be transferred in three-necked flask.Add nitration mixture, logical nitrogen, heating reflux reaction under mechanical stirring.TLC tracking monitor finishes to reaction, and about 10h, pours in 250mL beaker, standing cooling, with strong aqua, regulates pH=7.Standing over night at 4 ℃, suction filtration is dry, and gained crude product methanol/water recrystallization, obtains sterling.
9. the metal cleaner as described in claim 1 to 8, is characterized in that: described defoamer is selected from one or more in octanol, mineral oil, tributyl phosphate.
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| CN105420743A (en) * | 2015-12-22 | 2016-03-23 | 安徽省春谷3D打印智能装备产业技术研究院有限公司 | Material composition and preparation method of metal shell surface cleaning agent |
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| CN103882461A (en) * | 2014-03-17 | 2014-06-25 | 苏州龙腾万里化工科技有限公司 | Detergent for steel meshes |
| CN104311813A (en) * | 2014-10-11 | 2015-01-28 | 淄博德信联邦化学工业有限公司 | Antioxidant polyether polyol and preparation method thereof |
| CN105420743A (en) * | 2015-12-22 | 2016-03-23 | 安徽省春谷3D打印智能装备产业技术研究院有限公司 | Material composition and preparation method of metal shell surface cleaning agent |
| CN111788288A (en) * | 2018-03-28 | 2020-10-16 | 花王株式会社 | Detergent composition |
| CN108677199A (en) * | 2018-04-10 | 2018-10-19 | 苏州捷德瑞精密机械有限公司 | Low bubble antibacterial metal cleaning agent of one kind and preparation method thereof |
| CN109370790A (en) * | 2018-12-05 | 2019-02-22 | 西安庄信新材料科技有限公司 | A kind of titanium building materials strong detergent |
| CN113186542A (en) * | 2021-04-30 | 2021-07-30 | 重庆勃润防锈技术有限公司 | Rinsing-free industrial cleaning agent and preparation and use methods thereof |
| CN114107998A (en) * | 2021-12-06 | 2022-03-01 | 佛山市顺德区正泽精细化工有限公司 | Environment-friendly cleaning degreaser |
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